Based on an analysis of the factors affecting rock breaking and the coupling between rock and fluid during water jet drilling, the rock damage model and the damage-coupling model suitable for the whole rock breaking p...Based on an analysis of the factors affecting rock breaking and the coupling between rock and fluid during water jet drilling, the rock damage model and the damage-coupling model suitable for the whole rock breaking process under the water jet is established with continuous damage mechanics and micro-damage mechanics. The evolvement of rock damage during swirling water jet drilling is simulated on a nonlinear FEM and dynamic rock damage model, and a decoupled method is used to analyze the rock damage. The numerical results agree with the test results to a high degree, which shows the rock breaking ability of the swirling water jet is strong. This is because the jet particle velocity of the swirling water jet is three-dimensional, and its rock-breaking manner mainly has a slopping impact. Thus, the interference from returning fluid is less. All these aspects make it easy to draw and shear the rock surface. The rock breaking process is to break out an annular on the rock surface first, and then the annular develops quickly in both the radial and axial directions, the last part of the rock broken hole bottom is a protruding awl. The advantage of the swirling water jet breaking rock is the heavy breaking efficiency,large breaking area and less energy used to break rock per unite volume, so the swirling water jet can drill in a hole of a large diameter.展开更多
The oil-in-water emulsion drilling fluids, prepared by adding 5～12% (by volume) of mineral oil (or diesel) to water-based muds, have been widely used for stuck-pipe prevention in the Shengli Oilfield. In some cases, ...The oil-in-water emulsion drilling fluids, prepared by adding 5～12% (by volume) of mineral oil (or diesel) to water-based muds, have been widely used for stuck-pipe prevention in the Shengli Oilfield. In some cases, the emulsion stability of this kind of mud system is not strong enough to meet the requirements of drilling operations. To overcome this drawback, a solid emulsifier, which is characterized by its very small particle size and special wetting behavior (slightly water-wet), has been developed and successfully applied to improve the emulsion stability and other performances of these drilling fluids. Prior to the development of this technology, an extensive study was conducted to deal with the influence of various kinds of finely divided insoluble solid particles on oil/water emulsification. The substances used include bentonite, organophilic clay, kaolinite, barite, two kinds of calcium carbonate with different particle sizes, two kinds of silica with different wetting behaviors, and a newly developed solid emulsifier. Both the emulsion stability experiments and the drop coalescence experiments are performed to evaluate the contribution of these particles to emulsification. The measured final emulsion volume disappears after 12 hours and the half-life for water and oil drops are used as the measures of emulsion stability. The experimental data show that the type, size, concentration and wettability of the particles, and the presence of some surfactants control the type and stability of emulsions for a given oil/water system, and the fine particles of the solids emulsifier provide the most effective stabilization for water-continuous emulsions compared with other kinds of particles. Meanwhile, it can be observed that these particles also stabilize oil-continuous emulsions effectively in some cases since their wetting behavior is close to neutral. The O/W emulsion mud stabilized by the newly developed solid emulsifier has become one of the major mud systems used in directional and horizontal well drilling in the Shengli Oilfield. In addition to the improvement of emulsion stability, this solid emulsifier has the advantages of improving the lubricity of mud cake and is beneficial to the control of rheological properties and filtration.展开更多
The density functional theory and the cluster model methods have been employed to investigate the interactions between ethanethiol and HZSM-5 zeolites. Molecular complexes formed by the adsorption of ethanethiol on si...The density functional theory and the cluster model methods have been employed to investigate the interactions between ethanethiol and HZSM-5 zeolites. Molecular complexes formed by the adsorption of ethanethiol on silanol H3SiOH with two coordination forms, model Bronsted acid sites of zeolite cluster H3Si(OH)Al(OH)2SiH3 interaction with ethanethiol, aluminum species adsorbed ethanethiol have been comparatively studied. Full optimization and frequency analysis of all cluster models have been carried out using B3LYP hybrid method at 3-21G basis level for hydrogen atoms and 6-31G(d) basis set level for silicon, aluminum, oxygen, carbon, and sulfur atoms. The structures and energy changes of different coordination forms of H3Si(OH)Al(OH)2SiH3-ethanethiol, silanol-ethanethiol and Al(OH)3-ethanethiol have been studied. The calculated results showed the nature of interactions was van der Waals force as exhibited by not much change in geometric structures and properties. The preference order of ethanethiol adsorbed on HZSM-5 zeolite may be residual aluminum species, bridging hydroxyl groups and silanol OH groups from the adsorption heat. The adsorbed models of protonized ethanethiol on bridging hydroxyl OH groups and linear hydrogen bonded ethanethiol on bridging OH groups suggested in literature might not exist as revealed by this theoretical calculation. Possible adsorption models were obtained for the first time.展开更多
Based on the analysis of experimental results, the rock damage model and thedamage coupling model suitable for the whole rock breaking process with water jet were establishedwith continuous damage mechanics and micro ...Based on the analysis of experimental results, the rock damage model and thedamage coupling model suitable for the whole rock breaking process with water jet were establishedwith continuous damage mechanics and micro damage mechanics, and the numerical method was developedwith continuum mechanics and the FEM theory. The rock breaking mechanism with water jet was studiedsystematically with numerical simulation for the first time in the field of water-jet rock breaking.The numerical results agree with the experimental ones which shows that the presented method isreasonable and can reflect the reality of water-jet rock breaking. The conclusion can be applied inpractice.展开更多
文摘Based on an analysis of the factors affecting rock breaking and the coupling between rock and fluid during water jet drilling, the rock damage model and the damage-coupling model suitable for the whole rock breaking process under the water jet is established with continuous damage mechanics and micro-damage mechanics. The evolvement of rock damage during swirling water jet drilling is simulated on a nonlinear FEM and dynamic rock damage model, and a decoupled method is used to analyze the rock damage. The numerical results agree with the test results to a high degree, which shows the rock breaking ability of the swirling water jet is strong. This is because the jet particle velocity of the swirling water jet is three-dimensional, and its rock-breaking manner mainly has a slopping impact. Thus, the interference from returning fluid is less. All these aspects make it easy to draw and shear the rock surface. The rock breaking process is to break out an annular on the rock surface first, and then the annular develops quickly in both the radial and axial directions, the last part of the rock broken hole bottom is a protruding awl. The advantage of the swirling water jet breaking rock is the heavy breaking efficiency,large breaking area and less energy used to break rock per unite volume, so the swirling water jet can drill in a hole of a large diameter.
文摘The oil-in-water emulsion drilling fluids, prepared by adding 5～12% (by volume) of mineral oil (or diesel) to water-based muds, have been widely used for stuck-pipe prevention in the Shengli Oilfield. In some cases, the emulsion stability of this kind of mud system is not strong enough to meet the requirements of drilling operations. To overcome this drawback, a solid emulsifier, which is characterized by its very small particle size and special wetting behavior (slightly water-wet), has been developed and successfully applied to improve the emulsion stability and other performances of these drilling fluids. Prior to the development of this technology, an extensive study was conducted to deal with the influence of various kinds of finely divided insoluble solid particles on oil/water emulsification. The substances used include bentonite, organophilic clay, kaolinite, barite, two kinds of calcium carbonate with different particle sizes, two kinds of silica with different wetting behaviors, and a newly developed solid emulsifier. Both the emulsion stability experiments and the drop coalescence experiments are performed to evaluate the contribution of these particles to emulsification. The measured final emulsion volume disappears after 12 hours and the half-life for water and oil drops are used as the measures of emulsion stability. The experimental data show that the type, size, concentration and wettability of the particles, and the presence of some surfactants control the type and stability of emulsions for a given oil/water system, and the fine particles of the solids emulsifier provide the most effective stabilization for water-continuous emulsions compared with other kinds of particles. Meanwhile, it can be observed that these particles also stabilize oil-continuous emulsions effectively in some cases since their wetting behavior is close to neutral. The O/W emulsion mud stabilized by the newly developed solid emulsifier has become one of the major mud systems used in directional and horizontal well drilling in the Shengli Oilfield. In addition to the improvement of emulsion stability, this solid emulsifier has the advantages of improving the lubricity of mud cake and is beneficial to the control of rheological properties and filtration.
文摘The density functional theory and the cluster model methods have been employed to investigate the interactions between ethanethiol and HZSM-5 zeolites. Molecular complexes formed by the adsorption of ethanethiol on silanol H3SiOH with two coordination forms, model Bronsted acid sites of zeolite cluster H3Si(OH)Al(OH)2SiH3 interaction with ethanethiol, aluminum species adsorbed ethanethiol have been comparatively studied. Full optimization and frequency analysis of all cluster models have been carried out using B3LYP hybrid method at 3-21G basis level for hydrogen atoms and 6-31G(d) basis set level for silicon, aluminum, oxygen, carbon, and sulfur atoms. The structures and energy changes of different coordination forms of H3Si(OH)Al(OH)2SiH3-ethanethiol, silanol-ethanethiol and Al(OH)3-ethanethiol have been studied. The calculated results showed the nature of interactions was van der Waals force as exhibited by not much change in geometric structures and properties. The preference order of ethanethiol adsorbed on HZSM-5 zeolite may be residual aluminum species, bridging hydroxyl groups and silanol OH groups from the adsorption heat. The adsorbed models of protonized ethanethiol on bridging hydroxyl OH groups and linear hydrogen bonded ethanethiol on bridging OH groups suggested in literature might not exist as revealed by this theoretical calculation. Possible adsorption models were obtained for the first time.
文摘Based on the analysis of experimental results, the rock damage model and thedamage coupling model suitable for the whole rock breaking process with water jet were establishedwith continuous damage mechanics and micro damage mechanics, and the numerical method was developedwith continuum mechanics and the FEM theory. The rock breaking mechanism with water jet was studiedsystematically with numerical simulation for the first time in the field of water-jet rock breaking.The numerical results agree with the experimental ones which shows that the presented method isreasonable and can reflect the reality of water-jet rock breaking. The conclusion can be applied inpractice.
