Recently,a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite materials.However,few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal ...Recently,a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite materials.However,few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal oxides for catalysis.In the present work,mesoporous MOx-Al2O3（M = Mn,Fe,Co,Ni,Cu,Ba）materials were prepared by a one-pot self-assembly method using Pluronic P123 as a structure-directing agent.The obtained mesoporous materials were loaded with Rh2O3 nanoparticles via impregnation with Rh（NO3）3 followed by calcination in air at 500°C.The resulting catalysts were characterized by X-ray diffraction,N2 adsorption-desorption measurements,transmission electron microscopy,inductively coupled plasma optical emission spectrometry,X-ray photoelectron spectroscopy,and their catalytic activity and stability for CO oxidation and N2O decomposition were tested.The Rh2O3 nanoparticles were found to be on the order of1 nm in size and were highly dispersed on the high surface area mesoporous MOx-Al2O3 supports.A number of the Rh2O3/mesoporous MOx-Al2O3 catalysts exhibited higher catalytic activity than the Rh2O3/mesoporous Al2O3 prepared for comparison.展开更多
本研究对氯霉素(CAP)在不同条件下的电子束辐照降解进行了研究.结果表明,电子束辐照可有效去除水中CAP,低浓度CAP在酸性条件下的辐照降解更为显著,且降解过程符合准一级动力学模型.通过添加不同的自由基清除剂,发现HO·在CAP降解中...本研究对氯霉素(CAP)在不同条件下的电子束辐照降解进行了研究.结果表明,电子束辐照可有效去除水中CAP,低浓度CAP在酸性条件下的辐照降解更为显著,且降解过程符合准一级动力学模型.通过添加不同的自由基清除剂,发现HO·在CAP降解中起关键作用,此外,CAP分子也会吸收辐照而发生分解.水中共存的阴离子和腐殖酸(HA)对CAP辐照降解均有抑制作用,这跟其与HO·的反应速率常数大小有关,并且反应速率越大,其抑制能力越强.CAP在去离子水中的去除率高于其他实际水体,但辐照剂量为4 k Gy时,污水厂污水过滤水和胶体浓缩液中的CAP也可分别去除89.1%和81.7%.利用GC-MS检测到辐照后溶液中有6种中间产物,主要是通过脱水、不对称中心断键和脱酰胺作用形成.此外,IC检测有Cl-、NO-3和NO-2的产生,并且TOC在一定程度上降低,说明部分CAP被矿化.展开更多
基金supported by the National Natural Science Foundation of China (21177028)~~国家自然科学基金(21177028)
文摘Recently,a one-pot self-assembly method was proposed for the synthesis of mesoporous Al2O3 and MOx-Al2O3 composite materials.However,few attempts have been made to use mesoporous MOx-Al2O3 composites to support metal oxides for catalysis.In the present work,mesoporous MOx-Al2O3（M = Mn,Fe,Co,Ni,Cu,Ba）materials were prepared by a one-pot self-assembly method using Pluronic P123 as a structure-directing agent.The obtained mesoporous materials were loaded with Rh2O3 nanoparticles via impregnation with Rh（NO3）3 followed by calcination in air at 500°C.The resulting catalysts were characterized by X-ray diffraction,N2 adsorption-desorption measurements,transmission electron microscopy,inductively coupled plasma optical emission spectrometry,X-ray photoelectron spectroscopy,and their catalytic activity and stability for CO oxidation and N2O decomposition were tested.The Rh2O3 nanoparticles were found to be on the order of1 nm in size and were highly dispersed on the high surface area mesoporous MOx-Al2O3 supports.A number of the Rh2O3/mesoporous MOx-Al2O3 catalysts exhibited higher catalytic activity than the Rh2O3/mesoporous Al2O3 prepared for comparison.
基金supported by the National Natural Science Foundation of China(21077025,21277028,21190053)Science&Technology Commission of Shanghai Municipality,China(10231203801,10JC1401600)~~
文摘本研究对氯霉素(CAP)在不同条件下的电子束辐照降解进行了研究.结果表明,电子束辐照可有效去除水中CAP,低浓度CAP在酸性条件下的辐照降解更为显著,且降解过程符合准一级动力学模型.通过添加不同的自由基清除剂,发现HO·在CAP降解中起关键作用,此外,CAP分子也会吸收辐照而发生分解.水中共存的阴离子和腐殖酸(HA)对CAP辐照降解均有抑制作用,这跟其与HO·的反应速率常数大小有关,并且反应速率越大,其抑制能力越强.CAP在去离子水中的去除率高于其他实际水体,但辐照剂量为4 k Gy时,污水厂污水过滤水和胶体浓缩液中的CAP也可分别去除89.1%和81.7%.利用GC-MS检测到辐照后溶液中有6种中间产物,主要是通过脱水、不对称中心断键和脱酰胺作用形成.此外,IC检测有Cl-、NO-3和NO-2的产生,并且TOC在一定程度上降低,说明部分CAP被矿化.
