1.IntroductionOxidation resistance of superalloys re-lies on the protectiveness of oxide scalesformed on their surfaces during service.Theformation and growth of oxide scales are de-termined by an extensive range ofpa...1.IntroductionOxidation resistance of superalloys re-lies on the protectiveness of oxide scalesformed on their surfaces during service.Theformation and growth of oxide scales are de-termined by an extensive range ofparameters which cover the alloy composi-展开更多
The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pur...The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pure base-metal sulphide and an inner layer containing both metals.The Nb addi- tions were not able to produce exclusive Nb sulphidation but yielded a significant decrease of the corrosion rates for both types of alloys with respect to the pure metals even though they were still much higher than that of pure Nb.The Ni-base alloys corroded rapidly forming a single complex scale layer,mainly due to the appearance of a liquid Ni-S solution.展开更多
文摘1.IntroductionOxidation resistance of superalloys re-lies on the protectiveness of oxide scalesformed on their surfaces during service.Theformation and growth of oxide scales are de-termined by an extensive range ofparameters which cover the alloy composi-
文摘The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pure base-metal sulphide and an inner layer containing both metals.The Nb addi- tions were not able to produce exclusive Nb sulphidation but yielded a significant decrease of the corrosion rates for both types of alloys with respect to the pure metals even though they were still much higher than that of pure Nb.The Ni-base alloys corroded rapidly forming a single complex scale layer,mainly due to the appearance of a liquid Ni-S solution.
