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Enhancing thermoelectric performance in P-type Mg_(3)Sb_(2)-based Zintls through optimization of band gap structure and nanostructuring
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作者 Yi-bo Zhang Ji-Sheng Liang +6 位作者 Chengyan Liu Qi Zhou Zhe Xu Hong-bo Chen Fu-cong Li Ying Peng Lei Miao 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第3期25-32,共8页
P-type Mg_(3)Sb_(2)-based Zintls have attracted considerable interest in the thermoelectric(TE)field due to their environmental friendliness and low cost.However,compared to their n-type counterparts,they show relativ... P-type Mg_(3)Sb_(2)-based Zintls have attracted considerable interest in the thermoelectric(TE)field due to their environmental friendliness and low cost.However,compared to their n-type counterparts,they show relatively low TE performance,limiting their application in TE devices.In this work,we simultaneously introduce Bi alloying at Sb sites and Ag doping at Mg sites into the Mg_(3)Sb_(2)to coopera-tively optimize the electrical and thermal properties for the first time,acquiring the highest ZT value of∼0.85 at 723 K and a high average ZT of 0.39 in the temperature range of 323-723 K in sample Mg_(2.94)Ag_(0.06)Sb_(1.9)Bi_(0.1).The first-principle calculations show that the codoping of Ag and Bi can shift the Fermi level into the valence band and narrow the band gap,resulting in the increased carrier concentration from 3.50×10^(17)cm^(-3)in the reference Mg 3 Sb 0.9 Bi 0.1 to∼7.88×10^(19)cm^(-3)in sample Mg 2.94 Ag 0.06 Sb 0.9 Bi 0.1.As a result,a remarkable power factor of∼778.9μW m^(-1)K^(-2)at 723 K is achieved in sample Mg 2.94 Ag 0.06 Sb 0.9 Bi 0.1.Meanwhile,a low lattice thermal conductivity of∼0.48 W m^(-1)K^(-1)at 723 K is also obtained with the help of phonon scattering at the distorted lattice,point defects,and nano-precipitates in sample Mg 2.94 Ag 0.06 Sb 0.9 Bi 0.1.The synergistic effect of using the multi-element co-doping/-alloying to optimize electrical properties in Mg_(3)Sb_(2)holds promise for further improving the TE performance of Zintl phase materials or even others. 展开更多
关键词 Thermoelectric materials Band engineering Nanostructuring P-type Mg_(3)Sb_(2) Ag and Bi Co-doping
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Collaboratively enhancing electrochemical properties of LiNi_(0.83)Co_(0.11)Mn_(0.06)O_(2) through doping and coating of quadrivalent elements 被引量:3
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作者 Zhao-Zhe Yu Gui-Quan Zhao +4 位作者 Fang-Li Ji Hao Tong Qi-Lin Tong Hua-Cheng Li Yan Cheng 《Rare Metals》 SCIE EI CAS CSCD 2023年第12期4103-4114,共12页
Ni-rich layered oxides(Ni>80%)with high energy density have become a mainstream cathode material for Li-ion batteries.However,irreversible phase transitions and interface instability are deep-seated challenges in c... Ni-rich layered oxides(Ni>80%)with high energy density have become a mainstream cathode material for Li-ion batteries.However,irreversible phase transitions and interface instability are deep-seated challenges in commercializing Ni-rich materials.This study used a collaborative modification strategy involving doping and coating with quadrivalent elements to construct Ni-rich materials.In particular,introducing tetravalent Zr makes the valence change of Ni(2+to 4+)more accessible to complete spontaneously during the charging and discharging processes,which significantly suppresses the cationic mixing and irreversible phase transition(H2?H3).Combining the strategy of constructing CeO_(2) coatings on the surface and interfacial spinel-like phases improves the Li+diffusion kinetics and interfacial stability.Simultaneously,part of the strongly oxidizing four-valence Ce^(4+)diffuses to the surface layer,further increasing the average valence state of Ni.Therefore,LiNi_(0.83)Co_(0.11)Mn_(0.06)O_(2)(NCM)-Zr@Ce achieves 78.5%outstanding retention at1.0C after 200 cycles within 3.0-4.3 V compared to unmodified NCM with 41.4%retention.The improved cyclic stability can be attributed to the collaborative modification strategy of the quadrivalent elements,which provides an effective synergistic modification strategy for developing high-performance Li-ion battery cathode materials. 展开更多
关键词 Collaborative modification strategy Quadrivalent elements Phase transitions Structural degradation Ni-rich layered oxides
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Over 18.2% efficiency of layer–by–layer all–polymer solar cells enabled by homoleptic iridium(Ⅲ)carbene complex as solid additive
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作者 Hang Zhou Yingjie Sun +10 位作者 Miao Zhang Yuheng Ni Fenghua Zhang Sang Young Jeong Tianhuan Huang Xiong Li Han Young Woo Jian Zhang Wai-Yeung Wong Xiaoling Ma Fujun Zhang 《Science Bulletin》 SCIE EI CAS CSCD 2024年第18期2862-2869,共8页
The vertical phase distribution of active layers plays a vital role in balancing exciton dissociation and cha rge transport for achieving efficient polymer solar cells(PSCs).The layer-by-layer(LbL)PSCs are commonly pr... The vertical phase distribution of active layers plays a vital role in balancing exciton dissociation and cha rge transport for achieving efficient polymer solar cells(PSCs).The layer-by-layer(LbL)PSCs are commonly prepared by using sequential spin-coating method from donor and acceptor solutions with distinct solvents and solvent additives.The enhanced exciton dissociation is expected in the LbL PSCs with efficient charge transport in the relatively neat donor or acceptor layers.In this work,a series of LbL all-polymer solar cells(APSCs)were fabricated with PM6 as donor and PY-DT as acceptor,and triplet material m-Ir(CPmPB)_(3)is deliberately incorporated into PY-DT layer to prolong exciton lifetimes of active layers.The power conversion efficiency(PCE)of LbL APSCs is improved to 18.24%from 17.32%by incorporating 0.3 wt%m-Ir(CPMPB)_(3)in PY-DT layer,benefiting from the simultaneously enhanced short-circuit current density(Isc)of 25.17 mA cm^(-2)and fill factor(FF)of 74.70%.The enhancement of PCE is attributed to the efficient energy transfer of m-Ir(CPmPB)_(3)to PM6 and PY-DT,resulting in the prolonged exciton lifetime in the active layer and the increased exciton diffusion distance.The efficient energy transfer from m-Ir(CPmPB)_(3)to PM6 and PY-DT layer can be confirmed by the increased photoluminescence(PL)intensity and the prolonged PL lifetime of PM6 and PY-DT in PM6+m-Ir(CPmPB)_(3)and PY-DT+m-Ir(CPmPB)_(3)films.This study indicates that the triplet material as solid additive has great potential in fabricating efficient LbL APSCs by prolonging exciton lifetimes in active layers. 展开更多
关键词 Layer-by-layer All-polymer solar cells Additive strategy Triplet material Energy transfer
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Bright and tunable emissive monodisperse CsPbI3@Cs4PbI6 nanocomposites via a precise and controllable dissolution−recrystallization method 被引量:2
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作者 Luyu Cao Bomei Liu +4 位作者 Lin Huang Zhi Zhou Chong-Geng Ma Jian Zhang Jing Wang 《Nano Research》 SCIE EI CSCD 2023年第1期1586-1594,共9页
Nowadays,due to uncontrolled synthesis and lack of more direct and systematic evidences,the photoluminescence origin of“zero-dimensional”Cs4PbI6 remains great controversy and the luminescence cannot be controlled.He... Nowadays,due to uncontrolled synthesis and lack of more direct and systematic evidences,the photoluminescence origin of“zero-dimensional”Cs4PbI6 remains great controversy and the luminescence cannot be controlled.Here we propose a controllable dissolution-recrystallization method to synthesize“emissive”and“non-emissive”Cs4PbI6 nanocrystals(NCs)respectively.Through comparing“emissive”and“non-emissive”Cs4PbI6 NCs,it is clearly proved that the visible emission in“emissive”Cs4PbI6 NCs comes from embedded CsPbI3 quantum dots(QDs).It is found for CsPbI3@Cs4PbI6 nanocomposites,methyl acetate(MeAC)and cyclohexane play an important role in dissolution and recrystallization respectively to obtain Cs4PbI6 matrix and CsPbI3 cores.Benefiting from this two-step method,the as-synthesized CsPbI3@Cs4PbI6 nanocomposites with CsPbI3 QDs uniformly distributed in Cs4PbI6 matrix are bright with photoluminescence quantum yield(PLQY)up to 71.4%and exhibit improved stability than CsPbI3 NCs.Moreover,utilizing its formation mechanism,the size of embedded CsPbI3 QDs can be controlled by reasonable designing the“dissolution”process,so that the luminescence of this CsPbI3@Cs4PbI6 nanocomposites can be adjusted in a wide range from green to red(554–630 nm).Our finding not only provides a novel method for synthesizing tunable“emissive”Cs4PbI6 NCs,but also makes clear the photoluminescence origin of“emissive”Cs4PbI6. 展开更多
关键词 CsPbI3@Cs4PbI6 dissolution-recrystallization NANOCOMPOSITES tunable emission
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Enhanced thermoelectric performance enabled by compositing ZrO_(2)in n-type SiGe alloy with low thermal conductivity 被引量:1
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作者 Meng-Fei Wang Hua-Jun Lai +6 位作者 Ji-Sheng Liang Jun-Liang Chen Wang-Yang Ding Qi Zhou Ying Peng Cheng-Yan Liu Lei Miao 《Rare Metals》 SCIE EI CAS CSCD 2024年第3期1167-1176,共10页
SiGe-based thermoelectric(TE)materials have gained increasing interests due to their low maintenance costs,environmental friendliness and long lifespan.However,the intrinsically high thermal conductivity of Si-based m... SiGe-based thermoelectric(TE)materials have gained increasing interests due to their low maintenance costs,environmental friendliness and long lifespan.However,the intrinsically high thermal conductivity of Si-based materials also results in poor TE properties.In this investigation,a zirconia(ZrO_(2))composite strategy was applied to an n-type SiGe alloy,tremendously elevating its TE performance.After mechanical alloying and spark plasma sintering(SPS)processes,the ZrO_(2)induced the formation of nanopores in the SiGe matrix via phosphorus adsorption.Moreover,such increase in porosity enhanced the phonon scattering and dramatically suppressed lattice thermal conductivity,from 2.83 to 1.59 W·m^(-1)·K^(-1)at 873 K.Additionally,reduced phosphorus doping led to an increase in Seebeck coefficients and a relatively minor decrease in electrical conductivity,The power factor didn't deteriorate significantly,either,as its maximum of~3.43 mW·m^(-1-)K^(-2)was achieved at 873 K with(Si_(0.8)Ge_(0.2))_(0.097)P_(0.03)(ZrO_(2))_(0.003).In short,a peak figure of merit(ZT)of~1.27 at 873 K and an average ZT~0.7 from 323 to 873 K were obtained.This study demonstrates that the electrical and thermal transportation of SiGe material can be synergistically tuned by compositing ZrO_(2),illustrating a novel strategy to optimize the TE properties of bulk materials. 展开更多
关键词 THERMOELECTRIC SiGe alloy ZrO2 composting P element adsorption NANOPORES
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Machine Learning-Based Comprehensive Prediction Model for L12 Phase-Strengthened Fe-Co-Ni-Based High-Entropy Alloys
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作者 Xin Li Chenglei Wang +9 位作者 Laichang Zhang Shengfeng Zhou Jian Huang Mengyao Gao Chong Liu Mei Huang Yatao Zhu Hu Chen Jingya Zhang Zhujiang Tan 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2024年第11期1858-1874,共17页
L1_(2)phase-strengthened Fe-Co-Ni-based high-entropy alloys(HEAs)have attracted considerable attention due to their excellent mechanical properties.Improving the properties of HEAs through conventional experimental me... L1_(2)phase-strengthened Fe-Co-Ni-based high-entropy alloys(HEAs)have attracted considerable attention due to their excellent mechanical properties.Improving the properties of HEAs through conventional experimental methods is costly.Therefore,a new method is needed to predict the properties of alloys quickly and accurately.In this study,a comprehensive prediction model for L1_(2)phase-strengthened Fe-Co-Ni-based HEAs was developed.The existence of the L1_(2)phase in the HEAs was first predicted.A link was then established between the microstructure(L1_(2)phase volume fraction)and properties(hardness)of HEAs,and comprehensive prediction was performed.Finally,two mutually exclusive properties(strength and plasticity)of HEAs were coupled and co-optimized.The Shapley additive explained algorithm was also used to interpret the contribution of each model feature to the comprehensive properties of HEAs.The vast compositional and process search space of HEAs was progressively screened in three stages by applying different prediction models.Finally,four HEAs were screened from hundreds of thousands of possible candidate groups,and the prediction results were verified by experiments.In this work,L1_(2)phase-strengthened Fe-Co-Ni-based HEAs with high strength and plasticity were successfully designed.The new method presented herein has a great cost advantage over traditional experimental methods.It is also expected to be applied in the design of HEAs with various excellent properties or to explore the potential factors affecting the microstructure/properties of alloys. 展开更多
关键词 High-entropy alloy Machine learning L1_(2)phase Comprehensive prediction Shapley additive explanation(SHAP)
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基于温度开关的光响应智能水凝胶用于可逆信息加密和解密
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作者 狄睿 宋志鹏 +7 位作者 李明通 练梦洁 王毅桐 郭俊江 苗豪杰 袁腾跃 刘静 周建华 《Science China Materials》 SCIE EI CAS CSCD 2024年第7期2123-2134,共12页
在智能凝胶防伪系统中使用的光、热、电、pH等刺激响应性水凝胶,是一种有前途的信息加密和解密材料.然而单一刺激会限制高水平的防伪.因此,需要协同使用多种刺激来提升信息安全等级.本研究设计了一种高透明度的海藻酸钠-聚丙烯酰胺(SA-P... 在智能凝胶防伪系统中使用的光、热、电、pH等刺激响应性水凝胶,是一种有前途的信息加密和解密材料.然而单一刺激会限制高水平的防伪.因此,需要协同使用多种刺激来提升信息安全等级.本研究设计了一种高透明度的海藻酸钠-聚丙烯酰胺(SA-PAM)水凝胶作为基体,利用无机变色材料钼酸铵(Mo7)赋予其凝胶光致变色特性.此外,温敏材料聚N-异丙基丙烯酰胺(PNIPAM)可使凝胶在最低临界相变温度(LCST)下发生体积相变,进而改变凝胶的宏观状态,可以通过调整凝胶体系中亲水单体和疏水单体的比例来控制LCST.利用紫外线(UV)作为“墨水”输入信息,以温度作为“开关”来加密/解密信息.总之,该水凝胶具有出色的光致变色能力,可在10 s内着色,紫外光吸收率最高可达96.23%.利用水凝胶对光-热刺激展现出的非凡响应能力,可以实现其迅速显示和隐藏信息的功能,从而确保信息安全,这为光致变色水凝胶在信息加密领域的应用提供了一种新方法. 展开更多
关键词 stimulus-responsive hydrogel information storage information security
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Realizing high thermoelectric performance for p-type SiGe in medium temperature region via TaC compositing 被引量:2
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作者 Zheng Fan JiSheng Liang +6 位作者 Jun-Liang Chen Ying Peng Huajun Lai Jian Nong Chengyan Liu Wangyang Ding Lei Miao 《Journal of Materiomics》 SCIE CSCD 2023年第5期984-991,共8页
SiGe is recognised as an excellent thermoelectric material with superior mechanical properties and thermal stability in regions with high temperatures.This study explores a novel strategy for coregulating thermoelectr... SiGe is recognised as an excellent thermoelectric material with superior mechanical properties and thermal stability in regions with high temperatures.This study explores a novel strategy for coregulating thermoelectric transport parameters to achieve high thermoelectric properties of p-type SiGe in the mid-temperature region by incorporating nano-TaC into SiGe combined ball milling with spark plasma sintering.By optimizing the amount of TaC in the SiGe matrix,the power factors were significantly increased due to the modulation doping effect based on the work function matching of SiGe with TaC.Simultaneously,the ensemble effect of the nanostructure leads to a significant decrease in thermal conductivity.Thus,a high ZT of 1.06 was accomplished at 873 K,which is 64%higher than that of typical radioisotope thermoelectric generator.Our research offers a novel strategy for expanding and enhancing the thermoelectric properties of SiGe materials in the medium temperature range. 展开更多
关键词 SIGE THERMOELECTRIC Work function matching Modulation doping effect Phonon scattering
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Constructed TiO_(2)/WO_(3)heterojunction with strengthened nano-trees structure for highly stable electrochromic energy storage device 被引量:1
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作者 Lili Zhao Zhuoan Cai +7 位作者 Xiaoyang Wang Wenbo Liao Simin Huang Lingyun Ye Jilie Fang Chunxing Wu Hao Qiu Lei Miao 《Journal of Advanced Ceramics》 SCIE EI CAS CSCD 2023年第3期634-648,共15页
Tungsten trioxide(WO_(3))has been widely regarded as a prospective bifunctional material due to its electrochromic and pseudocapacitive properties,while still facing the dilemma of inadequate cycle stability and trapp... Tungsten trioxide(WO_(3))has been widely regarded as a prospective bifunctional material due to its electrochromic and pseudocapacitive properties,while still facing the dilemma of inadequate cycle stability and trapping-induced degradation.Here,inspired by the trees-strengthening approach,a unique titanium dioxide(TiO_(2))nanorod arrays strengthened WO_(3)nano-trees(TWNTs)heterojunction was rationally designed and constructed.In sharp contrast to the transmittance modulation(ΔT)attenuation of primary WO_(3)nano-trees during cycling,the TWNTs film showed not only excellent electrochromic performance but also fascinating cycle stability(77.35%retention of the initialΔT after 10,000 cycles).Besides,the trapping-induced degradation could be easily rejuvenated by a potentiostatic de-trapping process.An electrochromic energy storage device(EESD)was further assembled based on the TWNTs film to deliver excellentΔT(up to 79.5%at 633 nm),fast switching speed(tc/tb=1.9 s/14.8 s),extremely high coloration efficiency value(443.4 cm^(2)·C^(−1)),and long-term cycle stability(over 10,000 charge/discharge cycles).This innovative study provided in-depth insights into the electrochromism nature and a significant step in the realization of stable electrochromic-energy storage application,paving the way for multifunctional smart windows as well as next-generation optoelectronic devices. 展开更多
关键词 electrochromic(EC) WO_(3)nano-trees cycle stability TiO_(2)nanorod arrays(TiO_(2)NRAs) energy storage
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通过5-氨基-4-甲酰基咪唑盐酸盐提高可印刷介观钙钛矿太阳能电池的光伏性能
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作者 郭荣荣 张声建 +11 位作者 陈怡文 王栋杰 吴晨术 王陇博 陶莹 朱稳定 张浩华 陈长青 熊健 张哲泠 黄瑜 张坚 《Science China Materials》 SCIE EI CAS CSCD 2023年第12期4622-4629,共8页
基于m-TiO_(2)/m-ZrO_(2)/C的无空穴可印刷介观钙钛矿太阳能电池(p-MPSCs)具有成本低廉、操作简便和稳定性优异的特点,被认为是最具商业应用潜力的新型光伏器件之一.然而,与传统PSC相比,p-MPSCs的开路电压(VOC)损失较大,导致能量转换效... 基于m-TiO_(2)/m-ZrO_(2)/C的无空穴可印刷介观钙钛矿太阳能电池(p-MPSCs)具有成本低廉、操作简便和稳定性优异的特点,被认为是最具商业应用潜力的新型光伏器件之一.然而,与传统PSC相比,p-MPSCs的开路电压(VOC)损失较大,导致能量转换效率(PCE)与传统PSC存在差距.在此,我们提出了一种利用5-氨基-4甲酰胺咪唑盐酸盐(AICA)提升p-MPSCs开路电压的方法.AICA不仅可以调节钙钛矿膜的功函数,其酰胺基团和氨基还能分别钝化钙钛矿中未配位的Pb2+和I−缺陷,稳定钙钛矿的结构,形成高质量钙钛矿薄膜,从而抑制缺陷诱导的非辐射复合.因此,引入AICA后p-MPSCs获得了16.68%的PCE,并且VOC从0.88提升至0.98 V. 展开更多
关键词 mesoscopic perovskite solar cells ADDITIVES opencircuit voltage defect passivation
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Development of thermodynamic database of the Mn-RE(RE=rare earth metals)binary systems
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作者 Hongjian Ye Jiang Wang +2 位作者 Qing Chen Guanghui Rao Huaiying Zhou 《Materials Genome Engineering Advances》 2024年第2期53-82,共30页
In this work,eight Mn-RE(RE=Ce,Pr,Sm,Tb,Er,Tm,Lu,and Y)binary systems were reassessed thermodynamically by the CALPHAD method based on the reported optimizations and experimental information.Self-consistent thermodyna... In this work,eight Mn-RE(RE=Ce,Pr,Sm,Tb,Er,Tm,Lu,and Y)binary systems were reassessed thermodynamically by the CALPHAD method based on the reported optimizations and experimental information.Self-consistent thermodynamic parameters to describe Gibbs energies of various phases in eight Mn-RE binary systems were obtained.The calculated phase equilibria and thermodynamic properties of eight Mn-RE binary systems are in good accor-dance with the experimental results.Furthermore,phase equilibria and ther-modynamic properties of 13 Mn-RE(RE=La,Ce,Pr,Nd,Sm,Gd,Tb,Dy,Ho,Er,Tm,Lu,and Y)binary systems were discussed systematically in combination with the present calculations and the reported optimizations.A trend was found for the variation of phase equilibria and thermodynamic properties of the Mn-RE binary systems.In general,as the RE atomic number increases,the enthalpies of mixing of liquid alloys as well as the enthalpies of formation of the intermetallic compounds become increasingly negative,and the formation temperatures of the intermetallic compounds become higher.The results provide a complete set of self-consistent thermodynamic parameters for the Mn-RE binary systems,and a thermodynamic database of 13 Mn-RE binary systems was finally achieved. 展开更多
关键词 Mn-RE binary systems phase equilibria thermodynamic
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