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Preparation of Corncob-Like WO3 Nanomaterials and Their Photocatalytic Treatment of Toluene
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作者 Jianhai Wang Lu Lu +2 位作者 Bing Xu Hongfeng Xu Hongwen Liu 《Journal of Materials Science and Chemical Engineering》 2024年第2期84-93,共10页
Corn rod-like WO<sub>3</sub> nanomaterials were successfully synthesized by a simple hydrothermal method. The morphology, structure and optical absorption properties of the prepared samples were characteri... Corn rod-like WO<sub>3</sub> nanomaterials were successfully synthesized by a simple hydrothermal method. The morphology, structure and optical absorption properties of the prepared samples were characterized by SEM, XRD, FTIR and UV-Vis-DRS. The WO<sub>3</sub> materials were corn rod-like morphology with about 800 nm for length and 150 nm for diameter, especially there were plenty of corn particles (about 20 nm) on the surface of corn rods. The X-ray diffraction peaks of the products corresponded with WO<sub>3</sub> standard card, and the characteristic peak of W-O bond was found in the infrared spectrum. The absorption band edge of the products was about 480 nm, indicating their potential visible-light-induced photocatalytic activity. In situ FTIR technology research showed that the prepared WO<sub>3</sub> nanomaterials had visible photocatalytic activity to gas-phase toluene. After a photocatalytic reaction for 8 hours toluene was effectively degraded, and carboxylic acid and aldehyde could be regarded as the intermediate products, and CO<sub>2</sub> was produced as the final product during the reaction process. 展开更多
关键词 WO3 Nanomaterials Visiblelight Photocatalytic Degradation TOLUENE In Situ FTIR
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Negative effects of artiffcial nest boxes on birds:A review
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作者 Luchang Zhang Xingjian Ma +4 位作者 Zhiyu Chen Chunying Wang Zicheng Liu Xiang Li Xiaoying Xing 《Avian Research》 SCIE CSCD 2023年第2期257-266,共10页
Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artific... Artificial nest boxes are placed to attract birds to nest and breed in a specific location,and they are widely used in avian ecology research and in the attraction of insectivorous birds.There is evidence that artificial nest boxes can adversely affect breeding fitness but no great focus has been placed on this issue by researchers.Therefore,we retrieved 321 research papers regarding artificial nest boxes published from 2003 to 2022 and used the'Biblioshiny'program to extract and integrate keywords;we then summarized the adverse effects of artificial nest boxes on avian breeding success.The studies highlighted many drawbacks and misuses in the designing and placement of nest boxes;furthermore,bird attraction was decreased by their inappropriate selection,thus reducing breeding success.Regarding nest box production,there were shortcomings in the construction material,color,smell,and structural design of the boxes used.Nest boxes were also placed at inappropriate densities,locations,orientations,heights,and managed incorrectly.Finally,we propose suggestions for more efficient and safer artificial nest boxes for future use in avian ecology research and bird conservation. 展开更多
关键词 Artificial nest box Avian breeding Management Negative effect Nest box hanging Nest box location Nest box structure
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Source apportionment and ecological risk assessment of PAHs in surface sediments from the Liaodong Bay,northern China 被引量:6
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作者 ZHANG Yufeng WU Jinhao +5 位作者 SONG Lun SONG Yonggang YANG Meng WANG Nianbin HAN Jiabo GUAN Daoming 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2018年第4期12-21,共10页
The sources and ecological risk from sixteen polycyclic aromatic hydrocarbons in surface sediment in the Liaodong Bay were investigated from 2014 to 2015.The total concentrations of PAHs ranged from 88.5 to 347.1 ng/g... The sources and ecological risk from sixteen polycyclic aromatic hydrocarbons in surface sediment in the Liaodong Bay were investigated from 2014 to 2015.The total concentrations of PAHs ranged from 88.5 to 347.1 ng/g,and the high value occurred in the central region of the Liaodong Bay.Cluster analysis identified two site clusters representing the coastal region affected by land-based pollution and the central region of the Liaodong Bay.Principal component analysis-multiple linear regression and diagnostic ratios suggested that PAHs contaminants originated from a mixture of combustion and petroleum sources,and the major was combustion sources.Based on sediment quality guideline,naphthalene,acenaphthylene,acenaphthene,phenanthrene and dibenz[a,h]anthracene may occasionally cause adverse biological effects in some stations.The toxic equivalent concentrations of carcinogenic PAHs indicated low carcinogenic risk for the Liaodong Bay.The ecological risk and toxic pollution levels of PAHs were higher in the central region than in the coastal region along the Liaodong Bay. 展开更多
关键词 风险评价 表面沉积 生态 海湾 分配 中国 中央区域 污染影响
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硅灰石玻璃陶瓷的析晶特性及其析晶热力学和动力学(英文) 被引量:7
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作者 司伟 丁超 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第8期1888-1894,共7页
将废玻璃粉与钙铝黄长石混合,使用反应析晶烧结法制备了硅灰石玻璃陶瓷。采用X射线衍射分析、扫描电镜、能谱、高分辨透射电镜和热分析等方法,研究了硅灰石玻璃陶瓷的析晶特性及其析晶热力学与动力学。结果表明,钙铝黄长石与二氧化硅发... 将废玻璃粉与钙铝黄长石混合,使用反应析晶烧结法制备了硅灰石玻璃陶瓷。采用X射线衍射分析、扫描电镜、能谱、高分辨透射电镜和热分析等方法,研究了硅灰石玻璃陶瓷的析晶特性及其析晶热力学与动力学。结果表明,钙铝黄长石与二氧化硅发生反应,析出硅灰石及氧化铝。该硅灰石晶体为一定长径比的板条状,能起到很好的桥联与补强作用。反应析晶过程中钙铝黄长石的铝离子向玻璃中扩散,玻璃的硅离子向钙铝黄长石中扩散,使具有三维架状结构的钙铝黄长石遭到部分破坏,形成链状结构的硅灰石。析晶热力学及动力学研究结果表明,在较低温度(1173 K)下,添加20 wt%钙铝黄长石作为反应析晶促进剂,该析晶反应可自发进行。使用Kissinger法计算析晶活化能为261.99 kJ/mol。制备的大块硅灰石玻璃陶瓷(7.5 cm×7.5 cm)抗压强度可达251 MPa。 展开更多
关键词 玻璃陶瓷 析晶热力学 析晶动力学
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Molecular cloning of partial 14-3-3 genes in the marine sponge Hymeniacidon perleve and its role in differentiating infectious and non-infectious bacteria 被引量:1
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作者 FU WanTao ZHANG JuLin +4 位作者 ZHENG ChangBo LIU Jing AN ZhongFu LIU HongWen ZHANG Wei 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第3期766-776,共11页
Sponges (phylum Porifera) are the phylogenetically oldest metazoa and highly efficient filter feeders.In the marine ecosystem,they are unconditionally exposed to environmental stresses.Understanding the sponge-bacteri... Sponges (phylum Porifera) are the phylogenetically oldest metazoa and highly efficient filter feeders.In the marine ecosystem,they are unconditionally exposed to environmental stresses.Understanding the sponge-bacteria interaction is hence of both ecological and biological significance.This study investigated the specific interaction between the sponge Hymeniacidon perleve and the non-infectious bacteria,Escherichia coli and infectious bacteria,Vibrio spp.by measuring the 14-3-3 mRNA expression of H.perleve.Three partial cDNAs of 14-3-3 proteins and partial 18S RNA in H.perleve were cloned and sequenced.Using Reverse-transcription real-time PCR,the 14-3-3 mRNA expression of H.perleve was examined when exposed to three common bacteria in aquatic water-E.coli and two Vibrio spp.for different time and dosages.H.perleve could efficiently remove E.coli from the water column without self-infection;however Vibrio at higher dosages infected H.perleve.When H.perleve was exposed to E.coli (1.1×10 7 CFU mL-1),V.anguillarum Ⅱ (1.2×10 6 CFU mL-1) and V.alginolyticus (3.6×105 CFU mL-1) for 6h,the 14-3-3 mRNA expression in the V.anguillarum Ⅱ and V.alginolyticus groups was down-regulated by 2.67-and 2.36-fold,respectively.The 14-3-3 mRNA expression in the E.coli group was not significantly different.However,no clear trend was observed on the 14-3-3 transcript levels of H.perleve in response to different doses of V.anguillarum Ⅱ for different time.The results demonstrated that infectious bacteria can be discriminated by 14-3-3 mRNA expression of sponge H.perleve. 展开更多
关键词 海洋生态系统 常见细菌 分子克隆 感染性 海绵 基因 14-3-3蛋白 mRNA表达
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