An important goal in ocean colour remote sensing is to accurately detect different phytoplankton groups with the potential uses including the validation of multi-phytoplankton carbon cycle models; synoptically monitor...An important goal in ocean colour remote sensing is to accurately detect different phytoplankton groups with the potential uses including the validation of multi-phytoplankton carbon cycle models; synoptically monitoring the health of our oceans, and improving our understanding of the bio-geochemical interactions between phytoplankton and their environment. In this paper a new algorithm is developed for detecting three dominant phytoplankton size classes based on distinct differences in their optical signatures. The technique is validated against an independent coupled satellite reflectance and in situ pigment dataset and run on the 10-year NASA Sea viewing Wide Field of view Sensor （SeaWiFS） data series. Results indicate that on average 3.6% of the global oceanic surface layer is dominated by microplankton, 18.0% by nanoplankton and 78.4% by pieoplankton. Results, however, are seen to vary depending on season and ocean basin.展开更多
The atmospheric carbon dioxide(CO 2)concentration has increased to more than 405 parts per million(ppm.1 ppm=10-6 m/s 2)in 2017 due to human activities such as deforestation,land-use change and burning of fossil fuels...The atmospheric carbon dioxide(CO 2)concentration has increased to more than 405 parts per million(ppm.1 ppm=10-6 m/s 2)in 2017 due to human activities such as deforestation,land-use change and burning of fossil fuels.Although there is broad scientific consensus on the damaging consequences of the change in climate associated with increasing concentrations of greenhouse gases,fossil CO 2 emissions have continued to increase in recent years mainly from rapidly developing economies and China is now the largest emitter of CO 2 generating about 30%of all emissions globally.To allow more reliable forecast of the future state of the carbon cycle and to support the efforts for mitigation greenhouse gas emissions,a better understanding of the global and regional carbon budget is needed.Space-based measurements of CO 2 can provide the necessary observations with dense coverage and sampling to provide improved constrains on of carbon fluxes and emissions.The Chinese Global Carbon Dioxide Monitoring Scientific Experimental Satellite(TanSat)was established by the National High Technology Research and Development Program of China with the main objective of monitoring atmospheric CO 2 and CO 2 fluxes at the regional and global scale.TanSat has been successfully launched in December 2016 and as part of the Dragon programme of ESA and the Ministry of Science and Technology(MOST),a team of researchers from Europe(UK and Finland)and China has evaluated early TanSat data and contrast it against data from the GOSAT mission and models.In this manuscript,we report on retrieval intercomparisons of TanSat data using two different retrieval algorithms,on validation efforts for the Eastern Asia region using GOSAT CO 2 data and first assessments of TanSat and GOSAT CO 2 data against model calculations using the GEOS-Chem model.展开更多
The attenuation of lateral propagating light （LPL） in sea ice was measured using an artificial light source in the Canadian Arctic during the 2007/2008 winter. The apparent attenuation coefficientμ（λ）for lateral...The attenuation of lateral propagating light （LPL） in sea ice was measured using an artificial light source in the Canadian Arctic during the 2007/2008 winter. The apparent attenuation coefficientμ（λ）for lateral prop-agating light was obtained from the measured logarithmic relative variation rate. In this study an analytical solution based on the strict optical theories is developed to validate the measured result. There is a good consistency between theoretical solution and measured data, by which a quite simple but very rigorous relationship among the light source, measurement geometry, and measured irradiance is established. The attenuation coefficients acquired by measurement and theory are the diffusion attenuation as an apparent optical property of ice, independent of the light source and shining condition. The attenuation ability of sea ice should be caused by the microstructure of sea ice, such as crystal size, ice density, brine volume, air inclusion, etc. It also includes the leak from both interfaces by directional scattering. It is verified that the measuring approach is operational and accurate to measure the attenuation of the LPL. The solution from this study did not tell the connection among the extinction and the inclusions of sea ice theoretically be-cause of insufficient understanding.展开更多
Monitoring changes in Annual Net Primary Productivity(ANPP)is required for reporting on UN Sustainable Development Goal(SDG)Indicator 15.3.1:the proportion of land that is degraded over the total land area.Calibrating...Monitoring changes in Annual Net Primary Productivity(ANPP)is required for reporting on UN Sustainable Development Goal(SDG)Indicator 15.3.1:the proportion of land that is degraded over the total land area.Calibrating time-series observations of ANPP to derive Water Use Efficiency(WUE;a measure of ANPP per unit of evapotranspiration)can minimize the influence of climate factors on ANPP observations and highlight the influence of non-climatic drivers of degradation such as land use changes.Comparing the ANPP and WUE time series may be useful for identifying the primary drivers of land degradation,which could be used to support the Land Degradation Neutrality objectives of the UN Convention to Combat Desertification(UNCCD).This paper presents an algorithm for the Google Earth Engine(freely and openly available upon request-http://doi.org/10.5281/zenodo.4429773)to calculate and compare ANPP and WUE time series for Santa Cruz,Bolivia,which has recently experienced an intensification in its land use.This code builds on the Good Practice Guidance document(ver-sion 1)for monitoring SDG Indicator 15.3.1.We use the MODIS 16-day average,250 m resolution to demonstrate that the Enhanced Vegetation Index(EVI)responds faster to changes in water avail-ability than the Normalized Difference Vegetation Index(NDVI).We also consider the relationships between ANPP and WUE.Significant and concordant trends may highlight good agricultural practices or increased resilience in ecosystem structure and productivity when they are positive or reducing resilience and functional integrity if negative.The sign and significance of the correlation between ANPP and WUE may also diverge over time.With further analysis,it may be possible to interpret this relationship in terms of the drivers of change in plant productivity and ecosystem resilience.展开更多
Thermal processes on the Tibetan Plateau(TP)influence atmospheric conditions on regional and global scales.Given this,previous work has shown that soil moisture−driven surface flux variations feed back onto the atmosp...Thermal processes on the Tibetan Plateau(TP)influence atmospheric conditions on regional and global scales.Given this,previous work has shown that soil moisture−driven surface flux variations feed back onto the atmosphere.Whilst soil moisture is a source of atmospheric predictability,no study has evaluated soil moisture−atmosphere coupling on the TP in general circulation models(GCMs).In this study,we use several analysis techniques to assess soil moisture−atmosphere coupling in CMIP6 simulations including:instantaneous coupling indices;analysis of flux and atmospheric behaviour during dry spells;and a quantification of the preference for convection over drier soils.Through these metrics we partition feedbacks into their atmospheric and terrestrial components.Consistent with previous global studies,we conclude substantial inter-model differences in the representation of soil moisture−atmosphere coupling,and that most models underestimate such feedbacks.Focusing on dry spell analysis,most models underestimate increased sensible heat during periods of rainfall deficiency.For example,the model-mean bias in anomalous sensible heat flux is 10 W m−2(≈25%)smaller compared to observations.Deficient dry-spell sensible heat fluxes lead to a weaker atmospheric response.We also find that most GCMs fail to capture the negative feedback between soil moisture and deep convection.The poor simulation of feedbacks in CMIP6 experiments suggests that forecast models also struggle to exploit soil moisture−driven predictability.To improve the representation of land−atmosphere feedbacks requires developments in not only atmospheric modelling,but also surface processes,as we find weak relationships between rainfall biases and coupling indexes.展开更多
Space-borne measurements of atmospheric greenhouse gas concentrations provide global observation constraints for top-down estimates of surface carbon flux.Here,the first estimates of the global distribution of carbon ...Space-borne measurements of atmospheric greenhouse gas concentrations provide global observation constraints for top-down estimates of surface carbon flux.Here,the first estimates of the global distribution of carbon surface fluxes inferred from dry-air CO_2 column (XCO_2) measurements by the Chinese Global Carbon Dioxide Monitoring Scientific Experimental Satellite (Tan Sat) are presented.An ensemble transform Kalman filter (ETKF) data assimilation system coupled with the GEOS-Chem global chemistry transport model is used to optimally fit model simulations with the Tan Sat XCO_2 observations,which were retrieved using the Institute of Atmospheric Physics Carbon dioxide retrieval Algorithm for Satellite remote sensing (IAPCAS).High posterior error reduction (30%–50%) compared with a priori fluxes indicates that assimilating satellite XCO_2 measurements provides highly effective constraints on global carbon flux estimation.Their impacts are also highlighted by significant spatiotemporal shifts in flux patterns over regions critical to the global carbon budget,such as tropical South America and China.An integrated global land carbon net flux of 6.71±0.76 Gt C yr^(-1) over12 months (May 2017–April 2018) is estimated from the Tan Sat XCO_2 data,which is generally consistent with other inversions based on satellite data,such as the JAXA GOSAT and NASA OCO-2 XCO_2 retrievals.However,discrepancies were found in some regional flux estimates,particularly over the Southern Hemisphere,where there may still be uncorrected bias between satellite measurements due to the lack of independent reference observations.The results of this study provide the groundwork for further studies using current or future Tan Sat XCO_2 data together with other surfacebased and space-borne measurements to quantify biosphere–atmosphere carbon exchange.展开更多
The Arctic sea-ice extent has shown a declining trend over the past 30 years. Ice coverage reached historic minima in 2007 and again in 2012. This trend has recently been assessed to be unique over at least the last 1...The Arctic sea-ice extent has shown a declining trend over the past 30 years. Ice coverage reached historic minima in 2007 and again in 2012. This trend has recently been assessed to be unique over at least the last 1450 years. In the summer of 2010, a very low sea-ice concentration(SIC) appeared at high Arctic latitudes—even lower than that of surrounding pack ice at lower latitudes. This striking low ice concentration—referred to here as a record low ice concentration in the central Arctic(CARLIC)—is unique in our analysis period of 2003–15, and has not been previously reported in the literature. The CARLIC was not the result of ice melt, because sea ice was still quite thick based on in-situ ice thickness measurements.Instead, divergent ice drift appears to have been responsible for the CARLIC. A high correlation between SIC and wind stress curl suggests that the sea ice drift during the summer of 2010 responded strongly to the regional wind forcing. The drift trajectories of ice buoys exhibited a transpolar drift in the Atlantic sector and an eastward drift in the Pacific sector,which appeared to benefit the CARLIC in 2010. Under these conditions, more solar energy can penetrate into the open water,increasing melt through increased heat flux to the ocean. We speculate that this divergence of sea ice could occur more often in the coming decades, and impact on hemispheric SIC and feed back to the climate.展开更多
The 1st Chinese carbon dioxide(CO2)monitoring satellite mission,TanSat,was launched in 2016.The 1st TanSat global map of CO2 dry-air mixing ratio(XCO2)measurements over land was released as version 1 data product with...The 1st Chinese carbon dioxide(CO2)monitoring satellite mission,TanSat,was launched in 2016.The 1st TanSat global map of CO2 dry-air mixing ratio(XCO2)measurements over land was released as version 1 data product with an accuracy of 2.11 ppmv(parts per million by volume).In this paper,we introduce a new(version 2)TanSat global XCO2 product that is approached by the Institute of Atmospheric Physics Carbon dioxide retrieval Algorithm for Satellite remote sensing(IAPCAS),and the European Space Agency(ESA)Climate Change Initiative plus(CCI+)TanSat XCO2 product by University of Leicester Full Physics(UoL-FP)retrieval algorithm.The correction of the measurement spectrum improves the accuracy(−0.08 ppmv)and precision(1.47 ppmv)of the new retrieval,which provides opportunity for further application in global carbon flux studies in the future.Inter-comparison between the two retrievals indicates a good agreement,with a standard deviation of 1.28 ppmv and a bias of−0.35 ppmv.展开更多
Digital Earth is an important field of information technology and a research frontier of geosciences in the 21st century.So far,the Grid computing technique is one of the best solutions for Digital Earth infrastructur...Digital Earth is an important field of information technology and a research frontier of geosciences in the 21st century.So far,the Grid computing technique is one of the best solutions for Digital Earth infrastructure.Digital Earth can only be realised through the interaction of people,heterogeneous computing resources,information systems,and instruments,all of which are geographically and organisationally dispersed.Earth observation(EO)includes information acquisition,processing and applications.Information acquisition provides a vast amount of spatial data for building the fabric resource infrastructure.Information processing means that spatial information processing middleware is used with large amounts of secure Grid computing resources for real-time processing of all kinds of spatial data.We are currently working on the development of coremiddleware for EO data processing and applications for the Digital Earth Prototype System,which is available in the Institute of Remote Sensing Applications(IRSA),Chinese Academy of Sciences(CAS)The further results will be available soon.展开更多
The historical annual loading to,removal from,and cumulative burden in the Arctic Ocean for β-hexachlorocyclohexane(β-HCH),an isomer comprising 5e12%of technical HCH,is investigated using a mass balance box model fr...The historical annual loading to,removal from,and cumulative burden in the Arctic Ocean for β-hexachlorocyclohexane(β-HCH),an isomer comprising 5e12%of technical HCH,is investigated using a mass balance box model from 1945 to 2020.Over the 76 years,loading occurred predominantly through ocean currents and river inflow(83%)and only a small portion via atmospheric transport(16%).β-HCH started to accumulate in the Arctic Ocean in the late 1940s,reached a peak of 810 t in 1986,and decreased to 87 t in 2020,when its concentrations in the Arctic water and air were~30 ng m^(-3)and~0.02 pg m^(-3),respectively.Even though β-HCH and α-HCH(60e70%of technical HCH)are both the isomers of HCHs with almost identical temporal and spatial emission patterns,these two chemicals have shown different major pathways entering the Arctic.Different from α-HCH with the long-range atmospheric transport(LRAT)as its major transport pathway,β-HCH reached the Arctic mainly through long-range oceanic transport(LROT).The much higher tendency of β-HCH to partition into the water,mainly due to its much lower Henry's Law Constant than α-HCH,produced an exceptionally strong pathway divergence with β-HCH favoring slow transport in water and α-HCH favoring rapid transport in air.The concentration and burden of β-HCH in the Arctic Ocean are also predicted for the year 2050 when only 4.4-5.3 t will remain in the Arctic Ocean under the influence of climate change.展开更多
The change in ocean net surface heat flux plays an important role in the climate system.It is closely related to the ocean heat content change and ocean heat transport,particularly over the North Atlantic,where the oc...The change in ocean net surface heat flux plays an important role in the climate system.It is closely related to the ocean heat content change and ocean heat transport,particularly over the North Atlantic,where the ocean loses heat to the atmosphere,affecting the AMOC(Atlantic Meridional Overturning Circulation)variability and hence the global climate.However,the difference between simulated surface heat fluxes is still large due to poorly represented dynamical processes involving multiscale interactions in model simulations.In order to explain the discrepancy of the surface heat flux over the North Atlantic,datasets from nineteen AMIP6 and eight highresSST-present climate model simulations are analyzed and compared with the DEEPC(Diagnosing Earth's Energy Pathways in the Climate system)product.As an indirect check of the ocean surface heat flux,the oceanic heat transport inferred from the combination of the ocean surface heat flux,sea ice,and ocean heat content tendency is compared with the RAPID(Rapid Climate Change-Meridional Overturning Circulation and Heat flux array)observations at 26°N in the Atlantic.The AMIP6 simulations show lower inferred heat transport due to less heat loss to the atmosphere.The heat loss from the AMIP6 ensemble mean north of 26°N in the Atlantic is about10 W m–2 less than DEEPC,and the heat transport is about 0.30 PW(1 PW=1015 W)lower than RAPID and DEEPC.The model horizontal resolution effect on the discrepancy is also investigated.Results show that by increasing the resolution,both surface heat flux north of 26°N and heat transport at 26°N in the Atlantic can be improved.展开更多
In recent studies,proxy XCH_(4)retrievals from the Japanese Greenhouse gases Observing SATellite(GOSAT)have been used to constrain top-down estimation of CH_(4)emissions.Still,the resulting interannual variations ofte...In recent studies,proxy XCH_(4)retrievals from the Japanese Greenhouse gases Observing SATellite(GOSAT)have been used to constrain top-down estimation of CH_(4)emissions.Still,the resulting interannual variations often show significant discrepancies over some of the most important CH_(4)source regions,such as China and Tropical South America,by causes yet to be determined.This study compares monthly CH_(4)flux estimates from two parallel assimilations of GOSAT XCH_(4)retrievals from 2010 to 2019 based on the same Ensemble Kalman Filter(EnKF)framework but with the global chemistry transport model(GEOS-Chem v12.5)being run at two different spatial resolutions of 4°×5°(R4,lon×lat)and 2°×2.5°(R2,lon×lat)to investigate the effects of resolution-related model errors on the derived long-term global and regional CH_(4)emission trends.We found that the mean annual global methane emission for the 2010s is 573.04 Tg yr^(-1)for the inversion using the R4 model,which becomes about 4.4 Tg yr^(-1)less(568.63 Tg yr^(-1))when a finer R2 model is used,though both are well within the ensemble range of the 22 top-down results(2008-17)included in the current Global Carbon Project(from 550 Tg yr^(-1)to 594 Tg yr^(-1)).Compared to the R2 model,the inversion based on the R4 tends to overestimate tropical emissions(by 13.3 Tg yr^(-1)),which is accompanied by a general underestimation(by 8.9 Tg yr^(-1))in the extratropics.Such a dipole reflects differences in tropical-mid-latitude air exchange in relation to the model’s convective and advective schemes at different resolutions.The two inversions show a rather consistent long-term CH_(4)emission trend at the global scale and over most of the continents,suggesting that the observed rapid increase in atmospheric methane can largely be attributed to the emission growth from North Africa(1.79 Tg yr^(-2)for R4 and 1.29 Tg yr^(-2)for R2)and South America Temperate(1.08 Tg yr^(-2)for R4 and 1.21 Tg yr^(-2)for R2)during the first half of the 2010s,and from Eurasia Boreal(1.46 Tg yr^(-2)for R4 and 1.63 Tg yr^(-2)for R2)and Tropical South America(1.72 Tg yr-2 for R4 and 1.43 Tg yr^(-2)for R2)over 2015-19.In the meantime,emissions in Europe have shown a consistent decrease over the past decade.However,the growth rates by the two parallel inversions show significant discrepancies over Eurasia Temperate,South America Temperate,and South Africa,which are also the places where recent GOSAT inversions usually disagree with one other.展开更多
Contaminants,such as polychlorinated biphenyls(PCBs),polycyclic aromatic hydrocarbons(PAHs),heavy metals,and per and polyfluoroalkyl substances(PFASs),primarily reach the Arctic through long-range atmospheric and ocea...Contaminants,such as polychlorinated biphenyls(PCBs),polycyclic aromatic hydrocarbons(PAHs),heavy metals,and per and polyfluoroalkyl substances(PFASs),primarily reach the Arctic through long-range atmospheric and oceanic transport.However,local sources within the Arctic also contribute to the levels observed in the environment,including legacy sources and new sources that arise from activities associated with increasing commercial and industrial development.The City of Iqaluit in Frobisher Bay,Nunavut(Canada),has seen rapid population growth and associated development during recent decades yet remains a site of interest for ocean protection,where Inuit continue to harvest country food.In the present study,seven dated marine sediment cores collected in Koojesse Inlet near Iqaluit,and from sites in inner and outer Frobisher Bay,respectively,were analyzed for total mercury(THg),major and trace elements,PAHs,PCBs,and PFASs.The sedimentary record in Koojesse Inlet shows a period of Aroclor 1260-like PCB input concurrent with military site presence in the 1950e60s,followed by decades of input of pyrogenic PAHs,averaging about ten times background levels.Near-surface sediments in Koojesse Inlet also show evidence of transient local-source inputs of THg and PFASs,and recycling or continued slow release of PCBs from legacy land-based sources.Differences in PFAS congener composition clearly distinguish the local sources from long-range transport.Outside Koojesse Inlet but still in inner Frobisher Bay,9.2 km from Iqaluit,sediments showed evidence of both local source(PCB)and longrange transport.In outer Frobisher Bay,an up-core increase in THg and PFASs in sediments may be explained by ongoing inputs of these contaminants from long-range transport.The context for ocean protection and country food harvesting in this region of the Arctic clearly involves both local sources and long-range transport,with past human activities leaving a long legacy insofar as levels of persistent organic pollutants are concerned.展开更多
The distribution and fractionation of persistent organic pollutants(POPs)in different matrices refer to how these pollutants are dispersed and separated within various environmental compartments.This is a significant ...The distribution and fractionation of persistent organic pollutants(POPs)in different matrices refer to how these pollutants are dispersed and separated within various environmental compartments.This is a significant study area as it helps us understand the transport efficiencies and long-range transport potentials of POPs to enter remote areas,particularly polar regions.This study provides a comprehensive review of the progress in understanding the distribution and fractionation of POPs.We focus on the contributions of four intermedia processes(dry and wet depositions for gaseous and particulate POPs)and determine their transfer between air and soil.These processes are controlled by their partitioning between gaseous and particulate phases in the atmosphere.The distribution patterns and fractionations can be categorized into primary and secondary types.Equations are developed to quantificationally study the primary and secondary distributions and fractionations of POPs.The analysis results suggest that the transfer of low molecular weight(LMW)POPs from air to soil is mainly through gas diffusion and particle deposition,whereas high molecular weight(HMW)POPs are mainly via particle deposition.HMW-POPs tend to be trapped near the source,whereas LMW-POPs are more prone to undergo long-range atmospheric transport.This crucial distinction elucidates the primary reason behind their temperatureindependent primary fractionation.However,the secondary distribution and fractionation can only be observed along a temperature gradient,such as latitudinal or altitudinal transects.An animation is produced by a one-dimensional transport model to simulate conceptively the transport of CB-28 and CB-180,revealing the similarities and differences between the primary and secondary distributions and fractionations.We suggest that the decreasing temperature trend along latitudes is not the major reason for POPs to be fractionated into the polar ecosystems,but drives the longer-term accumulation of POPs in cold climates or polar cold trapping.展开更多
The transformation of mercury(Hg) in the environment plays a vital role in the cycling of Hg and its risk to the ecosystem and human health. Of particular importance are Hg oxidation/reduction and methylation/demethyl...The transformation of mercury(Hg) in the environment plays a vital role in the cycling of Hg and its risk to the ecosystem and human health. Of particular importance are Hg oxidation/reduction and methylation/demethylation processes driven or mediated by the dynamics of light, microorganisms, and organic carbon, among others. Advances in understanding those Hg transformation processes determine our capacity of projecting and mitigating Hg risk. Here, we provide a critical analysis of major knowledge gaps in our understanding of Hg transformation in nature, with perspectives on approaches moving forward. Our analysis focuses on Hg transformation processes in the environment, as well as emerging methodology in exploring these processes. Future avenues for improving the understanding of Hg transformation processes to protect ecosystem and human health are also explored.展开更多
The asthenosphere upwelled on a large scale in the western Pacific and South China Sea during the Cenozoic, which formed strong upward throughflow and caused the thermal structure to be changed obviously. The mathemat...The asthenosphere upwelled on a large scale in the western Pacific and South China Sea during the Cenozoic, which formed strong upward throughflow and caused the thermal structure to be changed obviously. The mathematical analysis has demonstrated that the upward throughflow velocity may have varied from 3×10^11 to 6×10^12 m/s. From the relationship between the lithospheric thickness and the conductive heat flux, the lithospheric heat flux in the western Pacific should be above 30 mW/m^2, which is consistent with the observed data. The huge low-speed zone within the upper mantle of the marginal sea in the western Pacific reflects that the upper mantle melts partially, flows regionally in the regional stress field, forms the upward heat flux at its bottom, and causes the change of the lithospheric thermal structure in the region. The numerical simulation result of the expansion and evolution in the South China Sea has demonstrated that in the early expansion, the upward throughflow velocity was relatively fast, and the effect that it had on the thickness of the lithosphere was relatively great,resulting in the mid-ocean basin expanding rapidly. After the formation of the ocean basin in the South China Sea, the upward throughflow velocity decreased, but the conductive heat flux was relatively high, which is close to the actual situation. Therefore, from the heat transfer point of view, this article discusses how the upward heat flux affects the lithospheric thermal structure in the western Pacific and South China Sea. The conclusions show that the upward heat throughflow at the bottom of the lithospheric mantle resulted in the tectonic deformation at the shallow crust. The intensive uplifts and rifts at the crust led to the continent cracks and the expansion in the South China Sea.展开更多
Soil dissolved organic matter(DOM)plays an essential role in the Three Gorges Reservoir(TGR)as a linkage between terrestrial and aquatic systems.In particular,the reducing capacities of soil DOM influence the geochemi...Soil dissolved organic matter(DOM)plays an essential role in the Three Gorges Reservoir(TGR)as a linkage between terrestrial and aquatic systems.In particular,the reducing capacities of soil DOM influence the geochemistry of contaminants such as mercury(Hg).However,few studies have investigated the molecular information of soil DOM and its relationship with relevant geochemic al reactivities,including redox properties.We collected samples from eight sites in the TGR areas and studied the link between the molecular characteristics of DOM and their electron donation capacities(EDCs)toward Hg(II).The average kinetic rate and EDC of soil DOM in TGR areas were(0.004±0.001)hr-1 and(2.88±1.39)nmol e-/mg DOMbulk,respectively.Results suggest that higher EDCs and relatively rapid kinetics were related to the greater electron donating components of ligninderived and perhaps pyrogenic DOM,which are the aromatic constituents that influenced the reducing capacities of DOM in the present study.Molecular details revealed that even the typical autochthonous markers are important for the EDCs of DOM as well,in contrast to what is generally assumed.More studies identifying specific DOM molecular components involved in the abiotic reduction of Hg(II)are required to further understand the relations between DOM sources and their redox roles in the environmental fate of contaminants.展开更多
River channel shifting in the deltaic regime is an unabated occurrence.Channel shifting has become one of the concerns as it influences land use/land cover along the riverbank in various ways.For the management of the...River channel shifting in the deltaic regime is an unabated occurrence.Channel shifting has become one of the concerns as it influences land use/land cover along the riverbank in various ways.For the management of the river,it is indispensable to study the pattern of river course change both in qualitative and quantitative methods.This study is an attempt to understand the pattern of shifting and to quantify erosion and deposition of the river Ganga at upstream and downstream of Farakka Barrage during 1794-2017.The study has been carried out by using various historical maps,aerial photographs,satellite imagery,and remote sensing and GIS technique to understand the dynamic of the river.Over 223 years period shifting of the river accentuates the remarkable oscillation of the river.Perimeter of the river is determined to understand the area covered by the river course in the study area.To evaluate the meandering of the river sinuosity of the river has been computed in this study.The amount of erosion and deposition was calculated in this study by using ArcGIS 10.6.The study found a higher amount of erosion at the east bank where Manikchak,Kaliachak II and Kaliachak III blocks are situated between 1965 and 2017.At the west bank of the river,especially the Rajmahal block,the occurrence of deposition was remarkable during the same period.展开更多
基金funded by the National Environmental Research Council, UK, through a PhD studentship at the Centre for observation of Air-Sea Interactions & fluXes (CASIX)the National Centre for Earth Observation and NERC Oceans 2025 programme (Themes 6 and 10)
文摘An important goal in ocean colour remote sensing is to accurately detect different phytoplankton groups with the potential uses including the validation of multi-phytoplankton carbon cycle models; synoptically monitoring the health of our oceans, and improving our understanding of the bio-geochemical interactions between phytoplankton and their environment. In this paper a new algorithm is developed for detecting three dominant phytoplankton size classes based on distinct differences in their optical signatures. The technique is validated against an independent coupled satellite reflectance and in situ pigment dataset and run on the 10-year NASA Sea viewing Wide Field of view Sensor （SeaWiFS） data series. Results indicate that on average 3.6% of the global oceanic surface layer is dominated by microplankton, 18.0% by nanoplankton and 78.4% by pieoplankton. Results, however, are seen to vary depending on season and ocean basin.
基金ESA/MOST Dragon-4 Program(Project ID:32301)ESA CCI(GHG-CCI)and Copernicus Climate Change Initiative+2 种基金National Key R&D Program of China(No.2016YFA0600203)Key Research Program of the Chinese Academy of Sciences(No.ZDRW-ZS-2019-1)External Cooperation Program of the Chinese Academy of Sciences(No.GJHZ1507)。
文摘The atmospheric carbon dioxide(CO 2)concentration has increased to more than 405 parts per million(ppm.1 ppm=10-6 m/s 2)in 2017 due to human activities such as deforestation,land-use change and burning of fossil fuels.Although there is broad scientific consensus on the damaging consequences of the change in climate associated with increasing concentrations of greenhouse gases,fossil CO 2 emissions have continued to increase in recent years mainly from rapidly developing economies and China is now the largest emitter of CO 2 generating about 30%of all emissions globally.To allow more reliable forecast of the future state of the carbon cycle and to support the efforts for mitigation greenhouse gas emissions,a better understanding of the global and regional carbon budget is needed.Space-based measurements of CO 2 can provide the necessary observations with dense coverage and sampling to provide improved constrains on of carbon fluxes and emissions.The Chinese Global Carbon Dioxide Monitoring Scientific Experimental Satellite(TanSat)was established by the National High Technology Research and Development Program of China with the main objective of monitoring atmospheric CO 2 and CO 2 fluxes at the regional and global scale.TanSat has been successfully launched in December 2016 and as part of the Dragon programme of ESA and the Ministry of Science and Technology(MOST),a team of researchers from Europe(UK and Finland)and China has evaluated early TanSat data and contrast it against data from the GOSAT mission and models.In this manuscript,we report on retrieval intercomparisons of TanSat data using two different retrieval algorithms,on validation efforts for the Eastern Asia region using GOSAT CO 2 data and first assessments of TanSat and GOSAT CO 2 data against model calculations using the GEOS-Chem model.
基金The Global Change Research Program of China under contract No.2015CB953900the Key Program of National Natural Science Foundation of China under contract No.41330960
文摘The attenuation of lateral propagating light （LPL） in sea ice was measured using an artificial light source in the Canadian Arctic during the 2007/2008 winter. The apparent attenuation coefficientμ（λ）for lateral prop-agating light was obtained from the measured logarithmic relative variation rate. In this study an analytical solution based on the strict optical theories is developed to validate the measured result. There is a good consistency between theoretical solution and measured data, by which a quite simple but very rigorous relationship among the light source, measurement geometry, and measured irradiance is established. The attenuation coefficients acquired by measurement and theory are the diffusion attenuation as an apparent optical property of ice, independent of the light source and shining condition. The attenuation ability of sea ice should be caused by the microstructure of sea ice, such as crystal size, ice density, brine volume, air inclusion, etc. It also includes the leak from both interfaces by directional scattering. It is verified that the measuring approach is operational and accurate to measure the attenuation of the LPL. The solution from this study did not tell the connection among the extinction and the inclusions of sea ice theoretically be-cause of insufficient understanding.
基金This study was partially funded by UNDP Grant:BOL/118208(“Laboratorios de Recuperación Temprana”),a study led by Fundación para Conservación del Bosque Chiquitano(www.fcbc.org.bo)to determine forest patches requiring post-fire assisted recovery in the aftermath of 2019 wildfires in Santa Cruz,Bolivia:“Plan Estratégico para la Restauración de lasÁreas Afectadas por los Incendios en el 2019”.
文摘Monitoring changes in Annual Net Primary Productivity(ANPP)is required for reporting on UN Sustainable Development Goal(SDG)Indicator 15.3.1:the proportion of land that is degraded over the total land area.Calibrating time-series observations of ANPP to derive Water Use Efficiency(WUE;a measure of ANPP per unit of evapotranspiration)can minimize the influence of climate factors on ANPP observations and highlight the influence of non-climatic drivers of degradation such as land use changes.Comparing the ANPP and WUE time series may be useful for identifying the primary drivers of land degradation,which could be used to support the Land Degradation Neutrality objectives of the UN Convention to Combat Desertification(UNCCD).This paper presents an algorithm for the Google Earth Engine(freely and openly available upon request-http://doi.org/10.5281/zenodo.4429773)to calculate and compare ANPP and WUE time series for Santa Cruz,Bolivia,which has recently experienced an intensification in its land use.This code builds on the Good Practice Guidance document(ver-sion 1)for monitoring SDG Indicator 15.3.1.We use the MODIS 16-day average,250 m resolution to demonstrate that the Enhanced Vegetation Index(EVI)responds faster to changes in water avail-ability than the Normalized Difference Vegetation Index(NDVI).We also consider the relationships between ANPP and WUE.Significant and concordant trends may highlight good agricultural practices or increased resilience in ecosystem structure and productivity when they are positive or reducing resilience and functional integrity if negative.The sign and significance of the correlation between ANPP and WUE may also diverge over time.With further analysis,it may be possible to interpret this relationship in terms of the drivers of change in plant productivity and ecosystem resilience.
基金supported by the UK-China Research Innovation Partnership Fund through the Met Office Climate Science for Service Partnership (CSSP) China as part of the Newton Fundsupported by the Natural Environment Research Council as part of the NC-International programme (NE/X006247/1) delivering National Capability
文摘Thermal processes on the Tibetan Plateau(TP)influence atmospheric conditions on regional and global scales.Given this,previous work has shown that soil moisture−driven surface flux variations feed back onto the atmosphere.Whilst soil moisture is a source of atmospheric predictability,no study has evaluated soil moisture−atmosphere coupling on the TP in general circulation models(GCMs).In this study,we use several analysis techniques to assess soil moisture−atmosphere coupling in CMIP6 simulations including:instantaneous coupling indices;analysis of flux and atmospheric behaviour during dry spells;and a quantification of the preference for convection over drier soils.Through these metrics we partition feedbacks into their atmospheric and terrestrial components.Consistent with previous global studies,we conclude substantial inter-model differences in the representation of soil moisture−atmosphere coupling,and that most models underestimate such feedbacks.Focusing on dry spell analysis,most models underestimate increased sensible heat during periods of rainfall deficiency.For example,the model-mean bias in anomalous sensible heat flux is 10 W m−2(≈25%)smaller compared to observations.Deficient dry-spell sensible heat fluxes lead to a weaker atmospheric response.We also find that most GCMs fail to capture the negative feedback between soil moisture and deep convection.The poor simulation of feedbacks in CMIP6 experiments suggests that forecast models also struggle to exploit soil moisture−driven predictability.To improve the representation of land−atmosphere feedbacks requires developments in not only atmospheric modelling,but also surface processes,as we find weak relationships between rainfall biases and coupling indexes.
基金supported by the National Key R&D Program of China (Grant No.2016YFA0600203)the National Key R&D Program of China (Grant No.2017YFB0504000)+3 种基金the Key Research Program of the Chinese Academy of Sciences (ZDRW-ZS-2019-1)the Youth Program of the National Natural Science Foundation of China (Grant No.41905029)supported by the UK NERC National Centre for Earth Observation (NCEO)The TanSat L1B data service is provided by IRCSD and CASA (131211KYSB20180002)。
文摘Space-borne measurements of atmospheric greenhouse gas concentrations provide global observation constraints for top-down estimates of surface carbon flux.Here,the first estimates of the global distribution of carbon surface fluxes inferred from dry-air CO_2 column (XCO_2) measurements by the Chinese Global Carbon Dioxide Monitoring Scientific Experimental Satellite (Tan Sat) are presented.An ensemble transform Kalman filter (ETKF) data assimilation system coupled with the GEOS-Chem global chemistry transport model is used to optimally fit model simulations with the Tan Sat XCO_2 observations,which were retrieved using the Institute of Atmospheric Physics Carbon dioxide retrieval Algorithm for Satellite remote sensing (IAPCAS).High posterior error reduction (30%–50%) compared with a priori fluxes indicates that assimilating satellite XCO_2 measurements provides highly effective constraints on global carbon flux estimation.Their impacts are also highlighted by significant spatiotemporal shifts in flux patterns over regions critical to the global carbon budget,such as tropical South America and China.An integrated global land carbon net flux of 6.71±0.76 Gt C yr^(-1) over12 months (May 2017–April 2018) is estimated from the Tan Sat XCO_2 data,which is generally consistent with other inversions based on satellite data,such as the JAXA GOSAT and NASA OCO-2 XCO_2 retrievals.However,discrepancies were found in some regional flux estimates,particularly over the Southern Hemisphere,where there may still be uncorrected bias between satellite measurements due to the lack of independent reference observations.The results of this study provide the groundwork for further studies using current or future Tan Sat XCO_2 data together with other surfacebased and space-borne measurements to quantify biosphere–atmosphere carbon exchange.
基金funded by the Global Change Research Program of China(Grant No.2015CB953900)the Key Program of the National Natural Science Foundation of China(Grant Nos.41330960 and 41406208)+1 种基金the Canada Research Chairs Program,NSERCCanadian Federal IPY Program Office
文摘The Arctic sea-ice extent has shown a declining trend over the past 30 years. Ice coverage reached historic minima in 2007 and again in 2012. This trend has recently been assessed to be unique over at least the last 1450 years. In the summer of 2010, a very low sea-ice concentration(SIC) appeared at high Arctic latitudes—even lower than that of surrounding pack ice at lower latitudes. This striking low ice concentration—referred to here as a record low ice concentration in the central Arctic(CARLIC)—is unique in our analysis period of 2003–15, and has not been previously reported in the literature. The CARLIC was not the result of ice melt, because sea ice was still quite thick based on in-situ ice thickness measurements.Instead, divergent ice drift appears to have been responsible for the CARLIC. A high correlation between SIC and wind stress curl suggests that the sea ice drift during the summer of 2010 responded strongly to the regional wind forcing. The drift trajectories of ice buoys exhibited a transpolar drift in the Atlantic sector and an eastward drift in the Pacific sector,which appeared to benefit the CARLIC in 2010. Under these conditions, more solar energy can penetrate into the open water,increasing melt through increased heat flux to the ocean. We speculate that this divergence of sea ice could occur more often in the coming decades, and impact on hemispheric SIC and feed back to the climate.
基金This work was supported by the National Key R&D Program of China(Grant No.2016YFA0600203)the Key Research Program of the Chinese Academy of Sciences(Grant No.ZDRW-ZS-2019-1)+4 种基金the International Partnership Program of the Chinese Academy of Sciences(Grant No.GJHZ201903)the National Natural Science Foundation of China(Grant No.41905029)ESA Climate Change Initiative CCI+(GhG theme),Earthnet Data Assessment Pilot(EDAP)project and ESA-MOST Dragon-4 programme(ID 32301)supported by the UK NERC National Centre for Earth Observation(NCEO)(Grant Nos.nceo020005 and NE/N018079/1)The TanSat L1B data service is provided by IRCSD and CASA(131211KYSB20180002).
文摘The 1st Chinese carbon dioxide(CO2)monitoring satellite mission,TanSat,was launched in 2016.The 1st TanSat global map of CO2 dry-air mixing ratio(XCO2)measurements over land was released as version 1 data product with an accuracy of 2.11 ppmv(parts per million by volume).In this paper,we introduce a new(version 2)TanSat global XCO2 product that is approached by the Institute of Atmospheric Physics Carbon dioxide retrieval Algorithm for Satellite remote sensing(IAPCAS),and the European Space Agency(ESA)Climate Change Initiative plus(CCI+)TanSat XCO2 product by University of Leicester Full Physics(UoL-FP)retrieval algorithm.The correction of the measurement spectrum improves the accuracy(−0.08 ppmv)and precision(1.47 ppmv)of the new retrieval,which provides opportunity for further application in global carbon flux studies in the future.Inter-comparison between the two retrievals indicates a good agreement,with a standard deviation of 1.28 ppmv and a bias of−0.35 ppmv.
基金‘Multi-scale Aerosol Optical Thickness Quantitative Retrieval from Remotely Sensing Data at Urban Area’(40671142)‘Aerosol fast monitoring modelling using MODIS data and middlewares development’(40471091)+1 种基金NSFC,China,‘Digital Earth(KZCX2-312)’funded by CAS,China‘Dynamic Monitoring of Beijing Olympic Environment Using Remote Sensing’(2002BA904B07-2)funded by the MOST,China.
文摘Digital Earth is an important field of information technology and a research frontier of geosciences in the 21st century.So far,the Grid computing technique is one of the best solutions for Digital Earth infrastructure.Digital Earth can only be realised through the interaction of people,heterogeneous computing resources,information systems,and instruments,all of which are geographically and organisationally dispersed.Earth observation(EO)includes information acquisition,processing and applications.Information acquisition provides a vast amount of spatial data for building the fabric resource infrastructure.Information processing means that spatial information processing middleware is used with large amounts of secure Grid computing resources for real-time processing of all kinds of spatial data.We are currently working on the development of coremiddleware for EO data processing and applications for the Digital Earth Prototype System,which is available in the Institute of Remote Sensing Applications(IRSA),Chinese Academy of Sciences(CAS)The further results will be available soon.
基金supported by the National Natural Science Foundation of China(No.42077341)Natural Science Foundation of Heilongjiang Province of China(No.LH2021E096)+3 种基金State Key Laboratory of UrbanWater Resource and Environment(Harbin Institute of Technology)(No.2022TS05)the Polar Academy,Harbin Institute of Technology(No.PA-HIT-201901)the support from Heilongjiang Provincial Key Laboratory of Polar Environment and Ecosystem(HPKLPEE),Harbin Institute of Technologyfunding from Canada's Northern Contaminants Program(Crown-Indigenous Relations and Northern Affairs Canada).
文摘The historical annual loading to,removal from,and cumulative burden in the Arctic Ocean for β-hexachlorocyclohexane(β-HCH),an isomer comprising 5e12%of technical HCH,is investigated using a mass balance box model from 1945 to 2020.Over the 76 years,loading occurred predominantly through ocean currents and river inflow(83%)and only a small portion via atmospheric transport(16%).β-HCH started to accumulate in the Arctic Ocean in the late 1940s,reached a peak of 810 t in 1986,and decreased to 87 t in 2020,when its concentrations in the Arctic water and air were~30 ng m^(-3)and~0.02 pg m^(-3),respectively.Even though β-HCH and α-HCH(60e70%of technical HCH)are both the isomers of HCHs with almost identical temporal and spatial emission patterns,these two chemicals have shown different major pathways entering the Arctic.Different from α-HCH with the long-range atmospheric transport(LRAT)as its major transport pathway,β-HCH reached the Arctic mainly through long-range oceanic transport(LROT).The much higher tendency of β-HCH to partition into the water,mainly due to its much lower Henry's Law Constant than α-HCH,produced an exceptionally strong pathway divergence with β-HCH favoring slow transport in water and α-HCH favoring rapid transport in air.The concentration and burden of β-HCH in the Arctic Ocean are also predicted for the year 2050 when only 4.4-5.3 t will remain in the Arctic Ocean under the influence of climate change.
基金supported by the National Natural Science Foundation of China(Grant No.42075036)Fujian Key Laboratory of Severe Weather(Grant No.2021KFKT02)+2 种基金the scientific research start-up grant of Guangdong Ocean University(Grant No.R20001)supported by the University of Reading as a visiting fellowsupported by the UK National Centre for Earth Observation Grant No.NE/RO16518/1。
文摘The change in ocean net surface heat flux plays an important role in the climate system.It is closely related to the ocean heat content change and ocean heat transport,particularly over the North Atlantic,where the ocean loses heat to the atmosphere,affecting the AMOC(Atlantic Meridional Overturning Circulation)variability and hence the global climate.However,the difference between simulated surface heat fluxes is still large due to poorly represented dynamical processes involving multiscale interactions in model simulations.In order to explain the discrepancy of the surface heat flux over the North Atlantic,datasets from nineteen AMIP6 and eight highresSST-present climate model simulations are analyzed and compared with the DEEPC(Diagnosing Earth's Energy Pathways in the Climate system)product.As an indirect check of the ocean surface heat flux,the oceanic heat transport inferred from the combination of the ocean surface heat flux,sea ice,and ocean heat content tendency is compared with the RAPID(Rapid Climate Change-Meridional Overturning Circulation and Heat flux array)observations at 26°N in the Atlantic.The AMIP6 simulations show lower inferred heat transport due to less heat loss to the atmosphere.The heat loss from the AMIP6 ensemble mean north of 26°N in the Atlantic is about10 W m–2 less than DEEPC,and the heat transport is about 0.30 PW(1 PW=1015 W)lower than RAPID and DEEPC.The model horizontal resolution effect on the discrepancy is also investigated.Results show that by increasing the resolution,both surface heat flux north of 26°N and heat transport at 26°N in the Atlantic can be improved.
基金supported by the National Key R&D Plan of China(Grant No.SQ2019YFE013078)the Key Research Program of the Chinese Academy of Sciences(Grant No.ZDRW-ZS-2019-1)the National Key R&D Program of China(Grant No.2017YFB0504000)。
文摘In recent studies,proxy XCH_(4)retrievals from the Japanese Greenhouse gases Observing SATellite(GOSAT)have been used to constrain top-down estimation of CH_(4)emissions.Still,the resulting interannual variations often show significant discrepancies over some of the most important CH_(4)source regions,such as China and Tropical South America,by causes yet to be determined.This study compares monthly CH_(4)flux estimates from two parallel assimilations of GOSAT XCH_(4)retrievals from 2010 to 2019 based on the same Ensemble Kalman Filter(EnKF)framework but with the global chemistry transport model(GEOS-Chem v12.5)being run at two different spatial resolutions of 4°×5°(R4,lon×lat)and 2°×2.5°(R2,lon×lat)to investigate the effects of resolution-related model errors on the derived long-term global and regional CH_(4)emission trends.We found that the mean annual global methane emission for the 2010s is 573.04 Tg yr^(-1)for the inversion using the R4 model,which becomes about 4.4 Tg yr^(-1)less(568.63 Tg yr^(-1))when a finer R2 model is used,though both are well within the ensemble range of the 22 top-down results(2008-17)included in the current Global Carbon Project(from 550 Tg yr^(-1)to 594 Tg yr^(-1)).Compared to the R2 model,the inversion based on the R4 tends to overestimate tropical emissions(by 13.3 Tg yr^(-1)),which is accompanied by a general underestimation(by 8.9 Tg yr^(-1))in the extratropics.Such a dipole reflects differences in tropical-mid-latitude air exchange in relation to the model’s convective and advective schemes at different resolutions.The two inversions show a rather consistent long-term CH_(4)emission trend at the global scale and over most of the continents,suggesting that the observed rapid increase in atmospheric methane can largely be attributed to the emission growth from North Africa(1.79 Tg yr^(-2)for R4 and 1.29 Tg yr^(-2)for R2)and South America Temperate(1.08 Tg yr^(-2)for R4 and 1.21 Tg yr^(-2)for R2)during the first half of the 2010s,and from Eurasia Boreal(1.46 Tg yr^(-2)for R4 and 1.63 Tg yr^(-2)for R2)and Tropical South America(1.72 Tg yr-2 for R4 and 1.43 Tg yr^(-2)for R2)over 2015-19.In the meantime,emissions in Europe have shown a consistent decrease over the past decade.However,the growth rates by the two parallel inversions show significant discrepancies over Eurasia Temperate,South America Temperate,and South Africa,which are also the places where recent GOSAT inversions usually disagree with one other.
文摘Contaminants,such as polychlorinated biphenyls(PCBs),polycyclic aromatic hydrocarbons(PAHs),heavy metals,and per and polyfluoroalkyl substances(PFASs),primarily reach the Arctic through long-range atmospheric and oceanic transport.However,local sources within the Arctic also contribute to the levels observed in the environment,including legacy sources and new sources that arise from activities associated with increasing commercial and industrial development.The City of Iqaluit in Frobisher Bay,Nunavut(Canada),has seen rapid population growth and associated development during recent decades yet remains a site of interest for ocean protection,where Inuit continue to harvest country food.In the present study,seven dated marine sediment cores collected in Koojesse Inlet near Iqaluit,and from sites in inner and outer Frobisher Bay,respectively,were analyzed for total mercury(THg),major and trace elements,PAHs,PCBs,and PFASs.The sedimentary record in Koojesse Inlet shows a period of Aroclor 1260-like PCB input concurrent with military site presence in the 1950e60s,followed by decades of input of pyrogenic PAHs,averaging about ten times background levels.Near-surface sediments in Koojesse Inlet also show evidence of transient local-source inputs of THg and PFASs,and recycling or continued slow release of PCBs from legacy land-based sources.Differences in PFAS congener composition clearly distinguish the local sources from long-range transport.Outside Koojesse Inlet but still in inner Frobisher Bay,9.2 km from Iqaluit,sediments showed evidence of both local source(PCB)and longrange transport.In outer Frobisher Bay,an up-core increase in THg and PFASs in sediments may be explained by ongoing inputs of these contaminants from long-range transport.The context for ocean protection and country food harvesting in this region of the Arctic clearly involves both local sources and long-range transport,with past human activities leaving a long legacy insofar as levels of persistent organic pollutants are concerned.
基金supported by the National Natural Science Foundation of China(42077341),the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.2022TS05)the Special Project for Sustainable Development Science Technology in Shenzhen(No.KCXFZ20201221173000001)supported by the Heilongjiang Touyan Innovation Team Program and the Natural Science Foundation of Heilongjiang Province of China(Grant No.LH2021E096),China.
文摘The distribution and fractionation of persistent organic pollutants(POPs)in different matrices refer to how these pollutants are dispersed and separated within various environmental compartments.This is a significant study area as it helps us understand the transport efficiencies and long-range transport potentials of POPs to enter remote areas,particularly polar regions.This study provides a comprehensive review of the progress in understanding the distribution and fractionation of POPs.We focus on the contributions of four intermedia processes(dry and wet depositions for gaseous and particulate POPs)and determine their transfer between air and soil.These processes are controlled by their partitioning between gaseous and particulate phases in the atmosphere.The distribution patterns and fractionations can be categorized into primary and secondary types.Equations are developed to quantificationally study the primary and secondary distributions and fractionations of POPs.The analysis results suggest that the transfer of low molecular weight(LMW)POPs from air to soil is mainly through gas diffusion and particle deposition,whereas high molecular weight(HMW)POPs are mainly via particle deposition.HMW-POPs tend to be trapped near the source,whereas LMW-POPs are more prone to undergo long-range atmospheric transport.This crucial distinction elucidates the primary reason behind their temperatureindependent primary fractionation.However,the secondary distribution and fractionation can only be observed along a temperature gradient,such as latitudinal or altitudinal transects.An animation is produced by a one-dimensional transport model to simulate conceptively the transport of CB-28 and CB-180,revealing the similarities and differences between the primary and secondary distributions and fractionations.We suggest that the decreasing temperature trend along latitudes is not the major reason for POPs to be fractionated into the polar ecosystems,but drives the longer-term accumulation of POPs in cold climates or polar cold trapping.
基金supported by the National Natural Science Foundation of China (Nos. U2032201 and 21976193 )the Canada Research Chairs Program。
文摘The transformation of mercury(Hg) in the environment plays a vital role in the cycling of Hg and its risk to the ecosystem and human health. Of particular importance are Hg oxidation/reduction and methylation/demethylation processes driven or mediated by the dynamics of light, microorganisms, and organic carbon, among others. Advances in understanding those Hg transformation processes determine our capacity of projecting and mitigating Hg risk. Here, we provide a critical analysis of major knowledge gaps in our understanding of Hg transformation in nature, with perspectives on approaches moving forward. Our analysis focuses on Hg transformation processes in the environment, as well as emerging methodology in exploring these processes. Future avenues for improving the understanding of Hg transformation processes to protect ecosystem and human health are also explored.
基金supported jointly by the Important Direction Project of the CAS Knowledge Innovation Program (Nos. KZCX2-YW-203-01, KZCX2-YW-128-4)the Program of Key Laboratory of Marginal Sea Geology (No. MSGL04-8)
文摘The asthenosphere upwelled on a large scale in the western Pacific and South China Sea during the Cenozoic, which formed strong upward throughflow and caused the thermal structure to be changed obviously. The mathematical analysis has demonstrated that the upward throughflow velocity may have varied from 3×10^11 to 6×10^12 m/s. From the relationship between the lithospheric thickness and the conductive heat flux, the lithospheric heat flux in the western Pacific should be above 30 mW/m^2, which is consistent with the observed data. The huge low-speed zone within the upper mantle of the marginal sea in the western Pacific reflects that the upper mantle melts partially, flows regionally in the regional stress field, forms the upward heat flux at its bottom, and causes the change of the lithospheric thermal structure in the region. The numerical simulation result of the expansion and evolution in the South China Sea has demonstrated that in the early expansion, the upward throughflow velocity was relatively fast, and the effect that it had on the thickness of the lithosphere was relatively great,resulting in the mid-ocean basin expanding rapidly. After the formation of the ocean basin in the South China Sea, the upward throughflow velocity decreased, but the conductive heat flux was relatively high, which is close to the actual situation. Therefore, from the heat transfer point of view, this article discusses how the upward heat flux affects the lithospheric thermal structure in the western Pacific and South China Sea. The conclusions show that the upward heat throughflow at the bottom of the lithospheric mantle resulted in the tectonic deformation at the shallow crust. The intensive uplifts and rifts at the crust led to the continent cracks and the expansion in the South China Sea.
基金supported by the National Science Foundation of China(Nos.41977275 and 41877384)the Internal Funding for Early Careers from the Department of Forest Ecology and Management(FEM)of the Swedish University of Agricultural Science(SLU)+1 种基金the funding of the Sino-Swedish Mercury Management Research Framework(SMaRef)from the Swedish Research Council(VR)(No.D697801)supporting his researcher position at the Swedish University of Agricultural Sciences(SLU)
文摘Soil dissolved organic matter(DOM)plays an essential role in the Three Gorges Reservoir(TGR)as a linkage between terrestrial and aquatic systems.In particular,the reducing capacities of soil DOM influence the geochemistry of contaminants such as mercury(Hg).However,few studies have investigated the molecular information of soil DOM and its relationship with relevant geochemic al reactivities,including redox properties.We collected samples from eight sites in the TGR areas and studied the link between the molecular characteristics of DOM and their electron donation capacities(EDCs)toward Hg(II).The average kinetic rate and EDC of soil DOM in TGR areas were(0.004±0.001)hr-1 and(2.88±1.39)nmol e-/mg DOMbulk,respectively.Results suggest that higher EDCs and relatively rapid kinetics were related to the greater electron donating components of ligninderived and perhaps pyrogenic DOM,which are the aromatic constituents that influenced the reducing capacities of DOM in the present study.Molecular details revealed that even the typical autochthonous markers are important for the EDCs of DOM as well,in contrast to what is generally assumed.More studies identifying specific DOM molecular components involved in the abiotic reduction of Hg(II)are required to further understand the relations between DOM sources and their redox roles in the environmental fate of contaminants.
文摘River channel shifting in the deltaic regime is an unabated occurrence.Channel shifting has become one of the concerns as it influences land use/land cover along the riverbank in various ways.For the management of the river,it is indispensable to study the pattern of river course change both in qualitative and quantitative methods.This study is an attempt to understand the pattern of shifting and to quantify erosion and deposition of the river Ganga at upstream and downstream of Farakka Barrage during 1794-2017.The study has been carried out by using various historical maps,aerial photographs,satellite imagery,and remote sensing and GIS technique to understand the dynamic of the river.Over 223 years period shifting of the river accentuates the remarkable oscillation of the river.Perimeter of the river is determined to understand the area covered by the river course in the study area.To evaluate the meandering of the river sinuosity of the river has been computed in this study.The amount of erosion and deposition was calculated in this study by using ArcGIS 10.6.The study found a higher amount of erosion at the east bank where Manikchak,Kaliachak II and Kaliachak III blocks are situated between 1965 and 2017.At the west bank of the river,especially the Rajmahal block,the occurrence of deposition was remarkable during the same period.
