A novel type of A-type nanogrids(AGs)with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives,yielding 9%-30%.Additionally,the effect of ster...A novel type of A-type nanogrids(AGs)with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives,yielding 9%-30%.Additionally,the effect of stereoisomers of 1,1'-binaphthyl difluorenols(BINDFOH)was investigated to demonstrate that R/S-BINDFOH is more advantageous for the synthesis of AGs than Mix-BINDFOH.Furthermore,tests on OFET memory devices showed that AGs have a larger storage window,indicating potential for data storage applications.展开更多
基金supported by the National Natural Science Foundation of China(22071112 and 22275098)the Project of State Key Laboratory of Organic Electronics and Information Displays,Nanjing University of Posts and Telecommunications(GDX2022010005 and GZR2022010011).
文摘A novel type of A-type nanogrids(AGs)with axial and central chirality was synthesized via Friedel-Crafts gridization of thiophenes and difluorenyl biaromatic derivatives,yielding 9%-30%.Additionally,the effect of stereoisomers of 1,1'-binaphthyl difluorenols(BINDFOH)was investigated to demonstrate that R/S-BINDFOH is more advantageous for the synthesis of AGs than Mix-BINDFOH.Furthermore,tests on OFET memory devices showed that AGs have a larger storage window,indicating potential for data storage applications.
