The model performance in simulating soil water content(SWC) is crucial for successfully modeling earth’s system,especially in high mountainous areas.In this study,the performance of Community Land Model 5.0(CLM5.0) i...The model performance in simulating soil water content(SWC) is crucial for successfully modeling earth’s system,especially in high mountainous areas.In this study,the performance of Community Land Model 5.0(CLM5.0) in simulating liquid SWC was evaluated against observations from nine in-situ sites in the upper reach of the Heihe River Watershed(HRW),Northwest China.The CLM5.0 shows reliable performance in the study area with correlation coefficients(R) ranging between 0.79–0.93,root mean standard errors(RMSE)ranging between 0.044–0.097 m^(3)/m^(3),and the mean bias(BIAS) ranging between-0.084–0.061 m^(3)/m^(3).The slightly worse performance of CLM5.0 than CLM4.5 on alpine meadow and grassland is mainly caused by the revised canopy interception parameterization.The CLM5.0 overestimates interception and underestimates evapotranspiration(ET) on both alpine meadow and grassland during the growth period.The systematical overestimations at all the grassland sites indicate that the underestimation of ET is much larger than the overestimation of interception on grassland during growth period,while the errors of simulated interception and ET are partially canceled out on alpine meadow.Moreover,the underestimation of ET is more responsible for the overestimation of SWC than the overestimation of interception in the high mountainous area.It is necessary to estimate reasonable empirical parameter α(proportion of leaf water collection area) in interception parameterization scheme and further improve the dry surface layerbased soil evaporation resistance parameterization introduced in CLM5.0 in future researches.The performance of CLM5.0 is better under completely frozen stage than thawing stage and freezing stage,because of low variations of liquid SWC caused by extremely low hydraulic conductivity of soils.The underestimation of liquid SWC under frozen state is caused by underestimation of soil temperature,which leads to more ice mass and less liquid water in total water content.展开更多
New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable...New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.展开更多
China's infrastructure has gradually achieved large-scale development,and transportation construction has also shifted from east to west,transitioning from plains to mountainous areas.High-fill embankments of diff...China's infrastructure has gradually achieved large-scale development,and transportation construction has also shifted from east to west,transitioning from plains to mountainous areas.High-fill embankments of different sizes in mountainous areas are unavoidable,and the settlement of high-fill embankments is usually the most concerned issue in high-fill projects.According to the current research of highway projects,most of the high embankments in mountainous areas are soil-rock mixed embankments or rock-filled embankments,and their post-construction settlements are directly related to construction technology and the type of filler used.In this paper,the problems in the settlement control of earth-filled embankment and related factors are analyzed in detail.The settlement control technology of high-fill embankment in high-cold and high-altitude areas is also discussed,so as to ensure the overall quality of high-fill embankment.展开更多
With the recent development of high entropy materials, an alternative approach to develop advanced functional materials with distinctive properties that show improved values compared to conventional materials has been...With the recent development of high entropy materials, an alternative approach to develop advanced functional materials with distinctive properties that show improved values compared to conventional materials has been provided. The high entropy concept was later successfully transferred to metal fluorides and high entropy fluorides(HEFs) were successfully synthesized. Owing to their high theoretical specific capacities in energy storage applications, HEFs were utilized as cathode materials for lithiumion batteries(LIBs) and their underlying storage mechanisms were investigated. Instead of a step-bystep reduction of each individual metal cation, the HEFs seem to exhibit a single-step reduction process,indicating a solid solution compound instead of merely a mixture of different metal fluorides. It was also observed that the electrochemical behavior of the HEFs depends on each individual incorporated element. Therefore, by altering the elemental composition, new materials that exhibit improved electrochemical properties can be designed. Remarkably, HEFs with seven incorporated metal elements exhibited a better cycling stability as well as a lower hysteresis compared to binary metal fluorides.These findings offer new guidelines for material design and tailoring towards high performance LIBs.展开更多
[Objective] The research aimed to study the distribution characteristics of high temperature damage and its influence on the rice yield in the area along Huaihe River.[Method] The meteorological data of 10 stations in...[Objective] The research aimed to study the distribution characteristics of high temperature damage and its influence on the rice yield in the area along Huaihe River.[Method] The meteorological data of 10 stations in the area along Huaihe River during 1965-2009 and the yield data of Anhui single-season middle rice during 1967-2006 were selected.The occurrence characteristic of summer high temperature weather and the intensity of high temperature damage in the area along Huaihe River were analyzed.Based on the previous high temperature damage index of rice,Changfeng County where was the typical rice planting zone in the area along Huaihe River was as the representation,and the yield damage loss rate risk of high temperature damage in Changfeng was analyzed by combining with the historical yield data.[Result] The high temperature weather in the area along Huaihe River frequently happened.The high temperature damage presented "N" shape trend from west to east.The occurrence frequency of high temperature weather in Huainan and Bengbu where were in the middle area along Huaihe River was more and was less in Huoqiu and Shouxian where were near the south mountain area of Anhui.The occurrence time mainly focused from the middle and last dekads of July to the first dekad of August after the plum rain.At this time,it was the booting,heading and flowering periods of single-season middle rice,and the influence on the rice yield was obvious.The damage loss rate of single-season middle rice yield in Changfeng County along Huaihe River continued to increase as the increasing of high temperature damage duration.But the occurrence probability decreased.The intensity grade of high temperature damage disaster loss rate which happened frequently concentrated mainly in levels I and II.The longer the high temperature damage duration in the reproductive growth stage of rice was,the bigger the damage loss rate was.But the corresponding occurrence probability was small,and vice versa.[Conclusion] The research provided the reference for assessing the high temperature disaster risk.展开更多
Zirconia-ceria mixed oxide powders were prepared by high temperature aging method.The effects of the temperature and the time of aging, cerium content and calcination on powder performance were studied.The result show...Zirconia-ceria mixed oxide powders were prepared by high temperature aging method.The effects of the temperature and the time of aging, cerium content and calcination on powder performance were studied.The result shows that high temperature aging is an efficient way of preparation of ZrO2-CeO2 mixed oxide powders with high specific surface area and good thermal stability, and that addition of a small amount of cerium to hydrous zirconia can promote the preparation of high specific surface area powders.展开更多
The aim of this study was to investigate the effects of high dietary fluoride (F) on serum biochemistry and oxidative damage in broiler chickens. 280 one-day-old healthy avian broiler chickens were randomly allotted i...The aim of this study was to investigate the effects of high dietary fluoride (F) on serum biochemistry and oxidative damage in broiler chickens. 280 one-day-old healthy avian broiler chickens were randomly allotted into four equal groups and fed with a corn-soybean basal diet containing 22.6 mg·F/kg (control group) or same basal diets supplemented with 400, 800, and 1200 mg·F/kg (high F groups I, II, and III) in the form of sodium fluoride for 42 days. At 42 days of age, the serum F content was markedly higher in the three high F groups than that in the control group. From 28 to 42 days of age, the contents of serum total protein (TP) and albumin (ALB) were significantly lower in the three high F groups. From 14 to 42 days of age, the activities of alkaline phosphatase (ALP), alanine aminotransferase (ALT) and the creatinine (Crea) contents in the serum showed a marked increase in the three high F groups;aspartate aminotransferase (AST) activity and uric acid (Ua) content were significantly increased, and a significant increase in the content of malondialdehyde (MDA) along with marked decreases in the activities of total superoxide dismutase (T-SOD), glutathione peroxidase (GSH-Px), catalase (CAT), the glutathione (GSH) content and the ability to inhibit hydroxyl radical were observed in the high F groups II and III. In conclusion, F has accumulated in the blood circulatory system and dietary F in the range of 800 - 1200 mg/kg could significantly induce abnormalities of bone, liver and kidney, inhibit the synthesis of protein, enhance lipid peroxidation and disturb the antioxidative system of broiler chickens.展开更多
Quickly extraction of building information technology is an important application in urban development planning, electronic information, national defense and others. This paper takes Landsat-8 multispectral and panchr...Quickly extraction of building information technology is an important application in urban development planning, electronic information, national defense and others. This paper takes Landsat-8 multispectral and panchromatic data as data source, using the local variance method to select the optimal segmentation scale, normalized difference vegetation index (NDVI) and the normalized building index (NDBI) and panchromatic brightness value of an object oriented classification rule extraction. The high vegetation coverage area of buildings, and through the spatial relationships and distinguishing feature of collections of buildings independent buildings and villages. The results showed that Google earth high resolution image analysis and accuracy evaluation. the results of the extraction based on the overall accuracy of village extraction was 83%, the accuracy of extraction of independent buildings was 70%, according to the L8 remote sensing data, object oriented classification method can quickly and accurately extract the high vegetation coverage area of the building.展开更多
Thirty-two Wistar rats were divided randomly into four groups of eight with six females and two males in each group. The rats were exposed to high fluoride drinking water (45 mg F- L-1 from 100 mg NaF L-1), low dietar...Thirty-two Wistar rats were divided randomly into four groups of eight with six females and two males in each group. The rats were exposed to high fluoride drinking water (45 mg F- L-1 from 100 mg NaF L-1), low dietary iodine (0.0855 mg kg-1), or both together in order to assess the effects of these three regimens on the thyroid function of the offspring rats. After the animal model was established, the offspring rats were bred and 10-, 20-, 30-, 60-, and 90-d-old rats were used for the experiment. The treatments for the offspring rats were the same as those of their parents. In comparison with control rats, the relative thyroid glands were changed by three regimens, but the mean values of thyroid weight in the experimental groups saw no marked difference. Serum TT3 levels were increased in all stages in the low iodine (LI) group. In the high fluoride (HiF) group, increase in TT3 levels was observed except in 20-d-old rats. Decrease in TT3 at 20- and 90-d and increase in TT3 at 30- and 60-d were found in HiF+LI group. Serum TT4 levels first saw an increase, and then dropped in the LI and HiF+LI group. However, an increase in TT4 was found in the HiF group. The levels of TSH in serum rocketed at d 20, and then dropped in the next stages in experimental groups. The results suggested that thyroid disorder could be induced by high flroride in drinking water, low iodine diet, or both of them. Exposure time to fluoride or low iodine diet was one of the important factors that fluoride can induce the development of thyroid dyfunction.展开更多
AIM:To estimate the cost-benefit of endoscopic screening strategies of esophageal cancer(EC)in high-risk areas of China. METHODS:Markov model-based analyses were conducted to compare the net present values(NPVs)and th...AIM:To estimate the cost-benefit of endoscopic screening strategies of esophageal cancer(EC)in high-risk areas of China. METHODS:Markov model-based analyses were conducted to compare the net present values(NPVs)and the benefit-cost ratios(BCRs)of 12 EC endoscopic screening strategies.Strategies varied according to the targeted screening age,screening frequencies,and follow-up intervals.Model parameters were collected from population-based studies in China,published literatures,and surveillance data. RESULTS:Compared with non-screening outcomes,all strategies with hypothetical 100 000 subjects saved life years.Among five dominant strategies determined by the incremental cost-effectiveness analysis,screening once at age 50 years incurred the lowest NPV(international dollar-I$55 million)and BCR(2.52).Screening six times between 40-70 years at a 5-year interval[i.e., six times(40)f-strategy]yielded the highest NPV(I$99 million)and BCR(3.06).Compared with six times(40)fstrategy,screening thrice between 40-70 years at a 10-year interval resulted in relatively lower NPV,but the same BCR. CONCLUSION:EC endoscopic screening is cost-beneficial in high-risk areas of China.Policy-makers should consider the cost-benefit,population acceptance,and local economic status when choosing suitable screening strategies.展开更多
There are three abnormally high porosity zones developed in buried Paleogene nearshore subaqueous fan and sublacustrine fan clastic reservoirs at 2,800-3,200 m, 3,250-3,700 m and 3,900-4,400 m, respectively, within th...There are three abnormally high porosity zones developed in buried Paleogene nearshore subaqueous fan and sublacustrine fan clastic reservoirs at 2,800-3,200 m, 3,250-3,700 m and 3,900-4,400 m, respectively, within the Shengtuo area of the Dongying Sag. Here the porosity of reservoirs buried deeper than 4,000 m can still be greater than 20%. Investigation of these three abnormally high porosity(AHP) zones in the 3rd to 4th member of the Paleogene Shahejie Formation in the Shengtuo area was carried out with utilization of core observation, thin section identification, SEM observation, image analysis, core physical property testing and other technical methods. The results show that, the AHP zones in 2,800-3,200 m and 3,250-3,700 m are visible pores primary AHP zones dominated by significant primary intergranular pores(more than 50% of the total porosity), while secondary pores and micropores in authigenic clays may develop in some reservoirs. AHP reservoirs in the AHP zone of 3,900-4,400 m are dominated by micropores in matrix, visible pores are mainly grain dissolution pores but with low absolute content(< 1%), so this zone belongs to the micropores primary AHP zone. The genesis of the three AHP zones was studied to distinguish between porosity enhancement and porosity preservation. Our research shows that, in deeply buried clastic reservoirs in the Shengtuo area, mineral dissolution occurred in a relatively closed diagenetic system with high temperature and high salinity. Reservoir rocks underwent extensive feldspar dissolution, while detrital carbonate grains and carbonate cements show no evidence of extensive dissolution. Although significant feldspar dissolution pores developed, feldspar dissolution enhanced porosity only a little due to the precipitation of almost isovolumetric dissolution products in the nearby primary intergranular pores in forms of authigenic clays and quartz cements. Net enhanced porosity originating from feldspar dissolution is generally less than 0.25%. Thus, the subsurface dissolution has little impact on the mid-deep buried high porosity reservoirs. Reservoirs in braided channels of middle fans in sublacustrine fans and reservoirs in the middle-front of fan bodies of nearshore subaqueous fans provide the basis for the development of AHP zones. The shallow development of fluid overpressure and early hydrocarbon emplacement have effectively retarded compaction and carbonate cementation, so that the high porosity in the superficial layers is preserved in the mid-deep layers. These are the main controlling factors in the development of AHP zones.展开更多
In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamo...In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamorphic reactions. In addition to garnet, jadeititic-clinopyroxene and rutile, other peak stage (M2) minerals in some gneisses include phengite, aragonite and coesite or quartz pseudomorphs after coesite. The typical peak-stage mineral assemblages in gneisses are characterized by garnet + jadeitic-clinopyroxene + rutile + coesite, garnet + jadeitic-clinopyroxene + phengite + rutile ± coesite and garnet + jadeitic-clinopyroxene + aragonite + rutile ± coesite. The grossular content (Gro) in garnet is high and may reach 50. 1 mol%. The SiO2 content of phengite ranges from 54.37% to 54.84% with 3.54-3.57 p.f.u. Quartz pseudomorphs after coesite occur as inclusions in garnet.The gneisses of the Donghai area have been subjected to multistage recrystallization and exhibit a closewise P-T展开更多
Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivit...Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivity(45%) was similar to ZSM-5-OH synthesized via a hydroxide route. However, ZSM-5-F showed much longer lifetime(305 h) compared with ZSM-5-OH(157 h) in spite of similar crystal size and aluminum content. Characterization by NH_3-TPD, Py-IR, OH-IR, SEM, TG-DTA, XRD and ~1H MAS NMR techniques indicated that the enhanced catalytic performance of ZSM-5-F is attributed to the fewer structural defects in the form of internal silanol groups and silanol nests.展开更多
The tea tree [Camellia sinensis (L) Kuntze] is one of the world’s economic crops. It is an especially important crop for southern China. Environmental factors related to the tea yield and quality in some high mountai...The tea tree [Camellia sinensis (L) Kuntze] is one of the world’s economic crops. It is an especially important crop for southern China. Environmental factors related to the tea yield and quality in some high mountain areas of China are identified in this paper. These factors are: geology, topography, climate, hydrology, soil and vegetation. Climatological factors are the most important. Using data collected from meteorological stations which are situated at the summit and the base of high mountains, this paper discusses ecological climatic problems in growing tea in China. The ecological climatic characteristics of the famous tea areas mainly included are as follows: more . amounts of clouds and fog, less percentage of sunshine, abundant rainfall and high relative humidity in the air, temperatures that rise and fall slowly, daily and annual temperature ranges that are smaller, more days that are suitable for tea growing and low wind speeds in the lee-sides and valleys of mountains. All of these展开更多
The deformation fracture and stability of mountain under the earthquake action is an important issue that arouses concern of researchers in the field of engineering geology.The authors,from 2000 to 2006, selected the ...The deformation fracture and stability of mountain under the earthquake action is an important issue that arouses concern of researchers in the field of engineering geology.The authors,from 2000 to 2006, selected the 1933 earthquake in Diexi zone as a typical study site to carry out the genetic mechanism research of mountain deformation-fracture caused by earthquake; in order to have comparability,the breadth展开更多
This paper presents a paleoflood study to determine the flood frequency of the Changjiang River, based on core cj0702, taken from the Changjiang River subaqueous delta. We identified flood deposits by means of high-re...This paper presents a paleoflood study to determine the flood frequency of the Changjiang River, based on core cj0702, taken from the Changjiang River subaqueous delta. We identified flood deposits by means of high-resolution grain-size variation, sensitive population, geochemical indexes and magnetic susceptibility. The core covers a time span of 120 years by 210 Pb dating and was sampled at 1–2 cm intervals. Grain size, geochemical elements, and physical parameters were analyzed. The results indicate that the sediment of the core is mainly composed of silt and clay, as well as groups of interbedded silt, clay silt, and clay. Vertically, the grain size pattern was controlled by seasonal variations in water discharge and by the sediment input in winter from the abandoned Huanghe River delta. River flooding caused extreme values in all our measured parameters. We identified more than 20 flood events that occurred since 1887 using the physical parameter analysis method. The environmentally sensitive component of sediment grain size(14.32–96.39 μm) contribution>30%, Zr/Rb ratio>1.5, and magnetic susceptibility>16 were selected as the criteria for flood identification generally. We also found that floods that had taken place in the upstream, midstream, or downstream parts of the river were clearly identified by these indexes while the large-scale floods that covered the whole drainage area did not leave clear indications in the sediment record. This study for identification of flood events is of great significance for understanding hyperpycnal current sedimentation as well as for forecasting of floods.展开更多
Probabilistic safety assessment(PSA) is important in nuclear safety review and analysis. Because the design and physics of the fluoride salt-cooled high temperature reactor(FHR) differ greatly from the pressurized wat...Probabilistic safety assessment(PSA) is important in nuclear safety review and analysis. Because the design and physics of the fluoride salt-cooled high temperature reactor(FHR) differ greatly from the pressurized water reactor(PWR), the methods and steps of PSA in FHR should be studied. The high-temperature gascooled reactor(HTR-PM) and sodium-cooled fast reactors have built the PSA framework, and the framework to finish the PSA analysis. The FHR is compared with the PWR, HTR-PM and sodium-cooled fast reactors from the physics, design and safety. The PSA framework of FHR is discussed. In the FHR, the fuel and coolant combination provides large thermal margins to fuel damage(hundreds of degrees centigrade). The tristructuralisotropic(TRISO) as the fuel is independent in FHR core and its failure is limited for the core. The core damage in Level 1 PSA is of lower frequency. Levels 1 and 2 PSA are combined in the FHR PSA analysis. The initiating events analysis is the beginning, and the source term analysis and the release types are the target. Finally, Level3 PSA is done.展开更多
Underground research laboratories(URLs),including "generic URLs" and "site-specific URLs",are underground facilities in which characterisation,testing,technology development,and/or demonstration ac...Underground research laboratories(URLs),including "generic URLs" and "site-specific URLs",are underground facilities in which characterisation,testing,technology development,and/or demonstration activities are carried out in support of the development of geological repositories for high-level radioactive waste(HLW) disposal.In addition to the generic URL and site-specific URL,a concept of "areaspecific URL",or the third type of URL,is proposed in this paper.It is referred to as the facility that is built at a site within an area that is considered as a potential area for HLW repository or built at a place near the future repository site,and may be regarded as a precursor to the development of a repository at the site.It acts as a "generic URL",but also acts as a "site-specific URL" to some extent.Considering the current situation in China,the most suitable option is to build an "area-specific URL" in Beishan area,the first priority region for China's high-level waste repository.With this strategy,the goal to build China's URL by 2020 may be achieved,but the time left is limited.展开更多
The porous cubic yttrium oxides with high specific surface area were prepared by the explosive decomposition of yttrium nitrate and its complex formed with methyl salicylate. The specific surface area and properties o...The porous cubic yttrium oxides with high specific surface area were prepared by the explosive decomposition of yttrium nitrate and its complex formed with methyl salicylate. The specific surface area and properties of powders synthesized at various temperatures were characterized using BET, X-ray diffraction (XRD), infrared spectra (IR), and scanning electron microscopy (SEM). The results indicate that the highest specific surface area is found to be 65.37 m2·g -1 at the calcination temperature of 600 ℃, and then decreases to 20.33 m2·g -1 with the calcination temperature rising from 600 to 900 ℃. The powders show strong surface activity for adsorping water and carbon dioxide in air, which also decreases with the rising calcination temperature. The drop both on the surface area and surface activity of samples at higher temperatures may be due to pore-narrowing(sintering) effects.展开更多
基金partially funded by the National Natural Science Foundation of China (41877148 and 42030501)Key Laboratory of Ecohydrology of Inland River Basin,Chinese Academy of Sciences。
文摘The model performance in simulating soil water content(SWC) is crucial for successfully modeling earth’s system,especially in high mountainous areas.In this study,the performance of Community Land Model 5.0(CLM5.0) in simulating liquid SWC was evaluated against observations from nine in-situ sites in the upper reach of the Heihe River Watershed(HRW),Northwest China.The CLM5.0 shows reliable performance in the study area with correlation coefficients(R) ranging between 0.79–0.93,root mean standard errors(RMSE)ranging between 0.044–0.097 m^(3)/m^(3),and the mean bias(BIAS) ranging between-0.084–0.061 m^(3)/m^(3).The slightly worse performance of CLM5.0 than CLM4.5 on alpine meadow and grassland is mainly caused by the revised canopy interception parameterization.The CLM5.0 overestimates interception and underestimates evapotranspiration(ET) on both alpine meadow and grassland during the growth period.The systematical overestimations at all the grassland sites indicate that the underestimation of ET is much larger than the overestimation of interception on grassland during growth period,while the errors of simulated interception and ET are partially canceled out on alpine meadow.Moreover,the underestimation of ET is more responsible for the overestimation of SWC than the overestimation of interception in the high mountainous area.It is necessary to estimate reasonable empirical parameter α(proportion of leaf water collection area) in interception parameterization scheme and further improve the dry surface layerbased soil evaporation resistance parameterization introduced in CLM5.0 in future researches.The performance of CLM5.0 is better under completely frozen stage than thawing stage and freezing stage,because of low variations of liquid SWC caused by extremely low hydraulic conductivity of soils.The underestimation of liquid SWC under frozen state is caused by underestimation of soil temperature,which leads to more ice mass and less liquid water in total water content.
基金Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund for support of this research.
文摘New energy sources that reduce the volume of harmful gases such as SO_(x)and NO_(x)released into the atmosphere are in constant development.Natural gas,primarily made up of methane,is being widely used as one reliable energy source for heating and electricity generation due to its high combustion value.Currently,natural gas accounts for a large portion of electricity generation and chemical feedstock in manufacturing plastics and other commercially important organic chemicals.In the near future,natural gas will be widely used as a fuel for vehicles.Therefore,a practical storage device for its storage and transportation is very beneficial to the deployment of natural gas as an energy source for new technologies.In this tutorial review,biomaterials-based carbon monoliths(CMs),one kind of carbonaceous material,was reviewed as an adsorbent for natural gas(methane)adsorption and storage.
文摘China's infrastructure has gradually achieved large-scale development,and transportation construction has also shifted from east to west,transitioning from plains to mountainous areas.High-fill embankments of different sizes in mountainous areas are unavoidable,and the settlement of high-fill embankments is usually the most concerned issue in high-fill projects.According to the current research of highway projects,most of the high embankments in mountainous areas are soil-rock mixed embankments or rock-filled embankments,and their post-construction settlements are directly related to construction technology and the type of filler used.In this paper,the problems in the settlement control of earth-filled embankment and related factors are analyzed in detail.The settlement control technology of high-fill embankment in high-cold and high-altitude areas is also discussed,so as to ensure the overall quality of high-fill embankment.
基金the financial support received from the China Scholarship Council(CSC)MERAGEM graduate school and the Ministry of Science,Research and Arts of the State of Baden-Wu rttemberg for funding research+4 种基金the support of the German Research Foundation(DFG)project(SE 1407/4-2)the support of the En ABLES,a project funded by the European Union’s Horizon 2020 research and innovation program under grant agreement(730957)the support of Epi Store project under grant agreement(101017709)the Centre for Electrochemical Energy Storage Ulm-Karlsruhe(CELEST)the support from the Karlsruhe Nano Micro Facility(KNMF)。
文摘With the recent development of high entropy materials, an alternative approach to develop advanced functional materials with distinctive properties that show improved values compared to conventional materials has been provided. The high entropy concept was later successfully transferred to metal fluorides and high entropy fluorides(HEFs) were successfully synthesized. Owing to their high theoretical specific capacities in energy storage applications, HEFs were utilized as cathode materials for lithiumion batteries(LIBs) and their underlying storage mechanisms were investigated. Instead of a step-bystep reduction of each individual metal cation, the HEFs seem to exhibit a single-step reduction process,indicating a solid solution compound instead of merely a mixture of different metal fluorides. It was also observed that the electrochemical behavior of the HEFs depends on each individual incorporated element. Therefore, by altering the elemental composition, new materials that exhibit improved electrochemical properties can be designed. Remarkably, HEFs with seven incorporated metal elements exhibited a better cycling stability as well as a lower hysteresis compared to binary metal fluorides.These findings offer new guidelines for material design and tailoring towards high performance LIBs.
基金Supported by Public Welfare Industry (Meteorology) Science Research Special Item (GYHY201106027)National Science and Technology Support Plan (2011BAD16B06) .
文摘[Objective] The research aimed to study the distribution characteristics of high temperature damage and its influence on the rice yield in the area along Huaihe River.[Method] The meteorological data of 10 stations in the area along Huaihe River during 1965-2009 and the yield data of Anhui single-season middle rice during 1967-2006 were selected.The occurrence characteristic of summer high temperature weather and the intensity of high temperature damage in the area along Huaihe River were analyzed.Based on the previous high temperature damage index of rice,Changfeng County where was the typical rice planting zone in the area along Huaihe River was as the representation,and the yield damage loss rate risk of high temperature damage in Changfeng was analyzed by combining with the historical yield data.[Result] The high temperature weather in the area along Huaihe River frequently happened.The high temperature damage presented "N" shape trend from west to east.The occurrence frequency of high temperature weather in Huainan and Bengbu where were in the middle area along Huaihe River was more and was less in Huoqiu and Shouxian where were near the south mountain area of Anhui.The occurrence time mainly focused from the middle and last dekads of July to the first dekad of August after the plum rain.At this time,it was the booting,heading and flowering periods of single-season middle rice,and the influence on the rice yield was obvious.The damage loss rate of single-season middle rice yield in Changfeng County along Huaihe River continued to increase as the increasing of high temperature damage duration.But the occurrence probability decreased.The intensity grade of high temperature damage disaster loss rate which happened frequently concentrated mainly in levels I and II.The longer the high temperature damage duration in the reproductive growth stage of rice was,the bigger the damage loss rate was.But the corresponding occurrence probability was small,and vice versa.[Conclusion] The research provided the reference for assessing the high temperature disaster risk.
文摘Zirconia-ceria mixed oxide powders were prepared by high temperature aging method.The effects of the temperature and the time of aging, cerium content and calcination on powder performance were studied.The result shows that high temperature aging is an efficient way of preparation of ZrO2-CeO2 mixed oxide powders with high specific surface area and good thermal stability, and that addition of a small amount of cerium to hydrous zirconia can promote the preparation of high specific surface area powders.
文摘The aim of this study was to investigate the effects of high dietary fluoride (F) on serum biochemistry and oxidative damage in broiler chickens. 280 one-day-old healthy avian broiler chickens were randomly allotted into four equal groups and fed with a corn-soybean basal diet containing 22.6 mg·F/kg (control group) or same basal diets supplemented with 400, 800, and 1200 mg·F/kg (high F groups I, II, and III) in the form of sodium fluoride for 42 days. At 42 days of age, the serum F content was markedly higher in the three high F groups than that in the control group. From 28 to 42 days of age, the contents of serum total protein (TP) and albumin (ALB) were significantly lower in the three high F groups. From 14 to 42 days of age, the activities of alkaline phosphatase (ALP), alanine aminotransferase (ALT) and the creatinine (Crea) contents in the serum showed a marked increase in the three high F groups;aspartate aminotransferase (AST) activity and uric acid (Ua) content were significantly increased, and a significant increase in the content of malondialdehyde (MDA) along with marked decreases in the activities of total superoxide dismutase (T-SOD), glutathione peroxidase (GSH-Px), catalase (CAT), the glutathione (GSH) content and the ability to inhibit hydroxyl radical were observed in the high F groups II and III. In conclusion, F has accumulated in the blood circulatory system and dietary F in the range of 800 - 1200 mg/kg could significantly induce abnormalities of bone, liver and kidney, inhibit the synthesis of protein, enhance lipid peroxidation and disturb the antioxidative system of broiler chickens.
文摘Quickly extraction of building information technology is an important application in urban development planning, electronic information, national defense and others. This paper takes Landsat-8 multispectral and panchromatic data as data source, using the local variance method to select the optimal segmentation scale, normalized difference vegetation index (NDVI) and the normalized building index (NDBI) and panchromatic brightness value of an object oriented classification rule extraction. The high vegetation coverage area of buildings, and through the spatial relationships and distinguishing feature of collections of buildings independent buildings and villages. The results showed that Google earth high resolution image analysis and accuracy evaluation. the results of the extraction based on the overall accuracy of village extraction was 83%, the accuracy of extraction of independent buildings was 70%, according to the L8 remote sensing data, object oriented classification method can quickly and accurately extract the high vegetation coverage area of the building.
基金sponsored by the National Natural Science Foundation of China (30170681)the Foundation of Henan Institute of Science and Technology, China(6007)
文摘Thirty-two Wistar rats were divided randomly into four groups of eight with six females and two males in each group. The rats were exposed to high fluoride drinking water (45 mg F- L-1 from 100 mg NaF L-1), low dietary iodine (0.0855 mg kg-1), or both together in order to assess the effects of these three regimens on the thyroid function of the offspring rats. After the animal model was established, the offspring rats were bred and 10-, 20-, 30-, 60-, and 90-d-old rats were used for the experiment. The treatments for the offspring rats were the same as those of their parents. In comparison with control rats, the relative thyroid glands were changed by three regimens, but the mean values of thyroid weight in the experimental groups saw no marked difference. Serum TT3 levels were increased in all stages in the low iodine (LI) group. In the high fluoride (HiF) group, increase in TT3 levels was observed except in 20-d-old rats. Decrease in TT3 at 20- and 90-d and increase in TT3 at 30- and 60-d were found in HiF+LI group. Serum TT4 levels first saw an increase, and then dropped in the LI and HiF+LI group. However, an increase in TT4 was found in the HiF group. The levels of TSH in serum rocketed at d 20, and then dropped in the next stages in experimental groups. The results suggested that thyroid disorder could be induced by high flroride in drinking water, low iodine diet, or both of them. Exposure time to fluoride or low iodine diet was one of the important factors that fluoride can induce the development of thyroid dyfunction.
基金Supported by The National Science and Technology Pillar Program of the 11th National Five-Year Plan of China,No. 2006BAI02A15
文摘AIM:To estimate the cost-benefit of endoscopic screening strategies of esophageal cancer(EC)in high-risk areas of China. METHODS:Markov model-based analyses were conducted to compare the net present values(NPVs)and the benefit-cost ratios(BCRs)of 12 EC endoscopic screening strategies.Strategies varied according to the targeted screening age,screening frequencies,and follow-up intervals.Model parameters were collected from population-based studies in China,published literatures,and surveillance data. RESULTS:Compared with non-screening outcomes,all strategies with hypothetical 100 000 subjects saved life years.Among five dominant strategies determined by the incremental cost-effectiveness analysis,screening once at age 50 years incurred the lowest NPV(international dollar-I$55 million)and BCR(2.52).Screening six times between 40-70 years at a 5-year interval[i.e., six times(40)f-strategy]yielded the highest NPV(I$99 million)and BCR(3.06).Compared with six times(40)fstrategy,screening thrice between 40-70 years at a 10-year interval resulted in relatively lower NPV,but the same BCR. CONCLUSION:EC endoscopic screening is cost-beneficial in high-risk areas of China.Policy-makers should consider the cost-benefit,population acceptance,and local economic status when choosing suitable screening strategies.
基金financially supported by the National Natural Science Foundation of China (No. U1262203, No. 41102058)a National Science and Technology Special Grant (No. 2011ZX05006-003)Foundation for the Author of National Excellent Doctoral Dissertation of China
文摘There are three abnormally high porosity zones developed in buried Paleogene nearshore subaqueous fan and sublacustrine fan clastic reservoirs at 2,800-3,200 m, 3,250-3,700 m and 3,900-4,400 m, respectively, within the Shengtuo area of the Dongying Sag. Here the porosity of reservoirs buried deeper than 4,000 m can still be greater than 20%. Investigation of these three abnormally high porosity(AHP) zones in the 3rd to 4th member of the Paleogene Shahejie Formation in the Shengtuo area was carried out with utilization of core observation, thin section identification, SEM observation, image analysis, core physical property testing and other technical methods. The results show that, the AHP zones in 2,800-3,200 m and 3,250-3,700 m are visible pores primary AHP zones dominated by significant primary intergranular pores(more than 50% of the total porosity), while secondary pores and micropores in authigenic clays may develop in some reservoirs. AHP reservoirs in the AHP zone of 3,900-4,400 m are dominated by micropores in matrix, visible pores are mainly grain dissolution pores but with low absolute content(< 1%), so this zone belongs to the micropores primary AHP zone. The genesis of the three AHP zones was studied to distinguish between porosity enhancement and porosity preservation. Our research shows that, in deeply buried clastic reservoirs in the Shengtuo area, mineral dissolution occurred in a relatively closed diagenetic system with high temperature and high salinity. Reservoir rocks underwent extensive feldspar dissolution, while detrital carbonate grains and carbonate cements show no evidence of extensive dissolution. Although significant feldspar dissolution pores developed, feldspar dissolution enhanced porosity only a little due to the precipitation of almost isovolumetric dissolution products in the nearby primary intergranular pores in forms of authigenic clays and quartz cements. Net enhanced porosity originating from feldspar dissolution is generally less than 0.25%. Thus, the subsurface dissolution has little impact on the mid-deep buried high porosity reservoirs. Reservoirs in braided channels of middle fans in sublacustrine fans and reservoirs in the middle-front of fan bodies of nearshore subaqueous fans provide the basis for the development of AHP zones. The shallow development of fluid overpressure and early hydrocarbon emplacement have effectively retarded compaction and carbonate cementation, so that the high porosity in the superficial layers is preserved in the mid-deep layers. These are the main controlling factors in the development of AHP zones.
文摘In the gneisses from the drillhole ZK2304 of the Donghai area, there have been preserved high- and ultrahigh-pressure metamorphic mineral assemblages, a series of complicated retrogressive textures and relevant metamorphic reactions. In addition to garnet, jadeititic-clinopyroxene and rutile, other peak stage (M2) minerals in some gneisses include phengite, aragonite and coesite or quartz pseudomorphs after coesite. The typical peak-stage mineral assemblages in gneisses are characterized by garnet + jadeitic-clinopyroxene + rutile + coesite, garnet + jadeitic-clinopyroxene + phengite + rutile ± coesite and garnet + jadeitic-clinopyroxene + aragonite + rutile ± coesite. The grossular content (Gro) in garnet is high and may reach 50. 1 mol%. The SiO2 content of phengite ranges from 54.37% to 54.84% with 3.54-3.57 p.f.u. Quartz pseudomorphs after coesite occur as inclusions in garnet.The gneisses of the Donghai area have been subjected to multistage recrystallization and exhibit a closewise P-T
文摘Fluoride mediated nano-sized ZSM-5(ZSM-5-F) with a high Si/Al ratio of 181 was fabricated using a seed-induction method and evaluated the catalysis of the methanol to propylene(MTP) reaction. High propylene selectivity(45%) was similar to ZSM-5-OH synthesized via a hydroxide route. However, ZSM-5-F showed much longer lifetime(305 h) compared with ZSM-5-OH(157 h) in spite of similar crystal size and aluminum content. Characterization by NH_3-TPD, Py-IR, OH-IR, SEM, TG-DTA, XRD and ~1H MAS NMR techniques indicated that the enhanced catalytic performance of ZSM-5-F is attributed to the fewer structural defects in the form of internal silanol groups and silanol nests.
文摘The tea tree [Camellia sinensis (L) Kuntze] is one of the world’s economic crops. It is an especially important crop for southern China. Environmental factors related to the tea yield and quality in some high mountain areas of China are identified in this paper. These factors are: geology, topography, climate, hydrology, soil and vegetation. Climatological factors are the most important. Using data collected from meteorological stations which are situated at the summit and the base of high mountains, this paper discusses ecological climatic problems in growing tea in China. The ecological climatic characteristics of the famous tea areas mainly included are as follows: more . amounts of clouds and fog, less percentage of sunshine, abundant rainfall and high relative humidity in the air, temperatures that rise and fall slowly, daily and annual temperature ranges that are smaller, more days that are suitable for tea growing and low wind speeds in the lee-sides and valleys of mountains. All of these
文摘The deformation fracture and stability of mountain under the earthquake action is an important issue that arouses concern of researchers in the field of engineering geology.The authors,from 2000 to 2006, selected the 1933 earthquake in Diexi zone as a typical study site to carry out the genetic mechanism research of mountain deformation-fracture caused by earthquake; in order to have comparability,the breadth
基金Supported by the National Natural Science Foundation of China(Nos.41206073,41376079,41206051,41206052)the China Geological Survey(Nos.1212010611401,200900501)
文摘This paper presents a paleoflood study to determine the flood frequency of the Changjiang River, based on core cj0702, taken from the Changjiang River subaqueous delta. We identified flood deposits by means of high-resolution grain-size variation, sensitive population, geochemical indexes and magnetic susceptibility. The core covers a time span of 120 years by 210 Pb dating and was sampled at 1–2 cm intervals. Grain size, geochemical elements, and physical parameters were analyzed. The results indicate that the sediment of the core is mainly composed of silt and clay, as well as groups of interbedded silt, clay silt, and clay. Vertically, the grain size pattern was controlled by seasonal variations in water discharge and by the sediment input in winter from the abandoned Huanghe River delta. River flooding caused extreme values in all our measured parameters. We identified more than 20 flood events that occurred since 1887 using the physical parameter analysis method. The environmentally sensitive component of sediment grain size(14.32–96.39 μm) contribution>30%, Zr/Rb ratio>1.5, and magnetic susceptibility>16 were selected as the criteria for flood identification generally. We also found that floods that had taken place in the upstream, midstream, or downstream parts of the river were clearly identified by these indexes while the large-scale floods that covered the whole drainage area did not leave clear indications in the sediment record. This study for identification of flood events is of great significance for understanding hyperpycnal current sedimentation as well as for forecasting of floods.
基金Supported by Chinese Academy of Science Strategy Precursor Science and Technology Project(No.XDA0205050)
文摘Probabilistic safety assessment(PSA) is important in nuclear safety review and analysis. Because the design and physics of the fluoride salt-cooled high temperature reactor(FHR) differ greatly from the pressurized water reactor(PWR), the methods and steps of PSA in FHR should be studied. The high-temperature gascooled reactor(HTR-PM) and sodium-cooled fast reactors have built the PSA framework, and the framework to finish the PSA analysis. The FHR is compared with the PWR, HTR-PM and sodium-cooled fast reactors from the physics, design and safety. The PSA framework of FHR is discussed. In the FHR, the fuel and coolant combination provides large thermal margins to fuel damage(hundreds of degrees centigrade). The tristructuralisotropic(TRISO) as the fuel is independent in FHR core and its failure is limited for the core. The core damage in Level 1 PSA is of lower frequency. Levels 1 and 2 PSA are combined in the FHR PSA analysis. The initiating events analysis is the beginning, and the source term analysis and the release types are the target. Finally, Level3 PSA is done.
文摘Underground research laboratories(URLs),including "generic URLs" and "site-specific URLs",are underground facilities in which characterisation,testing,technology development,and/or demonstration activities are carried out in support of the development of geological repositories for high-level radioactive waste(HLW) disposal.In addition to the generic URL and site-specific URL,a concept of "areaspecific URL",or the third type of URL,is proposed in this paper.It is referred to as the facility that is built at a site within an area that is considered as a potential area for HLW repository or built at a place near the future repository site,and may be regarded as a precursor to the development of a repository at the site.It acts as a "generic URL",but also acts as a "site-specific URL" to some extent.Considering the current situation in China,the most suitable option is to build an "area-specific URL" in Beishan area,the first priority region for China's high-level waste repository.With this strategy,the goal to build China's URL by 2020 may be achieved,but the time left is limited.
文摘The porous cubic yttrium oxides with high specific surface area were prepared by the explosive decomposition of yttrium nitrate and its complex formed with methyl salicylate. The specific surface area and properties of powders synthesized at various temperatures were characterized using BET, X-ray diffraction (XRD), infrared spectra (IR), and scanning electron microscopy (SEM). The results indicate that the highest specific surface area is found to be 65.37 m2·g -1 at the calcination temperature of 600 ℃, and then decreases to 20.33 m2·g -1 with the calcination temperature rising from 600 to 900 ℃. The powders show strong surface activity for adsorping water and carbon dioxide in air, which also decreases with the rising calcination temperature. The drop both on the surface area and surface activity of samples at higher temperatures may be due to pore-narrowing(sintering) effects.
