To reveal the microbial community composition of regional shallow porous brackish groundwater and its response characteristics to groundwater environment,the first and second aquifers in Taocheng District,Hengshui Cit...To reveal the microbial community composition of regional shallow porous brackish groundwater and its response characteristics to groundwater environment,the first and second aquifers in Taocheng District,Hengshui City were selected,and 10 groundwater source samples were collected for hydrochemical analysis and microbial 16S RNA gene V4-V5 regional sequencing.The results showed that the shallow brackish groundwater in the study area is weakly alkaline and has high ion content.The hydrochemical types are SO_(4)·Cl-Na·Mg type and HCO3·Cl-Na·Mg type as a whole.The spatial zonation of the abundance and diversity of groundwater microorganisms is obvious.The number of endemic bacteria in groundwater from upstream,midstream to downstream is 11,135 and 22 respectively,with a total of 22 bacteria.Proteobacteria is the most dominant in groundwater level(38.82%-86.88%),and there are obvious differences in different sections.At the genus level,the main dominant species in each group and sample are Pseudomonas and Hydrogenophaga.In terms of composition difference,Pseudohongiella,Pseudorhodobacter and Limnohabitans are the representatives of UR,MR and LR.On the whole,the composition of flora in groundwater in the study area is sensitive and closely related to hydrochemical processes.Species abundance is affected by alkaline and high salinity environmental indicators,while species diversity is related to depth and dissolved oxygen in weak reduction environment.展开更多
Glacier disasters occur frequently in alpine regions around the world,but the current conventional geological disaster measurement technology cannot be directly used for glacier disaster measurement.Hence,in this stud...Glacier disasters occur frequently in alpine regions around the world,but the current conventional geological disaster measurement technology cannot be directly used for glacier disaster measurement.Hence,in this study,a distributed multi-sensor measurement system for glacier deformation was established by integrating piezoelectric sensing,coded sensing,attitude sensing technology and wireless communication technology.The traditional Modbus protocol was optimized to solve the problem of data identification confusion of different acquisition nodes.Through indoor wireless transmission,adaptive performance analysis,error measurement experiment and landslide simulation experiment,the performance of the measurement system was analyzed and evaluated.Using unmanned aerial vehicle technology,the reliability and effectiveness of the measurement system were verified on the site of Galongla glacier in southeastern Tibet,China.The results show that the mean absolute percentage errors were only 1.13%and 2.09%for the displacement and temperature,respectively.The distributed glacier deformation real-time measurement system provides a new means for the assessment of the development process of glacier disasters and disaster prevention and mitigation.展开更多
Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock,and it also plays important roles in safety and capacity of CO_(2)geological storage.Based on the published experimental results...Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock,and it also plays important roles in safety and capacity of CO_(2)geological storage.Based on the published experimental results,we present numerical simulations on CO_(2)breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions(which can keep CO_(2)in gaseous,liquid and supercritical states)and thus,a numerical method which can be used to accurately predict CO_(2)breakthrough pressure on rock-core scale is proposed.The simulation results show that CO_(2)breakthrough pressure and breakthrough time are exponential correlated with P-T conditions.Meanwhile,pressure has stronger effects on experimental results than that of temperature.Moreover,we performed sensitivity studies on the pore distribution indexλ(0.6,0.7,0.8,and 0.9)in van Genuchten-Muale model.Results show that with the increase ofλ,CO_(2)breakthrough pressure and breakthrough time both show decreasing trends.In other words,the larger the value ofλis,the better the permeability of the caprock is,and the worse the CO_(2)sealing capacity is.The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.展开更多
From 2010 to 2012, the China Geological Survey Center for Hydrogeology and Environmental Geology Survey(CHEGS) carried out the project "Potential evaluation and demonstration project of CO2 Geological Storage in ...From 2010 to 2012, the China Geological Survey Center for Hydrogeology and Environmental Geology Survey(CHEGS) carried out the project "Potential evaluation and demonstration project of CO2 Geological Storage in China". During this project, we developed an evaluation index system and technical methods for the potential and suitability of CO2 geological storage based on China's geological conditions, and evaluated the potential and suitability of the primary basins for CO2 geological storage, in order to draw a series of regional scale maps(at a scale of 1:5000000) and develop an atlas of the main sedimentary basins in China. By using these tools, we delineated many potential targets for CO2 storage. We also built techniques and methods for site selection and the exploration and assessment of CO2 geological storage in deep saline aquifers. Furthermore, through cooperation with the China Shenhua Coal to Liquid and Chemical Co., Ltd., we successfully constructed the first coal-based demonstration project for CO2 geological storage in deep saline aquifers in the Yijinhuoluo Banner of Ordos in the Inner Mongolia Autonomous Region, which brought about the basic preliminary theories, techniques, and methods of geological CO2 storage in deep saline aquifers under China's geological conditions.展开更多
The Yarlung Zangbo River Basin(YZRB)is situated in the southern part of the Tibetan Plateau and remains in a mostly natural state.To understand the chemical characteristics of spring water and its controlling factors ...The Yarlung Zangbo River Basin(YZRB)is situated in the southern part of the Tibetan Plateau and remains in a mostly natural state.To understand the chemical characteristics of spring water and its controlling factors in the YZRB,68 sets of spring water samples were analyzed using hydrochemical and isotopic techniques.The spring water was found to be slightly alkaline with total dissolved solids(TDS)below 1000 mg L−1.Major ions were Mg2+,Ca2+,SO42−,and HCO3−.The spring water types in this basin were determined to be HCO3-Ca·Mg and SO4·Cl-Ca·Mg.Ion exchange and dissolution of carbonate,gypsum,and silicate were identified as the prevalent hydrogeochemical processes contributing and defining spring water chemistry in this basin.Saturation indices(SI)of most major minerals studied in this region were below zero,indicating that these minerals remain under-saturated in the spring water in this area.Overall,the rank of different processes in terms of their contribution to the chemical composition of spring water in the YZRB was carbonate weathering>evaporate dissolution>silicate weathering>precipitation input.The content of 18O in spring water ranged from−22.22‰to−14.08‰with a mean of−18.15‰.Samples collected below and close to the local and global meteoric water lines indicated that spring water in this area is derived from meteoric water with chemistry affected by evaporation.展开更多
Hot dry rock(HDR)is a kind of clean energy with significant potential.Since the 1970s,the United States,Japan,France,Australia,and other countries have attempted to conduct several HDR development research projects to...Hot dry rock(HDR)is a kind of clean energy with significant potential.Since the 1970s,the United States,Japan,France,Australia,and other countries have attempted to conduct several HDR development research projects to extract thermal energy by breaking through key technologies.However,up to now,the development of HDR is still in the research,development,and demonstration stage.An HDR exploration borehole(with 236℃ at a depth of 3705 m)was drilled into Triassic granite in the Gonghe Basin in northwest China in 2017.Subsequently,China Geological Survey(CGS)launched the HDR resources exploration and production demonstration project in 2019.After three years of efforts,a sequence of significant technological breakthroughs have been made,including the genetic model of deep heat sources,directional drilling and well completion in high-temperature hard rock,large-scale reservoir stimulation,reservoir characterization,and productivity evaluation,reservoir connectivity and flow circulation,efficient thermoelectric conversion,monitoring,and geological risk assessment,etc.Then the whole-process technological system for HDR exploration and production has been preliminarily established accordingly.The first power generation test was completed in November 2021.The results of this project will provide scientific support for HDR development and utilization in the future.展开更多
The fresh groundwater in the Loess Plateau serves as a major source of water required for the production and livelihood of local residents and is greatly significant for regional economic and social development and ec...The fresh groundwater in the Loess Plateau serves as a major source of water required for the production and livelihood of local residents and is greatly significant for regional economic and social development and ecological protection.This paper analyzes the hydrogeological conditions and groundwater characteristics in the Loess Plateau,expatiates on the types and distribution characteristics of the fresh groundwater in the plateau,and analyzes the influencing factors and mechanisms in the formation of the fresh groundwater in the plateau as a priority.Based on this,it summarizes the impacts of human activities and climatic change on the regional fresh groundwater.The groundwater in Loess Plateau features uneven temporal-spatial distribution,with the distribution space of the fresh groundwater closely relating to precipitation.The groundwater shows a distinct zoning pattern of hydrochemical types.It is fresh water in shallow parts and is salt water in deep parts overall,while the fresh water of exploration value is distributed only in a small range.The storage space and migration pathways of fresh groundwater in the loess area feature dual voids,vertical multilayers,variable structure,poor renewability,complex recharge processes,and distinct spatial differences.In general,the total dissolved solids(TDS)of the same type of groundwater tends to gradually increase from recharge areas to discharge areas.Conditions favorable for the formation of fresh groundwater in loess tablelands include the low content of soluble salts in strata,weak evaporation,and special hydrodynamic conditions.Owing to climate change and human activities,the resource quantity of regional fresh water tends to decrease overall,and the groundwater dynamic field and the recharge-discharge relationships between groundwater and surface water have changed in local areas.Human activities have a small impact on the water quality but slightly affect the water quantity of the groundwater in loess.展开更多
Qarhan Salt Lake is located in the eastern part of the Qaidam Basin,which is first discovered the large potash deposit in the late 1950s.The Bieletan section is located in the west of Qarhan Salt Lake,where saline
Hydraulic fracture(HF) propagation behavior is significant when building enhanced geothermal systems(EGS). HF geometry is closely related to the structural planes(SPs) in hot dry rock(HDR), such as natural fractures(N...Hydraulic fracture(HF) propagation behavior is significant when building enhanced geothermal systems(EGS). HF geometry is closely related to the structural planes(SPs) in hot dry rock(HDR), such as natural fractures(NFs), quartz veins(QVs) and lithologic interfaces(LIs). However, the HF behaviors in HDR have not been well understood, especially the influence of multiple SPs on the HF geometry. To clarify this mechanism, several groups of physical simulation experiments of hydraulic fracturing were conducted to investigate the intersection relationship between the HFs and the SPs. Results show that the HF geometry shows great differences when intersecting with different SPs. In summary, the HF geometry displays four basic patterns, namely, propagation along the SPs, branching, capture, penetration/non-dilation. The fluctuation degree of the pressure-time curve and the HF complexity show a positive correlation. The cementing strength of the SP and their different mechanical properties from rock matrix influence the HF behaviors significantly. Therefore, the HF shows diverse geometries when intersecting with the NFs and LIs, while propagating along the QV when intersecting with it. For the complex networks, it is favorable for the HF to penetrate through and dilate several SPs, rather than simply cross or propagate along the SP.展开更多
Attenuation of noise is a persistent problem in seismic exploration. The authors use conventional denoising method to remove noise which may cause vibration near the discontinuity called pseudo-Gibbs artifact.In order...Attenuation of noise is a persistent problem in seismic exploration. The authors use conventional denoising method to remove noise which may cause vibration near the discontinuity called pseudo-Gibbs artifact.In order to remove the artifact,the study proposed a method combining the seislet transform and total variation minimization. Firstly,the data are converted into the seislet transform domain. Secondly,the hard threshold was used for eliminating the noise and keep useful signal,which is the initial input for the next step. Finally,total variation minimization dealed with denoised data to recover boundary information and further eliminated the noise. Synthetic data examples show that the method has feasibility in eliminating random noise and protecting detailed signal,and also shows better results than the classic f-x deconvolution. The field data example also shows effective in practice. It can remove the noise and preserve the discontinuity signal at the same time.展开更多
A novel solid-liquid-core fiber-optic biosensor was fabricated for highly sensitive and selective detection of 4-chlorophenol in water.The sensor comprised horseradish peroxidase(HRP)-coated U-shaped liquidcore optica...A novel solid-liquid-core fiber-optic biosensor was fabricated for highly sensitive and selective detection of 4-chlorophenol in water.The sensor comprised horseradish peroxidase(HRP)-coated U-shaped liquidcore optical fiber(LCOF)and 4-chlorophenol permselective polymer membrane.The U-shaped LCOF was flled with ethanol suspension of SiO_(2)particles and the polymer membrane was composed of molecularly imprinted polymer,sulfonated polyethersulfone,and polysulfone.The morphology,composition,and surface luminous properties of the sensing region were examined.The effects of the diameter and content of SiO_(2)particles and temperature of 4-chlorophenol solutions on the sensitivity of the biosensors were investigated.Further,the sensitivity,selectivity,response time,and limit of detection(LOD)of the biosensors was investigated.In addition,the effects of fiber core materials on the light transmission in sensing region were investigated and a biosensor sensing model was established.The proposed sensor exhibited high selectivity for 4-chlorophenol with satisfactory sensitivity,LOD,and response time:-1.18(μg/L)^(-1),30μg/L,and 400 s,respectively.The results are expected to aid in the development of methods for enhancing sensitivity of fiber-optic sensors and surface luminous intensity of optical fibers.展开更多
Hot dry rock(HDR)geothermal energy is a kind of widely distributed clean energy with huge reserves.However,its commercial development has been constrained by reservoir stimulation.In the early stage of HDR geothermal ...Hot dry rock(HDR)geothermal energy is a kind of widely distributed clean energy with huge reserves.However,its commercial development has been constrained by reservoir stimulation.In the early stage of HDR geothermal energy development,properly determining spatial distribution patterns of natural fractures in HDR reservoirs can effectively guide reservoir stimulation.This study analyzes the spatial distribution of natural fractures by using FracMan software based on the actual geological data and log data of well M-2 in the Matouying Uplift area,Hebei Province.The fracture parameters are counted and Monte Carlo simulation technique is introduced to optimize the parameters,which makes the natural fracture model more accurate and reliable.Furthermore,this study simulates hydraulic fracturing using the model combined with the actual in-situ stress parameters and the construction scheme.As verified by fitting the changes in simulated wellhead pressure during hydraulic fracturing with the actual wellhead pressure data detected during construction,the methods for natural fracture modeling used in this study are scientific and reasonable.The preliminary prediction results show that the displacement design scheme with a pump displacement of 2.0-3.0 m^(3)/min,4.0-5.5 m^(3)/min and 6-7 m^(3)/min in the early,middle and late stages,respectively,has good fracturing effect.The results of this study can be utilized as a reference for preparing development schemes for HDR reservoirs.展开更多
Carbon dioxide(CO_(2))geological utilization and storage(CGUS)is the key link of CO_(2)capture,utilization,and storage(CCUS).The accurate characterization of the geological body structure is a vital prerequisite of CG...Carbon dioxide(CO_(2))geological utilization and storage(CGUS)is the key link of CO_(2)capture,utilization,and storage(CCUS).The accurate characterization of the geological body structure is a vital prerequisite of CGUS.This paper gives a review of the multi-scale three-dimensional geological structure characterization and site selection of CO_(2)storage.It shows that there is a lack of systematic and high-precision methods for transparency characterization of multi-scale three-dimensional engineering geological structure and hydrogeological structure of a CO_(2)storage site.There is no clear understanding of the fracture evolution and gas-liquid migration process of multi-scale geological body structure under the disturbance of CO_(2)injection.There is a lack of sufficient quantitative methods for the dynamic evaluation of CO_(2)geological storage potential.The geological suitability evaluation method for site selection of CO_(2)storage is rough and has poor applicability,which is difficult to satisfy the urgent needs of CGUS site selection in the whole process of CO_(2)sequestration industrialization in the future.Thus,it is required to conduct studies on the transparency characterization of geological body structure and intelligent site selection for CO_(2)storage,which is of great importance for CGUS engineering practice.展开更多
Groundwater plays a critical role in maintaining ecological balance and ensuring social operations,especially in arid and semiarid regions(Hu et al.,2023;Han et al.,2022;Ma et al.,2014).The over-exploitation of ground...Groundwater plays a critical role in maintaining ecological balance and ensuring social operations,especially in arid and semiarid regions(Hu et al.,2023;Han et al.,2022;Ma et al.,2014).The over-exploitation of groundwater,coupled with the influx of pollutants from human activities into the soil,significantly degrades the environment in certain regions(Jia et al.,2019;Famiglietti,2014;Giordano,2009;Konikow and Kendy,2005;Bohlke,2002;Shah et al.,2000).展开更多
Carbon Capture and Storage(CCS)is one of the effective means to deal with global warming,and saline aquifer storage is considered to be the most promising storage method.Junggar Basin,located in the northern part of X...Carbon Capture and Storage(CCS)is one of the effective means to deal with global warming,and saline aquifer storage is considered to be the most promising storage method.Junggar Basin,located in the northern part of Xinjiang and with a large distribution area of saline aquifer,is an effective carbon storage site.Based on well logging data and 2D seismic data,a 3D heterogeneous geological model of the Cretaceous Donggou Formation reservoir near D7 well was constructed,and dynamic simulations under two scenarios of single-well injection and multi-well injection were carried out to explore the storage potential and CO2 storage mechanism of deep saline aquifer with real geological conditions in this study.The results show that within 100 km^(2)of the saline aquifer of Donggou Formation in the vicinity of D7 well,the theoretical static CO_(2)storage is 71.967×106 tons(P50)①,and the maximum dynamic CO_(2)storage is 145.295×106 tons(Case2).The heterogeneity of saline aquifer has a great influence on the spatial distribution of CO_(2)in the reservoir.The multi-well injection scenario is conducive to the efficient utilization of reservoir space and safer for storage.Based on the results from theoretical static calculation and the dynamic simulation,the effective coefficient of CO_(2)storage in deep saline aquifer in the eastern part of Xinjiang is recommended to be 4.9%.This study can be applied to the engineering practice of CO_(2)sequestration in the deep saline aquifer in Xinjiang.展开更多
The paper chooses the secondary tectonic units of Sichuan Basin as the evaluation object, and considers regional crustal stability conditions, basic geological conditions, reservoir and cap rock conditions, storage po...The paper chooses the secondary tectonic units of Sichuan Basin as the evaluation object, and considers regional crustal stability conditions, basic geological conditions, reservoir and cap rock conditions, storage potential conditions, geothermal conditions, research degree and potential resources conditions, social and economic conditions as first-level indexes. Based on collected data and a comprehensive analysis of 16 level-two indexes and 9 level-three indexes, and with the application of comprehensive index method, the conclusions regarding the suitability partition of the secondary tectonic units of Sichuan Basin are as follows: Central Sichuan low-flat structural belt is highly suitable for carbon dioxide geological storage, West Sichuan low-slope structural belt is relatively suitable, and SW low-slope structural belt is unsuitable for carbon dioxide geological storage, South Sichuan low-slope structural belt is relatively unsuitable, whereas East Sichuan high-slope faulted fold belt, and North Sichuan low-flat structural belt are fairly suitable for carbon dioxide geological storage. Based on the above, with a comprehensive analysis of corresponding hydrographic and geological conditions, and at the same time considering the non-cov- ered oil or gas resources and the buried structure, six CO2 geological target formations are identified, including lower Jurassic Ziliujing Group, upper Triassic Xujiahe Group, middle Triassic Leikoupo Group, lower Triassic Jialingjiang Group and Feixianguan Group, and lower Permian Qixia Group. This paper provides an important guidance and reference for the selection criteria of CO2 geologic storage sites in Sichuan Basin.展开更多
Adsorption behavior of Cr(Ⅵ) in vadose zone, which is silty clay and clayey soil, was studied through kinetics experiments, isothermal adsorption experiments under various conditions, including different ph, temperat...Adsorption behavior of Cr(Ⅵ) in vadose zone, which is silty clay and clayey soil, was studied through kinetics experiments, isothermal adsorption experiments under various conditions, including different ph, temperature and organic contents. The results from kinetics experiments showed that the sorption progress of Cr(Ⅵ) has clear features in different stages, and adsorption equilibrium showed at 30 min, the adsorption rate of silty clay and clayey soil were 60%. The isothermal adsorption curve of Cr(Ⅵ) fitted closely with Freundlich equation model. When pH is 3-5 a plateau were seen, thereafter with increase in pH the adsorption rate of Cr(Ⅵ) dropped sharply and the minimum achieved at pH 10, the adsorption rate were only 35%. Adsorption rate of Cr(Ⅵ) increased gradually with the increase of temperature, the temperature of vadose zone is 14.7 ℃, according to the experimental results, the adsorption rate of Cr(Ⅵ) is about 40%. The use of organics represents an important contribution to the sorption of Cr(Ⅵ), sorption rate up to 100% when 30% of organic content. These studies will provide basis for manager to minimize the impacts, and provide basic data for pollution prevention and remediation of vadose zone.展开更多
基金This work was financially supported by National key R&D plan(2019YFC1804804)Special project of national basic resources survey(2017FY100401)+1 种基金Sub task of National Major Water Science and Technology Project(2018ZX07109-001-02)National Natural Science Foundation(21976044).
文摘To reveal the microbial community composition of regional shallow porous brackish groundwater and its response characteristics to groundwater environment,the first and second aquifers in Taocheng District,Hengshui City were selected,and 10 groundwater source samples were collected for hydrochemical analysis and microbial 16S RNA gene V4-V5 regional sequencing.The results showed that the shallow brackish groundwater in the study area is weakly alkaline and has high ion content.The hydrochemical types are SO_(4)·Cl-Na·Mg type and HCO3·Cl-Na·Mg type as a whole.The spatial zonation of the abundance and diversity of groundwater microorganisms is obvious.The number of endemic bacteria in groundwater from upstream,midstream to downstream is 11,135 and 22 respectively,with a total of 22 bacteria.Proteobacteria is the most dominant in groundwater level(38.82%-86.88%),and there are obvious differences in different sections.At the genus level,the main dominant species in each group and sample are Pseudomonas and Hydrogenophaga.In terms of composition difference,Pseudohongiella,Pseudorhodobacter and Limnohabitans are the representatives of UR,MR and LR.On the whole,the composition of flora in groundwater in the study area is sensitive and closely related to hydrochemical processes.Species abundance is affected by alkaline and high salinity environmental indicators,while species diversity is related to depth and dissolved oxygen in weak reduction environment.
基金funded by National Key R&D Program of China((Nos.2022YFC3003403 and 2018YFC1505203)Key Research and Development Program of Tibet Autonomous Region(XZ202301ZY0039G)+1 种基金Natural Science Foundation of Hebei Province(No.F2021201031)Geological Survey Project of China Geological Survey(No.DD20221747)。
文摘Glacier disasters occur frequently in alpine regions around the world,but the current conventional geological disaster measurement technology cannot be directly used for glacier disaster measurement.Hence,in this study,a distributed multi-sensor measurement system for glacier deformation was established by integrating piezoelectric sensing,coded sensing,attitude sensing technology and wireless communication technology.The traditional Modbus protocol was optimized to solve the problem of data identification confusion of different acquisition nodes.Through indoor wireless transmission,adaptive performance analysis,error measurement experiment and landslide simulation experiment,the performance of the measurement system was analyzed and evaluated.Using unmanned aerial vehicle technology,the reliability and effectiveness of the measurement system were verified on the site of Galongla glacier in southeastern Tibet,China.The results show that the mean absolute percentage errors were only 1.13%and 2.09%for the displacement and temperature,respectively.The distributed glacier deformation real-time measurement system provides a new means for the assessment of the development process of glacier disasters and disaster prevention and mitigation.
基金supported by Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(Grant No.SKLGME021010)funded by the National Natural Science Foundation of China(Grant No.41702251 and 42141010)the MOE Key Laboratory of Groundwater Circulation and Environmental Evolution。
文摘Gas breakthrough pressure is a key parameter to evaluate the sealing capacity of caprock,and it also plays important roles in safety and capacity of CO_(2)geological storage.Based on the published experimental results,we present numerical simulations on CO_(2)breakthrough pressure in unsaturated low-permeability rock under 9 multiple P-T conditions(which can keep CO_(2)in gaseous,liquid and supercritical states)and thus,a numerical method which can be used to accurately predict CO_(2)breakthrough pressure on rock-core scale is proposed.The simulation results show that CO_(2)breakthrough pressure and breakthrough time are exponential correlated with P-T conditions.Meanwhile,pressure has stronger effects on experimental results than that of temperature.Moreover,we performed sensitivity studies on the pore distribution indexλ(0.6,0.7,0.8,and 0.9)in van Genuchten-Muale model.Results show that with the increase ofλ,CO_(2)breakthrough pressure and breakthrough time both show decreasing trends.In other words,the larger the value ofλis,the better the permeability of the caprock is,and the worse the CO_(2)sealing capacity is.The numerical method established in this study can provide an important reference for the prediction of gas breakthrough pressure on rock-core scale and for related numerical studies.
文摘From 2010 to 2012, the China Geological Survey Center for Hydrogeology and Environmental Geology Survey(CHEGS) carried out the project "Potential evaluation and demonstration project of CO2 Geological Storage in China". During this project, we developed an evaluation index system and technical methods for the potential and suitability of CO2 geological storage based on China's geological conditions, and evaluated the potential and suitability of the primary basins for CO2 geological storage, in order to draw a series of regional scale maps(at a scale of 1:5000000) and develop an atlas of the main sedimentary basins in China. By using these tools, we delineated many potential targets for CO2 storage. We also built techniques and methods for site selection and the exploration and assessment of CO2 geological storage in deep saline aquifers. Furthermore, through cooperation with the China Shenhua Coal to Liquid and Chemical Co., Ltd., we successfully constructed the first coal-based demonstration project for CO2 geological storage in deep saline aquifers in the Yijinhuoluo Banner of Ordos in the Inner Mongolia Autonomous Region, which brought about the basic preliminary theories, techniques, and methods of geological CO2 storage in deep saline aquifers under China's geological conditions.
基金supported by the Center for Hydrogeology and Environmental Geology Survey,China Geological Survey(112120114059601,DD20160298,2019QZKK020703,KKLFSE201304)the China Postdoctoral Science Foundation(2020M682207).
文摘The Yarlung Zangbo River Basin(YZRB)is situated in the southern part of the Tibetan Plateau and remains in a mostly natural state.To understand the chemical characteristics of spring water and its controlling factors in the YZRB,68 sets of spring water samples were analyzed using hydrochemical and isotopic techniques.The spring water was found to be slightly alkaline with total dissolved solids(TDS)below 1000 mg L−1.Major ions were Mg2+,Ca2+,SO42−,and HCO3−.The spring water types in this basin were determined to be HCO3-Ca·Mg and SO4·Cl-Ca·Mg.Ion exchange and dissolution of carbonate,gypsum,and silicate were identified as the prevalent hydrogeochemical processes contributing and defining spring water chemistry in this basin.Saturation indices(SI)of most major minerals studied in this region were below zero,indicating that these minerals remain under-saturated in the spring water in this area.Overall,the rank of different processes in terms of their contribution to the chemical composition of spring water in the YZRB was carbonate weathering>evaporate dissolution>silicate weathering>precipitation input.The content of 18O in spring water ranged from−22.22‰to−14.08‰with a mean of−18.15‰.Samples collected below and close to the local and global meteoric water lines indicated that spring water in this area is derived from meteoric water with chemistry affected by evaporation.
基金funded by the“Hot Dry Rock Resources Exploration and Production Demonstration Project”of the China Geological Survey(DD20190131,DD20190135,DD20211336).
文摘Hot dry rock(HDR)is a kind of clean energy with significant potential.Since the 1970s,the United States,Japan,France,Australia,and other countries have attempted to conduct several HDR development research projects to extract thermal energy by breaking through key technologies.However,up to now,the development of HDR is still in the research,development,and demonstration stage.An HDR exploration borehole(with 236℃ at a depth of 3705 m)was drilled into Triassic granite in the Gonghe Basin in northwest China in 2017.Subsequently,China Geological Survey(CGS)launched the HDR resources exploration and production demonstration project in 2019.After three years of efforts,a sequence of significant technological breakthroughs have been made,including the genetic model of deep heat sources,directional drilling and well completion in high-temperature hard rock,large-scale reservoir stimulation,reservoir characterization,and productivity evaluation,reservoir connectivity and flow circulation,efficient thermoelectric conversion,monitoring,and geological risk assessment,etc.Then the whole-process technological system for HDR exploration and production has been preliminarily established accordingly.The first power generation test was completed in November 2021.The results of this project will provide scientific support for HDR development and utilization in the future.
基金This work was funded by the project of China Geological Survey(DD20190333,DD20211563)the National Youth Science Foundation(41702280).
文摘The fresh groundwater in the Loess Plateau serves as a major source of water required for the production and livelihood of local residents and is greatly significant for regional economic and social development and ecological protection.This paper analyzes the hydrogeological conditions and groundwater characteristics in the Loess Plateau,expatiates on the types and distribution characteristics of the fresh groundwater in the plateau,and analyzes the influencing factors and mechanisms in the formation of the fresh groundwater in the plateau as a priority.Based on this,it summarizes the impacts of human activities and climatic change on the regional fresh groundwater.The groundwater in Loess Plateau features uneven temporal-spatial distribution,with the distribution space of the fresh groundwater closely relating to precipitation.The groundwater shows a distinct zoning pattern of hydrochemical types.It is fresh water in shallow parts and is salt water in deep parts overall,while the fresh water of exploration value is distributed only in a small range.The storage space and migration pathways of fresh groundwater in the loess area feature dual voids,vertical multilayers,variable structure,poor renewability,complex recharge processes,and distinct spatial differences.In general,the total dissolved solids(TDS)of the same type of groundwater tends to gradually increase from recharge areas to discharge areas.Conditions favorable for the formation of fresh groundwater in loess tablelands include the low content of soluble salts in strata,weak evaporation,and special hydrodynamic conditions.Owing to climate change and human activities,the resource quantity of regional fresh water tends to decrease overall,and the groundwater dynamic field and the recharge-discharge relationships between groundwater and surface water have changed in local areas.Human activities have a small impact on the water quality but slightly affect the water quantity of the groundwater in loess.
文摘Qarhan Salt Lake is located in the eastern part of the Qaidam Basin,which is first discovered the large potash deposit in the late 1950s.The Bieletan section is located in the west of Qarhan Salt Lake,where saline
基金support from the National Key Research and Development Project in China(Grant nos.2018YFB1501801,2020YFE020130005)the National Natural Science Foundation of China(Grant nos.42004115,42102353)the Open Research Fund Program of Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring(Central South University),Ministry of Education(Grant No.2021YSJS08)。
文摘Hydraulic fracture(HF) propagation behavior is significant when building enhanced geothermal systems(EGS). HF geometry is closely related to the structural planes(SPs) in hot dry rock(HDR), such as natural fractures(NFs), quartz veins(QVs) and lithologic interfaces(LIs). However, the HF behaviors in HDR have not been well understood, especially the influence of multiple SPs on the HF geometry. To clarify this mechanism, several groups of physical simulation experiments of hydraulic fracturing were conducted to investigate the intersection relationship between the HFs and the SPs. Results show that the HF geometry shows great differences when intersecting with different SPs. In summary, the HF geometry displays four basic patterns, namely, propagation along the SPs, branching, capture, penetration/non-dilation. The fluctuation degree of the pressure-time curve and the HF complexity show a positive correlation. The cementing strength of the SP and their different mechanical properties from rock matrix influence the HF behaviors significantly. Therefore, the HF shows diverse geometries when intersecting with the NFs and LIs, while propagating along the QV when intersecting with it. For the complex networks, it is favorable for the HF to penetrate through and dilate several SPs, rather than simply cross or propagate along the SP.
文摘Attenuation of noise is a persistent problem in seismic exploration. The authors use conventional denoising method to remove noise which may cause vibration near the discontinuity called pseudo-Gibbs artifact.In order to remove the artifact,the study proposed a method combining the seislet transform and total variation minimization. Firstly,the data are converted into the seislet transform domain. Secondly,the hard threshold was used for eliminating the noise and keep useful signal,which is the initial input for the next step. Finally,total variation minimization dealed with denoised data to recover boundary information and further eliminated the noise. Synthetic data examples show that the method has feasibility in eliminating random noise and protecting detailed signal,and also shows better results than the classic f-x deconvolution. The field data example also shows effective in practice. It can remove the noise and preserve the discontinuity signal at the same time.
基金support from the National Natural Science Foundation of China(NSFC)(Nos.U19A20107,52176178 and 51876018)Innovation Research Group of Universities in Chongqing(No.CXQT21035)+1 种基金Chongqing Natural Science Foundation Innovation and Development Joint Fund Project(No.CSTB2022NSCQ-LZX0059)the Scientific and Technological Research Program of Chongqing Municipal Education Commission of China(No.KJZD-M202201101).
文摘A novel solid-liquid-core fiber-optic biosensor was fabricated for highly sensitive and selective detection of 4-chlorophenol in water.The sensor comprised horseradish peroxidase(HRP)-coated U-shaped liquidcore optical fiber(LCOF)and 4-chlorophenol permselective polymer membrane.The U-shaped LCOF was flled with ethanol suspension of SiO_(2)particles and the polymer membrane was composed of molecularly imprinted polymer,sulfonated polyethersulfone,and polysulfone.The morphology,composition,and surface luminous properties of the sensing region were examined.The effects of the diameter and content of SiO_(2)particles and temperature of 4-chlorophenol solutions on the sensitivity of the biosensors were investigated.Further,the sensitivity,selectivity,response time,and limit of detection(LOD)of the biosensors was investigated.In addition,the effects of fiber core materials on the light transmission in sensing region were investigated and a biosensor sensing model was established.The proposed sensor exhibited high selectivity for 4-chlorophenol with satisfactory sensitivity,LOD,and response time:-1.18(μg/L)^(-1),30μg/L,and 400 s,respectively.The results are expected to aid in the development of methods for enhancing sensitivity of fiber-optic sensors and surface luminous intensity of optical fibers.
文摘Hot dry rock(HDR)geothermal energy is a kind of widely distributed clean energy with huge reserves.However,its commercial development has been constrained by reservoir stimulation.In the early stage of HDR geothermal energy development,properly determining spatial distribution patterns of natural fractures in HDR reservoirs can effectively guide reservoir stimulation.This study analyzes the spatial distribution of natural fractures by using FracMan software based on the actual geological data and log data of well M-2 in the Matouying Uplift area,Hebei Province.The fracture parameters are counted and Monte Carlo simulation technique is introduced to optimize the parameters,which makes the natural fracture model more accurate and reliable.Furthermore,this study simulates hydraulic fracturing using the model combined with the actual in-situ stress parameters and the construction scheme.As verified by fitting the changes in simulated wellhead pressure during hydraulic fracturing with the actual wellhead pressure data detected during construction,the methods for natural fracture modeling used in this study are scientific and reasonable.The preliminary prediction results show that the displacement design scheme with a pump displacement of 2.0-3.0 m^(3)/min,4.0-5.5 m^(3)/min and 6-7 m^(3)/min in the early,middle and late stages,respectively,has good fracturing effect.The results of this study can be utilized as a reference for preparing development schemes for HDR reservoirs.
基金supported by the National Natural Science Foundation of China(Grant No.42141009)the Key Research Program of the Institute of Geology and Geophysics,CAS(Grant No.IGGCAS-202201).
文摘Carbon dioxide(CO_(2))geological utilization and storage(CGUS)is the key link of CO_(2)capture,utilization,and storage(CCUS).The accurate characterization of the geological body structure is a vital prerequisite of CGUS.This paper gives a review of the multi-scale three-dimensional geological structure characterization and site selection of CO_(2)storage.It shows that there is a lack of systematic and high-precision methods for transparency characterization of multi-scale three-dimensional engineering geological structure and hydrogeological structure of a CO_(2)storage site.There is no clear understanding of the fracture evolution and gas-liquid migration process of multi-scale geological body structure under the disturbance of CO_(2)injection.There is a lack of sufficient quantitative methods for the dynamic evaluation of CO_(2)geological storage potential.The geological suitability evaluation method for site selection of CO_(2)storage is rough and has poor applicability,which is difficult to satisfy the urgent needs of CGUS site selection in the whole process of CO_(2)sequestration industrialization in the future.Thus,it is required to conduct studies on the transparency characterization of geological body structure and intelligent site selection for CO_(2)storage,which is of great importance for CGUS engineering practice.
基金supported by the Center for Hydrogeology and Environmental Geology Survey,1:50000 Hydrogeological Survey of Yimeng Mountains(No.12120114010902)。
文摘Groundwater plays a critical role in maintaining ecological balance and ensuring social operations,especially in arid and semiarid regions(Hu et al.,2023;Han et al.,2022;Ma et al.,2014).The over-exploitation of groundwater,coupled with the influx of pollutants from human activities into the soil,significantly degrades the environment in certain regions(Jia et al.,2019;Famiglietti,2014;Giordano,2009;Konikow and Kendy,2005;Bohlke,2002;Shah et al.,2000).
基金This work was supported by the National Natural Science Foundation of China(NSFC,Grant No.41702284,41602272)National key R&D program of China(Grant No.2019YFE0100100)+2 种基金the Na-tural Science Foundation of Hubei Province,China(Grant No.2019CFB451)and the Open Fund of Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources(Grant No.2020zy003)This work was also par-tially supported by the China Australia Geological Storage of CO_(2)project(CAGS),and the China Geo-logical Survey project(Grant No.DD20160307).
文摘Carbon Capture and Storage(CCS)is one of the effective means to deal with global warming,and saline aquifer storage is considered to be the most promising storage method.Junggar Basin,located in the northern part of Xinjiang and with a large distribution area of saline aquifer,is an effective carbon storage site.Based on well logging data and 2D seismic data,a 3D heterogeneous geological model of the Cretaceous Donggou Formation reservoir near D7 well was constructed,and dynamic simulations under two scenarios of single-well injection and multi-well injection were carried out to explore the storage potential and CO2 storage mechanism of deep saline aquifer with real geological conditions in this study.The results show that within 100 km^(2)of the saline aquifer of Donggou Formation in the vicinity of D7 well,the theoretical static CO_(2)storage is 71.967×106 tons(P50)①,and the maximum dynamic CO_(2)storage is 145.295×106 tons(Case2).The heterogeneity of saline aquifer has a great influence on the spatial distribution of CO_(2)in the reservoir.The multi-well injection scenario is conducive to the efficient utilization of reservoir space and safer for storage.Based on the results from theoretical static calculation and the dynamic simulation,the effective coefficient of CO_(2)storage in deep saline aquifer in the eastern part of Xinjiang is recommended to be 4.9%.This study can be applied to the engineering practice of CO_(2)sequestration in the deep saline aquifer in Xinjiang.
文摘The paper chooses the secondary tectonic units of Sichuan Basin as the evaluation object, and considers regional crustal stability conditions, basic geological conditions, reservoir and cap rock conditions, storage potential conditions, geothermal conditions, research degree and potential resources conditions, social and economic conditions as first-level indexes. Based on collected data and a comprehensive analysis of 16 level-two indexes and 9 level-three indexes, and with the application of comprehensive index method, the conclusions regarding the suitability partition of the secondary tectonic units of Sichuan Basin are as follows: Central Sichuan low-flat structural belt is highly suitable for carbon dioxide geological storage, West Sichuan low-slope structural belt is relatively suitable, and SW low-slope structural belt is unsuitable for carbon dioxide geological storage, South Sichuan low-slope structural belt is relatively unsuitable, whereas East Sichuan high-slope faulted fold belt, and North Sichuan low-flat structural belt are fairly suitable for carbon dioxide geological storage. Based on the above, with a comprehensive analysis of corresponding hydrographic and geological conditions, and at the same time considering the non-cov- ered oil or gas resources and the buried structure, six CO2 geological target formations are identified, including lower Jurassic Ziliujing Group, upper Triassic Xujiahe Group, middle Triassic Leikoupo Group, lower Triassic Jialingjiang Group and Feixianguan Group, and lower Permian Qixia Group. This paper provides an important guidance and reference for the selection criteria of CO2 geologic storage sites in Sichuan Basin.
文摘Adsorption behavior of Cr(Ⅵ) in vadose zone, which is silty clay and clayey soil, was studied through kinetics experiments, isothermal adsorption experiments under various conditions, including different ph, temperature and organic contents. The results from kinetics experiments showed that the sorption progress of Cr(Ⅵ) has clear features in different stages, and adsorption equilibrium showed at 30 min, the adsorption rate of silty clay and clayey soil were 60%. The isothermal adsorption curve of Cr(Ⅵ) fitted closely with Freundlich equation model. When pH is 3-5 a plateau were seen, thereafter with increase in pH the adsorption rate of Cr(Ⅵ) dropped sharply and the minimum achieved at pH 10, the adsorption rate were only 35%. Adsorption rate of Cr(Ⅵ) increased gradually with the increase of temperature, the temperature of vadose zone is 14.7 ℃, according to the experimental results, the adsorption rate of Cr(Ⅵ) is about 40%. The use of organics represents an important contribution to the sorption of Cr(Ⅵ), sorption rate up to 100% when 30% of organic content. These studies will provide basis for manager to minimize the impacts, and provide basic data for pollution prevention and remediation of vadose zone.