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Boosted sodium ion storage performance in MnO_(2):Understanding the bond angle-mediated orbital overlap in MnO_(6)units for fast charge transfer
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作者 Jinrui Wang Zishan Hou +12 位作者 Xia Liu Shiyu Wang Shuyun Yao Yebo Yao Dewei Wang Xueying Gao Huiying Zhang Zheng Tang Yuanming Liu Kaiqi Nie Jiangzhou Xie Zhiyu Yang Yi-Ming Yan 《Journal of Energy Chemistry》 SCIE EI CSCD 2023年第12期295-303,I0008,共10页
Symmetric six oxygen-coordinated Mn structural units(MnO6)in MnO2 with small Mn–O orbital overlap hamper electron transfer rates during energy storage.Herein,we report a novel bond angle modulation strategy to manipu... Symmetric six oxygen-coordinated Mn structural units(MnO6)in MnO2 with small Mn–O orbital overlap hamper electron transfer rates during energy storage.Herein,we report a novel bond angle modulation strategy to manipulate Mn–O orbital overlap in MnO2 through the construction of Mn vacancies(MnO2-VMn),aiming at expediting electron transfer,and thus enhancing energy storage performance.Both experimental and theoretical results disclose that the amplification of Mn–O–Mn bond angles exclusively augments the Mn(dx2-y2)-O(py)orbital overlap and triggers the electron redistribution in MnO2-VMn,inducing an augmented Mn dx2-y2 electron occupation.This heightened presence of active electrons in the Mn dx2-y2 orbital paves the way for accelerating electron transfer and ion transfer in MnO2-VMn.Notably,MnO2-VMn delivers an improved specific capacitance of 425 F g−1 at 1 A g−1 and a superior rate capacity of 265 F g−1 at 20 A g−1.Furthermore,an asymmetric supercapacitor(MnO2-VMn//AC ASC)was fabricated,exhibiting a high energy density of 64.3 Wh kg−1 at a power density of 1000 W kg−1.Furthermore,theoretical insights uncover the profound implications of metal–oxygen–metal bond angle regulation on interatomic orbital overlap modulation.These revelations illuminate pathways for the design of advanced energy storage materials. 展开更多
关键词 Bond angle Orbital overlap Cation vacancies Manganese oxides Electron transfer
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The transition from 2G to 3G-feedstocks enabled efficient production of fuelsand chemicals
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作者 Kai Wang Changsheng Su +8 位作者 Haoran Bi Changwei Zhang Di Cai Yanhui Liu Meng Wang Biqiang Chen Jens Nielsen Zihe Liu Tianwei Tan 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第11期1759-1770,共12页
For decades micoorganisms have been engineered for the utilization of lignocellulose-based second-generation (2G) feedstocks, but with theconcerns of increased levels of atmospheric CO_(2) causing global warming there... For decades micoorganisms have been engineered for the utilization of lignocellulose-based second-generation (2G) feedstocks, but with theconcerns of increased levels of atmospheric CO_(2) causing global warming there is an emergent need to transition from the utilization of 2Gfeedstocks to third-generation (3G) feedstocks such as CO_(2) and its derivatives. Here, we established a yeast platform that is capable ofsimultaneously converting 2G and 3G feedstocks into bulk and value-added chemicals. We demonstrated that by adopting 3G substrates such asCO_(2) and formate, the conversion of 2G feedstocks could be substantially improved. Specifically, formate could provide reducing power andenergy for xylose conversion into valuable chemicals. Simultaneously, it can form a concentrated CO_(2) pool inside the cell, providing thermodynamically and kinetically favoured amounts of precursors for CO_(2) fixation pathways, e.g., the Calvin–Benson–Bassham (CBB) cycle.Furthermore, we demonstrated that formate could directly be utilized as a carbon source by yeast to synthesize endogenous amino acids. Theengineered strain achieved a one-carbon (C1) assimilation efficiency of 9.2%, which was the highest efficiency observed in the co-utilization of2G and 3G feedstocks. We applied this strategy for productions of both bulk and value-added chemicals, including ethanol, free fatty acids(FFAs), and longifolene, resulting in yield enhancements of 18.4%, 49.0%, and ~100%, respectively. The strategy demonstrated here for coutilization of 2G and 3G feedstocks sheds lights on both basic and applied research for the up-coming establishment of 3G biorefineries. 展开更多
关键词 TRANSITION utilized BENSON
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Non-destructive buffer enabling near-infrared-transparent inverted inorganic perovskite solar cells toward 1400 h light-soaking stable perovskite/Cu(In,Ga)Se_(2) tandem solar cells
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作者 Yu Zhang Zhaoheng Tang +14 位作者 Zhongyang Zhang Jiahong Tang Minghua Li Siyuan Zhu Wenyan Tan Xi Jin Tongsheng Chen Jinsong Hu Chao Zhou Chunlei Yang Qijie Liang Xugang Guo Weimin Li Weiqiang Chen Yan Jiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期622-629,I0013,共9页
Near-infrared(NIR)transparent inverted all-inorganic perovskite solar cells(PSCs)are excellent top cell candidates in tandem applications.An essential challenge is the replacement of metal contacts with transparent co... Near-infrared(NIR)transparent inverted all-inorganic perovskite solar cells(PSCs)are excellent top cell candidates in tandem applications.An essential challenge is the replacement of metal contacts with transparent conductive oxide(TCO)electrodes,which requires the introduction of a buffer layer to prevent sputtering damage.In this study,we show that the conventional buffers(i.e.,small organic molecules and atomic layer deposited metal oxides)used for organic-inorganic hybrid perovskites are not applicable to all-inorganic perovskites,due to non-uniform coverage of the vulnerable layers underneath,deterioration upon ion bombardment and moisture induced perovskite phase transition,A thin film of metal oxide nanoparticles by the spin-coating method serves as a non-destructive buffer layer for inorganic PSCs.All-inorganic inverted near-infrared-transparent PSCs deliver a PCE of 17.46%and an average transmittance of 73.7%between 780 and 1200 nm.In combination with an 18.56%Cu(In,Ga)Se_(2) bottom cell,we further demonstrate the first all-inorganic perovskite/CIGS 4-T tandem solar cell with a PCE of 24.75%,which exhibits excellent illumination stability by maintaining 86.7%of its initial efficiency after 1400 h.The non-destructive buffer lays the foundation for efficient and stable NIR-transparent inverted inorganic perovskite solar cells and perovskite-based tandems. 展开更多
关键词 CsPbI_(3)perovskite Inverted perovskite solar cells Tandem solar cells Buffer layer Stability
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3D Lamellar-Structured Graphene Aerogels for Thermal Interface Composites with High Through-Plane Thermal Conductivity and Fracture Toughness 被引量:13
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作者 Pengfei Liu Xiaofeng Li +4 位作者 Peng Min Xiyuan Chang Chao Shu Yun Ding Zhong-Zhen Yu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第2期13-27,共15页
Although thermally conductive graphene sheets are efficient in enhancing in-plane thermal conductivities of polymers,the resulting nanocomposites usually exhibit low through-plane thermal conductivities,limiting their... Although thermally conductive graphene sheets are efficient in enhancing in-plane thermal conductivities of polymers,the resulting nanocomposites usually exhibit low through-plane thermal conductivities,limiting their application as thermal interface materials.Herein,lamellarstructured polyamic acid salt/graphene oxide(PAAS/GO)hybrid aerogels are constructed by bidirectional freezing of PAAS/GO suspension followed by lyophilization.Subsequently,PAAS monomers are polymerized to polyimide(PI),while GO is converted to thermally reduced graphene oxide(RGO)during thermal annealing at 300℃.Final graphitization at 2800℃ converts PI to graphitized carbon with the inductive effect of RGO,and simultaneously,RGO is thermally reduced and healed to high-quality graphene.Consequently,lamellar-structured graphene aerogels with superior through-plane thermal conduction capacity are fabricated for the first time,and its superior through-plane thermal conduction capacity results from its vertically aligned and closely stacked high-quality graphene lamellae.After vacuum-assisted impregnation with epoxy,the resultant epoxy composite with 2.30 vol% of graphene exhibits an outstanding through-plane thermal conductivity of as high as 20.0 W m^−1 K^−1,100 times of that of epoxy,with a record-high specific thermal conductivity enhancement of 4310%.Furthermore,the lamellar-structured graphene aerogel endows epoxy with a high fracture toughness,~1.71 times of that of epoxy. 展开更多
关键词 Anisotropic aerogels GRAPHENE Thermal conductivity Epoxy composites Fracture toughness
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Direct Ink Writing of Highly Conductive MXene Frames for Tunable Electromagnetic Interference Shielding and Electromagnetic Wave-Induced Thermochromism 被引量:12
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作者 Xinyu Wu Tingxiang Tu +6 位作者 Yang Dai Pingping Tang Yu Zhang Zhiming Deng Lulu Li Hao-Bin Zhang Zhong-Zhen Yu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第10期14-28,共15页
The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference(EMI)shielding materials to assure the normal operation of their closely assembled compo... The highly integrated and miniaturized next-generation electronic products call for high-performance electromagnetic interference(EMI)shielding materials to assure the normal operation of their closely assembled components.However,the most current techniques are not adequate for the fabrication of shielding materials with programmable structure and controllable shielding efficiency.Herein,we demonstrate the direct ink writing of robust and highly conductive Ti3C2Tx MXene frames with customizable structures by using MXene/AlOOH inks for tunable EMI shielding and electromagnetic wave-induced thermochromism applications.The as-printed frames are reinforced by immersing in AlCl_(3)/HCl solution to remove the electrically insulating AlOOH nanoparticles,as well as cross-link the MXene sheets and fuse the filament interfaces with aluminum ions.After freeze-drying,the resultant robust and porous MXene frames exhibit tunable EMI shielding efficiencies in the range of 25-80 dB with the highest electrical conductivity of 5323 S m−1.Furthermore,an electromagnetic wave-induced thermochromic MXene pattern is assembled by coating and curing with thermochromic polydimethylsiloxane on a printed MXene pattern,and its color can be changed from blue to red under the high-intensity electromagnetic irradiation.This work demonstrates a direct ink printing of customizable EMI frames and patterns for tuning EMI shielding efficiency and visualizing electromagnetic waves. 展开更多
关键词 MXene Electromagnetic interference shielding Direct ink writing Electrical conductivity THERMOCHROMISM
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Superior adsorption performance of graphitic carbon nitride nanosheets for both cationic and anionic heavy metals from wastewater 被引量:6
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作者 Gang Xiao Yaoqiang Wang +5 位作者 Shengnan Xu Peifeng Li Chen Yang Yu Jin Qiufeng Sun Haijia Su 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第2期305-313,共9页
Water pollution caused by highly toxic Cd(II), Pb(II), and Cr(VI) is a serious problem. In the present work,a green and low-cost adsorbent of g-C_3N_4 nanosheets was developed with superior capacity for both cationic ... Water pollution caused by highly toxic Cd(II), Pb(II), and Cr(VI) is a serious problem. In the present work,a green and low-cost adsorbent of g-C_3N_4 nanosheets was developed with superior capacity for both cationic and anionic heavy metals. The adsorbent was easily fabricated through one-step calcination of guanidine hydrochloride with thickness less than 1.6 nm and specific surface area of 111.2 m^2·g^(-1). Kinetic and isotherm studies suggest that the adsorption is an endothermic chemisorption process, occurring on the energetically heterogeneous surface based on a hybrid mechanism of multilayer and monolayer adsorption. The tri-s-triazine units and surface N-containing groups of g-C_3N_4 nanosheets are proposed to be responsible for the adsorption process.Further study on pH demonstrates that electrostatic interaction plays an important role. The maximum adsorption capacity of Cd(II), Pb(II), and Cr(VI) on g-C_3N_4 nanosheets is 123.205 mg·g^(-1), 136.571 mg·g^(-1),and 684.451 mg·g^(-1), respectively. The better adsorption performance of the adsorbent than that of the recently reported nanomaterials and low-cost adsorbents proves its great application potential in the removal of heavy metal contaminants from wastewater. The present paper developed a promising adsorbent which will certainly find applications in wastewater treatment and also provides guiding significance in designing adsorption processes. 展开更多
关键词 g-C3N4 NANOSHEETS NANOMATERIALS Adsorption Heavy metals WASTEWATER
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A gelatin-based artificial SEI for lithium deposition regulation and polysulfide shuttle suppression in lithium-sulfur batteries 被引量:8
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作者 Naseem Akhtar Xiaogang Sun +7 位作者 Muhammad Yasir Akram Fakhar Zaman Weikun Wang Anbang Wang Long Chen Hao Zhang Yuepeng Guan Yaqin Huang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第1期310-317,I0010,共9页
Lithium-sulfur(Li-S) battery is one of the best candidates for the next-generation energy storage system due to its high theoretical capacity(1675 mA h-1),low cost and environment friendliness.However,lithium(Li) dend... Lithium-sulfur(Li-S) battery is one of the best candidates for the next-generation energy storage system due to its high theoretical capacity(1675 mA h-1),low cost and environment friendliness.However,lithium(Li) dendrites formation and polysulfide shuttle effect are two major challenges that limit the commercialization of Li-S batteries.Here we design a facile bifunctional interlayer of gelatin-based fibers(GFs),aiming to protect the Li anode surface from the dendrites growth and also hinder the polysulfide shuttle effect.We reveal that the 3D structural network of GFs layer with abundant polar sites helps to homogenize Li-ion flux,leading to uniform Li-ion deposition.Meanwhile,the polar moieties also immobilize the lithium polysulfides and protect the Li metal from the side-reaction.As a result,the anodeprotected batteries have shown significantly enhanced performance.A high coulombic efficiency of 96% after 160 cycles has been achieved in the Li-Cu half cells.The Li-Li symmetric cells exhibit a prolonged lifespan for 800 h with voltage hysteresis(10 mV).With the as-prepared GFs layer,the Li-S battery shows approximately 14% higher capacity retention than the pristine battery at 0.5 C after 100 cycles.Our work presents that this gelatin-based bi-functional interlayer provides a viable strategy for the manufacturing of advanced Li-S batteries. 展开更多
关键词 Bifunctional layer Gelatin-based fibers Shuttle effect Artificial SEI Lithium-sulfur battery
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Facile and Scalable Preparation of Fluorescent Carbon Dots for Multifunctional Applications 被引量:9
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作者 Dan Wang Zhiyong Wang +4 位作者 Qiuqiang Zhan Yuan Pu Jie-xin wang Neil R. Foster Liming Dai 《Engineering》 SCIE EI 2017年第3期402-408,共7页
The synthesis of fluorescent nanomaterials has received considerable attention due to the great potential of these materials for a wide range of applications, from chemical sensing through bioimaging to optoelectron- ... The synthesis of fluorescent nanomaterials has received considerable attention due to the great potential of these materials for a wide range of applications, from chemical sensing through bioimaging to optoelectron- ics. Herein, we report a facile and scalable approach to prepare fluorescent carbon dots (FCDs) via a one-pot reaction of citric acid with ethylenediamine at 150 ℃ under ambient air pressure. The resultant FCDs pos- sess an optical bandgap of 3.4 eV and exhibit strong excitation-wavelength-independent blue emission (λEm = 450 nm) under either one- or two-photon excitation. Owing to their low cytotoxicity and long fluorescence lifetime, these FCDs were successfully used as internalized fluorescent probes in human cancer cell lines (HeLa cells) for two-photon excited imaging of cells by fluorescence lifetime imaging microscopy with a high-contrast resolution. They were also homogenously mixed with commercial inks and used to draw fluo- rescent patterns on normal papers and on many other substrates (e.g., certain flexible plastic films, textiles, and clothes). Thus, these nanomaterials are promising for use in solid-state fluorescent sensing, security labeling, and wearable optoelectronics. 展开更多
关键词 SCALABLE Carbon dots TWO-PHOTON Fluorescence lifetime imaging PATTERNING
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New development in Fe/Co catalysts:Structure modulation and performance optimization for syngas conversion 被引量:4
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作者 Yinwen Li Xin Zhang Min Wei 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第8期1329-1346,共18页
C1 chemistry is the essence of coal chemistry and natural gas chemistry. Catalytic methods to efficiently convert C1 molecules into fuels and chemicals have been extensively studied. Syngas(CO +H_2) conversion is t... C1 chemistry is the essence of coal chemistry and natural gas chemistry. Catalytic methods to efficiently convert C1 molecules into fuels and chemicals have been extensively studied. Syngas(CO +H_2) conversion is the most important industrial reaction system in C1 chemistry, and Fe and Co catalysts, two major industrial catalysts, have been the focus of fundamental research and industrial application. In the last decade, considerable research efforts have been devoted to discoveries concerning catalyst structure and increasing market demands for olefins and oxygenates. Since the development of efficient catalysts would strongly benefit from catalyst design and the establishment of a new reaction system, this review comprehensively overviews syngas conversion in three main reactions, highlights the advances recently made and the challenges that remain open, and will stimulate future research activities. The first part of the review summarizes the breakthroughs in Fischer-Tropsch synthesis regarding the optimization of activity and stability, determination of the active phase, and mechanistic studies. The second part overviews the modulation of catalytic structure and product selectivity for Fischer-Tropsch to olefins(FTO). Catalysts designed to produce higher alcohols, as well as to tune product selectivity in C1 chemistry, are described in the third section. Finally, present challenges in syngas conversion are proposed, and the solutions and prospects are discussed from the viewpoint of fundamental research and practical application. This review summarizes the latest advances in the design, preparation, and application of Fe/Co-based catalysts toward syngas conversion and presents the challenges and future directions in producing value-added fuels. 展开更多
关键词 Syngas conversion Fe/Cocatalyst Structure modulation Performance optimization Product selectivity
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The influence of temperature on flow-induced forces on quartz-crystal-microbalance sensors in a Chinese liquor identification electronic-nose: three-dimensional computational fluid dynamics simulation and analysis 被引量:2
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作者 Qiang LI Yu GU Huatao WANG 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2019年第9期1301-1312,共12页
An electronic-nose is developed based on eight quartz-crystal-microbalance (QCM) gas sensors in a sensor box, and is used to detect Chinese liquors at room temperature. Each sensor is a highly-accurate and highly-sens... An electronic-nose is developed based on eight quartz-crystal-microbalance (QCM) gas sensors in a sensor box, and is used to detect Chinese liquors at room temperature. Each sensor is a highly-accurate and highly-sensitive oscillator that has experienced airflow disturbances under the condition of varying room temperatures due to unstable flow-induced forces on the sensors surfaces. The three-dimensional (3D) nature of the airflow inside the sensor box and the interactions of the airflow on the sensors surfaces at different temperatures are studied by computational fluid dynamics (CFD) tools. Higher simulation accuracy is achieved by optimizing meshes, meshing the computational domain using a fine unstructural tetrahedron mesh. An optimum temperature, 30 ℃, is obtained by analyzing the distributions of velocity streamlines and the static pressure, as well as the flow-induced forces over time, all of which may be used to improve the identification accuracy of the electronic-nose for achieving stable and repeatable signals by removing the influence of temperature. 展开更多
关键词 computational fluid dynamics (CFD) TEMPERATURE quartz-crystalmicrobalance (QCM) gas sensor ELECTRONIC NOSE IDENTIFICATION accuracy
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An energy saving and fluorine-free electrorefining process for ultrahigh purity lead refining 被引量:2
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作者 Xuan Zhang Junqing Pan +2 位作者 Yanzhi Sun Yongjun Feng Huixia Niu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2019年第5期1191-1199,共9页
The present paper reports a new fluoride-free and energy-saving lead electrolytic refining process in order to solve the serious problems of the existing Betts lead electrorefining process, such as low production effi... The present paper reports a new fluoride-free and energy-saving lead electrolytic refining process in order to solve the serious problems of the existing Betts lead electrorefining process, such as low production efficiency,high energy consumption and fluorine pollution. In the process, a mixed solution of perchloric acid and lead perchlorate(HClO4-Pb(ClO4)2) with the additives of gelatin and sodium lignin sulfonate is employed as the new electrolyte. The cathodic polarization curves show that HClO4 is very stable, and there is no any reduction reaction of HClO4 during the electrolytic process. The redox reactions of lead ions in HClO4 solution are very reversible with an ultrahigh capacity efficiency, so the HClO4 acts as a stable support electrolyte with higher ionic conductivity than the traditional H2SiF6 electrolyte. The results of the scale-up experiments show that under the optimal conditions of 2.8 mol·L-1 HClO4, 0.4 mol·L-1 Pb(ClO4)2 and electrolysis temperature of 45 ℃, the energy consumption is as low as 24.5 kW·h·(t Pb)-1 , only about 20% of that by Betts method at the same current density of 20 mA·cm-2, and the purity of the refined lead is up to 99.9992%, much higher than that specified by Chinese national standard(99.994%, GB/T 469-2013) and European standard(99.99%, EN 12659–1999). 展开更多
关键词 LEAD REFINING Perchloric ACID Fluoride-free ELECTROREFINING process
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High-throughput computational screening and design of nanoporous materials for methane storage and carbon dioxide capture 被引量:2
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作者 Minman Tong Youshi Lan +1 位作者 Qingyuan Yang Chongli Zhong 《Green Energy & Environment》 SCIE 2018年第2期107-119,共13页
The globally increasing concentrations of greenhouse gases in atmosphere after combustion of coal-or petroleum-based fuels give rise to tremendous interest in searching for porous materials to efficiently capture carb... The globally increasing concentrations of greenhouse gases in atmosphere after combustion of coal-or petroleum-based fuels give rise to tremendous interest in searching for porous materials to efficiently capture carbon dioxide(CO_2) and store methane(CH4), where the latter is a kind of clean energy source with abundant reserves and lower CO_2 emission. Hundreds of thousands of porous materials can be enrolled on the candidate list, but how to quickly identify the really promising ones, or even evolve materials(namely, rational design high-performing candidates) based on the large database of present porous materials? In this context, high-throughput computational techniques, which have emerged in the past few years as powerful tools, make the targets of fast evaluation of adsorbents and evolving materials for CO_2 capture and CH_4 storage feasible. This review provides an overview of the recent computational efforts on such related topics and discusses the further development in this field. 展开更多
关键词 High-throughput computation Screening and design Nanoporous materials CO2 capture CH4 storage
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Co-pyrolysis of soybean soapstock with iron slag/aluminum scrap,and characterization and analysis of their products 被引量:1
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作者 Xueguang Li Mengyan Yu +8 位作者 Changfa Zhang Xiangtong Li Guangqing Liu Jianjun Dai Chunbao Zhou Yang Liu Jie Fu Yingwen Zhang Bang Yao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第1期25-36,共12页
Soybean soapstock(SS) is one of the main solid wastes produced in the refinery of edible oil processing. In this study, the co-pyrolysis of SS with iron slag(IS) and aluminum scrap(AS) was carried out in a tubular fur... Soybean soapstock(SS) is one of the main solid wastes produced in the refinery of edible oil processing. In this study, the co-pyrolysis of SS with iron slag(IS) and aluminum scrap(AS) was carried out in a tubular furnace. The gas, liquid and solid products were characterized and the char yield decreased with increasing IS/AS ratio. IS and AS can improve the gas yield, and when the ratio of SS/IS was 1:0.25, the total pyrolysis gas and hydrogen contents were significantly increased. The content of oxygen compounds in pyrolysis oil decreased during co-pyrolysis, while AS promoted the content of polycyclic aromatic hydrocarbons in pyrolysis oil. The co-pyrolysis reaction can be divided into four stages, the mass loss rate reaches the maximum at the third stage(390–575 ℃). The molar ratio of H/C was lower for pyrolysis,indicating good stability of pyrolysis char owing to the high degree of carbonization and aromaticity.The possible co-pyrolysis reaction mechanism was explored. 展开更多
关键词 PYROLYSIS Soybean soapstock Iron slag Aluminum scrap Adsorption CATALYST
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Transformation of single drop breakup from binary to ternary and multiple in turbulent jet flows
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作者 Wenjun Liang Dengfei Wang +3 位作者 Meijuan Qian Ziqi Cai Zhipeng Li Zhengming Gao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第6期32-39,共8页
By releasing liquid drops in turbulent jet flows,we investigated the transformation of single drop breakup from binary to ternary and multiple.Silicone oil and deionized water were the dispersed phase and continuous p... By releasing liquid drops in turbulent jet flows,we investigated the transformation of single drop breakup from binary to ternary and multiple.Silicone oil and deionized water were the dispersed phase and continuous phase,respectively.The probability of binary,ternary,and multiple breakup of oil drops in jet flows is a function of the jet Reynolds number.To address the underlying mechanisms of this transformation of drop breakup,we performed two-dimensional particle image velocimetry(PIV)experiments of single-phase jet flows.With the combination of drop breakup phenomenon and two-dimensional PIV results in a single-phase flow field,these transformation conditions can be estimated:the capillary number ranges from 0.17 to 0.27,and the Weber number ranges from 55 to 111. 展开更多
关键词 DROP Multiple breakup Jet flows PIV Breakup mechanism
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2D polyaniline with exchangeable interlayer fluid for fast and stable volumetric dual ion storage
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作者 Xiaochen Yang Jiaxing Liang +5 位作者 Aditya Rawal Kefeng Xiao Yuan Pu Xiao Li Zhang Ruopian Fang Da-Wei Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第3期587-594,共8页
Two-dimensional(2D) layered materials are widely applied in energy devices including lithium-ion battery and supercapacitor due to their unique properties,such as tunable interlayer structure,numerous active sites,lar... Two-dimensional(2D) layered materials are widely applied in energy devices including lithium-ion battery and supercapacitor due to their unique properties,such as tunable interlayer structure,numerous active sites,large aspect ratio versatile interlayer chemistry.In this work,2D layered tungstate acidlinked polyaniline(TALP) presented a fluid-in-solid structure,which allowed facile exchange of the interlayer fluid from moisture to conventional Li^(+) containing electrolyte.With fast and stable dual ion storage(Li^(+) and PF_(6)^(-)),TALP demonstrates high-rate volumetric capacity(39 mAh cm_(-3) at 2000 mA g^(-1)) and good stability(2000 cycles at 200 mA g^(-1)) within the working potential window of 1.5-4.5 V versus Li^(+)/Li. 展开更多
关键词 Tungsten acid-linked polyaniline 2D material Fluid-in-solid Lithium-ion capacitor VOLUMETRIC
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Formation of the structure-Ⅱgas hydrate from low-concentration propane mixed with methane
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作者 Sanya Du Xiaomin Han +8 位作者 Wenjiu Cai Jinlong Zhu Xiaobai Ma Songbai Han Dongfeng Chen Yusheng Zhao Hui Li Hailong Lu Xiaohui Yu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第6期306-314,共9页
It has been recognized that a small amount of propane mixed with methane can change greatly in not only the thermodynamics but also the structural properties of gas hydrate.However,its mechanism is still not well unde... It has been recognized that a small amount of propane mixed with methane can change greatly in not only the thermodynamics but also the structural properties of gas hydrate.However,its mechanism is still not well understood yet.In this research,structure-Ⅱ(sⅡ)hydrate is synthesized using a methanepropane gas mixture with an initial mole ratio of 99:1,and it is found that large(5~(12)6~4)cages are cooccupied by multiple gases based on the rigid structure analysis of neutron diffraction data.The first principles calculation and molecular dynamics simulation are conducted to uncover the molecular mechanism for sⅡmethane-propane hydrate formation,revealing that the presence of propane inhibits the formation of structure-Ⅰ(sⅠ)hydrate but promotes sⅡhydrate formation.The results help to understand the accumulation mechanism of natural gas hydrate and benefit to optimize the condition for gas storage and transportation in hydrate form. 展开更多
关键词 Multiple guest molecules CLATHRATES Neutron powder diffraction Structural transformation Molecular mechanism
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When insulating polymers meet conjugated polymers:the noncovalent bonding does matter
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作者 Zhonggao Bu Chengyi Xiao +2 位作者 Jie Sun Weiwei Li Liming Ding 《Journal of Semiconductors》 EI CAS CSCD 2023年第11期5-7,共3页
Insulating polymers are characterized by a predominantlyσ-covalent structure,which localize electrons in the atoms and exhibit dielectricity.Insulating polymers typically adopt a more linear and extended conformation... Insulating polymers are characterized by a predominantlyσ-covalent structure,which localize electrons in the atoms and exhibit dielectricity.Insulating polymers typically adopt a more linear and extended conformation,as the repeating units are connected by single covalent bonds,resulting in a relatively straight and extended chain structure.For most insulating polymers,the contour length(L_(c))is significantly larger than their persistence length(Lp)due to the rotation of C−C single bonds(Fig.1(a)).Consequently,this leads to a flexible,random-coil chain conformation.This structural feature contributes to the great mechanical durability and resistance to crack initiation during stretching or bending processes.In contrast,conjugated polymers possess aπ-conjugated molecular structure,allowing electron mobility along the main chain,called delocalization,which imparts semiconducting properties[1,2].The presence of rigid,alternating single and multiple bonds results in comparable Lc and Lp,thereby yielding a stiff or semi-flexible conformation(Fig.1(b))[3,4].As a consequence,most conjugated polymers are prone to fracture under low strain levels(<10%)[5−7]. 展开更多
关键词 structure CONJUGATED BONDS
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Electrochemical converting ethanol to hydrogen and acetic acid for large scale green hydrogen production
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作者 Yufeng Zhang Wei Zhu +7 位作者 Jinjie Fang Zhiyuan Xu Yanrong Xue Jiajing Pei Rui Sui Xingdong Wang Xuejiang Zhang Zhongbin Zhuang 《Nano Research》 SCIE EI CSCD 2024年第3期1542-1551,共10页
Electrochemical coupling hydrogen evolution with biomass reforming reaction(named electrochemical hydrogen and chemical cogeneration(EHCC)),which realizes green hydrogen production and chemical upgrading simultaneousl... Electrochemical coupling hydrogen evolution with biomass reforming reaction(named electrochemical hydrogen and chemical cogeneration(EHCC)),which realizes green hydrogen production and chemical upgrading simultaneously,is a promising method to build a carbon-neutral society.Herein,we analyze the EHCC process by considering the market assessment.The ethanol to acetic acid and hydrogen approach is the most feasible for large-scale hydrogen production.We develop AuCu nanocatalysts,which can selectively oxidize ethanol to acetic acid(>97%)with high long-term activity.The isotopic and in-situ infrared experiments reveal that the promoted water dissociation step by alloying contributes to the enhanced activity of the partial oxidation reaction path.A flow-cell electrolyzer equipped with the AuCu anodic catalyst achieves the steady production of hydrogen and acetic acid simultaneously in both high selectivity(>90%),demonstrating the potential scalable application for green hydrogen production with low energy consumption and high profitability. 展开更多
关键词 selective ethanol electrooxidation gold alloy catalyst electrochemical-coupled hydrogen production market assessment interfacial water activation
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Buried interface management via bifunctional NH_(4)BF_(4)towards efficient CsPbI_(2)Br solar cells with a V_(oc)over 1.4 V
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作者 Fazheng Qiu Ming-Hua Li +1 位作者 Jinpeng Wu Jin-Song Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期364-370,I0009,共8页
CsPbI_(2)Br perovskite solar cells(PSCs)have drawn tremendous attention due to their suitable bandgap,excellent photothermal stability,and great potential as an ideal candidate for top cells in tandem solar cells.Howe... CsPbI_(2)Br perovskite solar cells(PSCs)have drawn tremendous attention due to their suitable bandgap,excellent photothermal stability,and great potential as an ideal candidate for top cells in tandem solar cells.However,the abundant defects at the buried interface and perovskite layer induce severe charge recombination,resulting in the open-circuit voltage(V_(oc))output and stability much lower than anticipated.Herein,a novel buried interface management strategy is developed to regulate interfacial carrier dynamics and CsPbI_(2)Br defects by introducing ammonium tetrafluoroborate(NH_(4)BF_(4)),thereby resulting in both high CsPbI_(2)Br crystallization and minimized interfacial energy losses.Specifically,NH_(4)^(+)ions could preferentially heal hydroxyl groups on the SnO_(2)surface and balance energy level alignment between SnO_(2)and CsPbI_(2)Br,enhancing charge transport efficiency,while BF_(4)^(-)anions as a quasi-halogen regulate crystal growth of CsPbI_(2)Br,thus reducing perovskite defects.Additionally,it is proved that eliminating hydroxyl groups at the buried interface enhances the iodide migration activation energy of CsPbI_(2)Br for strengthening the phase stability.As a result,the optimized CsPbI_(2)Br PSCs realize a remarkable efficiency of 17.09%and an ultrahigh V_(oc)output of 1.43 V,which is one of the highest values for CsPbI_(2)Br PSCs. 展开更多
关键词 Inorganic perovskite Buried interface Defect Stability Open-circuit voltage loss
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A general and facile calcination method to synthesize single-site catalysts for highly efficient electrochemical CO_(2) reduction
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作者 Rui Sui Bingyan Wang +6 位作者 Yongsheng Wang Jiajing Pei Wei Zhu Wenxing Chen Chunhui Li Ailing Sun Zhongbin Zhuang 《Nano Research》 SCIE EI CSCD 2024年第5期3895-3901,共7页
The electrochemical CO_(2) reduction reaction(CO_(2)RR)has received widespread attention as a promising method for producing sustainable chemicals and mitigating the global warming.Here,we demonstrate a general and fa... The electrochemical CO_(2) reduction reaction(CO_(2)RR)has received widespread attention as a promising method for producing sustainable chemicals and mitigating the global warming.Here,we demonstrate a general and facile synthetic route for the metal-nitrogen-carbon(M-N-C)type catalyst by simply calcinating metal acetate and urea with commercial carbon black,which have potential application in CO_(2)RR.The synthesized Ni-NC-600 catalyst has the structure of single Ni atom coordinated with one N atom and three C atoms(Ni-N_(1)C_(3)),which is suggested by X-ray absorption spectroscopy.The Ni-NC-600 catalyst exhibits high CO_(2)RR catalytic performance and a high CO Faraday efficiency above 98%in a wide potential range from-0.7 to-1.3 V(vs.reversible hydrogen electrode(RHE)),superior to most of the reported Ni-N-C catalysts.This work has developed a facile strategy to synthesize high performance CO_(2)RR catalyst. 展开更多
关键词 nickel single atom catalyst CO_(2)reduction reaction CO production ELECTROCATALYST
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