Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carb...Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carbon dioxide utilization and sequestration,but it also alleviates the environmental burden.However,significant challenges exist in assessment of CO_(2)footprint and water-rock interactions,due to complex geochemical processes.Herein this study conducts a three-dimensional,multicomponent reactive transport model(RTM)of a field-scale CO_(2)and O_(2)ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin,China.Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas(CO_(2))footprint and environmental impact(SO_(4)^(2–))of the CO_(2)and O_(2)ISL,considering the potential chemical reaction network for uranium recovery at the field scale.RTM results demonstrate that the fate of the CO_(2)could be summarized as injected CO_(2)dissolution,dissolved CO_(2)mineralization and storage of CO_(2)as a gas phase during the CO_(2)and O_(2)ISL process.Furthermore,compared to acid ISL,CO_(2)and O_(2)ISL has a potentially smaller environmental footprint,with 20%of SO_(4)^(2–)concentration in the aquifer.The findings improve our fundamental understanding of carbon utilization in a long-term CO_(2)and O_(2)ISL system and provide important environmental implications when considering complex geochemical processes.展开更多
A novel method of synthesizing seismic wave using wavelet reconstruction is proposed and compared with the traditional method of using theory of Fourier transform. By adjusting the frequency band energy and taking it ...A novel method of synthesizing seismic wave using wavelet reconstruction is proposed and compared with the traditional method of using theory of Fourier transform. By adjusting the frequency band energy and taking it as criterion, the formula of synthesizing seismic wave is deduced. Using the design parameters specified in Chinese Seismic Design Code for buildings, seismic waves are synthesized. Moreover, the method of selecting wavelet bases in synthesizing seismic wave and the influence of the damping ratio on synthesizing results are analyzed. The results show that the synthesis seismic waves using wavelet bases can represent the characteristics of the seismic wave as well as the ground characteristic period, and have good time-frequency non-stationary.展开更多
Calibration-free(CF)laser-induced breakdown spectroscopy(LIBS)is normally only applicable for gated detectors due to its dependence on the assumption of a steady-state plasma.However,most currently available LIBS syst...Calibration-free(CF)laser-induced breakdown spectroscopy(LIBS)is normally only applicable for gated detectors due to its dependence on the assumption of a steady-state plasma.However,most currently available LIBS systems are equipped with non-gated detectors such as chargecoupled device(CCD),which degrades the accuracy of CF method.In this paper,the reason for the less satisfactory quantification performance of CF for LIBS with non-gated detectors was clarified and a time-integration calibration-free(TICF)model was proposed for applications with non-gated detectors.It was based on an assumed temporal profile of plasma properties,including temperature and electron density,obtained from another pre-experiment.The line intensity at different time during the signal collection time window was estimated with self-absorption correction according to the temporal profile of the plasma properties.The proposed model was validated on titanium alloys and compared with traditional CF.The accuracy of elemental concentration measurement was improved significantly:the average relative error of aluminum and vanadium decreased from 6.07%and 22.34%to 2.01%and 1.92%,respectively.The quantification results showed that TICF method was able to extend the applicability of CF to LIBS with non-gated detectors.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.U2167212)。
文摘Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carbon dioxide utilization and sequestration,but it also alleviates the environmental burden.However,significant challenges exist in assessment of CO_(2)footprint and water-rock interactions,due to complex geochemical processes.Herein this study conducts a three-dimensional,multicomponent reactive transport model(RTM)of a field-scale CO_(2)and O_(2)ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin,China.Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas(CO_(2))footprint and environmental impact(SO_(4)^(2–))of the CO_(2)and O_(2)ISL,considering the potential chemical reaction network for uranium recovery at the field scale.RTM results demonstrate that the fate of the CO_(2)could be summarized as injected CO_(2)dissolution,dissolved CO_(2)mineralization and storage of CO_(2)as a gas phase during the CO_(2)and O_(2)ISL process.Furthermore,compared to acid ISL,CO_(2)and O_(2)ISL has a potentially smaller environmental footprint,with 20%of SO_(4)^(2–)concentration in the aquifer.The findings improve our fundamental understanding of carbon utilization in a long-term CO_(2)and O_(2)ISL system and provide important environmental implications when considering complex geochemical processes.
基金'Qing Lan' Talent Engineering Funds by Lanzhou Jiaotong University (QL-05-08A).
文摘A novel method of synthesizing seismic wave using wavelet reconstruction is proposed and compared with the traditional method of using theory of Fourier transform. By adjusting the frequency band energy and taking it as criterion, the formula of synthesizing seismic wave is deduced. Using the design parameters specified in Chinese Seismic Design Code for buildings, seismic waves are synthesized. Moreover, the method of selecting wavelet bases in synthesizing seismic wave and the influence of the damping ratio on synthesizing results are analyzed. The results show that the synthesis seismic waves using wavelet bases can represent the characteristics of the seismic wave as well as the ground characteristic period, and have good time-frequency non-stationary.
基金supports from National Natural Science Foundation of China(No.51906124)Shanxi Province Science and Technology Department(No.20201101013)+1 种基金Guoneng Bengbu Power Generation Co.,Ltd.(20212000001)Scientific Research Program for Young Talents of China National Nuclear Corporation(2020).
文摘Calibration-free(CF)laser-induced breakdown spectroscopy(LIBS)is normally only applicable for gated detectors due to its dependence on the assumption of a steady-state plasma.However,most currently available LIBS systems are equipped with non-gated detectors such as chargecoupled device(CCD),which degrades the accuracy of CF method.In this paper,the reason for the less satisfactory quantification performance of CF for LIBS with non-gated detectors was clarified and a time-integration calibration-free(TICF)model was proposed for applications with non-gated detectors.It was based on an assumed temporal profile of plasma properties,including temperature and electron density,obtained from another pre-experiment.The line intensity at different time during the signal collection time window was estimated with self-absorption correction according to the temporal profile of the plasma properties.The proposed model was validated on titanium alloys and compared with traditional CF.The accuracy of elemental concentration measurement was improved significantly:the average relative error of aluminum and vanadium decreased from 6.07%and 22.34%to 2.01%and 1.92%,respectively.The quantification results showed that TICF method was able to extend the applicability of CF to LIBS with non-gated detectors.
