PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and...PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and eco-friendly business models,Huntsman Textile Effects has introduced the new PHOBOTEX~?RSY non-fluorinated durable water repellent(DWR)that raises the standard for repellency especially on high-performance synthetic textiles.This new product will allow brands and retailers to meet global demand for eco-friendly clothing that require extreme rain-and stain-protection.展开更多
In order to enhance the water repellence property of cotton fabric, cotton fabric was grafted using hexafluorobutyl methacrylate( HFMT) monomer via atom transfer radical polymerization( ATRP) method. Water repellent c...In order to enhance the water repellence property of cotton fabric, cotton fabric was grafted using hexafluorobutyl methacrylate( HFMT) monomer via atom transfer radical polymerization( ATRP) method. Water repellent cotton fabric was successfully prepared, and characterized by scanning electron microscopy( SEM),Fourier transform infrared spectroscopy( FTIR), and X-ray photoelectron spectroscopy( XPS). The SEM images of the HFMT-treated cotton displayed significant difference from the untreated one. FT-IR characterization of the HFMTtreated cotton indicated that HFMT was successfully grafted onto the surface of the cotton fabric. XPS analysis indicated that the fluorine element of the HFMT-treated cotton existing on the surface of the cotton fabric. The surface contact angle test as well as the water repellence rating test showed that the water repellence of the HFMTtreated cotton fabric was much better than that of the untreated cotton fabric. The surface contact angle of the HFMT-treated cotton fabric could reach( 132. 4 ± 2. 2) °,and the water repellence rating could achieve grade 3. The washing durability of the HFMT-treated fabric was also investigated. The surface contact angle of the HFMTtreated cotton fabric could reach( 121. 1 ± 2. 1) ° after 20 washing times. Furthermore, the whiteness, air permeability, breaking strength,and breaking elongation of the HFMT-treated cotton fabric decreased slightly compared with the untreated cotton fabric.Finally,cotton fabric with good water repellence property and excellent washing durability could be obtained with little effect on the intrinsic properties of cotton fabric.展开更多
Recycled polystyrene in combination with paraffin wax,alkyd resin,and gum rosin were used as components in formulations to investigate their water repellency when applied to cellulosic filter paper substrates.Polystyr...Recycled polystyrene in combination with paraffin wax,alkyd resin,and gum rosin were used as components in formulations to investigate their water repellency when applied to cellulosic filter paper substrates.Polystyrene was used in concentration of 5,10,15 and 20%,alkyd resin and gum rosin of 5%each and paraffin wax of 0.5%.Totally,twenty four water repellent solutions were prepared.Water repellency was evaluated in terms of water absorption of the cellulosic fibrous mats.The relations between retention of solid substances of the formulations and grammage and water absorption of filter paper samples were also determined.The results showed that all the water repellent formulations exhibited a degree of water repellency.Water absorption decreased by increasing the polystyrene concentration in the solution and polystyrene retention by the impregnated filter paper samples.The incorporation of 0.5%paraffin wax improved the hydrophobicity of treated samples.The best of the three water repellent formulations including paraffin wax was found to be the“polystyrene+gum rosin+paraffin wax”solution followed by the“polystyrene+alkyd resin+paraffin wax”and“polystyrene+paraffin wax”solution.The inclusion of 5%gum rosin in polystyrene solutions compared to that of 0.5%paraffin wax was found more effective in almost all cases.展开更多
Water striders have intrigued researchers for centuries from the viewpoints of biology to biomechanics. In this review, we introduce the basic theories and techniques of physics and force measurement for biomechanical...Water striders have intrigued researchers for centuries from the viewpoints of biology to biomechanics. In this review, we introduce the basic theories and techniques of physics and force measurement for biomechanical research into water striders. Morphological and behavioral traits of water striders are summarized and discussed from biomechanical perspectives, along with comparative study. This integrated review also highlights potential directions for studies on water-walking arthropods,which might inspire future biological and biomechanical research.展开更多
Water repellant,flexible biofoams using tannin esterified with various fatty acid chains,namely lauric,palmitic and oleic acids,by reaction with lauryl chloride,palmitoyl chloride,and oleyl chloride were developed and...Water repellant,flexible biofoams using tannin esterified with various fatty acid chains,namely lauric,palmitic and oleic acids,by reaction with lauryl chloride,palmitoyl chloride,and oleyl chloride were developed and their characteristics compared with the equivalently esterified rigid biofoams.Glycerol,while initially added to control the reaction temperature,was used as a plasticizer yielding flexible biofoams presenting the same water repellant character that the equivalent rigid foams.Acetaldehyde was used as the cross-linking agent instead of formaldehyde,as it showed a better performance with the esterified tannin.The compression results showed a significant decrease of the Modulus of Elasticity(MOE)of the flexible foams in relation to that of the rigid foams,confirming their flexible character.The lauryl-and palmitoyl-esterified biofoams presented similar mechanical properties,while the oleyl-esterified biofoam presented different mechanical and morphological result not really showing the expected flexibility.Both the esterified rigid and flexible tannin-based biofoams showed good water resistance and their sessile drop contact angle analysis as a function of time confirmed this characteristic.Scanning Electron Microscope(SEM)analysis showed the flexible foams to present a higher proportion of closed cells than the rigid foams.Conversely,the cells depth of the flexible foams was lower than that of the rigid foam.As regards their thermal resistance,the flexible foams showed a slight loss of mass compared to the rigid ones without glycerol.Both types of foams presented much lower surface friability of non-esterified rigid foams.展开更多
Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many,if not all of the tannin hydroxyl groups with–NH_(2)groups.A tannin-aminated tannin(ATT)partic...Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many,if not all of the tannin hydroxyl groups with–NH_(2)groups.A tannin-aminated tannin(ATT)particleboard coating was then prepared by reacting raw tannin extract with aminated tannin extract and thus cross-linking the two by substituting tannin’s hydroxyl groups with the–NH_(2)groups on the aminated tannin to form–NH-bridges between the two.The resulting particleboard coating gave encouraging results when pressed at 180℃for 3 min.Conversely,the system in which tannin was reacted/cross-liked with urea(ATU)by a similar amination reaction did not perform as well as the ATT system,and this even when a higher curing temperature and longer hot press time were used.In particular its water repellence was worse probably due to the presence of urea and such a system with lower reactivity.Nonetheless,substituting the tannin–OHs with the urea–NH_(2)groups appeared to also take place.ATT gave better results than ATU as regards water repellence and mechanical resistance as shown by the cross cut test.The ATT system was shown to be between 95%and 98%biosourced.The difference appeared to be due,by TMA analysis,to the much faster formation of the ATT hardened network leading to a better cross-linked polymer coating.The chemical species formed for both the ATT and ATU system were studied by MALDI ToF and CP MAS^(13)C NMR.展开更多
Plantation establishment using invasive alien plants is common in South Africa,but the effects of these plants on soil physical properties in the Vhembe biosphere is unknown.In this comparative study,soils underneath ...Plantation establishment using invasive alien plants is common in South Africa,but the effects of these plants on soil physical properties in the Vhembe biosphere is unknown.In this comparative study,soils underneath Pinus elliottii and Eucalyptus cloeziana were assessed for differences in physical properties compared to soils underneath adjacent natural sites in the Entabeni plantation in the Vhembe biosphere in Limpopo Province,South Africa.Soils were collected from topsoil over 3 months and quantified for gravimetric soil moisture,penetration resistance,soil infiltration,hydraulic conductivity and soil water repellency.For all 3 months,soils from both P.elliottii and E.cloeziana plantations were compact and had low penetration resistance compared to soils from adjacent natural sites.Soil infiltration and hydraulic conductivity were significantly(p\0.05)lower in soils from plantations compared to soils from adjacent natural sites,and more so from the E.cloeziana plantation than from P.elliottii.Soil water repellency was observed in soils from E.cloeziana only in May and June.Soils from the invasive alien tree plantation have decreased soil moisture,infiltration rate,hydraulic conductivity and are compact as well as repellent(only E.cloeziana),all poor soil physical properties.However,this decline in soil physical properties was not uniform between the two invasive alien plantation species;hence we cannot generalize about the effects of invasive alien plantation species on soil physical properties,and further research is required across different ecological regions.展开更多
Polyoxetanes bearing short fluorinated and/or bromomethyl pendant groups were prepared from 3,3-bis(2,2,2-trifluoroethoxymethyl)oxetane and/or 3,3-bisbromomethyloxetane by ring-opening polymerization.A series of novel...Polyoxetanes bearing short fluorinated and/or bromomethyl pendant groups were prepared from 3,3-bis(2,2,2-trifluoroethoxymethyl)oxetane and/or 3,3-bisbromomethyloxetane by ring-opening polymerization.A series of novel polyurethanes(PUs)containing polyoxetanes as soft blocks was synthesized by the reaction of polyoxetanes,isophorone diisocyanate(IPDI),and 1,4-butanediol(BD).The thermal properties and wetting behavior of these novel polymers were evaluated using TGA,DSC and contact angle analysis.The cotton fabrics treated with PU3 showed good hydrophobic property,and its contact angle for water was 133°.展开更多
Durable superomniphobic surfaces are desirable for their practical applications,including selfcleaning,non-fouling,protective clothing and the separation of liquids.The plasma-induced polymerization of environmentally...Durable superomniphobic surfaces are desirable for their practical applications,including selfcleaning,non-fouling,protective clothing and the separation of liquids.The plasma-induced polymerization of environmentally friendly C6 from a perfluoralkyl methlacrylate copolymer emulsion,AG-E081,was performed and a durable omniphobic fabric was achieved.C6 is an ecological alternative to C8(eight CF2 groups)fluorinated compounds,and it was thereafter successfully incorporated into aramid fabric to achieve a durable superomniphobic surface.The fabric became water and oil repellent with an extremely high water contact angle of 180°.As tested by the water spray AATCC test and hydrocarbon resistance test,the as-prepared fabric gained 100°(ISO 5)and grade number 4 respectively.Furthermore,the fabrics also showed significantly improved washing durability after ten washing cycles.By scanning electron microscopy(SEM),Fourier-transform infrared spectroscopy(FTIR)and x-ray photoelectron spectroscopy(XPS)tests,it is indicated that the durable superomniphobicity can be attributed to the roughness and activation of the aramid surface by the plasma pre-treatment,which induces more adsorption and chemical graft of the C6 copolymer.展开更多
Oil spills and oil/water wastewater are among the great concerns regarding oil pollution.Existing technologies face many limitations and in some cases are responsible for causing secondary pollution,therefore there is...Oil spills and oil/water wastewater are among the great concerns regarding oil pollution.Existing technologies face many limitations and in some cases are responsible for causing secondary pollution,therefore there is as seek for environmental friendly solutions.Biomass,from which celluloses are highlighted,are being employed for oil/water separation or oil absorbents membranes.Usually,these membranes are obtained by freeze drying of CNF(cellulose nano-fibrils)suspensions followed by chemical modification for hydrophobization,which involves expensive process as chemical vapor deposition and expensive reactants as sylanes,turning these processes hardly scalable.Here,we produced a natural porous structure paper from eucalyptus pulp fibers modified by a dipping and heating process in a blocked diisocyanate solution.After the surface treatment,contact angle with water reached 144°and water absorption reduced seven times,keeping the good oil absorbance.The chemical modification process is simple to be performed and use a very low quantity of reactant estimated to be less than 0.1 wt%based on cellulose.The good mechanical properties of the material allows its use in non usual conditions which can be of great importance depending on the environmental conditions.展开更多
<div style="text-align:justify;"> A series of different sequence structure containing stearyl acrylate (SA) and hydroxyethyl acrylate (HEA) copolymer were synthesized via reversible addition-fragmentat...<div style="text-align:justify;"> A series of different sequence structure containing stearyl acrylate (SA) and hydroxyethyl acrylate (HEA) copolymer were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. The crystallization property of PHEA-<em>b</em>-PSA, PHEA-<em>b</em>-PSA-<em>b</em>-PHEA, PSA-<em>b</em>-PHEA-<em>b</em>-PSA, PHEA-<em>co</em>-PSA, and PHEA-<em>grad-b</em>-PSA were characterized by Differential Scanning Calorimetry (DSC). The condensed structure of different sequence copolymers were investigated using small-angle X-ray scattering (SAXS). A series of copolymers with different sequence structure were coated on the surface of polyester fabric, which can be found that PHEA-b-PSA-b-PHEA block copolymer has good water repellency. </div>展开更多
Despite ample literature,the influence of the individual soil properties and covers on the hydrological response of burned soils of forests has not clearly identified.A clear understanding of the surface runoff and er...Despite ample literature,the influence of the individual soil properties and covers on the hydrological response of burned soils of forests has not clearly identified.A clear understanding of the surface runoff and erosion rates altered by wildfires and prescribed fires is beneficial to identify the most suitable post-fire treatment This study has carried out a combined analysis of the hydrological response of soil and its driving factors in burned forests of Central-Eastern Spain.The pine stands of these forests were subjected to both prescribed fire and wildfire,and,in the latter case,to post-fire treatment with mulching.Moreover,simple multi-regression models are proposed to predict runoff and erosion in the experi-mental conditions.In the case of the prescribed burning,the fire had a limited impact on runoff and erosion compared to the unburned areas,due to the limited changes in soil parameters.In contrast,the wildfire increased many-fold the runoff and erosion rates,but the mulching reduced the hydrological response of the burned soils,particularly for the first two-three rainfalls after the fire.The increase in runoff and erosion after the wildfire was associated to the removal of the vegetation cover,soil water repellency,and ash left by fire;the changes in water infiltration played a minor role on runoff and erosion.The multi-regression models developed for the prescribed fire were accurate to predict the post-fire runoff coefficients.However,these models were less reliable for predictions of the mean erosion rates.The predictions of erosion after wildfire and mulching were excellent,while those of runoff were not satisfactory(except for the mean values).These results are useful to better understand the relations among the hydrological effects of fire on one side and the main soil properties and covers on the other side.Moreover,the proposed prediction models are useful to support the planning activities of forest managers and hydrologists towards a more effective conservation of forest soils.展开更多
Aims studying the ecological significance of highly specialized morpho-logical traits evolved by alpine plants could help us to understand the adaptation and evolution of these plants under severe alpine environ-ment....Aims studying the ecological significance of highly specialized morpho-logical traits evolved by alpine plants could help us to understand the adaptation and evolution of these plants under severe alpine environ-ment.We explored the adaptive significance of woolly and overlap-ping leaves for reproduction in Eriophyton wallichii,a perennial herb native to the subnival belt of the Himalaya-Hengduan mountains.Methods We examined whether the trichomes could influence the leaf wet-tability,temperature and leaf reflectance spectra in the lab.and we investigated the thermal benefits of the woolly and overlapping leaves for flowers and fruits in the field.Pollen viability and seed germination were also examined in the lab to assess whether these leaves enhance reproductive fitness.Important Findingsour results showed that dense trichomes impart good water repel-lency,absorption of solar radiation and accumulation of leaf heat.The woolly and overlapping leaves increased the interior tempera-ture of flowers and fruits to an optimal level on sunny hours,but prevented them from overheating when transient intense solar radi-ation occurs.This kept optimal temperatures in plants’reproduc-tive organs,thus promoting the development of pollen and seed in alpine environment.展开更多
Two oil spills occurred in the Evrona Nature Reserve(southern Israel),in 1975 and 2014.This oil contamination induced highly persistent soil hydrophobicity.The objective of this study was to investigate the decrease i...Two oil spills occurred in the Evrona Nature Reserve(southern Israel),in 1975 and 2014.This oil contamination induced highly persistent soil hydrophobicity.The objective of this study was to investigate the decrease in oil-induced soil hydrophobicity under different environmental conditions and to assess the relationship between the hydrophobicity and hydrocarbon content.A laboratory incubation experiment was conducted over 1.5 years to monitor the soil hydrophobicity and total hydrocarbon concentration under different environmental conditions.We hypothesized that the addition of water(20% or 50% saturation),nutrients,and biosurfactants can accelerate the reduction in hydrophobicity and decomposition of hydrocarbons.Water drop penetration time and molarity of ethanol droplet tests were used to assess soil hydrophobicity.In parallel,alkane composition and total petroleum hydrocarbons were evaluated to indicate oil attenuation.The addition of water,nutrients,and biosurfactants resulted in a concomitant reduction in hydrophobicity and hydrocarbon concentration of varying degrees,exhibiting enhanced degradation and hydrophobicity reduction observed in treatments to which nutrients and biosurfactants were added.At the end of the incubation,however,soil hydrophobicity in all treatments remained severe,even though total petroleum hydrocarbon removal was fairly high and reached 40%–80%in the treatments to which water with or without nutrients and/or surfactants was added.展开更多
文摘PHOBOTEX~? RSY durable water repellent delivers best-in-class performance to support the industry's shift to non-fluorinated formulations Continuing to lead the textile sector’s transition to more sustainable and eco-friendly business models,Huntsman Textile Effects has introduced the new PHOBOTEX~?RSY non-fluorinated durable water repellent(DWR)that raises the standard for repellency especially on high-performance synthetic textiles.This new product will allow brands and retailers to meet global demand for eco-friendly clothing that require extreme rain-and stain-protection.
基金National Natural Science Foundations of China(Nos.51203107,51273134,and 51273140)Jiangsu Province Project of Postgraduate Innovation Engineering,China(No.CXZZ13_0818)+1 种基金Qing Lan Project,Jiangsu,ChinaPriority Academic Program Development of Jiangsu Higher Education Institutions,China
文摘In order to enhance the water repellence property of cotton fabric, cotton fabric was grafted using hexafluorobutyl methacrylate( HFMT) monomer via atom transfer radical polymerization( ATRP) method. Water repellent cotton fabric was successfully prepared, and characterized by scanning electron microscopy( SEM),Fourier transform infrared spectroscopy( FTIR), and X-ray photoelectron spectroscopy( XPS). The SEM images of the HFMT-treated cotton displayed significant difference from the untreated one. FT-IR characterization of the HFMTtreated cotton indicated that HFMT was successfully grafted onto the surface of the cotton fabric. XPS analysis indicated that the fluorine element of the HFMT-treated cotton existing on the surface of the cotton fabric. The surface contact angle test as well as the water repellence rating test showed that the water repellence of the HFMTtreated cotton fabric was much better than that of the untreated cotton fabric. The surface contact angle of the HFMT-treated cotton fabric could reach( 132. 4 ± 2. 2) °,and the water repellence rating could achieve grade 3. The washing durability of the HFMT-treated fabric was also investigated. The surface contact angle of the HFMTtreated cotton fabric could reach( 121. 1 ± 2. 1) ° after 20 washing times. Furthermore, the whiteness, air permeability, breaking strength,and breaking elongation of the HFMT-treated cotton fabric decreased slightly compared with the untreated cotton fabric.Finally,cotton fabric with good water repellence property and excellent washing durability could be obtained with little effect on the intrinsic properties of cotton fabric.
基金Financial support has been provided by the Swedish Research Council Formas(Project Grant No.942-2016-2,2017-21).
文摘Recycled polystyrene in combination with paraffin wax,alkyd resin,and gum rosin were used as components in formulations to investigate their water repellency when applied to cellulosic filter paper substrates.Polystyrene was used in concentration of 5,10,15 and 20%,alkyd resin and gum rosin of 5%each and paraffin wax of 0.5%.Totally,twenty four water repellent solutions were prepared.Water repellency was evaluated in terms of water absorption of the cellulosic fibrous mats.The relations between retention of solid substances of the formulations and grammage and water absorption of filter paper samples were also determined.The results showed that all the water repellent formulations exhibited a degree of water repellency.Water absorption decreased by increasing the polystyrene concentration in the solution and polystyrene retention by the impregnated filter paper samples.The incorporation of 0.5%paraffin wax improved the hydrophobicity of treated samples.The best of the three water repellent formulations including paraffin wax was found to be the“polystyrene+gum rosin+paraffin wax”solution followed by the“polystyrene+alkyd resin+paraffin wax”and“polystyrene+paraffin wax”solution.The inclusion of 5%gum rosin in polystyrene solutions compared to that of 0.5%paraffin wax was found more effective in almost all cases.
基金the National Natural Science Foundation of China(51425502)。
文摘Water striders have intrigued researchers for centuries from the viewpoints of biology to biomechanics. In this review, we introduce the basic theories and techniques of physics and force measurement for biomechanical research into water striders. Morphological and behavioral traits of water striders are summarized and discussed from biomechanical perspectives, along with comparative study. This integrated review also highlights potential directions for studies on water-walking arthropods,which might inspire future biological and biomechanical research.
基金The Malaysia-France Bilateral Research Collaboration Project Grant 2021 (MATCH 2021)funded this research work,MOHE-Fire-Resistant and Water-Repellent Tannin-Furanic-Fatty Acid Biofoams。
文摘Water repellant,flexible biofoams using tannin esterified with various fatty acid chains,namely lauric,palmitic and oleic acids,by reaction with lauryl chloride,palmitoyl chloride,and oleyl chloride were developed and their characteristics compared with the equivalently esterified rigid biofoams.Glycerol,while initially added to control the reaction temperature,was used as a plasticizer yielding flexible biofoams presenting the same water repellant character that the equivalent rigid foams.Acetaldehyde was used as the cross-linking agent instead of formaldehyde,as it showed a better performance with the esterified tannin.The compression results showed a significant decrease of the Modulus of Elasticity(MOE)of the flexible foams in relation to that of the rigid foams,confirming their flexible character.The lauryl-and palmitoyl-esterified biofoams presented similar mechanical properties,while the oleyl-esterified biofoam presented different mechanical and morphological result not really showing the expected flexibility.Both the esterified rigid and flexible tannin-based biofoams showed good water resistance and their sessile drop contact angle analysis as a function of time confirmed this characteristic.Scanning Electron Microscope(SEM)analysis showed the flexible foams to present a higher proportion of closed cells than the rigid foams.Conversely,the cells depth of the flexible foams was lower than that of the rigid foam.As regards their thermal resistance,the flexible foams showed a slight loss of mass compared to the rigid ones without glycerol.Both types of foams presented much lower surface friability of non-esterified rigid foams.
基金supported by a grant of the French Agence Nationale de la Recherche(ANR)in the Ambit of the Laboratory of Excellence(Labex)ARBRE.This work was also supported by“The 111 Project(D21027)”.
文摘Aminated tannins were prepared by reacting mimosa condensed tannin extract with ammonia yielding the substitution of many,if not all of the tannin hydroxyl groups with–NH_(2)groups.A tannin-aminated tannin(ATT)particleboard coating was then prepared by reacting raw tannin extract with aminated tannin extract and thus cross-linking the two by substituting tannin’s hydroxyl groups with the–NH_(2)groups on the aminated tannin to form–NH-bridges between the two.The resulting particleboard coating gave encouraging results when pressed at 180℃for 3 min.Conversely,the system in which tannin was reacted/cross-liked with urea(ATU)by a similar amination reaction did not perform as well as the ATT system,and this even when a higher curing temperature and longer hot press time were used.In particular its water repellence was worse probably due to the presence of urea and such a system with lower reactivity.Nonetheless,substituting the tannin–OHs with the urea–NH_(2)groups appeared to also take place.ATT gave better results than ATU as regards water repellence and mechanical resistance as shown by the cross cut test.The ATT system was shown to be between 95%and 98%biosourced.The difference appeared to be due,by TMA analysis,to the much faster formation of the ATT hardened network leading to a better cross-linked polymer coating.The chemical species formed for both the ATT and ATU system were studied by MALDI ToF and CP MAS^(13)C NMR.
文摘Plantation establishment using invasive alien plants is common in South Africa,but the effects of these plants on soil physical properties in the Vhembe biosphere is unknown.In this comparative study,soils underneath Pinus elliottii and Eucalyptus cloeziana were assessed for differences in physical properties compared to soils underneath adjacent natural sites in the Entabeni plantation in the Vhembe biosphere in Limpopo Province,South Africa.Soils were collected from topsoil over 3 months and quantified for gravimetric soil moisture,penetration resistance,soil infiltration,hydraulic conductivity and soil water repellency.For all 3 months,soils from both P.elliottii and E.cloeziana plantations were compact and had low penetration resistance compared to soils from adjacent natural sites.Soil infiltration and hydraulic conductivity were significantly(p\0.05)lower in soils from plantations compared to soils from adjacent natural sites,and more so from the E.cloeziana plantation than from P.elliottii.Soil water repellency was observed in soils from E.cloeziana only in May and June.Soils from the invasive alien tree plantation have decreased soil moisture,infiltration rate,hydraulic conductivity and are compact as well as repellent(only E.cloeziana),all poor soil physical properties.However,this decline in soil physical properties was not uniform between the two invasive alien plantation species;hence we cannot generalize about the effects of invasive alien plantation species on soil physical properties,and further research is required across different ecological regions.
基金Program for Changjiang Scholars and Innovative Research Teamin University,China(No.IRT0526)Shanghai Municipal Scientific Committee,China(No.08JC1400400)
文摘Polyoxetanes bearing short fluorinated and/or bromomethyl pendant groups were prepared from 3,3-bis(2,2,2-trifluoroethoxymethyl)oxetane and/or 3,3-bisbromomethyloxetane by ring-opening polymerization.A series of novel polyurethanes(PUs)containing polyoxetanes as soft blocks was synthesized by the reaction of polyoxetanes,isophorone diisocyanate(IPDI),and 1,4-butanediol(BD).The thermal properties and wetting behavior of these novel polymers were evaluated using TGA,DSC and contact angle analysis.The cotton fabrics treated with PU3 showed good hydrophobic property,and its contact angle for water was 133°.
基金supported by the Fundamental Research Funds for the Central Universities 2232019A3-12National Natural Science Foundation of China(No.11375042)。
文摘Durable superomniphobic surfaces are desirable for their practical applications,including selfcleaning,non-fouling,protective clothing and the separation of liquids.The plasma-induced polymerization of environmentally friendly C6 from a perfluoralkyl methlacrylate copolymer emulsion,AG-E081,was performed and a durable omniphobic fabric was achieved.C6 is an ecological alternative to C8(eight CF2 groups)fluorinated compounds,and it was thereafter successfully incorporated into aramid fabric to achieve a durable superomniphobic surface.The fabric became water and oil repellent with an extremely high water contact angle of 180°.As tested by the water spray AATCC test and hydrocarbon resistance test,the as-prepared fabric gained 100°(ISO 5)and grade number 4 respectively.Furthermore,the fabrics also showed significantly improved washing durability after ten washing cycles.By scanning electron microscopy(SEM),Fourier-transform infrared spectroscopy(FTIR)and x-ray photoelectron spectroscopy(XPS)tests,it is indicated that the durable superomniphobicity can be attributed to the roughness and activation of the aramid surface by the plasma pre-treatment,which induces more adsorption and chemical graft of the C6 copolymer.
基金This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil(CAPES)—Finance Code 001.Authors also acknowledge CNPq for financial support in special for the doctoral fellowship granted to G.S(CNPq Proc.140249/2017-6).AJFC acknowledge CNPq for research funding project#03847/2019-0.
文摘Oil spills and oil/water wastewater are among the great concerns regarding oil pollution.Existing technologies face many limitations and in some cases are responsible for causing secondary pollution,therefore there is as seek for environmental friendly solutions.Biomass,from which celluloses are highlighted,are being employed for oil/water separation or oil absorbents membranes.Usually,these membranes are obtained by freeze drying of CNF(cellulose nano-fibrils)suspensions followed by chemical modification for hydrophobization,which involves expensive process as chemical vapor deposition and expensive reactants as sylanes,turning these processes hardly scalable.Here,we produced a natural porous structure paper from eucalyptus pulp fibers modified by a dipping and heating process in a blocked diisocyanate solution.After the surface treatment,contact angle with water reached 144°and water absorption reduced seven times,keeping the good oil absorbance.The chemical modification process is simple to be performed and use a very low quantity of reactant estimated to be less than 0.1 wt%based on cellulose.The good mechanical properties of the material allows its use in non usual conditions which can be of great importance depending on the environmental conditions.
文摘<div style="text-align:justify;"> A series of different sequence structure containing stearyl acrylate (SA) and hydroxyethyl acrylate (HEA) copolymer were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. The crystallization property of PHEA-<em>b</em>-PSA, PHEA-<em>b</em>-PSA-<em>b</em>-PHEA, PSA-<em>b</em>-PHEA-<em>b</em>-PSA, PHEA-<em>co</em>-PSA, and PHEA-<em>grad-b</em>-PSA were characterized by Differential Scanning Calorimetry (DSC). The condensed structure of different sequence copolymers were investigated using small-angle X-ray scattering (SAXS). A series of copolymers with different sequence structure were coated on the surface of polyester fabric, which can be found that PHEA-b-PSA-b-PHEA block copolymer has good water repellency. </div>
基金the Open Research Fund Program of State Key Laboratory of Water Resources and Hydropower Engineering Science-Wuhan University(2019HLG02).
文摘Despite ample literature,the influence of the individual soil properties and covers on the hydrological response of burned soils of forests has not clearly identified.A clear understanding of the surface runoff and erosion rates altered by wildfires and prescribed fires is beneficial to identify the most suitable post-fire treatment This study has carried out a combined analysis of the hydrological response of soil and its driving factors in burned forests of Central-Eastern Spain.The pine stands of these forests were subjected to both prescribed fire and wildfire,and,in the latter case,to post-fire treatment with mulching.Moreover,simple multi-regression models are proposed to predict runoff and erosion in the experi-mental conditions.In the case of the prescribed burning,the fire had a limited impact on runoff and erosion compared to the unburned areas,due to the limited changes in soil parameters.In contrast,the wildfire increased many-fold the runoff and erosion rates,but the mulching reduced the hydrological response of the burned soils,particularly for the first two-three rainfalls after the fire.The increase in runoff and erosion after the wildfire was associated to the removal of the vegetation cover,soil water repellency,and ash left by fire;the changes in water infiltration played a minor role on runoff and erosion.The multi-regression models developed for the prescribed fire were accurate to predict the post-fire runoff coefficients.However,these models were less reliable for predictions of the mean erosion rates.The predictions of erosion after wildfire and mulching were excellent,while those of runoff were not satisfactory(except for the mean values).These results are useful to better understand the relations among the hydrological effects of fire on one side and the main soil properties and covers on the other side.Moreover,the proposed prediction models are useful to support the planning activities of forest managers and hydrologists towards a more effective conservation of forest soils.
基金Natural National Science Foundation of China(U1136601 to H.S.,31360049 to Z.M.L.and 31270005,31470321 to Y.Y.)Strategic Priority Research Program(B)of the Chinese Academy of Science(XDB03030112 to H.S.).
文摘Aims studying the ecological significance of highly specialized morpho-logical traits evolved by alpine plants could help us to understand the adaptation and evolution of these plants under severe alpine environ-ment.We explored the adaptive significance of woolly and overlap-ping leaves for reproduction in Eriophyton wallichii,a perennial herb native to the subnival belt of the Himalaya-Hengduan mountains.Methods We examined whether the trichomes could influence the leaf wet-tability,temperature and leaf reflectance spectra in the lab.and we investigated the thermal benefits of the woolly and overlapping leaves for flowers and fruits in the field.Pollen viability and seed germination were also examined in the lab to assess whether these leaves enhance reproductive fitness.Important Findingsour results showed that dense trichomes impart good water repel-lency,absorption of solar radiation and accumulation of leaf heat.The woolly and overlapping leaves increased the interior tempera-ture of flowers and fruits to an optimal level on sunny hours,but prevented them from overheating when transient intense solar radi-ation occurs.This kept optimal temperatures in plants’reproduc-tive organs,thus promoting the development of pollen and seed in alpine environment.
基金funded by the Ministry of Environmental Protection of Israelfinancial support of the China Scholarship Council。
文摘Two oil spills occurred in the Evrona Nature Reserve(southern Israel),in 1975 and 2014.This oil contamination induced highly persistent soil hydrophobicity.The objective of this study was to investigate the decrease in oil-induced soil hydrophobicity under different environmental conditions and to assess the relationship between the hydrophobicity and hydrocarbon content.A laboratory incubation experiment was conducted over 1.5 years to monitor the soil hydrophobicity and total hydrocarbon concentration under different environmental conditions.We hypothesized that the addition of water(20% or 50% saturation),nutrients,and biosurfactants can accelerate the reduction in hydrophobicity and decomposition of hydrocarbons.Water drop penetration time and molarity of ethanol droplet tests were used to assess soil hydrophobicity.In parallel,alkane composition and total petroleum hydrocarbons were evaluated to indicate oil attenuation.The addition of water,nutrients,and biosurfactants resulted in a concomitant reduction in hydrophobicity and hydrocarbon concentration of varying degrees,exhibiting enhanced degradation and hydrophobicity reduction observed in treatments to which nutrients and biosurfactants were added.At the end of the incubation,however,soil hydrophobicity in all treatments remained severe,even though total petroleum hydrocarbon removal was fairly high and reached 40%–80%in the treatments to which water with or without nutrients and/or surfactants was added.
