To improve the soil and water stability of expansive soil slopes and reduce the probability of slope failure,novel protection systems based on polymer waterproof coatings(PWC)were used in this study.Herein,three group...To improve the soil and water stability of expansive soil slopes and reduce the probability of slope failure,novel protection systems based on polymer waterproof coatings(PWC)were used in this study.Herein,three groups of expansive soil slope model tests were designed to investigate the effects of polyester nonwovens and PWC(P-PWC)composite protection system,three-dimensional vegetation network and PWC(T-PWC)composite protection system,and nonprotection on the soil and water behavior in the slopes under precipitation–evaporation cycles.The results showed that the moisture change of P-PWC and T-PWC composite protected slopes was significantly smaller than that of bare slope,which reduced the sensitivity of slope moisture to environmental changes and improved its stability.The soil temperature of the slope protected by the P-PWC and T-PWC systems at a depth of 70 cm increased by 5.6℃ and 2.7℃,respectively.Using PWC composite protection systems exhibited better thermal storage performance,which could increase the utilization of shallow geothermal resources.Moreover,the maximum average crack widths of the bare slopes were 7.89 and 3.17 times those of the P-PWC and TPWC protected slopes,respectively,and the maximum average crack depths were 6.87 and 3 times those of the P-PWC and T-PWC protected slopes,separately.The PPWC protection system weakened the influence of hydro–thermal coupling on the slopes,inhibited the development of cracks on the slopes,and reduced the soil erosion.The maximum soil erosion of slopes protected by P-PWC and T-PWC systems was 332 and 164 times lower than that of bare slope,respectively.The P-PWC and T-PWC protection systems achieved excellent"anti-seepage and moisture retention"and anti-erosion effects,thus improving the soil and water stability of slopes.These findings can provide important guiding reference for controlling rainwater infiltration and soil erosion in expansive soil slope projects.展开更多
In general,acid aggregates are not used in combination with asphalt concrete because of their poor compatibility with the asphalt binder,which typically results in a scarce water stability of the concrete.In the prese...In general,acid aggregates are not used in combination with asphalt concrete because of their poor compatibility with the asphalt binder,which typically results in a scarce water stability of the concrete.In the present study,the feasibility of a new approach based on the combination of acid granite fine aggregate with alkaline limestone coarse aggregate and Portland cement filler has been assessed.The mineral and chemical compositions of these three materials have first been analyzed and compared.Then,the effect of different amounts of Portland cement(0%,25%,50%,75%and 100%of the total filler by weight)on the mechanical performance and water stability of the asphalt concrete has been considered.Asphalt concrete has been designed by using the Marshall method,and the mechanical performance indexes of this material,including the Marshall stability and indirect tensile strength(ITS),have been measured together with the related water stability indexes(namely the Marshall stability(RMS)and tensile strength ratio(TSR)).The results indicate that the alkaline limestone coarse aggregate and Portland cement filler can balance the drawback caused by the acid granite fine aggregate.The asphalt concrete has good mechanical performances and water stability when the amount of common limestone powder filler replaced by cement is not less than 75%.展开更多
Rubber trees (Hevea brasiliensis Müll. Arg.) have been commercially cultivated for a century and a half in Asia, particularly in China, and they constitute a common element of plantation ecosystems in tropical re...Rubber trees (Hevea brasiliensis Müll. Arg.) have been commercially cultivated for a century and a half in Asia, particularly in China, and they constitute a common element of plantation ecosystems in tropical regions. Soil health is fundamental to the sustainable development of rubber plantations. The objective of the study is to explore the influence of different complex ecological cultivation modes on the stability of soil aggregates in rubber based agroforestry systems. In this study, the ecological cultivation mode of rubber—Alpinia oxyphylla plantation, the ecological cultivation mode of rubber—Phrynium hainanense plantations, the ecological cultivation mode of rubber—Homalium ceylanicum plantations and monoculture rubber plantations were selected, and the particle size distribution of soil aggregates and their water stability characteristics were analyzed. The soil depth of 0 - 20 cm and 20 - 40 cm was collected for four cultivation modes. Soil was divided into 6 particle levels > 20 cm. soil was divided into 6 particle levels > 5 mm, 2 - 5 mm, 1 - 2 mm, 0.5 - 1 mm, 0.25 - 0.5 mm, and 0.053 - 0.25 mm according to the wet sieve method. The particle size proportion and water stability of soil aggregates were determined by the wet sieve method. The particle size proportion and water stability of soil aggregates under different ecological cultivation modes were analyzed. The results showed that under different ecological cultivation modes in the shallow soil layer (0 - 20 cm), the rubber—Alpinia oxyphylla plantation and the rubber—Phrynium hainanense plantation promoted the development of dominant soil aggregates towards larger size classes, whereas the situation is the opposite for rubber—Homalium ceylanicum plantation. In soil layer (20 - 40 cm), the ecological cultivation mode of rubber—Phrynium hainanense plantation developed the dominant radial level of soil aggregates to the diameter level of large aggregates. Rubber—Alpinia oxyphylla plantation and rubber—Homalium ceylanicum plantation, three indicators, including the water-stable aggregate content R<sub>0.25</sub> (>0.25 mm water-stable aggregates), mean weight diameter (MWD), and geometric mean diameter (GMD), were all lower than those in the rubber monoculture mode. However, in the rubber—Phrynium hainanense plantation, the water-stable aggregate content R<sub>0.25</sub>, mean weight diameter, and geometric mean diameter were higher than in the rubber monoculture mode, although these differences did not reach statistical significance.展开更多
The fibre pullout test was conducted to investigate the influence of the water stability on the bond behaviour between the Magnesium phosphate cement(MPC)matrix and the steel fibre.The composition of the MPC-matrix an...The fibre pullout test was conducted to investigate the influence of the water stability on the bond behaviour between the Magnesium phosphate cement(MPC)matrix and the steel fibre.The composition of the MPC-matrix and the immersion age of the specimens are experimentally investigated.The average bond strength and the pullout energy are investigated by analysing the experimental results.In addition,the microscopic characteristics of the interface transition zone are investigated using scanning electron microscopy(SEM).The experimental results showed that the bond performance between the MPC-matrix and the steel fibre decreased significantly with the increase of the duration of immersion in water.The average bond strength between the steel fibre and the MPC-matrix reduced by more than 50%when the specimens were immersed in the water for 28 days.The effect of the water on the interface between the steel fibre and the MPC-matrix was found to be more significant compared to the composition of the MPC-matrix.In addition,the MgO-KH2PO4 mole ratio of the MPC significantly influenced the water stability of the interface zone between the steel fibre and MPC-matrix.展开更多
Water and moisture stability have been recognized as one of the most important characteristics of metal–organic frameworks(MOFs)in regards to their future applications.Nonetheless,most MOFs are water-labile to some d...Water and moisture stability have been recognized as one of the most important characteristics of metal–organic frameworks(MOFs)in regards to their future applications.Nonetheless,most MOFs are water-labile to some degree.One promising solution for the collapse of MOFs toward water is surface hydrophobic modification.展开更多
The use of concrete wastes in asphalt treated base (ATB) not only prevents environmental pollution but also protect stone resources. But the strength of the concrete wastes is often weaker than nature aggregates and t...The use of concrete wastes in asphalt treated base (ATB) not only prevents environmental pollution but also protect stone resources. But the strength of the concrete wastes is often weaker than nature aggregates and the binding properties with asphalt is poor. So it difficult to meet the requirements of asphalt treated base. In this paper,The organosilicone waterproofing material is used to improve the performance of concrete wastes and the long term immersing frozen-thaw cycle test were used to investigate the anti-stripping performance of limestone asphalt mixture,concrete wastes asphalt mixture and concrete wastes asphalt mixture having treated by organosilicone waterproofing material. The experimental results show that organosilicone waterproofing material can improve the water stability of asphalt mixture. The use of concrete wastes in ATB is achievable.展开更多
Porous polyurethane concrete(PPUC)is a novel material for permeable pavements and is considered as an alternative to porous asphalt or porous cement concrete.However,studies of the mechanical properties of PPUC are st...Porous polyurethane concrete(PPUC)is a novel material for permeable pavements and is considered as an alternative to porous asphalt or porous cement concrete.However,studies of the mechanical properties of PPUC are still insufficient.In this study,the comprehensive mechanical properties and water stability of PPUC with different gradations and polyurethane dosages were investigated,and its water damage mechanism was preliminarily explored.The results show that the flexural strength and Marshall stability of PPUC can more easily reach the index in the standards of porous cement concrete or porous asphalt,while the compressive strength and abrasion resistance are the weak points of its mechanical properties and need to be further optimized.The mechanical properties and water stability of PPUC were effectively improved by increasing the polyurethane dosage and using continuously graded aggregates.PPUC is more susceptible to water damage because water reacts with the residual isocyanate groups within the polyurethane film to generate carbon dioxide gas,which reduces the cohesion and adhesion performance of polyurethane film.This study provides a comprehensive understanding of the mechanical properties of PPUC and an initial insight into the mechanism of water damage.展开更多
Flexible p–n thermoelectric generator(TEG)technology has rapidly advanced with power enhancement and size reduction.To achieve a stable power supply and highly efficient energy conversion,absolute chemical stability ...Flexible p–n thermoelectric generator(TEG)technology has rapidly advanced with power enhancement and size reduction.To achieve a stable power supply and highly efficient energy conversion,absolute chemical stability of n-type materials is essential to ensuring large temperature differences between device terminals and ambient stability.With the aim of improving the long-term stability of the n-type operation of carbon nanotubes(CNTs)in air and water,this study uses cationic surfactants,such as octylene-1,8-bis(dimethyldodecylammonium bromide)(12-8-12),a gemini surfactant,to stabilize the nanotubes in a coating,which retains the n-doped state for more than 28 days after exposure to air and water in experiments.TEGs with 10 p-n units of 12-8-12/CNT(n-type)and sodium dodecylbenzene sulfonate/CNT(p-type)layers are manufactured,and their water stability is evaluated.The initial maximum output of 16.1μW(75 K temperature difference)is retained after water immersion for 40 days without using a sealant to prevent TEG module degradation.The excellent stability of these CNT-based TEGs makes them suitable for underwater applications,such as battery-free health monitoring and information gathering systems,and facilitates the development of soft electronics.展开更多
With the development of the production scale and the increasing of the process technologies and facilities,product quality and the requirement of water supply continuously put forward new requirements to water treatme...With the development of the production scale and the increasing of the process technologies and facilities,product quality and the requirement of water supply continuously put forward new requirements to water treatment technology.The practice of the water saving technology should ensure the safe of water using and the innovation of technique data.Especially the stabilization of water quality should also meet the production at full capacity,reduce equipment failure rate and maintain the sustainable development under the condition of the minimal resource consumption.This article describes the practice of Baosteel saving technology,water-saving ideas from the system to start,according to Baosteel raw water intake requirements and process water and drainage characteristics,water and salt water tidal according to changes in the Yangtze River and the Yangtze River upstream and downstream trends in water discharge on water quality factors,established the electrical conductivity,chloride ion indicators for the control of the Yangtze River water,the implementation of 'avoid salt build light' water at the same time,combined with the actual situation of water pollution in the Yangtze River,the use of force coefficient correlation theory,the implementation of 'avoid taking clear pollution' to ensure the quality of raw water intake. System and cascade utilization of water,process water,based on whole plant water balance testing, analysis,technical parameters of the system and processes the user running the pressure balance pipe network,and implemented a stabilization system to adjust water pressure,reducing the water supply network systemwater loss;application of electrochemical principles,the implementation of the protection of underground pipes Baosteel,implemented a water use,steps to use,the operating mode of water supply in series to increase water reuse,reduce wastewater discharge system. Water quality stability and water-saving in the process;carry out water quality stability technology in the different complicated processes of the steel industry;apply the environmental protection and water quality, sterilization,non-phosphorus and low phosphorus technologies which are suitable for high concentration of circulating water.By these technologies,we achieved the water-saving in the process in different seasons and solved the technical problems affecting production such as equipment corrosion,scaling and the formation of the water quality proprietary technology under the conditions of high heat load production as well. The use of water ecological conservation and biological treatment technology:the implementation of the reservoir to the ecological technology is characterized by food chain and wetland environmental technology characterized by plants chain.Reservoir ecological management techniques in the use of natural conditions, wind direction,temperature,light and fish biomass in the reservoir water level regulation of balance and combination of organic,control and resolve the reservoirs in spring and summer algae problems and water quality changes rot of the 'fresh' operating problems.The artificial wetland technology develops a new way for metallurgical plants’ wastewater treatment.All the measures by the implementation of water to create the conditions for the system to achieve the water target of constant innovation,reaching the advanced level of iron and steel enterprises.展开更多
For evaluating the water stability of hot-mixed renewable asphalt mixture(HRM),the traditional methods are all tested under still water conditions.Except for damage in still water conditions,the hydrodynamic pore pres...For evaluating the water stability of hot-mixed renewable asphalt mixture(HRM),the traditional methods are all tested under still water conditions.Except for damage in still water conditions,the hydrodynamic pore pressure generated by the tire driving on the surface water has a great impact.Thus,the RAP contents of the HRMs were designed at 0%,30%,45%and 60%with AC-25 gradation.Then,the self-designed evaluation methods of water stability and dynamic modulus were studied.Finally,the mechanism of the influence of hydrodynamic pore pressure damage on HRMs was studied.The results show that the water stability of HRM containing 30%RAP is equivalent to that of 45%RAP,and the water stability of HRM containing 60%RAP decreases significantly.The Contabro test after MIST treatment can be used as an evaluation method for hydrodynamic pore pressure damage on HRM.Low-speed,heavy-load traffic and larger RAP content have greater damage to the mixture after hydrodynamic pore pressure damage.The performance differences between the aged bitumen and pure bitumen,as well as the aged minerals and new minerals,are continuing to be enlarged in hydrodynamic pore pressure conditions,finally affecting the water stability and dynamic modulus of the HRMs.展开更多
A phosphogypsum-based subgrade stabilizer(PBSS)was formulated using industrial by-product phosphogypsum(PG),mixed with slag and calcium-silicon-rich active material(GSR).The active powder(AP)was used to modify PBSS,an...A phosphogypsum-based subgrade stabilizer(PBSS)was formulated using industrial by-product phosphogypsum(PG),mixed with slag and calcium-silicon-rich active material(GSR).The active powder(AP)was used to modify PBSS,and PBSS-AP was obtained.PBSS and PBSS-AP were each mixed with 10%silty soil,and cement and lime(CAL:5%lime+2%cement)were used as the traditional material for comparative experiments.Samples were cured under standard conditions,and tested for unconfined compressive strength(UCS),water stability,volume expansion,and leachate,to explore the stabilization effect of the three solidified materials on silty soil.The results showed that the comprehensive performance of sility soil mixed with 12%PBSS-AP was the best.The CaO,SiO_(2)and Al_(2)O_(3)provided by PG,Slag and GSR will react with water to form a stable C-S-H gel,which is conducive to stabilizing the soil.Field application results showed that the compaction exceeded 95%,the deflection was 144.9 mm,and UCS was 2.5 MPa after 28 days.These findings indicated that PBSS-AP is an effective stabilizer for subgrade soils.展开更多
Variations of seawater properties and stratification of water column in the southern deep water zone(470 m depth)of the Caspian Sea were evaluated based on field measured data.Variations of physical characteristics(te...Variations of seawater properties and stratification of water column in the southern deep water zone(470 m depth)of the Caspian Sea were evaluated based on field measured data.Variations of physical characteristics(temperature,salinity,density and sound speed)of seawater mainly were limited to the upper 100 m layers.Below this layer,seasonal changes of seawater parameters were minor.Vertical structure of temperature in the southern Caspian Sea waters was characterized by a significant seasonal thermocline approximately between 20 and 50 m depths in summer with a vertical gradient of around 16℃.Destruction of the thermocline occurred with the general cooling of the sea surface water and deepening of the mixed layer during late of autumn and winter.Frequency of stability in water column often across the upper layers(surface mixed and thermocline)was more than deeper levels.Variations of salinity were around 12.4 PSU in the time of measurements.Structures of thermocline and pycnocline were characterized by a significant homogeneity especially in offshore stations during the year.According to high agreement between density and temperature in the Caspian Seawater,a strong seasonal pycnocline was observed in the position of the thermocline.Furthermore,structure of sound speed variations followed vertical variations of seawater temperature.Variations of chemical characteristics(dissolved oxygen and pH)of seawater mainly were continued from sea surface to near the sea bed in deep water zone.展开更多
InP shows a very high efficiency for solar light to electricity conversion in solar cell and may present an expectation property in photocatalytic hydrogen evolution.However,it suffers serious corrosion in water dispe...InP shows a very high efficiency for solar light to electricity conversion in solar cell and may present an expectation property in photocatalytic hydrogen evolution.However,it suffers serious corrosion in water dispersion.In this paper,it is demonstrated that the stability and activity of the InP-based catalyst are effectively enhanced by applying an anti-corrosion SnO layer and In(OH)_(3)transition layer,which reduces the crystal mismatch between SnO and InP and increases charge transfer.The obtained Pt/SnO/In(OH)_(3)/InP exhibits a hydrogen production rate of 144.42μmol/g in_(3)h under visible light illumination in multi-cycle tests without remarkable decay,12_(3)times higher than that of naked In(OH)_(3)/InP without any electron donor under visible irradiation.展开更多
A robust microporous praseodymium-organic framework,{[Pr3(NTB)3(H2O)3]·(DMF)3(H2O)4}n(Pr-NTB,1),was solvothermally synthesized based on 4,4′,4″-nitrilotribenzoic acid(H3 NTB)and fully characterized.Single-cryst...A robust microporous praseodymium-organic framework,{[Pr3(NTB)3(H2O)3]·(DMF)3(H2O)4}n(Pr-NTB,1),was solvothermally synthesized based on 4,4′,4″-nitrilotribenzoic acid(H3 NTB)and fully characterized.Single-crystal X-ray diffraction analysis reveals compound 1 possesses a three-dimensional porous coordination network,in which discrete cages are connected through microporous windows.1 shows extraordinary thermal and water stability;in particular,it is stable in aqueous media from pH=3 to 11,which is outstanding in benzyl-carboxylate based MOFs.Furthermore,1 exhibits permanent porosity with the BET surface area of 156.2 m^2·g^-1 and can adsorb suitable CO2(1.14 mmol·g^-1 at 273K/1 bar)with isosteric heat of adsorption(Q(st))of 28.5 kJ·mol^-1.These features suggest that the porous material 1 is a good candidate for CO2 capture in real-world application.Notably,the integration of fluorescent property,porosity and water stability in 1 promises it as a selective fluorescent sensor for Fe^3+cation in water.展开更多
Full-spectrum underwater optical communication(UOC)is of great significance for major strategic needs including resource development,scientific exploration,and homeland security.As the core of the full-spectrum UOC sy...Full-spectrum underwater optical communication(UOC)is of great significance for major strategic needs including resource development,scientific exploration,and homeland security.As the core of the full-spectrum UOC system,photodetectors(PDs)are plagued by stringent requirements including a broadband response,intrinsic water resistance,and a high detectivity.In this work,two-dimensional(2D)halide perovskites(HPs)and corresponding PDs are constructed by stearamine(SA),representing the rarely explored long-chain aliphatic amine series,to own waterproofness,ultralow noise,and superior optoelectronic performance,which consequently enable a high suitability for UOC.By dimensionality and composition modulations to extend the absorption onset down to 1.5 eV,a broadband response covering the entire transmission window of water(>1.55 eV)for full-spectrum UOC can be obtained.Besides,featuring a high responsivity of 3.27 A·W^(-1),a peak external quantum efficiency(EQE)of 630%,fast rise/decay times of 0.35 ms/0.54 ms,a superior detectivity up to 1.35×10^(12)Jones and the capability to distinguish various waveforms and light intensities,the PDs present sensitive and persistent photoresponse underwater.As a result,proof-of-concept wireless transmission of ASCII codes in water is demonstrated.展开更多
A three-dimensional(3 D) metal-organic framework(MOF) ZnL·0.5 H_2O·0.75 DMF(H_2L=9-(pyridin-4-yl)-9 H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide) has been synthesized under solvothermal condi...A three-dimensional(3 D) metal-organic framework(MOF) ZnL·0.5 H_2O·0.75 DMF(H_2L=9-(pyridin-4-yl)-9 H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide) has been synthesized under solvothermal condition. Crystal structure analysis shows that, in ZnL, each dinuclear Zn_2(COO)_2 unit is doubly-bridged to the other two by the carbazole moieties to form the 1 D chains, which are further connected together by pyridine moieties to lead to the 3 D framework. ZnL exhibits both high structural stability and good luminescent stability in water with the pH range of 4–10. ZnL displays the luminescent quenching response for Fe^(3+) in water with good linear correlation between the quenching efficiency and the concentration with K_(sv) of 10800 M^(-1) in the low concentration range of 0–0.1 mM. Interestingly, it is observed that the sensing performance for Fe^(3+) is stable in the pH range of 4–9, enabling ZnL to detect Fe^(3+) ions in weak acidic and weak basic solutions.展开更多
The qualified finished water from water treatment plants(WTPs) may become discolored and deteriorated during transportation in drinking water distribution systems(DWDSs), which affected tap water quality seriously. Th...The qualified finished water from water treatment plants(WTPs) may become discolored and deteriorated during transportation in drinking water distribution systems(DWDSs), which affected tap water quality seriously. This water stability problem often occurs due to pipe corrosion and the destabilization of corrosion scales. This paper provides a comprehensive review of pipe corrosion in DWDSs, including corrosion process, corrosion scale formation, influencing factors and monitoring technologies utilized in DWDSs. In terms of corrosion process, corrosion occurrence, development mechanisms, currently applied assays, and indices used to determine the corrosion possibility are summarized, as well as the chemical and bacterial influences. In terms of scale formation, explanations for the nature of corrosion and scale formation mechanisms are discussed and its typical multilayered structure is illustrated. Furthermore, the influences of water quality and microbial activity on scale transformation are comprehensively discussed. Corrosion-related bacteria at the genus level and their associated corrosion mechanism are also summarized. This review helps deepen the current understanding of pipe corrosion and scale formation in DWDSs, providing guidance for water supply utilities to ensure effective measures to maintain water quality stability and guarantee drinking water safety.展开更多
River is one of the geomorphic units that are the most sensitive to tectonic activity, of which the longitudinal profile serves as a key archieve to record information on active tectonics. The stream-power incision mo...River is one of the geomorphic units that are the most sensitive to tectonic activity, of which the longitudinal profile serves as a key archieve to record information on active tectonics. The stream-power incision model is an important means to analyze channel long profiles and to extract both temporal and spatial patterns of regional tectonic activity. Analytical solutions to the steady-state and linear transient-state equations of the model provides means to calibrate drainage basin concavity,calculate channel steepness index, determine drainage divide stability, project the paleo-channel profile, and to invert the tectonic uplift rate history. Yet, not all of these functions have been implemented in the published open-source tools. Here, we developed a set of open-source codes, RiverProAnalysis, which was based on the Matlab platform and integrated all of these functions. The products of the tool set are in the format of image, text and vector files, which not only can be used for visual analysis, but be read by softwares of geographic information system. Taking examples of two transient drainage catchments in the northern margin of the Taiyuan Basin, we analyzed the long profiles of the trunk streams, identified two generations of knickpoints, and estimated the minimum amount of river incision. We combined all the trunk and tributary channels together to model the catchment-wide uplift history and found moderate increases in the uplift rates since the Middle Pliocene and rapid accelation since the late Quaternary. The inverted results are consistent with the sedimentary records in the adjacent basin. By comparing the chi value,slope, and topographic relief of both sides of the catchment divide, we concluded the stability of the drainage divide. Our tool set integrates the main functions of the modern studies on fluvial landsape, thus providing a powerful tool for analyzing river long profiles and for understanding tectonic geomorphology.展开更多
基金the financial supports from the Key Research and Development Program of Guangxi(No.GUIKE AB22080061)the Guangxi Transportation Industry Key Science and Technology Projects(No.GXJT-2020-02-08)+2 种基金the National Natural Science Foundation of China(No.52268062)the Guangxi Key Project of Nature Science Foundation(No.2020GXNSFDA238024)。
文摘To improve the soil and water stability of expansive soil slopes and reduce the probability of slope failure,novel protection systems based on polymer waterproof coatings(PWC)were used in this study.Herein,three groups of expansive soil slope model tests were designed to investigate the effects of polyester nonwovens and PWC(P-PWC)composite protection system,three-dimensional vegetation network and PWC(T-PWC)composite protection system,and nonprotection on the soil and water behavior in the slopes under precipitation–evaporation cycles.The results showed that the moisture change of P-PWC and T-PWC composite protected slopes was significantly smaller than that of bare slope,which reduced the sensitivity of slope moisture to environmental changes and improved its stability.The soil temperature of the slope protected by the P-PWC and T-PWC systems at a depth of 70 cm increased by 5.6℃ and 2.7℃,respectively.Using PWC composite protection systems exhibited better thermal storage performance,which could increase the utilization of shallow geothermal resources.Moreover,the maximum average crack widths of the bare slopes were 7.89 and 3.17 times those of the P-PWC and TPWC protected slopes,respectively,and the maximum average crack depths were 6.87 and 3 times those of the P-PWC and T-PWC protected slopes,separately.The PPWC protection system weakened the influence of hydro–thermal coupling on the slopes,inhibited the development of cracks on the slopes,and reduced the soil erosion.The maximum soil erosion of slopes protected by P-PWC and T-PWC systems was 332 and 164 times lower than that of bare slope,respectively.The P-PWC and T-PWC protection systems achieved excellent"anti-seepage and moisture retention"and anti-erosion effects,thus improving the soil and water stability of slopes.These findings can provide important guiding reference for controlling rainwater infiltration and soil erosion in expansive soil slope projects.
基金supported by the Science and Technology Planning Project of Zhejiang Provincial Department of Transportation(2021012)Zhejiang Provincial Natural Science Foundation of China under Grant(No.LGG21E080002).
文摘In general,acid aggregates are not used in combination with asphalt concrete because of their poor compatibility with the asphalt binder,which typically results in a scarce water stability of the concrete.In the present study,the feasibility of a new approach based on the combination of acid granite fine aggregate with alkaline limestone coarse aggregate and Portland cement filler has been assessed.The mineral and chemical compositions of these three materials have first been analyzed and compared.Then,the effect of different amounts of Portland cement(0%,25%,50%,75%and 100%of the total filler by weight)on the mechanical performance and water stability of the asphalt concrete has been considered.Asphalt concrete has been designed by using the Marshall method,and the mechanical performance indexes of this material,including the Marshall stability and indirect tensile strength(ITS),have been measured together with the related water stability indexes(namely the Marshall stability(RMS)and tensile strength ratio(TSR)).The results indicate that the alkaline limestone coarse aggregate and Portland cement filler can balance the drawback caused by the acid granite fine aggregate.The asphalt concrete has good mechanical performances and water stability when the amount of common limestone powder filler replaced by cement is not less than 75%.
文摘Rubber trees (Hevea brasiliensis Müll. Arg.) have been commercially cultivated for a century and a half in Asia, particularly in China, and they constitute a common element of plantation ecosystems in tropical regions. Soil health is fundamental to the sustainable development of rubber plantations. The objective of the study is to explore the influence of different complex ecological cultivation modes on the stability of soil aggregates in rubber based agroforestry systems. In this study, the ecological cultivation mode of rubber—Alpinia oxyphylla plantation, the ecological cultivation mode of rubber—Phrynium hainanense plantations, the ecological cultivation mode of rubber—Homalium ceylanicum plantations and monoculture rubber plantations were selected, and the particle size distribution of soil aggregates and their water stability characteristics were analyzed. The soil depth of 0 - 20 cm and 20 - 40 cm was collected for four cultivation modes. Soil was divided into 6 particle levels > 20 cm. soil was divided into 6 particle levels > 5 mm, 2 - 5 mm, 1 - 2 mm, 0.5 - 1 mm, 0.25 - 0.5 mm, and 0.053 - 0.25 mm according to the wet sieve method. The particle size proportion and water stability of soil aggregates were determined by the wet sieve method. The particle size proportion and water stability of soil aggregates under different ecological cultivation modes were analyzed. The results showed that under different ecological cultivation modes in the shallow soil layer (0 - 20 cm), the rubber—Alpinia oxyphylla plantation and the rubber—Phrynium hainanense plantation promoted the development of dominant soil aggregates towards larger size classes, whereas the situation is the opposite for rubber—Homalium ceylanicum plantation. In soil layer (20 - 40 cm), the ecological cultivation mode of rubber—Phrynium hainanense plantation developed the dominant radial level of soil aggregates to the diameter level of large aggregates. Rubber—Alpinia oxyphylla plantation and rubber—Homalium ceylanicum plantation, three indicators, including the water-stable aggregate content R<sub>0.25</sub> (>0.25 mm water-stable aggregates), mean weight diameter (MWD), and geometric mean diameter (GMD), were all lower than those in the rubber monoculture mode. However, in the rubber—Phrynium hainanense plantation, the water-stable aggregate content R<sub>0.25</sub>, mean weight diameter, and geometric mean diameter were higher than in the rubber monoculture mode, although these differences did not reach statistical significance.
基金Financial support from National Key R&D Program of China(2016YFE0125600)National Natural Science Foundation of China(Grant No.51308504)+1 种基金Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China(IRT_16R67),Scientific&Technological Project of Henan Province(152102310068)Training Program of Young-backbone teachers in Universities of Henan Province of China are gratefully acknowledged.
文摘The fibre pullout test was conducted to investigate the influence of the water stability on the bond behaviour between the Magnesium phosphate cement(MPC)matrix and the steel fibre.The composition of the MPC-matrix and the immersion age of the specimens are experimentally investigated.The average bond strength and the pullout energy are investigated by analysing the experimental results.In addition,the microscopic characteristics of the interface transition zone are investigated using scanning electron microscopy(SEM).The experimental results showed that the bond performance between the MPC-matrix and the steel fibre decreased significantly with the increase of the duration of immersion in water.The average bond strength between the steel fibre and the MPC-matrix reduced by more than 50%when the specimens were immersed in the water for 28 days.The effect of the water on the interface between the steel fibre and the MPC-matrix was found to be more significant compared to the composition of the MPC-matrix.In addition,the MgO-KH2PO4 mole ratio of the MPC significantly influenced the water stability of the interface zone between the steel fibre and MPC-matrix.
基金support by the National Natural Science Foundation of China(nos.21725101,21673213,21871244,and 21521001).
文摘Water and moisture stability have been recognized as one of the most important characteristics of metal–organic frameworks(MOFs)in regards to their future applications.Nonetheless,most MOFs are water-labile to some degree.One promising solution for the collapse of MOFs toward water is surface hydrophobic modification.
文摘The use of concrete wastes in asphalt treated base (ATB) not only prevents environmental pollution but also protect stone resources. But the strength of the concrete wastes is often weaker than nature aggregates and the binding properties with asphalt is poor. So it difficult to meet the requirements of asphalt treated base. In this paper,The organosilicone waterproofing material is used to improve the performance of concrete wastes and the long term immersing frozen-thaw cycle test were used to investigate the anti-stripping performance of limestone asphalt mixture,concrete wastes asphalt mixture and concrete wastes asphalt mixture having treated by organosilicone waterproofing material. The experimental results show that organosilicone waterproofing material can improve the water stability of asphalt mixture. The use of concrete wastes in ATB is achievable.
基金supported by the Fundamental Research Funds for the Central Universities (No.22120210027).
文摘Porous polyurethane concrete(PPUC)is a novel material for permeable pavements and is considered as an alternative to porous asphalt or porous cement concrete.However,studies of the mechanical properties of PPUC are still insufficient.In this study,the comprehensive mechanical properties and water stability of PPUC with different gradations and polyurethane dosages were investigated,and its water damage mechanism was preliminarily explored.The results show that the flexural strength and Marshall stability of PPUC can more easily reach the index in the standards of porous cement concrete or porous asphalt,while the compressive strength and abrasion resistance are the weak points of its mechanical properties and need to be further optimized.The mechanical properties and water stability of PPUC were effectively improved by increasing the polyurethane dosage and using continuously graded aggregates.PPUC is more susceptible to water damage because water reacts with the residual isocyanate groups within the polyurethane film to generate carbon dioxide gas,which reduces the cohesion and adhesion performance of polyurethane film.This study provides a comprehensive understanding of the mechanical properties of PPUC and an initial insight into the mechanism of water damage.
基金Mazda FoundationTEPCO Memorial FoundationJapan Society for the Promotion of Science,Grant/Award Numbers:19K05633,21K14428。
文摘Flexible p–n thermoelectric generator(TEG)technology has rapidly advanced with power enhancement and size reduction.To achieve a stable power supply and highly efficient energy conversion,absolute chemical stability of n-type materials is essential to ensuring large temperature differences between device terminals and ambient stability.With the aim of improving the long-term stability of the n-type operation of carbon nanotubes(CNTs)in air and water,this study uses cationic surfactants,such as octylene-1,8-bis(dimethyldodecylammonium bromide)(12-8-12),a gemini surfactant,to stabilize the nanotubes in a coating,which retains the n-doped state for more than 28 days after exposure to air and water in experiments.TEGs with 10 p-n units of 12-8-12/CNT(n-type)and sodium dodecylbenzene sulfonate/CNT(p-type)layers are manufactured,and their water stability is evaluated.The initial maximum output of 16.1μW(75 K temperature difference)is retained after water immersion for 40 days without using a sealant to prevent TEG module degradation.The excellent stability of these CNT-based TEGs makes them suitable for underwater applications,such as battery-free health monitoring and information gathering systems,and facilitates the development of soft electronics.
文摘With the development of the production scale and the increasing of the process technologies and facilities,product quality and the requirement of water supply continuously put forward new requirements to water treatment technology.The practice of the water saving technology should ensure the safe of water using and the innovation of technique data.Especially the stabilization of water quality should also meet the production at full capacity,reduce equipment failure rate and maintain the sustainable development under the condition of the minimal resource consumption.This article describes the practice of Baosteel saving technology,water-saving ideas from the system to start,according to Baosteel raw water intake requirements and process water and drainage characteristics,water and salt water tidal according to changes in the Yangtze River and the Yangtze River upstream and downstream trends in water discharge on water quality factors,established the electrical conductivity,chloride ion indicators for the control of the Yangtze River water,the implementation of 'avoid salt build light' water at the same time,combined with the actual situation of water pollution in the Yangtze River,the use of force coefficient correlation theory,the implementation of 'avoid taking clear pollution' to ensure the quality of raw water intake. System and cascade utilization of water,process water,based on whole plant water balance testing, analysis,technical parameters of the system and processes the user running the pressure balance pipe network,and implemented a stabilization system to adjust water pressure,reducing the water supply network systemwater loss;application of electrochemical principles,the implementation of the protection of underground pipes Baosteel,implemented a water use,steps to use,the operating mode of water supply in series to increase water reuse,reduce wastewater discharge system. Water quality stability and water-saving in the process;carry out water quality stability technology in the different complicated processes of the steel industry;apply the environmental protection and water quality, sterilization,non-phosphorus and low phosphorus technologies which are suitable for high concentration of circulating water.By these technologies,we achieved the water-saving in the process in different seasons and solved the technical problems affecting production such as equipment corrosion,scaling and the formation of the water quality proprietary technology under the conditions of high heat load production as well. The use of water ecological conservation and biological treatment technology:the implementation of the reservoir to the ecological technology is characterized by food chain and wetland environmental technology characterized by plants chain.Reservoir ecological management techniques in the use of natural conditions, wind direction,temperature,light and fish biomass in the reservoir water level regulation of balance and combination of organic,control and resolve the reservoirs in spring and summer algae problems and water quality changes rot of the 'fresh' operating problems.The artificial wetland technology develops a new way for metallurgical plants’ wastewater treatment.All the measures by the implementation of water to create the conditions for the system to achieve the water target of constant innovation,reaching the advanced level of iron and steel enterprises.
基金This work was financially by the Self-Financing Technology Plan Project of Foshan(2020001005386).
文摘For evaluating the water stability of hot-mixed renewable asphalt mixture(HRM),the traditional methods are all tested under still water conditions.Except for damage in still water conditions,the hydrodynamic pore pressure generated by the tire driving on the surface water has a great impact.Thus,the RAP contents of the HRMs were designed at 0%,30%,45%and 60%with AC-25 gradation.Then,the self-designed evaluation methods of water stability and dynamic modulus were studied.Finally,the mechanism of the influence of hydrodynamic pore pressure damage on HRMs was studied.The results show that the water stability of HRM containing 30%RAP is equivalent to that of 45%RAP,and the water stability of HRM containing 60%RAP decreases significantly.The Contabro test after MIST treatment can be used as an evaluation method for hydrodynamic pore pressure damage on HRM.Low-speed,heavy-load traffic and larger RAP content have greater damage to the mixture after hydrodynamic pore pressure damage.The performance differences between the aged bitumen and pure bitumen,as well as the aged minerals and new minerals,are continuing to be enlarged in hydrodynamic pore pressure conditions,finally affecting the water stability and dynamic modulus of the HRMs.
基金the Jiangsu Provincial Science and Technology Department’s Social Development-Major Science and Technology Demonstration Project(Grant No.BE2018697)the Jiangsu Provincial Science and Technology Department Social Development Project(Grant No.BE2017704)the Scientific Research Project of the Suqian Municipal Transportation Bureau.
文摘A phosphogypsum-based subgrade stabilizer(PBSS)was formulated using industrial by-product phosphogypsum(PG),mixed with slag and calcium-silicon-rich active material(GSR).The active powder(AP)was used to modify PBSS,and PBSS-AP was obtained.PBSS and PBSS-AP were each mixed with 10%silty soil,and cement and lime(CAL:5%lime+2%cement)were used as the traditional material for comparative experiments.Samples were cured under standard conditions,and tested for unconfined compressive strength(UCS),water stability,volume expansion,and leachate,to explore the stabilization effect of the three solidified materials on silty soil.The results showed that the comprehensive performance of sility soil mixed with 12%PBSS-AP was the best.The CaO,SiO_(2)and Al_(2)O_(3)provided by PG,Slag and GSR will react with water to form a stable C-S-H gel,which is conducive to stabilizing the soil.Field application results showed that the compaction exceeded 95%,the deflection was 144.9 mm,and UCS was 2.5 MPa after 28 days.These findings indicated that PBSS-AP is an effective stabilizer for subgrade soils.
基金The data used in this study were obtained during a research project entitled“Seasonal variations of physical parameters and stratification of water column in the south-western deep water zone of the Caspian Sea”,No.:393-012-03,fundedsupported by Iranian National Institute for Oceanography and Atmospheric Science.
文摘Variations of seawater properties and stratification of water column in the southern deep water zone(470 m depth)of the Caspian Sea were evaluated based on field measured data.Variations of physical characteristics(temperature,salinity,density and sound speed)of seawater mainly were limited to the upper 100 m layers.Below this layer,seasonal changes of seawater parameters were minor.Vertical structure of temperature in the southern Caspian Sea waters was characterized by a significant seasonal thermocline approximately between 20 and 50 m depths in summer with a vertical gradient of around 16℃.Destruction of the thermocline occurred with the general cooling of the sea surface water and deepening of the mixed layer during late of autumn and winter.Frequency of stability in water column often across the upper layers(surface mixed and thermocline)was more than deeper levels.Variations of salinity were around 12.4 PSU in the time of measurements.Structures of thermocline and pycnocline were characterized by a significant homogeneity especially in offshore stations during the year.According to high agreement between density and temperature in the Caspian Seawater,a strong seasonal pycnocline was observed in the position of the thermocline.Furthermore,structure of sound speed variations followed vertical variations of seawater temperature.Variations of chemical characteristics(dissolved oxygen and pH)of seawater mainly were continued from sea surface to near the sea bed in deep water zone.
文摘InP shows a very high efficiency for solar light to electricity conversion in solar cell and may present an expectation property in photocatalytic hydrogen evolution.However,it suffers serious corrosion in water dispersion.In this paper,it is demonstrated that the stability and activity of the InP-based catalyst are effectively enhanced by applying an anti-corrosion SnO layer and In(OH)_(3)transition layer,which reduces the crystal mismatch between SnO and InP and increases charge transfer.The obtained Pt/SnO/In(OH)_(3)/InP exhibits a hydrogen production rate of 144.42μmol/g in_(3)h under visible light illumination in multi-cycle tests without remarkable decay,12_(3)times higher than that of naked In(OH)_(3)/InP without any electron donor under visible irradiation.
基金Financially supported by the National Natural Science Foundation of China (21501086,21701978,21801108)the Shandong Provincial Natural Science Foundation (ZR2014BQ035)+1 种基金the Youth Innovation Team of Shandong Colleges and Universities (2019KJC027)the financial supports from Liaocheng University (318051401)the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry
文摘A robust microporous praseodymium-organic framework,{[Pr3(NTB)3(H2O)3]·(DMF)3(H2O)4}n(Pr-NTB,1),was solvothermally synthesized based on 4,4′,4″-nitrilotribenzoic acid(H3 NTB)and fully characterized.Single-crystal X-ray diffraction analysis reveals compound 1 possesses a three-dimensional porous coordination network,in which discrete cages are connected through microporous windows.1 shows extraordinary thermal and water stability;in particular,it is stable in aqueous media from pH=3 to 11,which is outstanding in benzyl-carboxylate based MOFs.Furthermore,1 exhibits permanent porosity with the BET surface area of 156.2 m^2·g^-1 and can adsorb suitable CO2(1.14 mmol·g^-1 at 273K/1 bar)with isosteric heat of adsorption(Q(st))of 28.5 kJ·mol^-1.These features suggest that the porous material 1 is a good candidate for CO2 capture in real-world application.Notably,the integration of fluorescent property,porosity and water stability in 1 promises it as a selective fluorescent sensor for Fe^3+cation in water.
基金the Natural Science Foundation of Jiangsu Province(Nos.BK20190443,BK20160815)Young Elite Scientists Sponsorship Program by Jiangsu CAST(No.JS19TJGC132574)+3 种基金2019 Overseas Students Science and Technology Innovation Project Selection Funding o f Nanjing,Fundam ental Research Funds for the Central Universities(Nos.30919011298,30919011299,30919012107)the National Key R&D Program of China(No.2017YFA0305500)the National Natural Science Foundation of China(Nos.61725402,11604152,51672132)the Six top talent innovation teams of Jiangsu Province(No.TD-XCL-004).
文摘Full-spectrum underwater optical communication(UOC)is of great significance for major strategic needs including resource development,scientific exploration,and homeland security.As the core of the full-spectrum UOC system,photodetectors(PDs)are plagued by stringent requirements including a broadband response,intrinsic water resistance,and a high detectivity.In this work,two-dimensional(2D)halide perovskites(HPs)and corresponding PDs are constructed by stearamine(SA),representing the rarely explored long-chain aliphatic amine series,to own waterproofness,ultralow noise,and superior optoelectronic performance,which consequently enable a high suitability for UOC.By dimensionality and composition modulations to extend the absorption onset down to 1.5 eV,a broadband response covering the entire transmission window of water(>1.55 eV)for full-spectrum UOC can be obtained.Besides,featuring a high responsivity of 3.27 A·W^(-1),a peak external quantum efficiency(EQE)of 630%,fast rise/decay times of 0.35 ms/0.54 ms,a superior detectivity up to 1.35×10^(12)Jones and the capability to distinguish various waveforms and light intensities,the PDs present sensitive and persistent photoresponse underwater.As a result,proof-of-concept wireless transmission of ASCII codes in water is demonstrated.
基金supported by Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) (YX03001)Jiangsu Province Double Innovation Talent Program (090300014001)Nanjing University of Posts & Telecommunications (NY212004)
文摘A three-dimensional(3 D) metal-organic framework(MOF) ZnL·0.5 H_2O·0.75 DMF(H_2L=9-(pyridin-4-yl)-9 H-carbazole-3,6-dicarboxylic acid, DMF=N,N-dimethylformamide) has been synthesized under solvothermal condition. Crystal structure analysis shows that, in ZnL, each dinuclear Zn_2(COO)_2 unit is doubly-bridged to the other two by the carbazole moieties to form the 1 D chains, which are further connected together by pyridine moieties to lead to the 3 D framework. ZnL exhibits both high structural stability and good luminescent stability in water with the pH range of 4–10. ZnL displays the luminescent quenching response for Fe^(3+) in water with good linear correlation between the quenching efficiency and the concentration with K_(sv) of 10800 M^(-1) in the low concentration range of 0–0.1 mM. Interestingly, it is observed that the sensing performance for Fe^(3+) is stable in the pH range of 4–9, enabling ZnL to detect Fe^(3+) ions in weak acidic and weak basic solutions.
基金supported by the Shandong Provincial Key Research and Development Program- Major Scientific and Technological Innovation Project (No. 2020CXGC011406)the R&D project of Suzhou Water Resource and Management (No. 2020011)the National Water Major Project (Nos. 2018ZX07111-006 , 2012ZX07404-002 , 2012ZX07403-001)。
文摘The qualified finished water from water treatment plants(WTPs) may become discolored and deteriorated during transportation in drinking water distribution systems(DWDSs), which affected tap water quality seriously. This water stability problem often occurs due to pipe corrosion and the destabilization of corrosion scales. This paper provides a comprehensive review of pipe corrosion in DWDSs, including corrosion process, corrosion scale formation, influencing factors and monitoring technologies utilized in DWDSs. In terms of corrosion process, corrosion occurrence, development mechanisms, currently applied assays, and indices used to determine the corrosion possibility are summarized, as well as the chemical and bacterial influences. In terms of scale formation, explanations for the nature of corrosion and scale formation mechanisms are discussed and its typical multilayered structure is illustrated. Furthermore, the influences of water quality and microbial activity on scale transformation are comprehensively discussed. Corrosion-related bacteria at the genus level and their associated corrosion mechanism are also summarized. This review helps deepen the current understanding of pipe corrosion and scale formation in DWDSs, providing guidance for water supply utilities to ensure effective measures to maintain water quality stability and guarantee drinking water safety.
基金supported by the National Natural Science Foundation of China (Grant No. 41802227)。
文摘River is one of the geomorphic units that are the most sensitive to tectonic activity, of which the longitudinal profile serves as a key archieve to record information on active tectonics. The stream-power incision model is an important means to analyze channel long profiles and to extract both temporal and spatial patterns of regional tectonic activity. Analytical solutions to the steady-state and linear transient-state equations of the model provides means to calibrate drainage basin concavity,calculate channel steepness index, determine drainage divide stability, project the paleo-channel profile, and to invert the tectonic uplift rate history. Yet, not all of these functions have been implemented in the published open-source tools. Here, we developed a set of open-source codes, RiverProAnalysis, which was based on the Matlab platform and integrated all of these functions. The products of the tool set are in the format of image, text and vector files, which not only can be used for visual analysis, but be read by softwares of geographic information system. Taking examples of two transient drainage catchments in the northern margin of the Taiyuan Basin, we analyzed the long profiles of the trunk streams, identified two generations of knickpoints, and estimated the minimum amount of river incision. We combined all the trunk and tributary channels together to model the catchment-wide uplift history and found moderate increases in the uplift rates since the Middle Pliocene and rapid accelation since the late Quaternary. The inverted results are consistent with the sedimentary records in the adjacent basin. By comparing the chi value,slope, and topographic relief of both sides of the catchment divide, we concluded the stability of the drainage divide. Our tool set integrates the main functions of the modern studies on fluvial landsape, thus providing a powerful tool for analyzing river long profiles and for understanding tectonic geomorphology.
