In order to study the modification effect of recycled sand on cement reinforced waste slurry(CWS),triaxial test,scanning electron microscope test and X-ray diffraction test were carried out.The mechanical test of recy...In order to study the modification effect of recycled sand on cement reinforced waste slurry(CWS),triaxial test,scanning electron microscope test and X-ray diffraction test were carried out.The mechanical test of recycled sand and cement reinforced waste slurry(RCWS)shows that the deviatoric stress–strain curve of RCWS samples changes from hardening type to softening type with the increase of recycled sand content;the peak stress increases with the increase of recycled sand content;recycled sand can enhance the shear strength of CWS by increasing both cohesion and internal friction angle.The microscopic test shows that recycled sand can improve the structural compactness by cementing with hydrated calcium silicate and can reduce the void ratio and orientation index of RCWS samples.Finally,the mathematical model between shear strength parameters and void ratio is established.The research shows that adding an appropriate amount of recycled sand and cement has a good modification effect on waste slurry.This is an effective method to treat two kinds of construction wastes:construction waste slurry and waste concrete.展开更多
Si-based photovoltaic solar power has been rapidly developed as a renewable and green energy source.The widespread use of Sibased solar cells requires large amounts of solar-grade Si(SoG-Si)to manufacture Si wafers.Ch...Si-based photovoltaic solar power has been rapidly developed as a renewable and green energy source.The widespread use of Sibased solar cells requires large amounts of solar-grade Si(SoG-Si)to manufacture Si wafers.Chemical routes,mainly the modified Siemens process,have dominated the preparation of polycrystalline SoG-Si;however,traditional chemical techniques employ a series of complex chemical reactions involving various corrosive and hazardous reagents.In addition,large amounts of complex waste solar cells and Si kerf slurry waste gradually accumulate and are difficult to recycle using these approaches.New methods are required to meet the demand for SoGSi preparation and Si waste recycling.The metallurgical route shows promise but is hindered by the problem of eliminating B and P from metallurgical-grade Si(MG-Si).Various pyrometallurgical treatments have been proposed to enhance the removal of B and P from MG-Si.This article reviews Si refining with slag treatment,chlorination,vacuum evaporation,and solvent refining,and summarizes and discusses the basic principles and recent representative studies of the four methods.Among these,solvent refining is the most promising and environmentally friendly approach for obtaining low-cost SoG-Si and is a popular research topic.Finally,a simple and green approach,i.e.,a combination of solvent refining,slag treatment,or vacuum directional solidification,is proposed for low-cost SoG-Si preparation using MG-Si or Si wastes as raw materials.展开更多
基金the National Natural Science Foundation of China(41772311,52179107)College Student Xinmiao Plan of Zhejiang Province(15002001007)Student Research Fund Funded Project of Shaoxing University.
文摘In order to study the modification effect of recycled sand on cement reinforced waste slurry(CWS),triaxial test,scanning electron microscope test and X-ray diffraction test were carried out.The mechanical test of recycled sand and cement reinforced waste slurry(RCWS)shows that the deviatoric stress–strain curve of RCWS samples changes from hardening type to softening type with the increase of recycled sand content;the peak stress increases with the increase of recycled sand content;recycled sand can enhance the shear strength of CWS by increasing both cohesion and internal friction angle.The microscopic test shows that recycled sand can improve the structural compactness by cementing with hydrated calcium silicate and can reduce the void ratio and orientation index of RCWS samples.Finally,the mathematical model between shear strength parameters and void ratio is established.The research shows that adding an appropriate amount of recycled sand and cement has a good modification effect on waste slurry.This is an effective method to treat two kinds of construction wastes:construction waste slurry and waste concrete.
文摘Si-based photovoltaic solar power has been rapidly developed as a renewable and green energy source.The widespread use of Sibased solar cells requires large amounts of solar-grade Si(SoG-Si)to manufacture Si wafers.Chemical routes,mainly the modified Siemens process,have dominated the preparation of polycrystalline SoG-Si;however,traditional chemical techniques employ a series of complex chemical reactions involving various corrosive and hazardous reagents.In addition,large amounts of complex waste solar cells and Si kerf slurry waste gradually accumulate and are difficult to recycle using these approaches.New methods are required to meet the demand for SoGSi preparation and Si waste recycling.The metallurgical route shows promise but is hindered by the problem of eliminating B and P from metallurgical-grade Si(MG-Si).Various pyrometallurgical treatments have been proposed to enhance the removal of B and P from MG-Si.This article reviews Si refining with slag treatment,chlorination,vacuum evaporation,and solvent refining,and summarizes and discusses the basic principles and recent representative studies of the four methods.Among these,solvent refining is the most promising and environmentally friendly approach for obtaining low-cost SoG-Si and is a popular research topic.Finally,a simple and green approach,i.e.,a combination of solvent refining,slag treatment,or vacuum directional solidification,is proposed for low-cost SoG-Si preparation using MG-Si or Si wastes as raw materials.
