Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using exi...Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using existing alloys for laser powder bed fusion(L-PBF)AM have persisted.These challenges arise because commercial alloys are primarily designed for conventional casting or forging processes,overlooking the fast cooling rates,steep temperature gradients and multiple thermal cycles of L-PBF.To address this,there is an urgent need to develop novel alloys specifically tailored for L-PBF technologies.This review provides a comprehensive summary of the strategies employed in alloy design for L-PBF.It aims to guide future research on designing novel alloys dedicated to L-PBF instead of adapting existing alloys.The review begins by discussing the features of the L-PBF processes,focusing on rapid solidification and intrinsic heat treatment.Next,the printability of the four main existing alloys(Fe-,Ni-,Al-and Ti-based alloys)is critically assessed,with a comparison of their conventional weldability.It was found that the weldability criteria are not always applicable in estimating printability.Furthermore,the review presents recent advances in alloy development and associated strategies,categorizing them into crack mitigation-oriented,microstructure manipulation-oriented and machine learning-assisted approaches.Lastly,an outlook and suggestions are given to highlight the issues that need to be addressed in future work.展开更多
The paper gives an analysis on technical characteristics of repair techniques for friction stir welding defects. To overcome the defects,a new repair technique, inertia friction pull plug welding( IFPPW), was research...The paper gives an analysis on technical characteristics of repair techniques for friction stir welding defects. To overcome the defects,a new repair technique, inertia friction pull plug welding( IFPPW), was researched and its equipment was developed as well. Elementary datum was achieved by investigating the influences of technological parameters on mechanical properties and by analyzing the structural characteristics of repair joint with IFPPW. The study shows that the stability and reliability of welding process of IFPPW can be guaranteed through the constant energy from the flywheel.Integrated with the advantages of friction pull plug welding,the IFPPW,free from back anvil,is considered as a promising technique in repair of termination keyhole of bobbin tool friction stir welding and point-like defects in aluminum alloy welding.展开更多
In order to clarify the characteristics and formation mechanism of the reheat cracking in Ti2AlNb weldments,a series of heat treatment conditions were performed to the circular joints welded by electron beam,and then ...In order to clarify the characteristics and formation mechanism of the reheat cracking in Ti2AlNb weldments,a series of heat treatment conditions were performed to the circular joints welded by electron beam,and then the macrostructures and microstructures were investigated using optical microscopy,scanning electron microscopy,X-ray diffractometry,and transmission electron microscopy.The results show that the reheat cracking occurs primarily along the grain boundaries in the weld when the Ti2AlNb circular welded joints are heated up to about 700℃.During the heat treatment,an almost complete transformation of B2→O happens while the temperature goes up through the O single-phase region.Then,O→B2+O phase transformation occurs primarily along the grain boundaries as the weld metal continues to heat up to the B2+O dual-phase region.Under the high tension stress consisting of welding residual stress and phase transformation stress,reheat cracking occurs at the interface between the B2+O dual-phase layer and the O-phase matrix.展开更多
In order to estimate the residual stresses in Ti2AlNb alloy jointed by electron beam welding (EBW), a computational approach based on finite element method was developed. Meanwhile, experiments were carried out to ver...In order to estimate the residual stresses in Ti2AlNb alloy jointed by electron beam welding (EBW), a computational approach based on finite element method was developed. Meanwhile, experiments were carried out to verify the numerical results. The comparison between the simulation results and measurements suggests that the developed computational approach has sufficient accuracy to predict the welding residual stress distributions. The results show that the central area of the fusion zone suffers tensile stresses in three directions. When the other parameters remain unchanged, the focus current has great impact on the weld shape and size, and then affects the residual stress level significantly. Moreover, the thick plate full-penetrated EBW weld suffers near 1000 MPa tensile stress of Z-direction in the center of the fusion zone. The wider weld has lower tensile stress in Z-direction, resulting in lower risk for cracking.展开更多
Numerical simulation and experimental methods were used to investigate the effects of weld penetration on tensile properties of 2219 aluminum alloy tungsten inert gas(TIG)welded joints.The results show that when other...Numerical simulation and experimental methods were used to investigate the effects of weld penetration on tensile properties of 2219 aluminum alloy tungsten inert gas(TIG)welded joints.The results show that when other geometric parameters are consistent,within a certain range,the deeper the weld penetration of the capping weld is,the lower the tensile strength of the j oint is.The deeper weld penetration of the capping weld can cause the more concentrated stress at the weld toe and the joint is more likely to crack accordingly.Based on necessary assumptions,a model for analyzing the mathematical relation between the weld penetration of the capping weld and the tensile strength of the joint was proposed to validate the experimental results. The decrease of weld penetration of capping weld can be controlled by decreasing welding current,helium content or increasing welding voltage.展开更多
In this work, transformation behaviors and mechanical properties of cold-rolled shape memory alloy TisoNia9Fel by severe plastic deformation （SPD） were intensively investigated. The phase transformation behaviors, p...In this work, transformation behaviors and mechanical properties of cold-rolled shape memory alloy TisoNia9Fel by severe plastic deformation （SPD） were intensively investigated. The phase transformation behaviors, phase analysis, and microstructures were characterized by differential scanning calorimetry （DSC）, X-ray diffraction （XRD）, and transmission electron microscopy （TEM）, respectively. Tensile testing was performed to analyze the effect of SPD on the mechanical properties and shape memory of TisoNi49Fel alloy. When the thickness reduction is beyond 30 %, the martensitic transformation is suppressed. After cold-rolling, the alloy is mainly com- posed of B2 parent phases with some stress-induced martensitic B 19t phases, and high density of dislocations are generated and the grains are obviously refined. The yield stress ab significantly raises from 618 MPa of 0 % cold rolling to 1,338 MPa of 50 % SPD. Shape-memory effect increases from 6.5 % without cold rolling to 8.5 % after 30 % SPD, ascribed to the induced defects in cold rolling. Those results indicate that TisoNi49Fel alloy has improved mechanical properties and potential commercial applications after SPD.展开更多
Rice straw physicochemical characteristics and anaerobic digestion(AD)performance via ammonia pretreatment at varying ammonia concentrations(2%,4%,and 6%)and moisture contents(30%,50%,70%,and 90%)under a mild conditio...Rice straw physicochemical characteristics and anaerobic digestion(AD)performance via ammonia pretreatment at varying ammonia concentrations(2%,4%,and 6%)and moisture contents(30%,50%,70%,and 90%)under a mild condition were investigated.The results showed that the ammonia pretreatment effectively damaged the rice straw structure,increased the soluble organic concentration,and improved rice straw hydrolysis and AD performance.After pretreatment,the ester bond and ether bond were ruptured in lignocellulose and the volatile fatty acids(VFAs)were within the range of 1457.81–1823.67 mg·L-1.In addition,ammonia pretreatment had high selectivity on lignin removal,resulting in a maximum lignin removal rate of 50.80%.The highest methane yield of rice straw was 250.34 ml·(g VS)-1 at a 4%ammonia concentration coupled with a 70%moisture content,which was 28.55%higher than that of the control.The result showed that ammonia pretreatment of rice straw is technically suitable to enhance AD performance for further application.展开更多
The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron m...The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron microscopy(TEM). The results indicate that with the increase of second-step aging time of two-step aging, the mechanical properties increase first and then decrease, while the SCC resistance increases. Compared with two-step aging, three-step aging treatment improves SCC resistance and the strength increases by about 5%. The effects of novel three-step aging on strength and SCC resistance are explained by the role of matrix precipitates and grain boundary precipitates, respectively.展开更多
The butt welds of 4-mm thick 5A06 aluminum alloy plates were produced by adjustable-gap bobbin-tool friction stir travel with travel speeds of 200, 300, and 400 mm/min in this study.The microstructure was studied usin...The butt welds of 4-mm thick 5A06 aluminum alloy plates were produced by adjustable-gap bobbin-tool friction stir travel with travel speeds of 200, 300, and 400 mm/min in this study.The microstructure was studied using optical microscopy and electron backscatter diffraction(EBSD).Tensile tests and microhardness measurements were performed to identify the effect of the travel speed on the joint mechanical properties.Sound joints were obtained at 200 mm/min while voids were present at different positions of the joints as the travel speed increased.The EBSD results show that the grain size, high angle grain boundaries, and density of geometrically necessary dislocations in different regions of the joint vary depending on the recovery and recrystallization behavior.Specific attention was given to the relationship between the local microstructure and mechanical properties.Microhardness measurements show that the average hardness of the stir zone(SZ) was greater than that of the base material, which was only affected slightly by the travel speed.The tensile strength of the joint decreased with increasing travel speed and the maximal strength efficiency reached 99%.展开更多
Wall structures were made by cold metal transfer-based wire and arc additive manufacturing using two kinds of ER2319 welding wires with and without Cd elements. T6 heat treatment was used to improve mechanical propert...Wall structures were made by cold metal transfer-based wire and arc additive manufacturing using two kinds of ER2319 welding wires with and without Cd elements. T6 heat treatment was used to improve mechanical properties of these wall structures. Due to the higher vacancy binding energy of Cd, Cd-vacancy clusters are formed in the aging process and provide a large number of nucleation locations for θ′ phases. The higher diffusion coefficient of the Cd-vacancy cluster and the lower interfacial energy of θ′ phase lead to the formation of dense θ′ phases in the heat-treated α(Al). According to the strengthening model, after adding Cd in ER2319 welding wires, the yield strength increases by 43 MPa in the building direction of the heat-treated wall structures.展开更多
To investigate the influence of temperature field of friction stir welding(FSW)2219 aluminum alloy thick plate,and to achieve effective prediction of temperature field,the authors establish a three-dimensional numeric...To investigate the influence of temperature field of friction stir welding(FSW)2219 aluminum alloy thick plate,and to achieve effective prediction of temperature field,the authors establish a three-dimensional numerical simulation model of FSW 18 mm thick 2219 aluminum alloy based on ABAQUS/CEL,considering the morphological characteristics of the tool pin.The simulations of plunging,dwelling,and welding stages are achieved.The distribution of temperature and temperature cycle curve of characteristic points in welding process are obtained.The validity of the simulation results is verified by experiments.The influence of the tool-rotational speed and welding speed on temperature field is explored.The work lays a foundation for the prediction and control of temperature field in FSW medium thickness 2219 aluminum alloy,and provides reference for selection of welding parameters to ensure high quality welding of fuel tank of heavy-lift rocket.展开更多
Microstructure, texture and hardness evolutions of Al-Mg-Si-Cu alloy during annealing treatment were studied by microstructure, texture and hardness characterization in the present study. The experimental results show...Microstructure, texture and hardness evolutions of Al-Mg-Si-Cu alloy during annealing treatment were studied by microstructure, texture and hardness characterization in the present study. The experimental results show that microstructure, texture and hardness will change to some extent with the increase of annealing temperature. The microstructure transforms from the elongated bands to elongated grains first, and then the grains grow continuously. The texture transforms from the initial deformation texture b fiber to recrystallization texture mainly consisting of CubeND {001}<310> and P {011}<122> orientations first, and then the recrystallization texture may be enhanced continuously as a result of the grain growth. Hardness decreases slowly at first, and then decreases sharply and increases significantly finally. Besides, the particle distributions also have great changes. As the annealing temperature increases, they increase firstly as a result of precipitation, and then gradually disappear as a result of dissolution. Finally, the effect of annealing temperature on microstructure, texture and hardness evolutions is discussed.展开更多
The distribution of residual stresses through thickness of 5 mm-thick ME21 magnesium alloy extruded plates was analyzed non-destructively using short-wavelength X-ray diffraction(SWXRD),and the effect of homogenizatio...The distribution of residual stresses through thickness of 5 mm-thick ME21 magnesium alloy extruded plates was analyzed non-destructively using short-wavelength X-ray diffraction(SWXRD),and the effect of homogenization annealing before extrusion on the residual stress was discussed.The classic d 0 method with an annealed stress-free reference specimen was employed to determine the residual stress of the extruded plates.The residual stress results showed that the gradient of residual stress in the transverse direction was larger than that of the extrusion direction.The homogenization process prior to extrusion weaken the formed sample’s texture.The maximum residual stress of the as-extruded plate was reduced,and the residual stress distribution was homogenized.展开更多
Wire arc additive manufacture(WAAM) is a new technique to fabricate large-scale complex aluminum alloy components.However, the performance of the parts is critically influenced by residual stresses and deformation. A ...Wire arc additive manufacture(WAAM) is a new technique to fabricate large-scale complex aluminum alloy components.However, the performance of the parts is critically influenced by residual stresses and deformation. A sequentially thermal-mechanical coupled model of residual stress and deformation for aluminum alloy WAAM parts was established based on commercial FE software ABAQUS. The temperature field was calculated by the moving heat source(MHS) method. The temperature function was obtained according to the distribution of the peak temperature. Furthermore, the MHS method and segmented temperature function(STF) method were used to calculate the residual stress and deformation. The results show that the STF method satisfies both the efficiency and accuracy requirements. 1-segment, 3-segment, and 5-segment STF methods can shorten the time for mechanical analysis by 91%, 79%, 63%, respectively.The error of the residual stress and deformation are all less than 20%. STF method provides an effective way to predict the residual stress and deformation of large-scale WAAM parts.展开更多
In order to study the effect of dynamic recrystallization on the metal flow behavior during thermal deformation,the elevated temperature compression experiments of CuCrZr alloy and 35CrMo steel are carried out using G...In order to study the effect of dynamic recrystallization on the metal flow behavior during thermal deformation,the elevated temperature compression experiments of CuCrZr alloy and 35CrMo steel are carried out using Gleeble-3810 thermal simulator.It is proved that the samples underwent obvious dynamic recrystallization behavior during thermal deformation by microstructure observation of deformed specimens.The size of recrystallized grains increases as the temperature improved and the strain rate decreased.Meanwhile,the net softening rate caused by dynamic recrystallization is determined based on the stress-dislocation relationship.It can be found that the value of net softening rate increases quadratically as the Z parameter decreases,and the dynamic recrystallization net softening rate of CuCrZr alloy and 35CrMo steel are calculated to be 21.9%and 29.8%,respectively.Based on the dynamic recrystallization softening effect proposed,the novel elevated temperature flow constitutive models of two different alloys are proposed,and the related parameters are well defined and solved in detail.The predicted values of the obtained models are agreed well with the experimental values.展开更多
The effect of particle size distribution on the microstructure,texture,and mechanical properties of Al–Mg–Si–Cu alloy was investigated on the basis of the mechanical properties,microstructure,and texture of the all...The effect of particle size distribution on the microstructure,texture,and mechanical properties of Al–Mg–Si–Cu alloy was investigated on the basis of the mechanical properties,microstructure,and texture of the alloy.The results show that the particle size distribution influences the microstructure and the final mechanical properties but only slightly influences the recrystallization texture.After the pre-aging treatment and natural aging treatment(T4 P treatment),in contrast to the sheet with a uniform particle size distribution,the sheet with a bimodal particle size distribution of large constituent particles and small dispersoids exhibits higher strength and a somewhat lower plastic strain ratio(r) and strain hardening exponent(n).After solution treatment,the sheet with a bimodal particle size distribution of large constituent particles and small dispersoids possesses a finer and slightly elongated grain structure compared with the sheet with a uniform particle size distribution.Additionally,they possess almost identical weak recrystallization textures,and their textures are dominated by CubeND {001}<310> and P {011}<122> orientations.展开更多
Microstructural evolution and its effect on mechanical properties in different regions of 2219-C10S aluminum alloy tungsten inert gas(TIG)welded joint were analyzed in detail.In weld zone(WZ),α+θeutectic structure f...Microstructural evolution and its effect on mechanical properties in different regions of 2219-C10S aluminum alloy tungsten inert gas(TIG)welded joint were analyzed in detail.In weld zone(WZ),α+θeutectic structure formed at grain boundaries with no precipitates inside the grains.In partially melted zone(PMZ),symbiotic eutectic or divorced eutectic formed at grain boundaries and needle-likeθ′phases appeared in the secondary heated zone.In over aged zone(OAZ),the coarsening and dissolution ofθ′phases occurred and mostθ′phases transformed intoθphases.In general heat affected zone(HAZ),θ′phases coarsened.Factors such as the strengthening phases,the grain size,the Cu content in matrix and the dislocation density can affect the mechanical properties in different regions of the joint.Moreover,a model describing the relationship between mechanical properties of the material and the volume fraction of precipitates,the average diameter of precipitates and the concentration of soluble elements was proposed.展开更多
The parasitic motion has been widely recognized as the major drawback of the parallel mechanism.Therefore a class of 2R1T PMs(parallel mechanism)without parasitic motion has been synthesized.However,these PMs can only...The parasitic motion has been widely recognized as the major drawback of the parallel mechanism.Therefore a class of 2R1T PMs(parallel mechanism)without parasitic motion has been synthesized.However,these PMs can only rotate around two axes in sequential order.It decreases the performance of the balancing adjustment of the end-efector.In this paper,a family of 2R1T PMs without parasitic motion was reconstructed by using a novel method based on the remarkable properties of rotational bifurcation mechanisms,which can rotate in sequential order.Furthermore,some PMs rotating around two continuous axes in an arbitrary order are established by adding single joints.Taking the practicability of these structures into consideration,the workspace of 3-PRPS PM was analyzed as an example.Moreover,this study explores the practical application of the PMs without parasitic motion in developing balance mechanisms in rough-terrain fre-fghting robots.During the climbing process,the tank is adjusted to be parallel to the horizontal plane in real-time.It is proved that this kind of structure realizes continuous rotation around two rotation axes on the premise of no parasitic motion.展开更多
The bobbin tool friction stir welding process was used to join 6 mm thick 5A06 aluminum alloy plates.Optical microscope was used to characterize the microstructure.The electron backscatter diffraction(EBSD)identified ...The bobbin tool friction stir welding process was used to join 6 mm thick 5A06 aluminum alloy plates.Optical microscope was used to characterize the microstructure.The electron backscatter diffraction(EBSD)identified the effect of non-homogeneous microstructure on the tensile properties.It was observed that the grain size in the top of the stir zone(SZ)is smaller than that in the centre region.The lowest ratio of recrystallization and density of the geometrically-necessary dislocations(GNDs)in the SZ was found in the middle near the thermo-mechanically affected zone(TMAZ)being 22%and 1.15×10^(−13) m^(−2),respectively.The texture strength of the heat-affected zone(HAZ)is the largest,followed by that in the SZ,with the lowest being in the TMAZ.There were additional interfaces developed which contributed to the strengthening mechanism,and their effect on tensile strength was analysed.The tensile tests identified the weakest part in the joint at the interfaces,and the specific reduction value is about 93 MPa.展开更多
In the friction stir welding （FSW） process, welding speed and tool rotation speed are two important parameters, which have great effect on the weld quality. Because neither of each parameter can ensure the welding p...In the friction stir welding （FSW） process, welding speed and tool rotation speed are two important parameters, which have great effect on the weld quality. Because neither of each parameter can ensure the welding process effectively, an energy factor n, which is the ratio of rotation speed（to） to welding speed （v）, was selected to represent the heat generation intensity. According to this energy input factor n, the effect of heat input on the weld quality was estimated qualitatively. The results show that the optimized scope for the factor n should be within 2. 5 and 6. 0, outside of which groove defects and burr defects will appear.展开更多
基金financially supported by the National Key Research and Development Program of China(2022YFB4600302)National Natural Science Foundation of China(52090041)+1 种基金National Natural Science Foundation of China(52104368)National Major Science and Technology Projects of China(J2019-VII-0010-0150)。
文摘Metal additive manufacturing(AM)has been extensively studied in recent decades.Despite the significant progress achieved in manufacturing complex shapes and structures,challenges such as severe cracking when using existing alloys for laser powder bed fusion(L-PBF)AM have persisted.These challenges arise because commercial alloys are primarily designed for conventional casting or forging processes,overlooking the fast cooling rates,steep temperature gradients and multiple thermal cycles of L-PBF.To address this,there is an urgent need to develop novel alloys specifically tailored for L-PBF technologies.This review provides a comprehensive summary of the strategies employed in alloy design for L-PBF.It aims to guide future research on designing novel alloys dedicated to L-PBF instead of adapting existing alloys.The review begins by discussing the features of the L-PBF processes,focusing on rapid solidification and intrinsic heat treatment.Next,the printability of the four main existing alloys(Fe-,Ni-,Al-and Ti-based alloys)is critically assessed,with a comparison of their conventional weldability.It was found that the weldability criteria are not always applicable in estimating printability.Furthermore,the review presents recent advances in alloy development and associated strategies,categorizing them into crack mitigation-oriented,microstructure manipulation-oriented and machine learning-assisted approaches.Lastly,an outlook and suggestions are given to highlight the issues that need to be addressed in future work.
文摘The paper gives an analysis on technical characteristics of repair techniques for friction stir welding defects. To overcome the defects,a new repair technique, inertia friction pull plug welding( IFPPW), was researched and its equipment was developed as well. Elementary datum was achieved by investigating the influences of technological parameters on mechanical properties and by analyzing the structural characteristics of repair joint with IFPPW. The study shows that the stability and reliability of welding process of IFPPW can be guaranteed through the constant energy from the flywheel.Integrated with the advantages of friction pull plug welding,the IFPPW,free from back anvil,is considered as a promising technique in repair of termination keyhole of bobbin tool friction stir welding and point-like defects in aluminum alloy welding.
文摘In order to clarify the characteristics and formation mechanism of the reheat cracking in Ti2AlNb weldments,a series of heat treatment conditions were performed to the circular joints welded by electron beam,and then the macrostructures and microstructures were investigated using optical microscopy,scanning electron microscopy,X-ray diffractometry,and transmission electron microscopy.The results show that the reheat cracking occurs primarily along the grain boundaries in the weld when the Ti2AlNb circular welded joints are heated up to about 700℃.During the heat treatment,an almost complete transformation of B2→O happens while the temperature goes up through the O single-phase region.Then,O→B2+O phase transformation occurs primarily along the grain boundaries as the weld metal continues to heat up to the B2+O dual-phase region.Under the high tension stress consisting of welding residual stress and phase transformation stress,reheat cracking occurs at the interface between the B2+O dual-phase layer and the O-phase matrix.
基金Project(CALT201309)supported by Joint Innovation Fund for China Academy of Launch Vehicle Technology and Colleges
文摘In order to estimate the residual stresses in Ti2AlNb alloy jointed by electron beam welding (EBW), a computational approach based on finite element method was developed. Meanwhile, experiments were carried out to verify the numerical results. The comparison between the simulation results and measurements suggests that the developed computational approach has sufficient accuracy to predict the welding residual stress distributions. The results show that the central area of the fusion zone suffers tensile stresses in three directions. When the other parameters remain unchanged, the focus current has great impact on the weld shape and size, and then affects the residual stress level significantly. Moreover, the thick plate full-penetrated EBW weld suffers near 1000 MPa tensile stress of Z-direction in the center of the fusion zone. The wider weld has lower tensile stress in Z-direction, resulting in lower risk for cracking.
基金Project(U1637601)supported by the Joint Funds of the National Natural Science Foundation of China
文摘Numerical simulation and experimental methods were used to investigate the effects of weld penetration on tensile properties of 2219 aluminum alloy tungsten inert gas(TIG)welded joints.The results show that when other geometric parameters are consistent,within a certain range,the deeper the weld penetration of the capping weld is,the lower the tensile strength of the j oint is.The deeper weld penetration of the capping weld can cause the more concentrated stress at the weld toe and the joint is more likely to crack accordingly.Based on necessary assumptions,a model for analyzing the mathematical relation between the weld penetration of the capping weld and the tensile strength of the joint was proposed to validate the experimental results. The decrease of weld penetration of capping weld can be controlled by decreasing welding current,helium content or increasing welding voltage.
基金supported by the National Natural Science Foundation of China (No. 50921003)the Industry, Education and Research Projects of the China Aviation Industrial (No. cxy2012BH04)
文摘In this work, transformation behaviors and mechanical properties of cold-rolled shape memory alloy TisoNia9Fel by severe plastic deformation （SPD） were intensively investigated. The phase transformation behaviors, phase analysis, and microstructures were characterized by differential scanning calorimetry （DSC）, X-ray diffraction （XRD）, and transmission electron microscopy （TEM）, respectively. Tensile testing was performed to analyze the effect of SPD on the mechanical properties and shape memory of TisoNi49Fel alloy. When the thickness reduction is beyond 30 %, the martensitic transformation is suppressed. After cold-rolling, the alloy is mainly com- posed of B2 parent phases with some stress-induced martensitic B 19t phases, and high density of dislocations are generated and the grains are obviously refined. The yield stress ab significantly raises from 618 MPa of 0 % cold rolling to 1,338 MPa of 50 % SPD. Shape-memory effect increases from 6.5 % without cold rolling to 8.5 % after 30 % SPD, ascribed to the induced defects in cold rolling. Those results indicate that TisoNi49Fel alloy has improved mechanical properties and potential commercial applications after SPD.
基金the funding support from the Tianjin City Science and Technology Planning Project of the People’s Republic of China(grant number 18ZXSZSF00120).
文摘Rice straw physicochemical characteristics and anaerobic digestion(AD)performance via ammonia pretreatment at varying ammonia concentrations(2%,4%,and 6%)and moisture contents(30%,50%,70%,and 90%)under a mild condition were investigated.The results showed that the ammonia pretreatment effectively damaged the rice straw structure,increased the soluble organic concentration,and improved rice straw hydrolysis and AD performance.After pretreatment,the ester bond and ether bond were ruptured in lignocellulose and the volatile fatty acids(VFAs)were within the range of 1457.81–1823.67 mg·L-1.In addition,ammonia pretreatment had high selectivity on lignin removal,resulting in a maximum lignin removal rate of 50.80%.The highest methane yield of rice straw was 250.34 ml·(g VS)-1 at a 4%ammonia concentration coupled with a 70%moisture content,which was 28.55%higher than that of the control.The result showed that ammonia pretreatment of rice straw is technically suitable to enhance AD performance for further application.
基金Project(2012CB619502)supported by the National Basic Research Program of ChinaProject(2016YFB0300800)supported by the National Key Research and Development Program of China+1 种基金Project(CALT201507)supported by the CALT Research Innovation Partnership Fund,ChinaProject(HPCM-201403)supported by the State Key Laboratory of High Performance Complex Manufacturing,China
文摘The influence of a novel three-step aging on strength, stress corrosion cracking(SCC) and microstructure of AA7085 was investigated by tensile testing and slow strain rate testing combined with transmission electron microscopy(TEM). The results indicate that with the increase of second-step aging time of two-step aging, the mechanical properties increase first and then decrease, while the SCC resistance increases. Compared with two-step aging, three-step aging treatment improves SCC resistance and the strength increases by about 5%. The effects of novel three-step aging on strength and SCC resistance are explained by the role of matrix precipitates and grain boundary precipitates, respectively.
基金financially supported by the State Key Laboratory of Solidification Processing (Northwestern Polytechnical University, China) under Grant 2019-QZ-01。
文摘The butt welds of 4-mm thick 5A06 aluminum alloy plates were produced by adjustable-gap bobbin-tool friction stir travel with travel speeds of 200, 300, and 400 mm/min in this study.The microstructure was studied using optical microscopy and electron backscatter diffraction(EBSD).Tensile tests and microhardness measurements were performed to identify the effect of the travel speed on the joint mechanical properties.Sound joints were obtained at 200 mm/min while voids were present at different positions of the joints as the travel speed increased.The EBSD results show that the grain size, high angle grain boundaries, and density of geometrically necessary dislocations in different regions of the joint vary depending on the recovery and recrystallization behavior.Specific attention was given to the relationship between the local microstructure and mechanical properties.Microhardness measurements show that the average hardness of the stir zone(SZ) was greater than that of the base material, which was only affected slightly by the travel speed.The tensile strength of the joint decreased with increasing travel speed and the maximal strength efficiency reached 99%.
基金the financial support from the National Key Technologies Research & Development Program of China (No. 2018YFB1106000)the Youth Talent Project of CAST (No. 2019QNRC001)。
文摘Wall structures were made by cold metal transfer-based wire and arc additive manufacturing using two kinds of ER2319 welding wires with and without Cd elements. T6 heat treatment was used to improve mechanical properties of these wall structures. Due to the higher vacancy binding energy of Cd, Cd-vacancy clusters are formed in the aging process and provide a large number of nucleation locations for θ′ phases. The higher diffusion coefficient of the Cd-vacancy cluster and the lower interfacial energy of θ′ phase lead to the formation of dense θ′ phases in the heat-treated α(Al). According to the strengthening model, after adding Cd in ER2319 welding wires, the yield strength increases by 43 MPa in the building direction of the heat-treated wall structures.
基金supported by the National Key Research and Development Program of China(Grant No.2019YFA0709003)Dalian Science and Technology Innovation Fund(Grant No.2020JJ26GX041)the Fundamental Research Funds for the Central Universities(Grant No.DUT20ZD204)。
文摘To investigate the influence of temperature field of friction stir welding(FSW)2219 aluminum alloy thick plate,and to achieve effective prediction of temperature field,the authors establish a three-dimensional numerical simulation model of FSW 18 mm thick 2219 aluminum alloy based on ABAQUS/CEL,considering the morphological characteristics of the tool pin.The simulations of plunging,dwelling,and welding stages are achieved.The distribution of temperature and temperature cycle curve of characteristic points in welding process are obtained.The validity of the simulation results is verified by experiments.The influence of the tool-rotational speed and welding speed on temperature field is explored.The work lays a foundation for the prediction and control of temperature field in FSW medium thickness 2219 aluminum alloy,and provides reference for selection of welding parameters to ensure high quality welding of fuel tank of heavy-lift rocket.
基金Funded by the Science Challenge Project(No.TZ2018001)the Zhejiang Provincial Natural Science Foundation of China(No.LQ17E010001)+2 种基金the Ningbo Natural Science Foundation(No.2018A610174)the Natural Science Foundation of Ningbo University(No.XYL18017)the KC Wong Magna Fund from Ningbo University
文摘Microstructure, texture and hardness evolutions of Al-Mg-Si-Cu alloy during annealing treatment were studied by microstructure, texture and hardness characterization in the present study. The experimental results show that microstructure, texture and hardness will change to some extent with the increase of annealing temperature. The microstructure transforms from the elongated bands to elongated grains first, and then the grains grow continuously. The texture transforms from the initial deformation texture b fiber to recrystallization texture mainly consisting of CubeND {001}<310> and P {011}<122> orientations first, and then the recrystallization texture may be enhanced continuously as a result of the grain growth. Hardness decreases slowly at first, and then decreases sharply and increases significantly finally. Besides, the particle distributions also have great changes. As the annealing temperature increases, they increase firstly as a result of precipitation, and then gradually disappear as a result of dissolution. Finally, the effect of annealing temperature on microstructure, texture and hardness evolutions is discussed.
基金This work is supported by the National Key R&D Plan(grant No.2016YFB0301105)the Fundamental Research Funds for the Central Universities(grant No.FRF-TP-16-016A1).
文摘The distribution of residual stresses through thickness of 5 mm-thick ME21 magnesium alloy extruded plates was analyzed non-destructively using short-wavelength X-ray diffraction(SWXRD),and the effect of homogenization annealing before extrusion on the residual stress was discussed.The classic d 0 method with an annealed stress-free reference specimen was employed to determine the residual stress of the extruded plates.The residual stress results showed that the gradient of residual stress in the transverse direction was larger than that of the extrusion direction.The homogenization process prior to extrusion weaken the formed sample’s texture.The maximum residual stress of the as-extruded plate was reduced,and the residual stress distribution was homogenized.
基金supported by the National Key Technologies R&D Program (Grant No. 2018YFB1106000)Innovation Funds of China Academy of Launch Vehicle Technology (CALT) for Universities (Grant No.CALT201709)Tsinghua Grants for Autonomous Research。
文摘Wire arc additive manufacture(WAAM) is a new technique to fabricate large-scale complex aluminum alloy components.However, the performance of the parts is critically influenced by residual stresses and deformation. A sequentially thermal-mechanical coupled model of residual stress and deformation for aluminum alloy WAAM parts was established based on commercial FE software ABAQUS. The temperature field was calculated by the moving heat source(MHS) method. The temperature function was obtained according to the distribution of the peak temperature. Furthermore, the MHS method and segmented temperature function(STF) method were used to calculate the residual stress and deformation. The results show that the STF method satisfies both the efficiency and accuracy requirements. 1-segment, 3-segment, and 5-segment STF methods can shorten the time for mechanical analysis by 91%, 79%, 63%, respectively.The error of the residual stress and deformation are all less than 20%. STF method provides an effective way to predict the residual stress and deformation of large-scale WAAM parts.
基金Project(2019zzts525)supported by the Fundamental Research Funds for the Central Universities,ChinaProjects(U1837207,U1637601)supported by the National Natural Science Foundation of China
文摘In order to study the effect of dynamic recrystallization on the metal flow behavior during thermal deformation,the elevated temperature compression experiments of CuCrZr alloy and 35CrMo steel are carried out using Gleeble-3810 thermal simulator.It is proved that the samples underwent obvious dynamic recrystallization behavior during thermal deformation by microstructure observation of deformed specimens.The size of recrystallized grains increases as the temperature improved and the strain rate decreased.Meanwhile,the net softening rate caused by dynamic recrystallization is determined based on the stress-dislocation relationship.It can be found that the value of net softening rate increases quadratically as the Z parameter decreases,and the dynamic recrystallization net softening rate of CuCrZr alloy and 35CrMo steel are calculated to be 21.9%and 29.8%,respectively.Based on the dynamic recrystallization softening effect proposed,the novel elevated temperature flow constitutive models of two different alloys are proposed,and the related parameters are well defined and solved in detail.The predicted values of the obtained models are agreed well with the experimental values.
基金financially supported by the National Key Research and Development Program of China (No.2016YFB0300801)the National Natural Science Foundation of China (No.51571023)+3 种基金Zhejiang Provincial Natural Science Foundation of China (No.LQ17E010001)the Beijing Municipal Natural Science Foundation (No.2172038)the Beijing Laboratory of Metallic Materials and Processing for Modern Transportation (No.FRF-SD-B-005B)sponsored by the K.C.Wong Magna Fund in Ningbo University
文摘The effect of particle size distribution on the microstructure,texture,and mechanical properties of Al–Mg–Si–Cu alloy was investigated on the basis of the mechanical properties,microstructure,and texture of the alloy.The results show that the particle size distribution influences the microstructure and the final mechanical properties but only slightly influences the recrystallization texture.After the pre-aging treatment and natural aging treatment(T4 P treatment),in contrast to the sheet with a uniform particle size distribution,the sheet with a bimodal particle size distribution of large constituent particles and small dispersoids exhibits higher strength and a somewhat lower plastic strain ratio(r) and strain hardening exponent(n).After solution treatment,the sheet with a bimodal particle size distribution of large constituent particles and small dispersoids possesses a finer and slightly elongated grain structure compared with the sheet with a uniform particle size distribution.Additionally,they possess almost identical weak recrystallization textures,and their textures are dominated by CubeND {001}<310> and P {011}<122> orientations.
基金Project(U1637601)supported by the Joint Funds of the National Natural Science Foundation of China。
文摘Microstructural evolution and its effect on mechanical properties in different regions of 2219-C10S aluminum alloy tungsten inert gas(TIG)welded joint were analyzed in detail.In weld zone(WZ),α+θeutectic structure formed at grain boundaries with no precipitates inside the grains.In partially melted zone(PMZ),symbiotic eutectic or divorced eutectic formed at grain boundaries and needle-likeθ′phases appeared in the secondary heated zone.In over aged zone(OAZ),the coarsening and dissolution ofθ′phases occurred and mostθ′phases transformed intoθphases.In general heat affected zone(HAZ),θ′phases coarsened.Factors such as the strengthening phases,the grain size,the Cu content in matrix and the dislocation density can affect the mechanical properties in different regions of the joint.Moreover,a model describing the relationship between mechanical properties of the material and the volume fraction of precipitates,the average diameter of precipitates and the concentration of soluble elements was proposed.
基金Supported by National Natural Science Foundation of China(Grant No.31670719).
文摘The parasitic motion has been widely recognized as the major drawback of the parallel mechanism.Therefore a class of 2R1T PMs(parallel mechanism)without parasitic motion has been synthesized.However,these PMs can only rotate around two axes in sequential order.It decreases the performance of the balancing adjustment of the end-efector.In this paper,a family of 2R1T PMs without parasitic motion was reconstructed by using a novel method based on the remarkable properties of rotational bifurcation mechanisms,which can rotate in sequential order.Furthermore,some PMs rotating around two continuous axes in an arbitrary order are established by adding single joints.Taking the practicability of these structures into consideration,the workspace of 3-PRPS PM was analyzed as an example.Moreover,this study explores the practical application of the PMs without parasitic motion in developing balance mechanisms in rough-terrain fre-fghting robots.During the climbing process,the tank is adjusted to be parallel to the horizontal plane in real-time.It is proved that this kind of structure realizes continuous rotation around two rotation axes on the premise of no parasitic motion.
基金This work was financially supported by the State Key Laboratory of Solidification Processing(Northwestern Polytechnical University,China,No.2019-QZ-01)the National Natural Science Foundation of China(No.52105402)the Natural Science Foundation of Shaanxi Province(No.2021-JQ-102).
文摘The bobbin tool friction stir welding process was used to join 6 mm thick 5A06 aluminum alloy plates.Optical microscope was used to characterize the microstructure.The electron backscatter diffraction(EBSD)identified the effect of non-homogeneous microstructure on the tensile properties.It was observed that the grain size in the top of the stir zone(SZ)is smaller than that in the centre region.The lowest ratio of recrystallization and density of the geometrically-necessary dislocations(GNDs)in the SZ was found in the middle near the thermo-mechanically affected zone(TMAZ)being 22%and 1.15×10^(−13) m^(−2),respectively.The texture strength of the heat-affected zone(HAZ)is the largest,followed by that in the SZ,with the lowest being in the TMAZ.There were additional interfaces developed which contributed to the strengthening mechanism,and their effect on tensile strength was analysed.The tensile tests identified the weakest part in the joint at the interfaces,and the specific reduction value is about 93 MPa.
文摘In the friction stir welding （FSW） process, welding speed and tool rotation speed are two important parameters, which have great effect on the weld quality. Because neither of each parameter can ensure the welding process effectively, an energy factor n, which is the ratio of rotation speed（to） to welding speed （v）, was selected to represent the heat generation intensity. According to this energy input factor n, the effect of heat input on the weld quality was estimated qualitatively. The results show that the optimized scope for the factor n should be within 2. 5 and 6. 0, outside of which groove defects and burr defects will appear.
