采用AG MP-1阴离子交换树脂,分别以7 mol/L HC l、2 mol/L HC l、0.5 mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标...采用AG MP-1阴离子交换树脂,分别以7 mol/L HC l、2 mol/L HC l、0.5 mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标准溶液在离子交换分离前后同位素组成一致,可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。展开更多
The precision and accuracy of Nd isotope analysis using multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) is verified through repeated measurements of standard reference materials of JMC Nd2O3 and...The precision and accuracy of Nd isotope analysis using multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) is verified through repeated measurements of standard reference materials of JMC Nd2O3 and GBW04419. A mixed solution of Nd separated from hundreds of geological samples is measured for 143Nd/144Nd ratio, which produces excellent long-term repeatability. This solution, named as CAGS-Nd-1, can be used as an in-house reference material for monitoring instrument stability during Nd isotope measurements.展开更多
The employment of either doping or standard-sample-bracketing method for mass fractionation during isotope ratio measurement using multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) assumes that th...The employment of either doping or standard-sample-bracketing method for mass fractionation during isotope ratio measurement using multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) assumes that the instrumental fractionation is the same for both standards and samples. The effect of Pb in Cu solutions on Cu isotope measurement using MC-ICPMS is reported.展开更多
A method for determining Mg/Ca of stalagmite by LA-MC-ICPMS is studied. 24Mg/44Ca (Mass 22, intensity of 44Ca2+ , collected by ion counting and mass 24, intensity of 24Mg+, collected by Faraday cup) ratios were measur...A method for determining Mg/Ca of stalagmite by LA-MC-ICPMS is studied. 24Mg/44Ca (Mass 22, intensity of 44Ca2+ , collected by ion counting and mass 24, intensity of 24Mg+, collected by Faraday cup) ratios were measured in replace of Mg/Ca ratios. Both diameter of laser sampling spot and laser moving increment were 20 μm. The curve of Mg/Ca vs. distance directly was obtained. The result indicates that relative Mg/Ca ratios changed from 0.5 to 2.0 in this stalagmite and it is enough to reflect environmental factors act.展开更多
文摘采用AG MP-1阴离子交换树脂,分别以7 mol/L HC l、2 mol/L HC l、0.5 mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标准溶液在离子交换分离前后同位素组成一致,可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。
文摘The precision and accuracy of Nd isotope analysis using multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) is verified through repeated measurements of standard reference materials of JMC Nd2O3 and GBW04419. A mixed solution of Nd separated from hundreds of geological samples is measured for 143Nd/144Nd ratio, which produces excellent long-term repeatability. This solution, named as CAGS-Nd-1, can be used as an in-house reference material for monitoring instrument stability during Nd isotope measurements.
文摘The employment of either doping or standard-sample-bracketing method for mass fractionation during isotope ratio measurement using multicollector-inductively coupled plasma mass spectrometry (MC-ICPMS) assumes that the instrumental fractionation is the same for both standards and samples. The effect of Pb in Cu solutions on Cu isotope measurement using MC-ICPMS is reported.
文摘A method for determining Mg/Ca of stalagmite by LA-MC-ICPMS is studied. 24Mg/44Ca (Mass 22, intensity of 44Ca2+ , collected by ion counting and mass 24, intensity of 24Mg+, collected by Faraday cup) ratios were measured in replace of Mg/Ca ratios. Both diameter of laser sampling spot and laser moving increment were 20 μm. The curve of Mg/Ca vs. distance directly was obtained. The result indicates that relative Mg/Ca ratios changed from 0.5 to 2.0 in this stalagmite and it is enough to reflect environmental factors act.
