Li_(4)Ti_(5)O_(12)(LTO) anode material demonstrates superior cycling performance due to its stable spinel structure and high lithiation/de-lithiation potential.Herein,a novel energy-saving solid-phase synthesis route ...Li_(4)Ti_(5)O_(12)(LTO) anode material demonstrates superior cycling performance due to its stable spinel structure and high lithiation/de-lithiation potential.Herein,a novel energy-saving solid-phase synthesis route for LTO has been successfully designed,employing the cheap industrial intermediate product of metatitanic acid (HTO) as titanium source.Through the in-situ Fourier transform infrared spectroscopy (FTIR)and ex-situ X-ray diffraction (XRD),it is revealed for the first time that the amorphous crystal structure of HTO is more conducive for the Li+insertion,making it possible to prepare LTO at a relatively lower sintering temperature.Utilizing the dehydration carbonization reaction between glucose and sulfuric acid,an ingenious strategy of glucose pre-coating is adopted to avoid the generation of Li_(2)SO_(4) impurity caused by the residual sulfuric acid on the surface of HTO,which meanwhile enhances the conductivity and inhibits the particle growth of LTO.The obtained ALTO@C anode material consequently exhibits excellent electrochemical performance that 132.0 m Ah g^(-1)is remained even at 20 C,and ultra low decay rate of 0.015% per cycle is achieved during 1000 cycles at 2 C.Remarkably,LiCoO_(2)//ALTO@C full cell delivers conspicuous low-temperature property (130.7 m Ah g^(-1)at 0.5 C and almost no attenuation after 300 cycles under-20℃).展开更多
The continuum-discritized coupled channel method and the glauber model are applied for the description of deuteron elastic breakup and the stripping processes,respectively.Combined with the conventional two-component ...The continuum-discritized coupled channel method and the glauber model are applied for the description of deuteron elastic breakup and the stripping processes,respectively.Combined with the conventional two-component exciton model for pre-equilibrium processes and the Hauser-Feshbach theory for compound process,an approach based on models is proposed to analyze the inclusive proton energy spectra of a deuteron-induced reaction.The contributions from each process to the energy spectra of the 58Ni(d,xp)reaction are quantitatively given.The results show that this approach is able to reasonably reproduce the experimental data of the double differential cross sections,energy spectra and cross sections,although further improvements are needed.展开更多
Despite the significant progress in the fabrication of advanced electrode materials,complex control strategies and tedious processing are often involved for most targeted materials to tailor their compositions,morphol...Despite the significant progress in the fabrication of advanced electrode materials,complex control strategies and tedious processing are often involved for most targeted materials to tailor their compositions,morphologies,and chemistries.Inspired by the unique geometric structures of natural biomacromolecules together with their high affinities for metal species,we propose the use of skin collagen fibers for the template crafting of a novel multicore-shell Fe2N-carbon framework anode configuration,composed of hierarchical N-doped carbon nanofiber bundles firmly embedded with Fe2N nanoparticles(Fe2N@N-CFBs).In the resultant heterostructure,the Fe2N nanoparticles firmly confined inside the carbon shells are spatially isolated but electronically well connected by the long-range carbon nanofiber framework.This not only provides direct and continuous conductive pathways to facilitate electron/ion transport,but also helps cushion the volume expansion of the encapsulated Fe2N to preserve the electrode microstructure.Considering its unique structural characteristics,Fe2N@N-CFBs as an advanced anode material exhibits remarkable electrochemical performances for lithium-and potassium-ion batteries.Moreover,this bio-derived structural strategy can pave the way for novel low-cost and high-efficiency syntheses of metal-nitride/carbon nanofiber heterostructures for potential applications in energy-related fields and beyond.展开更多
Boosting the utilization efficiency of sulfur electrodes and suppressing the“shuttle effect”of intermediate polysulfides remain the critical challenge for high-performance lithium-sulfur batteries(LSBs).However,most...Boosting the utilization efficiency of sulfur electrodes and suppressing the“shuttle effect”of intermediate polysulfides remain the critical challenge for high-performance lithium-sulfur batteries(LSBs).However,most of reported sulfur electrodes are not competent to realize the fast conversion of polysulfides into insoluble lithium sulfides when applied with high sulfur loading,as well as to mitigate the more serious shuttle effect of polysulfides,especially when worked at an elevated temperature.Herein,we reported a unique structural engineering strategy of crafting a unique hierarchical multifunctional electrode architecture constructed by rooting MOF-derived CoS2/carbon nanoleaf arrays(CoS2-CNA)into a nitrogen-rich 3D conductive scaffold(CTNF@CoS2-CNA)for LSBs.An accelerated electrocatalytic effect and improved polysulfide redox kinetics arising from CoS2-CNA were investigated.Besides,the strong capillarity effect and chemisorption of CTNF@CoS2-CNA to polysulfides enable high loading and efficient utilization of sulfur,thus leading to high-performance LIBs performed not only at room temperature but also up to an elevated temperature(55°C).Even with the ultrahigh sulfur loading of 7.19 mg cm?2,the CTNF@CoS2-CNA/S cathode still exhibits high rate capacity at 55°C.展开更多
Li-rich layered oxide of Li_(1.2)Mn_(0.6)Ni_(0.2)O_(2)(LMNO)with a considerable specific capacity and higher voltage is regarded as a kind of promising cathode material.However,it suffers from transition metal ion dis...Li-rich layered oxide of Li_(1.2)Mn_(0.6)Ni_(0.2)O_(2)(LMNO)with a considerable specific capacity and higher voltage is regarded as a kind of promising cathode material.However,it suffers from transition metal ion dissolution and oxygen escape that leads to rapid capacity decay.In addition,the poor lithium-ion diffusion kinetics gives rise to unsatisfied rate performance.Herein,a stable layer of Li_(0.5)Mn_(0.5)O(LMO)out of LMNO is in-situ constructed through acetic passivation and following calcination process.The generated defect structure in the composite material exhibits fast ion diffusion kinetics and the produced LMO layer can stabilize the substructure,resulting in elevated cycling stability and rate performance.In specific,the LMNO@LMO material exhibits a high initial coulombic efficiency of 80.3%and remarkable capacity retention of 80.7%after 200 cycles at 1 C.Besides,the composite material reveals prominent rate performance that delivers discharge capacities of 158 and 131 m Ah g^(-1) at 5 and 10 C,respectively.At last,this study presents a new approach to optimizing the Li-rich cathode materials.展开更多
The impact and penetration of a projectile in a particle-laden space, which are expected to have frequently occurred during the formation of the solar system and will occur in the case of an impact probe for future pl...The impact and penetration of a projectile in a particle-laden space, which are expected to have frequently occurred during the formation of the solar system and will occur in the case of an impact probe for future planetary exploration, were experimentally simulated by using the ballistic range. A two-dimensional sheet made from small glass beads or emery powder was formed by the free-falling device through a long slit in the test chamber evacuated down to about 35 Pa. A polycarbonate projectile of a hemi-sphere-cylinder or sphere shape with the mass and diameter about 4 g and 25 mm, respectively, was launched at the velocity up to 430 m/s, and the phenomena were observed by the high-speed camera at 20,000 fps. From a series of images, the bow-shock-wave-like laterally facing U-shaped pattern over the projectile and the absence of particles in the trail behind it were clearly seen. At the impact of the particles on the projectile surface, fine grains were formed due to the destructive collision and injected outward from the projectile. The images obtained by different lighting methods including the laser light sheet were compared. The effects of the particle diameter, its material and the impact velocity were also investigated.展开更多
For application to exploration under the surface of icy objects in the solar system, the penetration of an impact probe into an icy target was experimentally simulated by using the ballistic range. Slender projectiles...For application to exploration under the surface of icy objects in the solar system, the penetration of an impact probe into an icy target was experimentally simulated by using the ballistic range. Slender projectiles with a cylindrical body and various nose shapes were tested at the impact velocity 130 - 420 m/s. The motion of the penetrator, fragmentation of ice and crater forming were observed by the high-speed camera. It revealed that the crown-shaped ejection was made for a short time after the impact and then the outward normal jet-like stream of ice pieces continued for much longer time. The concave shape of the crater was successfully visualized by pouring the plaster into it. The two-stage structure, the pit and the spall, was clearly confirmed. The rim was not formed around the crater. Observation of the crater surface and the ice around the trace of the penetrator shows that both crushing into smaller ice pieces and recompression into ice blocks are caused by the forward motion of the penetrator. In case of a body with a flow-through duct, ice pieces entering the inlet at the nose tip were ejected from the tail, resulting in relaxation of the impact force. The correlation of the penetration distance and the crater diameter with the impact velocity was investigated.展开更多
Wireless power transfer (WPT) from a transmitter resonator on the ground to an electrically powered miniature heli-copter was attempted to demonstrate WPT using magnetic resonance coupling to an object moving in 3D sp...Wireless power transfer (WPT) from a transmitter resonator on the ground to an electrically powered miniature heli-copter was attempted to demonstrate WPT using magnetic resonance coupling to an object moving in 3D space. The transmission efficiency was optimized by automatic impedance matching for different flight attitudes: a maximum flight altitude of 590 mm was achieved. Furthermore, an estimation method of transmission efficiency using only the properties on the transmitter side was proposed, with transmission power regulated as constant against the change in the coupling coefficient.展开更多
Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2&l...Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2</sub>, and air showed that oxygen and air plasma efficiently decomposed 2,6-DBP to bromide ion, and inorganic carbon. The molecular orbital model was applied in the analysis of the degradation in electrophilic, nucleophilic, and radical reactions.展开更多
Anodic oxidation with different electrolyte was employed to improve the electrochemical properties of carbon paper as negative electrode for vanadium redox battery(VRB).The treated carbon paper exhibits enhanced elect...Anodic oxidation with different electrolyte was employed to improve the electrochemical properties of carbon paper as negative electrode for vanadium redox battery(VRB).The treated carbon paper exhibits enhanced electrochemical activity for V^2+/V^3+redox reaction.The sample(CP-NH3)treated in NH3 solution demonstrates superior performance in comparison with the sample(CP-NaOH)treated in NaOH solution.X-ray photoelectron spectroscopy results show that oxygen-and nitrogen-containing functional groups have been introduced on CP-NH3 surface by the treatment,and Raman spectra confirm the increased surface defect of CP-NH3.Energy storage performance of cell was evaluated by charge/discharge measurement by using CP-NH3.Usage of CP-NH3 can greatly improve the cell performance with energy efficiency increase of 4.8%at 60 mA/cm^2.The excellent performance of CP-NH3 mainly results from introduction of functional groups as active sites and improved wetting properties.This work reveals that anodic oxidation is a clean,simple,and efficient method for boosting the performance of carbon paper as negative electrode for VRB.展开更多
Si-based hydrolysis material system can be used in mobile/portable hydrogen source applications connected to fuel cells but is limited by alkaline solutions.In the present research,we reported an acid/alkaline free hy...Si-based hydrolysis material system can be used in mobile/portable hydrogen source applications connected to fuel cells but is limited by alkaline solutions.In the present research,we reported an acid/alkaline free hydrolysis systemcombining siliconwith NaBH4.Sampleswith different ratios between Si and NaBH4 are prepared via high energy ball milling and hydrolyzed in deionized water at different temperatures.Synergetic effect between silicon and NaBH4was found in the hydrolysis process.2Si-NaBH4 sample displays the best hydrolysis performances with the hydrogen yield of 1594 ml·g^(−1) in deionized water at 70℃.Thereafter,AlCl3 is added into the 2Si-NaBH4 sample to further improve its comprehensive properties.The effect of AlCl3 content and promotion mechanism of the reaction are explored.2Si-NaBH4-5 wt% AlCl3 sample shows a significant improvement with a high hydrogen yield of 1689 ml·g^(−1) in deionized water at 70℃ and a corresponding conversion rate of 95.8%,indicating that the Si-NaBH4-AlCl3 composite is promising to be a hydrogen source in applications of mobile/portable fuelcell-powered facilities.展开更多
The silicon oxide nano-powders (SiO<sub>x</sub>-NPs) were obtained in an atmospheric microwave plasma torch using a gas-phase silicon tetrachloride (SiCl<sub>4</sub>) with N<sub>2</sub...The silicon oxide nano-powders (SiO<sub>x</sub>-NPs) were obtained in an atmospheric microwave plasma torch using a gas-phase silicon tetrachloride (SiCl<sub>4</sub>) with N<sub>2</sub> and H<sub>2</sub>. The gas-phase SiCl<sub>4</sub> was injected with H<sub>2</sub> gas into the microwave plasma torch generated by N<sub>2</sub> and air swirl gas, and then the dark brown powders were deposited on the inner wall of a quartz tube. The sample was analyzed by an X-ray photoelectron spectroscopy (XPS), a scanning electron microscope (SEM), an energy dispersive spectrometer (EDS), and an X-ray diffraction (XRD). The average size and oxidation x values of synthesized SiO<sub>x</sub>-NPs were approximately 230 nm and 0.91, respectively. Furthermore, the volumetric charge capacity is 1127 mAh/g and has 89.2% retention after 100 cycles.展开更多
Glioblastoma(GBM)has a highly genetic heterogeneity and immunosuppressive microenvironment,leading to the inevitable emergence of treatment resistance and poor prognosis.This study aimed to explore the role of macroph...Glioblastoma(GBM)has a highly genetic heterogeneity and immunosuppressive microenvironment,leading to the inevitable emergence of treatment resistance and poor prognosis.This study aimed to explore the role of macrophages related pathways in the occurrence and development of GBM.Firstly,we developed an immune-related prognostic model and verified its ability to signi cantly distinguish between good and bad outcomes of patients(Fig.1(a)).展开更多
Zinc-based flow batteries(ZFBs)have aroused great favor in large-scale energy storage due to the high security and low cost.However,the low areal capacity arising from the limited space for Zn plating hinders the furt...Zinc-based flow batteries(ZFBs)have aroused great favor in large-scale energy storage due to the high security and low cost.However,the low areal capacity arising from the limited space for Zn plating hinders the further development.Herein,a novel carbon felt-Sn-carbon felt sandwich host(CSCH)is designed and constructed.Benefiting from the strong chemical absorption and the dehydration effect on Zn(H_(2)O)_(6)^(2+),the Sn activation layer in the CSCH demonstrates the lowest comprehensive resistance for Zn deposition.Thus,Zn is induced to nucleate preferentially on the Sn activation layer,and grows towards the membrane,regulating the spatial distribution of Zn electrochemical deposits,which remarkably improves the areal capacity and cyclic stability of Zn anode.Consequently,the zinc-bromine flow batteries equipped with CSCH electrodes can achieve the ultra-high areal capacity of 120 mA h cm^(-2)at 80 mA cm^(-2),and run stably for 140 h with average energy efficiency of 80.3%in the extreme condition(80 mA cm^(-2),80 mA h cm^(-2)).This innovative work will inspire future advanced designs for high areal capacity electrodes in ZFBs.展开更多
Carbon dioxide(CO_2) is greenhouse gas which originates primarily as a main combustion product of biogas and landfill gas. To separate this gas, an inside coated thin film composite(TFC) hollow fiber membrane was deve...Carbon dioxide(CO_2) is greenhouse gas which originates primarily as a main combustion product of biogas and landfill gas. To separate this gas, an inside coated thin film composite(TFC) hollow fiber membrane was developed by interfacial polymerization between 1,3–cyclohexanebis–methylamine(CHMA) and trimesoyl chloride(TMC). ATR-FTIR, SEM and AFM were used to characterize the active thin layer formed inside the PSf hollow fiber. The separation behavior of the CHMA-TMC/PSf membrane was scrutinized by studying various effects like feed gas pressure and temperature. Furthermore, the influence of CHMA concentration and TMC concentration on membrane morphology and performance were investigated. As a result, it was found that mutually the CHMA concentration and TMC concentration play key roles in determining membrane morphology and performance. Moreover, the CHMA-TMC/PSf composite membrane showed good CO_2/CH_4 separation performance. For CO_2/CH_4 mixture gas(30/70 by volume) test, the membrane(PD1 prepared by CHMA 1.0% and TMC 0.5%) showed a CO_2 permeance of 25 GPU and the best CO_2/CH_4 selectivity of 28 at stage cut of 0.1. The high CO_2/CH_4 separation performance of CHMA-TMC/PSf thin film composite membrane was mostly accredited to the thin film thickness and the properties of binary amino groups.展开更多
Wireless power feeding was examined with strongly coupled magnetic resonance for an object moving in 3-D space. Electric power was transmitted from the ground to an electrically powered toy helicopter in the air. A li...Wireless power feeding was examined with strongly coupled magnetic resonance for an object moving in 3-D space. Electric power was transmitted from the ground to an electrically powered toy helicopter in the air. A lightweight receiver resonator was developed using copper foil. High Q of greater than 200 was obtained. One-side impedance matching the transmitter side was proposed to cope with high transmission efficiency and the receiver’s weight reduction. Results show that the efficiency drop near the ground was drastically improved. Moreover, the measured efficiency showed good agreement with theoretical predictions. A fully equipped helicopter of 6.56 g weight was lifted up with source power of about 5 W to an altitude of approximately 10 cm.展开更多
Solution infiltration is a popular technique for the surface modification of solid oxide fuel cell(SOFC)cathodes.However,the synthesis of nanostructured SOFC cathodes by infiltration is a tedious process that often re...Solution infiltration is a popular technique for the surface modification of solid oxide fuel cell(SOFC)cathodes.However,the synthesis of nanostructured SOFC cathodes by infiltration is a tedious process that often requires several infiltration and high temperature(≥500℃)calcination cycles.Moreover,fabricating large-area nanostructured cathodes via infiltration still requires serious attention.Here,we propose a facile and scalable urea assisted ultrasonic spray infiltration technique for nanofabrication of SOFC cathodes.It is demonstrated that by using urea as a precipitating agent,the calcination after each infiltration cycle can be omitted and the next infiltration can be performed just after a drying step(≤100℃).Finally,the precipitates can be converted into a desired catalyst phase in single calcination thus,a nanostructured cathode can be fabricated in a much faster manner.It is also shown that the low calcination temperature of the cathode(≤900℃)can produce highly durable SOFC performance even without employing a Ce_(0.9)Gd_(0.1)O_(2)(GDC)diffusion barrier layer which provides the ease of SOFC fabrication.While coupling with an ultrasonic spray technique,the urea assisted infiltration can be scaled up for any desired cathode area.La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3) nanolayered cathode was fabricated and it was characterized by scanning electron microscope(SEM),X-ray diffraction(XRD),and transmission electron microscopy(TEM)techniques.SEM showed the formation of a nanolayer cathode just after 5 cycles of the urea assisted infiltration while the XRD and TEM confirmed the phase and stoichiometric uniformity of the 100 nm cathode nanolayer.The effectiveness of the newly developed technique was further verified by the stable operation of a GDC buffer layer free SOFC having an active cathode area of 25 cm^(2) during a 1200 h durability test.The research outcomes propose urea assisted ultrasonic spray infiltration as a facile,scalable,and commercially viable method for the fabrication of durable nanostructured SOFC cathodes.展开更多
Transient separation behavior in tritiated water distillation tower packed with materials having ability to adsorb water is investigated analytically and experimentally for nuclear reactor safety. Analytical equations...Transient separation behavior in tritiated water distillation tower packed with materials having ability to adsorb water is investigated analytically and experimentally for nuclear reactor safety. Analytical equations based on the stage model are set up for simulation of the transient behavior of tritium (T) separation from wastewater. It is found that a dimensionless time defined in terms of the inside vapor flow rate and the liquid holdups in tower, reboiler and condenser can correlate variations over time to achieve a steady-state T concentration. However, when mixing with different T concentrations at a feed point occurs, the transition time period becomes longer than expected. Effects of the reflux ratio, the stage separation factor and the total stage number on the transient and steady-state T concentrations are numerically calculated. Variations over time to achieve each steady-state value are compared with experimental data using a small-scale tower. Long time distillation experiment for one month has been completed, and it is confirmed that a distillation column packed with ceramic Raschig rings coated with zeolite 13X adsorbent is hardly affected by water corrosion.展开更多
Nanotechnology is a field of research with objects up to 100 nm in size. Nanomaterials belong to a wide area in the field of material engineering. These include nanolayers, nanoslabs, nanopores, nanotubes, nanofibers,...Nanotechnology is a field of research with objects up to 100 nm in size. Nanomaterials belong to a wide area in the field of material engineering. These include nanolayers, nanoslabs, nanopores, nanotubes, nanofibers, nanoparticles and quantum dots. Nanostructures are characterized by special properties due to their nanometric dimensions. The natural properties of nanostructures allow their wide application in various industries. The paper presents an overview of the application and significance of nanostructures in fuel cell technology, with particular emphasis on nanocatalysts. The article includes the classification of nanomaterials, new hybrid nanostructures, types of surface modification, division by area of application, with particular emphasis on nanomaterials in the advanced energy system. The design and operation of fuel cells and the role of nanoparticles have been described taking into account existing solutions to reduce generator costs. The high price of low temperature fuel cells depends on the number of nanoparticles used. The article describes the risk associated with using products at the nano scale. Higher concentrations of these extremely active materials can be dangerous and can cause ecological problems and harm natural ecosystems.展开更多
In this paper, a wireless power transmission system using magnetic resonance coupling was proposed and demonstrated for supplying power at high efficiency to electrical devices in a space enclosed by metal walls. This...In this paper, a wireless power transmission system using magnetic resonance coupling was proposed and demonstrated for supplying power at high efficiency to electrical devices in a space enclosed by metal walls. This is applicable to power supply to electrical sensors or devices working in the area surrounded by metal walls. Proposed magnetic resonance coupling system is driven at a resonance frequency of 50 Hz, which is selected to avoid eddy current loss on the surrounding metals. Firstly, resonator designs and its performance limitation were described. Secondly, the equivalent circuits and theoretical transmission efficiency were presented. Finally, power transmission was experimentally demonstrated and transmission efficiency was measured in some conceivable situations. As a result, electric power of 3 W was supplied to LEDs over a stainless steel wall. When the stainless steel wall thickness was 10 mm, transmission efficiency of approximately 40% was achieved over the transmission distance of 12 cm. Moreover, in the demonstration of transmission through a metal pipe, 1.2 W of power was transmitted to LEDs in a 10 mm thick metal pipe.展开更多
基金financial support from the Major Science and Technology Projects of Sichuan Province(2019KJT0078)the National Natural Science Foundation of China(51904193)the Fundamental Research Funds for the Central Universities。
文摘Li_(4)Ti_(5)O_(12)(LTO) anode material demonstrates superior cycling performance due to its stable spinel structure and high lithiation/de-lithiation potential.Herein,a novel energy-saving solid-phase synthesis route for LTO has been successfully designed,employing the cheap industrial intermediate product of metatitanic acid (HTO) as titanium source.Through the in-situ Fourier transform infrared spectroscopy (FTIR)and ex-situ X-ray diffraction (XRD),it is revealed for the first time that the amorphous crystal structure of HTO is more conducive for the Li+insertion,making it possible to prepare LTO at a relatively lower sintering temperature.Utilizing the dehydration carbonization reaction between glucose and sulfuric acid,an ingenious strategy of glucose pre-coating is adopted to avoid the generation of Li_(2)SO_(4) impurity caused by the residual sulfuric acid on the surface of HTO,which meanwhile enhances the conductivity and inhibits the particle growth of LTO.The obtained ALTO@C anode material consequently exhibits excellent electrochemical performance that 132.0 m Ah g^(-1)is remained even at 20 C,and ultra low decay rate of 0.015% per cycle is achieved during 1000 cycles at 2 C.Remarkably,LiCoO_(2)//ALTO@C full cell delivers conspicuous low-temperature property (130.7 m Ah g^(-1)at 0.5 C and almost no attenuation after 300 cycles under-20℃).
文摘The continuum-discritized coupled channel method and the glauber model are applied for the description of deuteron elastic breakup and the stripping processes,respectively.Combined with the conventional two-component exciton model for pre-equilibrium processes and the Hauser-Feshbach theory for compound process,an approach based on models is proposed to analyze the inclusive proton energy spectra of a deuteron-induced reaction.The contributions from each process to the energy spectra of the 58Ni(d,xp)reaction are quantitatively given.The results show that this approach is able to reasonably reproduce the experimental data of the double differential cross sections,energy spectra and cross sections,although further improvements are needed.
基金financial support from the National Natural Science Foundation of China(21878192,51502180)the Fundamental Research Funds for the Central Universities(2016SCU04A18)+1 种基金the 1000 Talents Program of Sichuan Province,the Sichuan Province Science and Technology Support Program(2014GZ0093)the Australian Research Council(DP160102627).
文摘Despite the significant progress in the fabrication of advanced electrode materials,complex control strategies and tedious processing are often involved for most targeted materials to tailor their compositions,morphologies,and chemistries.Inspired by the unique geometric structures of natural biomacromolecules together with their high affinities for metal species,we propose the use of skin collagen fibers for the template crafting of a novel multicore-shell Fe2N-carbon framework anode configuration,composed of hierarchical N-doped carbon nanofiber bundles firmly embedded with Fe2N nanoparticles(Fe2N@N-CFBs).In the resultant heterostructure,the Fe2N nanoparticles firmly confined inside the carbon shells are spatially isolated but electronically well connected by the long-range carbon nanofiber framework.This not only provides direct and continuous conductive pathways to facilitate electron/ion transport,but also helps cushion the volume expansion of the encapsulated Fe2N to preserve the electrode microstructure.Considering its unique structural characteristics,Fe2N@N-CFBs as an advanced anode material exhibits remarkable electrochemical performances for lithium-and potassium-ion batteries.Moreover,this bio-derived structural strategy can pave the way for novel low-cost and high-efficiency syntheses of metal-nitride/carbon nanofiber heterostructures for potential applications in energy-related fields and beyond.
基金financial support from the National Key Research and Development Program of China(2018YFB0104201).
文摘Boosting the utilization efficiency of sulfur electrodes and suppressing the“shuttle effect”of intermediate polysulfides remain the critical challenge for high-performance lithium-sulfur batteries(LSBs).However,most of reported sulfur electrodes are not competent to realize the fast conversion of polysulfides into insoluble lithium sulfides when applied with high sulfur loading,as well as to mitigate the more serious shuttle effect of polysulfides,especially when worked at an elevated temperature.Herein,we reported a unique structural engineering strategy of crafting a unique hierarchical multifunctional electrode architecture constructed by rooting MOF-derived CoS2/carbon nanoleaf arrays(CoS2-CNA)into a nitrogen-rich 3D conductive scaffold(CTNF@CoS2-CNA)for LSBs.An accelerated electrocatalytic effect and improved polysulfide redox kinetics arising from CoS2-CNA were investigated.Besides,the strong capillarity effect and chemisorption of CTNF@CoS2-CNA to polysulfides enable high loading and efficient utilization of sulfur,thus leading to high-performance LIBs performed not only at room temperature but also up to an elevated temperature(55°C).Even with the ultrahigh sulfur loading of 7.19 mg cm?2,the CTNF@CoS2-CNA/S cathode still exhibits high rate capacity at 55°C.
基金financial support from the National Natural Science Foundation of China(51904193)the Major Science and Technology Projects of Sichuan Province(2019ZDZX0029)the Fundamental Research Funds for the Central Universities。
文摘Li-rich layered oxide of Li_(1.2)Mn_(0.6)Ni_(0.2)O_(2)(LMNO)with a considerable specific capacity and higher voltage is regarded as a kind of promising cathode material.However,it suffers from transition metal ion dissolution and oxygen escape that leads to rapid capacity decay.In addition,the poor lithium-ion diffusion kinetics gives rise to unsatisfied rate performance.Herein,a stable layer of Li_(0.5)Mn_(0.5)O(LMO)out of LMNO is in-situ constructed through acetic passivation and following calcination process.The generated defect structure in the composite material exhibits fast ion diffusion kinetics and the produced LMO layer can stabilize the substructure,resulting in elevated cycling stability and rate performance.In specific,the LMNO@LMO material exhibits a high initial coulombic efficiency of 80.3%and remarkable capacity retention of 80.7%after 200 cycles at 1 C.Besides,the composite material reveals prominent rate performance that delivers discharge capacities of 158 and 131 m Ah g^(-1) at 5 and 10 C,respectively.At last,this study presents a new approach to optimizing the Li-rich cathode materials.
文摘The impact and penetration of a projectile in a particle-laden space, which are expected to have frequently occurred during the formation of the solar system and will occur in the case of an impact probe for future planetary exploration, were experimentally simulated by using the ballistic range. A two-dimensional sheet made from small glass beads or emery powder was formed by the free-falling device through a long slit in the test chamber evacuated down to about 35 Pa. A polycarbonate projectile of a hemi-sphere-cylinder or sphere shape with the mass and diameter about 4 g and 25 mm, respectively, was launched at the velocity up to 430 m/s, and the phenomena were observed by the high-speed camera at 20,000 fps. From a series of images, the bow-shock-wave-like laterally facing U-shaped pattern over the projectile and the absence of particles in the trail behind it were clearly seen. At the impact of the particles on the projectile surface, fine grains were formed due to the destructive collision and injected outward from the projectile. The images obtained by different lighting methods including the laser light sheet were compared. The effects of the particle diameter, its material and the impact velocity were also investigated.
文摘For application to exploration under the surface of icy objects in the solar system, the penetration of an impact probe into an icy target was experimentally simulated by using the ballistic range. Slender projectiles with a cylindrical body and various nose shapes were tested at the impact velocity 130 - 420 m/s. The motion of the penetrator, fragmentation of ice and crater forming were observed by the high-speed camera. It revealed that the crown-shaped ejection was made for a short time after the impact and then the outward normal jet-like stream of ice pieces continued for much longer time. The concave shape of the crater was successfully visualized by pouring the plaster into it. The two-stage structure, the pit and the spall, was clearly confirmed. The rim was not formed around the crater. Observation of the crater surface and the ice around the trace of the penetrator shows that both crushing into smaller ice pieces and recompression into ice blocks are caused by the forward motion of the penetrator. In case of a body with a flow-through duct, ice pieces entering the inlet at the nose tip were ejected from the tail, resulting in relaxation of the impact force. The correlation of the penetration distance and the crater diameter with the impact velocity was investigated.
文摘Wireless power transfer (WPT) from a transmitter resonator on the ground to an electrically powered miniature heli-copter was attempted to demonstrate WPT using magnetic resonance coupling to an object moving in 3D space. The transmission efficiency was optimized by automatic impedance matching for different flight attitudes: a maximum flight altitude of 590 mm was achieved. Furthermore, an estimation method of transmission efficiency using only the properties on the transmitter side was proposed, with transmission power regulated as constant against the change in the coupling coefficient.
文摘Degradation of 2,6-dibromophenol (2,6-DBP) in the aqueous solution was studied using dielectric barrier discharge in micro-bubbles. Experimental comparison of working gas Ar, N<sub>2</sub>, O<sub>2</sub>, and air showed that oxygen and air plasma efficiently decomposed 2,6-DBP to bromide ion, and inorganic carbon. The molecular orbital model was applied in the analysis of the degradation in electrophilic, nucleophilic, and radical reactions.
基金Project(NCET-10-0946)supported by Program for New Century Excellent Talents in University of ChinaProject(2017JY0038)supported by Science and Technology Key Project of Sichuan Province,ChinaProject(2013TX8)supported by Titanium and Titanium Alloy Innovation Team of Panzhihua City,China
文摘Anodic oxidation with different electrolyte was employed to improve the electrochemical properties of carbon paper as negative electrode for vanadium redox battery(VRB).The treated carbon paper exhibits enhanced electrochemical activity for V^2+/V^3+redox reaction.The sample(CP-NH3)treated in NH3 solution demonstrates superior performance in comparison with the sample(CP-NaOH)treated in NaOH solution.X-ray photoelectron spectroscopy results show that oxygen-and nitrogen-containing functional groups have been introduced on CP-NH3 surface by the treatment,and Raman spectra confirm the increased surface defect of CP-NH3.Energy storage performance of cell was evaluated by charge/discharge measurement by using CP-NH3.Usage of CP-NH3 can greatly improve the cell performance with energy efficiency increase of 4.8%at 60 mA/cm^2.The excellent performance of CP-NH3 mainly results from introduction of functional groups as active sites and improved wetting properties.This work reveals that anodic oxidation is a clean,simple,and efficient method for boosting the performance of carbon paper as negative electrode for VRB.
基金financially supported by National Key R&D Program of China(No.2018YFB1502101)the International/Hongkong,Macao&Taiwan Scientific and Technological Innovation Cooperation Project(2019YFH0148)。
文摘Si-based hydrolysis material system can be used in mobile/portable hydrogen source applications connected to fuel cells but is limited by alkaline solutions.In the present research,we reported an acid/alkaline free hydrolysis systemcombining siliconwith NaBH4.Sampleswith different ratios between Si and NaBH4 are prepared via high energy ball milling and hydrolyzed in deionized water at different temperatures.Synergetic effect between silicon and NaBH4was found in the hydrolysis process.2Si-NaBH4 sample displays the best hydrolysis performances with the hydrogen yield of 1594 ml·g^(−1) in deionized water at 70℃.Thereafter,AlCl3 is added into the 2Si-NaBH4 sample to further improve its comprehensive properties.The effect of AlCl3 content and promotion mechanism of the reaction are explored.2Si-NaBH4-5 wt% AlCl3 sample shows a significant improvement with a high hydrogen yield of 1689 ml·g^(−1) in deionized water at 70℃ and a corresponding conversion rate of 95.8%,indicating that the Si-NaBH4-AlCl3 composite is promising to be a hydrogen source in applications of mobile/portable fuelcell-powered facilities.
文摘The silicon oxide nano-powders (SiO<sub>x</sub>-NPs) were obtained in an atmospheric microwave plasma torch using a gas-phase silicon tetrachloride (SiCl<sub>4</sub>) with N<sub>2</sub> and H<sub>2</sub>. The gas-phase SiCl<sub>4</sub> was injected with H<sub>2</sub> gas into the microwave plasma torch generated by N<sub>2</sub> and air swirl gas, and then the dark brown powders were deposited on the inner wall of a quartz tube. The sample was analyzed by an X-ray photoelectron spectroscopy (XPS), a scanning electron microscope (SEM), an energy dispersive spectrometer (EDS), and an X-ray diffraction (XRD). The average size and oxidation x values of synthesized SiO<sub>x</sub>-NPs were approximately 230 nm and 0.91, respectively. Furthermore, the volumetric charge capacity is 1127 mAh/g and has 89.2% retention after 100 cycles.
文摘Glioblastoma(GBM)has a highly genetic heterogeneity and immunosuppressive microenvironment,leading to the inevitable emergence of treatment resistance and poor prognosis.This study aimed to explore the role of macrophages related pathways in the occurrence and development of GBM.Firstly,we developed an immune-related prognostic model and verified its ability to signi cantly distinguish between good and bad outcomes of patients(Fig.1(a)).
基金supported by the National Natural Science Foundation of China(22179019)the Natural Science Foundation of Hebei Province,China(B2020501003)the Fundamental Research Funds for the Central Universities(N2023030)。
文摘Zinc-based flow batteries(ZFBs)have aroused great favor in large-scale energy storage due to the high security and low cost.However,the low areal capacity arising from the limited space for Zn plating hinders the further development.Herein,a novel carbon felt-Sn-carbon felt sandwich host(CSCH)is designed and constructed.Benefiting from the strong chemical absorption and the dehydration effect on Zn(H_(2)O)_(6)^(2+),the Sn activation layer in the CSCH demonstrates the lowest comprehensive resistance for Zn deposition.Thus,Zn is induced to nucleate preferentially on the Sn activation layer,and grows towards the membrane,regulating the spatial distribution of Zn electrochemical deposits,which remarkably improves the areal capacity and cyclic stability of Zn anode.Consequently,the zinc-bromine flow batteries equipped with CSCH electrodes can achieve the ultra-high areal capacity of 120 mA h cm^(-2)at 80 mA cm^(-2),and run stably for 140 h with average energy efficiency of 80.3%in the extreme condition(80 mA cm^(-2),80 mA h cm^(-2)).This innovative work will inspire future advanced designs for high areal capacity electrodes in ZFBs.
基金Supported by the National Research Council of Science&Technology(NST)grant by the Korea government(MSIP)(No.CRC-15-07-KIER)
文摘Carbon dioxide(CO_2) is greenhouse gas which originates primarily as a main combustion product of biogas and landfill gas. To separate this gas, an inside coated thin film composite(TFC) hollow fiber membrane was developed by interfacial polymerization between 1,3–cyclohexanebis–methylamine(CHMA) and trimesoyl chloride(TMC). ATR-FTIR, SEM and AFM were used to characterize the active thin layer formed inside the PSf hollow fiber. The separation behavior of the CHMA-TMC/PSf membrane was scrutinized by studying various effects like feed gas pressure and temperature. Furthermore, the influence of CHMA concentration and TMC concentration on membrane morphology and performance were investigated. As a result, it was found that mutually the CHMA concentration and TMC concentration play key roles in determining membrane morphology and performance. Moreover, the CHMA-TMC/PSf composite membrane showed good CO_2/CH_4 separation performance. For CO_2/CH_4 mixture gas(30/70 by volume) test, the membrane(PD1 prepared by CHMA 1.0% and TMC 0.5%) showed a CO_2 permeance of 25 GPU and the best CO_2/CH_4 selectivity of 28 at stage cut of 0.1. The high CO_2/CH_4 separation performance of CHMA-TMC/PSf thin film composite membrane was mostly accredited to the thin film thickness and the properties of binary amino groups.
文摘Wireless power feeding was examined with strongly coupled magnetic resonance for an object moving in 3-D space. Electric power was transmitted from the ground to an electrically powered toy helicopter in the air. A lightweight receiver resonator was developed using copper foil. High Q of greater than 200 was obtained. One-side impedance matching the transmitter side was proposed to cope with high transmission efficiency and the receiver’s weight reduction. Results show that the efficiency drop near the ground was drastically improved. Moreover, the measured efficiency showed good agreement with theoretical predictions. A fully equipped helicopter of 6.56 g weight was lifted up with source power of about 5 W to an altitude of approximately 10 cm.
基金supported by the Korea Institute of Energy Technology Evaluation and Planning(KETEP)and the Ministry of Trade,Industry&Energy(MOTIE)of the Republic of Korea(20203030030020,20203030030080,20213030030150)。
文摘Solution infiltration is a popular technique for the surface modification of solid oxide fuel cell(SOFC)cathodes.However,the synthesis of nanostructured SOFC cathodes by infiltration is a tedious process that often requires several infiltration and high temperature(≥500℃)calcination cycles.Moreover,fabricating large-area nanostructured cathodes via infiltration still requires serious attention.Here,we propose a facile and scalable urea assisted ultrasonic spray infiltration technique for nanofabrication of SOFC cathodes.It is demonstrated that by using urea as a precipitating agent,the calcination after each infiltration cycle can be omitted and the next infiltration can be performed just after a drying step(≤100℃).Finally,the precipitates can be converted into a desired catalyst phase in single calcination thus,a nanostructured cathode can be fabricated in a much faster manner.It is also shown that the low calcination temperature of the cathode(≤900℃)can produce highly durable SOFC performance even without employing a Ce_(0.9)Gd_(0.1)O_(2)(GDC)diffusion barrier layer which provides the ease of SOFC fabrication.While coupling with an ultrasonic spray technique,the urea assisted infiltration can be scaled up for any desired cathode area.La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.8)O_(3) nanolayered cathode was fabricated and it was characterized by scanning electron microscope(SEM),X-ray diffraction(XRD),and transmission electron microscopy(TEM)techniques.SEM showed the formation of a nanolayer cathode just after 5 cycles of the urea assisted infiltration while the XRD and TEM confirmed the phase and stoichiometric uniformity of the 100 nm cathode nanolayer.The effectiveness of the newly developed technique was further verified by the stable operation of a GDC buffer layer free SOFC having an active cathode area of 25 cm^(2) during a 1200 h durability test.The research outcomes propose urea assisted ultrasonic spray infiltration as a facile,scalable,and commercially viable method for the fabrication of durable nanostructured SOFC cathodes.
文摘Transient separation behavior in tritiated water distillation tower packed with materials having ability to adsorb water is investigated analytically and experimentally for nuclear reactor safety. Analytical equations based on the stage model are set up for simulation of the transient behavior of tritium (T) separation from wastewater. It is found that a dimensionless time defined in terms of the inside vapor flow rate and the liquid holdups in tower, reboiler and condenser can correlate variations over time to achieve a steady-state T concentration. However, when mixing with different T concentrations at a feed point occurs, the transition time period becomes longer than expected. Effects of the reflux ratio, the stage separation factor and the total stage number on the transient and steady-state T concentrations are numerically calculated. Variations over time to achieve each steady-state value are compared with experimental data using a small-scale tower. Long time distillation experiment for one month has been completed, and it is confirmed that a distillation column packed with ceramic Raschig rings coated with zeolite 13X adsorbent is hardly affected by water corrosion.
文摘Nanotechnology is a field of research with objects up to 100 nm in size. Nanomaterials belong to a wide area in the field of material engineering. These include nanolayers, nanoslabs, nanopores, nanotubes, nanofibers, nanoparticles and quantum dots. Nanostructures are characterized by special properties due to their nanometric dimensions. The natural properties of nanostructures allow their wide application in various industries. The paper presents an overview of the application and significance of nanostructures in fuel cell technology, with particular emphasis on nanocatalysts. The article includes the classification of nanomaterials, new hybrid nanostructures, types of surface modification, division by area of application, with particular emphasis on nanomaterials in the advanced energy system. The design and operation of fuel cells and the role of nanoparticles have been described taking into account existing solutions to reduce generator costs. The high price of low temperature fuel cells depends on the number of nanoparticles used. The article describes the risk associated with using products at the nano scale. Higher concentrations of these extremely active materials can be dangerous and can cause ecological problems and harm natural ecosystems.
文摘In this paper, a wireless power transmission system using magnetic resonance coupling was proposed and demonstrated for supplying power at high efficiency to electrical devices in a space enclosed by metal walls. This is applicable to power supply to electrical sensors or devices working in the area surrounded by metal walls. Proposed magnetic resonance coupling system is driven at a resonance frequency of 50 Hz, which is selected to avoid eddy current loss on the surrounding metals. Firstly, resonator designs and its performance limitation were described. Secondly, the equivalent circuits and theoretical transmission efficiency were presented. Finally, power transmission was experimentally demonstrated and transmission efficiency was measured in some conceivable situations. As a result, electric power of 3 W was supplied to LEDs over a stainless steel wall. When the stainless steel wall thickness was 10 mm, transmission efficiency of approximately 40% was achieved over the transmission distance of 12 cm. Moreover, in the demonstration of transmission through a metal pipe, 1.2 W of power was transmitted to LEDs in a 10 mm thick metal pipe.
