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Correlative spatter and vapour depression dynamics during laser powder bed fusion of an Al-Fe-Zr alloy
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作者 Da Guo Rubén Lambert-Garcia +7 位作者 Samy Hocine Xianqiang Fan Henry Greenhalgh Ravi Shahani Marta Majkut Alexander Rack Peter D Lee Chu Lun Alex Leung 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第5期298-310,共13页
Spatter during laser powder bed fusion(LPBF)can induce surface defects,impacting the fatigue performance of the fabricated components.Here,we reveal and explain the links between vapour depression shape and spatter dy... Spatter during laser powder bed fusion(LPBF)can induce surface defects,impacting the fatigue performance of the fabricated components.Here,we reveal and explain the links between vapour depression shape and spatter dynamics during LPBF of an Al-Fe-Zr aluminium alloy using high-speed synchrotron x-ray imaging.We quantify the number,trajectory angle,velocity,and kinetic energy of the spatter as a function of vapour depression zone/keyhole morphology under industry-relevant processing conditions.The depression zone/keyhole morphology was found to influence the spatter ejection angle in keyhole versus conduction melting modes:(i)the vapour-pressure driven plume in conduction mode with a quasi-semi-circular depression zone leads to backward spatter whereas;and(ii)the keyhole rear wall redirects the gas/vapour flow to cause vertical spatter ejection and rear rim droplet spatter.Increasing the opening of the keyhole or vapour depression zone can reduce entrainment of solid spatter.We discover a spatter-induced cavity mechanism in which small spatter particles are accelerated towards the powder bed after laser-spatter interaction,inducing powder denudation and cavities on the printed surface.By quantifying these laser-spatter interactions,we suggest a printing strategy for minimising defects and improving the surface quality of LPBF parts. 展开更多
关键词 SPATTER vapour depression x-ray imaging DEFECTS surface quality
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Mesomorphism of Lanthanide(Ⅲ) 4-Hexyloxybenzoates
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作者 Liesbet Jongen Bart Goderis +1 位作者 Igor P Dolbnya Koen Binnemans 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第2期193-196,共4页
The 4-alkoxybenzoic acids are well-known liquid crystals showing several mesophases (nematic, smectic C phase or both) depending on the alkoxy chain length and whereby the rigid core of the mesogen is formed by interm... The 4-alkoxybenzoic acids are well-known liquid crystals showing several mesophases (nematic, smectic C phase or both) depending on the alkoxy chain length and whereby the rigid core of the mesogen is formed by intermolecular hydrogen bonds. In this paper it is shown that the thermal behaviour of lanthanide salts of 4-hexyloxybenzoic acids depends on the lanthanide ion (Ln=La, Pr, Nd, Sm, Eu). The lanthanum(Ⅲ) and praseodymium(Ⅲ) 4-hexyloxybenzoates exhibit a smectic A mesophase. No mesophase is found for the corresponding compounds of heavier lanthanides. The thermal properties of the lanthanide(Ⅲ) 4-hexyloxybenzoates were investigated by differential scanning calorimetry (DSC), polarising thermo-optical microscopy and synchrotron X-ray radiation. 展开更多
关键词 LANTHANIDES 4-alkoxybenzoates thermal behaviour synchrotron measurements METALLOMESOGENS rare earths
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Linac Beam Dynamics Code Benchmarking
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作者 Xuejun Yin Wolfgang Bayer Andrea Franchi 《Journal of Modern Physics》 2015年第8期1044-1050,共7页
The code benchmarking for hadron linac using the 3D Particle-In-Cell (PIC) code is an important task in the European framework “High Intensity Pulsed Proton Injector” (HIPPI). PARMILA and HALODYN are two of the code... The code benchmarking for hadron linac using the 3D Particle-In-Cell (PIC) code is an important task in the European framework “High Intensity Pulsed Proton Injector” (HIPPI). PARMILA and HALODYN are two of the codes involved in this work. Both of these codes have been developed and used for linac design and beam dynamics studies. In this paper, the simulation results of the beam dynamics were compared and analyzed. As predicted by two codes, the simulation results show some agreements. The physical design strategy which was adopted in two codes was also discussed. 展开更多
关键词 HADRON LINAC 3D PIC CODE BENCHMARK Beam Dynamics Simulation
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Synthesis and X-Ray Diffraction Analyses of Calcium Hydroxide Nanoparticles in Aqueous Suspension
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作者 G. Taglieri C. Mondelli +2 位作者 V. Daniele E. Pusceddu A. Trapananti 《Advances in Materials Physics and Chemistry》 2013年第1期108-112,共5页
Calcium hydroxide nanoparticles in aqueous suspensions (also called nanolime) were successfully employed in Cultural Heritage conservation thanks to the ability of favoring readhesion of the pictorial layer on origina... Calcium hydroxide nanoparticles in aqueous suspensions (also called nanolime) were successfully employed in Cultural Heritage conservation thanks to the ability of favoring readhesion of the pictorial layer on original carbonatic substrates or allowing to a better superficial cohesion and protection of treated stones. In this work, we have synthesized nanolime particles in aqueous suspension by two different methods. The produced particles were characterized in the laboratory, in terms of structural and morphological features, by means of X-Ray diffraction powder (XRD) and by transmission electron microscopy (TEM), respectively. Nanoparticles were crystalline, regularly shaped, hexagonally plated and with side dimensions generally ranging from 300 nm to 30 nm or less. Crystal structure of nanolime particles directly in the aqueous suspension, has been also analyzed by synchrotron diffraction from X-ray synchrotron radiation (SR-XRD);data have been analyzed by means of the Rietveld method and we have investigated the structure of Ca(OH)2 particles in suspension in terms of cell parameters, atomic coordinates, bond lengths and angles. 展开更多
关键词 NANOPARTICLES CALCIUM HYDROXIDE CRYSTAL Structure X-Ray DIFFRACTION CRYSTAL Morphology
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Structure of the myenteric plexus in normal and diseased human ileum analyzed by X-ray virtual histology slices
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作者 Bela Veress Niccolo Peruzzi +4 位作者 Marina Eckermann Jasper Frohn Tim Salditt Martin Bech Bodil Ohlsson 《World Journal of Gastroenterology》 SCIE CAS 2022年第29期3994-4006,共13页
BACKGROUND The enteric nervous system(ENS)is situated along the entire gastrointestinal tract and is divided into myenteric and submucosal plexuses in the small and large intestines.The ENS consists of neurons,glial c... BACKGROUND The enteric nervous system(ENS)is situated along the entire gastrointestinal tract and is divided into myenteric and submucosal plexuses in the small and large intestines.The ENS consists of neurons,glial cells,and nerves assembled into ganglia,surrounded by telocytes,interstitial cells of Cajal,and connective tissue.Owing to the complex spatial organization of several interconnections with nerve fascicles,the ENS is difficult to examine in conventional histological sections of 3-5μm.AIM To examine human ileum full-thickness biopsies using X-ray phase-contrast nanotomography without prior staining to visualize the ENS.METHODS Six patients were diagnosed with gastrointestinal dysmotility and neuropathy based on routine clinical and histopathological examinations.As controls,fullthickness biopsies were collected from healthy resection ileal regions after hemicolectomy for right colon malignancy.From the paraffin blocks,4-μm thick sections were prepared and stained with hematoxylin and eosin for localization of the myenteric ganglia under a light microscope.A 1-mm punch biopsy(up to 1 cm in length)centered on the myenteric plexus was taken and placed into a Kapton®tube for mounting in the subsequent investigation.X-ray phase-contrast tomography was performed using two custom-designed laboratory setups with micrometer resolution for overview scanning.Subsequently,selected regions of interest were scanned at a synchrotron-based end-station,and high-resolution slices were reported.In total,more than 6000 virtual slices were analyzed from nine samples.RESULTS In the overview scans,the general architecture and quality of the samples were studied,and the myenteric plexus was localized.High-resolution scans revealed details,including the ganglia,interganglional nerve fascicles,and surrounding tissue.The ganglia were irregular in shape and contained neurons and glial cells.Spindle-shaped cells with very thin cellular projections could be observed on the surface of the ganglia,which appeared to build a network.In the patients,there were no alterations in the general architecture of the myenteric ganglia.Nevertheless,several pathological changes were observed,including vacuolar degeneration,autophagic activity,the appearance of sequestosomes,chromatolysis,and apoptosis.Furthermore,possible expulsion of pyknotic neurons and defects in the covering cellular network could be observed in serial slices.These changes partly corresponded to previous light microscopy findings.CONCLUSION The analysis of serial virtual slices could provide new information that cannot be obtained by classical light microscopy.The advantages,disadvantages,and future possibilities of this method are also discussed. 展开更多
关键词 Enteric nervous system IMMUNOHISTOCHEMISTRY NEUROPATHY SYNCHROTRON Virtual histology Xray phase-contrast nanotomography
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<i>In</i>-<i>Situ</i>XAFS Characterization of PtPd Nanoparticles Synthesized by Galvanic Replacement
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作者 Simon Tymen Andreas C. Scheinost +1 位作者 Christian Friebe Ulrich S. Schubert 《Advances in Nanoparticles》 2017年第2期75-91,共17页
Platinum-palladium nanoparticles are synthesized and characterized with regard to their application in fuel cells due to their high (electro) catalytic activity. Different preparation times are applied leading to diff... Platinum-palladium nanoparticles are synthesized and characterized with regard to their application in fuel cells due to their high (electro) catalytic activity. Different preparation times are applied leading to different structures, from Pd cubic to core-shell PtPd concave, and different chemical compositions. The resulting particles are studied via Transmission Electron Microscopy (TEM) and in-situ X-ray absorption fine structure (XAFS) measurements. The latter allows the investigation of the oxygen reduction reaction following the variations with varying applied potentials by analysis using the Iterative Transformation Factor Analysis (ITFA) and the creation of a two-component system that consists of metallic Pt-Pd and the related oxide. With the used model, the different concentrations of the oxide are linked to the consecutive chemical steps of the oxygen reduction reaction. Finally, the catalytic activity of the particles is determined via linear scanning voltammetry and reveals a dependence on the shape and the composition of the particles. 展开更多
关键词 PLATINUM PALLADIUM Nanoparticles Oxygen Reduction Reaction In-Situ XAFS ITFA
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Evolution and impact of cellulose architecture during enzymatic hydrolysis by fungal cellulases
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作者 Marie Chauve Loic Barre +4 位作者 Sandra Tapin-Lingua Denilson da Silva Perez Dominique Decottignies Serge Perez Nicolas Lopes Ferreira 《Advances in Bioscience and Biotechnology》 2013年第12期1095-1109,共15页
The enzymatic hydrolysis of cellulose is still considered as a main limiting step of the biological production of biofuels from ligno-cellulosic biomass. Glycoside hydrolases from Trichoderma reesei are currently used... The enzymatic hydrolysis of cellulose is still considered as a main limiting step of the biological production of biofuels from ligno-cellulosic biomass. Glycoside hydrolases from Trichoderma reesei are currently used to produce fermentable glucose units from degradation of cellulose packed in a complex assembly of cellulose microfibrils. The present work describes the structural evolution of two prototypical samples of cellulose (a micro-crystalline cellulose and a bleached sulfite pulp) over 5 length scale orders of magnitude. The results were obtained through wide angle, small angle and ultra-small angles synchrotron X-ray scattering, completed by Small Angle Neutron Scattering and particle size analyzers. These structural evolutions were followed as a function of enzymatic conversion. The results show that whereas there is no change at the nanometer scale, drastic changes occur at micron. The observed decrease of the size of the cellulose particles is accompanied by a smoothing of the crystalline surfaces that can be explained by a two-step mechanism of the enzymatic hydrolysis. 展开更多
关键词 CELLULOSE CELLULASE Trichoderma reesei Synchrotron X-Ray Scattering Neutron Scattering Particle Size
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铝合金熔焊微气孔的三维同步辐射X射线成像 被引量:19
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作者 喻程 吴圣川 +2 位作者 胡雅楠 张卫华 付亚楠 《金属学报》 SCIE EI CAS CSCD 北大核心 2015年第2期159-168,共10页
基于同步辐射X射线成像技术,对激光复合焊7020-T651铝合金接头内部的微气孔进行了研究,对气孔的体积、圆整度、扁平度及气孔形心至自由表面的距离等三维特征参数进行了统计分析与拟合.结果表明,铝合金熔焊微气孔主要为近球形的冶金型气... 基于同步辐射X射线成像技术,对激光复合焊7020-T651铝合金接头内部的微气孔进行了研究,对气孔的体积、圆整度、扁平度及气孔形心至自由表面的距离等三维特征参数进行了统计分析与拟合.结果表明,铝合金熔焊微气孔主要为近球形的冶金型气孔,圆整度在0.65以上,以焊缝中心近似呈现对称分布,且焊缝上部气孔尺寸较大,热影响区和下部气孔密集且尺寸较小.等效直径在20 mm范围内的气孔,在接头上部和下部的频率分别高达65%和85%,并且100 mm以上的大尺寸气孔较少见.此外,由于熔池的下塌倾向和快速凝固,残留于枝晶网络间液相导致焊缝下部形成垂直于焊缝且层叠分布的形状复杂的热裂纹,少部分气孔之间以及气孔和热裂纹之间存在着连通现象,从而使得下部微气孔的圆整度平均值变小.此外,焊接速率越大,整个接头内部气孔体积分数越小,但对气孔形貌和位置的分布影响并不明显. 展开更多
关键词 激光复合焊 铝合金 气孔 同步辐射X射线成像
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Design of molecule-based magnetic conductors
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作者 Naureen Akhtar Graeme R. Blake +3 位作者 Roberto Felici Heinz Amenitsch Thomas T. M. Palstra Petra Rudolf 《Nano Research》 SCIE EI CAS CSCD 2014年第12期1832-1842,共11页
Enabling the use of rationally designed thin films in technological devices is a recognized goal in materials science. However, constructing such thin films using highly ordered supramolecular architectures with well-... Enabling the use of rationally designed thin films in technological devices is a recognized goal in materials science. However, constructing such thin films using highly ordered supramolecular architectures with well-controlled size and growth direction has remained an elusive target. Here, we introduce a layer-by- layer protocol to grow hybrid thin films of molecule-based magnetic conductors comprising arachidic acid and donor bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) as the organic component and Cu/Gd complexes as the inorganic component. The construction of layered hybrid thin films was achieved at ambient conditions by employing the Langmuir-Blodgett method, which provides good control over film thickness and packing of molecules in the monolayer. As demonstrated by X-ray diffraction, these films are crystalline with distinct organic and inorganic sublattices, where the BEDO-TTF molecular layer is interfaced with the inorganic layer. Due to the flexibility of the Langmuir-Blodgett deposition technique, this result indicates a route toward the preparation of well-ordered films with various functionalities, determined by the choice of the inorganic compound that is combined with the π-unit of BEDO-TFF. Moreover, the ability to deposit films on a variety of substrates establishes the potential for lower-cost device fabrication on inexpensive substrates. 展开更多
关键词 molecule-based materials SELF-ASSEMBLY ordered heterostructures multifunctionality ultra-thin films
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4D imaging of void nucleation,growth,and coalescence from large and small inclusions in steel under tensile deformation
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作者 Yi Guo Timothy L.Burnett +3 位作者 Samuel A.McDonald Michael Daly Andrew H.Sherry Philip J.Withers 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第28期168-176,共9页
Samples of SA508 grade 3 nuclear pressure vessel ferritic steel were subjected to tensile straining whilst being simultaneously imaged in 3D in real time using high resolution,high frame rate time-lapse synchrotron co... Samples of SA508 grade 3 nuclear pressure vessel ferritic steel were subjected to tensile straining whilst being simultaneously imaged in 3D in real time using high resolution,high frame rate time-lapse synchrotron computed tomography(CT).This enabled direct observation of void development from nucleation,through growth to coalescence and final failure validating many inferences made post-mortem or by theoretical models,as well as raising new points.The sparse,large inclusions were found to nucleate voids at essentially zero plastic strain(consistent with zero interfacial strength);these became increasingly elongated with straining.In contrast,a high density of small spherical voids were found to nucleate from the sub-micron cementite particles at larger strains(>200%)only in the centre of the necked(high triaxiality)region.An interfacial strength approaching 2100 MPa was inferred and soon after their nucleation,these small voids coalesce to form internal microcracks that lead to the final failure of the specimen.Perhaps surprisingly,under these conditions of generally low triaxial constraint the large voids are simply cut across and appear to play no significant role in determining the final failure.The implications of these results are discussed in terms of ductile fracture behaviour and the Gurson model for ductile fracture. 展开更多
关键词 Void growth Ductile fracture Synchrotron X-ray tomography 4D imaging Bainitic steel
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Vasarely painting at the nanoscale on sapphire crystals
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作者 Caroline Matringe Elsa Thune +8 位作者 Rémy Cavalotti Ahmad Fakih Stephan Amaud Nils Blanc Nathalie Boudet Alessandro Coati Yves Garreau David Babonneau René Guinebretière 《Nano Research》 SCIE EI CAS CSCD 2020年第9期2512-2516,共5页
We demonstrate that convenient thermal treatment of a specific sapphire vicinal surface can induce the formation of a fully two-dimensional(2D)ordered surface made of a periodic assembly of(006)facets.The simiarity be... We demonstrate that convenient thermal treatment of a specific sapphire vicinal surface can induce the formation of a fully two-dimensional(2D)ordered surface made of a periodic assembly of(006)facets.The simiarity between the resuting surface topography and pattemns represented in the hexagon series"of paintings by Vasarely is really striking!We thus propose to call these surfaces as"nanoscaled Vasarely surfaces".We also show that the self-organization process,which is driven by the minimization of the free energy of a closed system,results in a quasi-linear isothermal growth of the facets'surface area over time. 展开更多
关键词 nanoscaled Vasarely surfaces two-dimensional(2D)-self-organization sapphire vicinal surfaces
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