Polyethylene glycol(PEG)with different chains was used to modify epoxy asphalt.Molecular models of PEG⁃modified epoxy asphalt were developed using molecu⁃lar simulations(MS).The thermodynamic and mechanical properties...Polyethylene glycol(PEG)with different chains was used to modify epoxy asphalt.Molecular models of PEG⁃modified epoxy asphalt were developed using molecu⁃lar simulations(MS).The thermodynamic and mechanical properties of PEG⁃modified epoxy asphalt were analyzed,and its toughening mechanisms were explored.A method based on the Dijkstra algorithm was proposed to evaluate ep⁃oxy asphalt crosslinked networks.The results show that the introduction of PEG chains into epoxy asphalt can lower the glass transition temperature and enhance its toughness be⁃cause of the extended length of the PEG chains,which can in⁃crease the free volume and improve the mobility of the epoxy resin in the epoxy asphalt.The crosslinked network quantita⁃tive evaluation method based on the Dijkstra algorithm can ef⁃fectively evaluate the distribution of epoxy asphalt crosslink⁃ing bonds,providing further explanation of the toughening mechanism of PEG⁃modified epoxy asphalt.The feasibility of designing and screening epoxy asphalt materials by MS is verified,and a guide for toughening mechanism research of epoxy asphalt at the molecular level is provided.展开更多
为推动钢渣在道路工程中的应用,缓解钢渣堆放造成的土地占用与环境污染问题,对钢渣陈化过程中的理化特征及钢渣沥青混合料性能进行了研究。采用粒度粒形、X射线荧光光谱试验探究钢渣陈化前后的形貌特征和矿物组成。随后,利用未处理钢渣...为推动钢渣在道路工程中的应用,缓解钢渣堆放造成的土地占用与环境污染问题,对钢渣陈化过程中的理化特征及钢渣沥青混合料性能进行了研究。采用粒度粒形、X射线荧光光谱试验探究钢渣陈化前后的形貌特征和矿物组成。随后,利用未处理钢渣、陈化钢渣和玄武岩制备了沥青混合料,对比评价了3种沥青混合料的体积膨胀性、水稳定性、高温稳定性和低温抗裂性能。此外,通过灰色关联法分析了集料特性与混合料性能的关联性。结果表明,钢渣的高粗糙度、高棱角性使其成为玄武岩等天然集料的理想替代品。然而,未陈化钢渣体积稳定性差,遇水易膨胀,导致无法满足路面使用要求。值得注意的是,CaO和Fe 2 O 3含量是影响钢渣体积稳定性的重要因素,而陈化处理可以在一定程度上降低这些负面影响,从而改善钢渣沥青混合料的路用性能。综合各项分析,陈化钢渣沥青混合料具有较好综合路用性能,钢渣的二次利用对于实现道路基础设施的可持续发展具有重要意义。展开更多
基金The Major Science and Technology Project of Nan⁃jing(No.202209012)the Postgraduate Research and Practice Innova⁃tion Program of Jiangsu Province(No.KYCX22⁃0277).
文摘Polyethylene glycol(PEG)with different chains was used to modify epoxy asphalt.Molecular models of PEG⁃modified epoxy asphalt were developed using molecu⁃lar simulations(MS).The thermodynamic and mechanical properties of PEG⁃modified epoxy asphalt were analyzed,and its toughening mechanisms were explored.A method based on the Dijkstra algorithm was proposed to evaluate ep⁃oxy asphalt crosslinked networks.The results show that the introduction of PEG chains into epoxy asphalt can lower the glass transition temperature and enhance its toughness be⁃cause of the extended length of the PEG chains,which can in⁃crease the free volume and improve the mobility of the epoxy resin in the epoxy asphalt.The crosslinked network quantita⁃tive evaluation method based on the Dijkstra algorithm can ef⁃fectively evaluate the distribution of epoxy asphalt crosslink⁃ing bonds,providing further explanation of the toughening mechanism of PEG⁃modified epoxy asphalt.The feasibility of designing and screening epoxy asphalt materials by MS is verified,and a guide for toughening mechanism research of epoxy asphalt at the molecular level is provided.
文摘为推动钢渣在道路工程中的应用,缓解钢渣堆放造成的土地占用与环境污染问题,对钢渣陈化过程中的理化特征及钢渣沥青混合料性能进行了研究。采用粒度粒形、X射线荧光光谱试验探究钢渣陈化前后的形貌特征和矿物组成。随后,利用未处理钢渣、陈化钢渣和玄武岩制备了沥青混合料,对比评价了3种沥青混合料的体积膨胀性、水稳定性、高温稳定性和低温抗裂性能。此外,通过灰色关联法分析了集料特性与混合料性能的关联性。结果表明,钢渣的高粗糙度、高棱角性使其成为玄武岩等天然集料的理想替代品。然而,未陈化钢渣体积稳定性差,遇水易膨胀,导致无法满足路面使用要求。值得注意的是,CaO和Fe 2 O 3含量是影响钢渣体积稳定性的重要因素,而陈化处理可以在一定程度上降低这些负面影响,从而改善钢渣沥青混合料的路用性能。综合各项分析,陈化钢渣沥青混合料具有较好综合路用性能,钢渣的二次利用对于实现道路基础设施的可持续发展具有重要意义。
