The presence of discontinuities(e.g.faults,fractures,veins,layering)in crystalline rocks can be challenging for seismic interpretations because the wide range of their size,orientation,and intensity,which controls the...The presence of discontinuities(e.g.faults,fractures,veins,layering)in crystalline rocks can be challenging for seismic interpretations because the wide range of their size,orientation,and intensity,which controls the mechanical properties of the rock and elastic wave propagation,resulting in equally varying seismic responses at different scales.The geometrical characterisation of adjacent outcrop discontinuity networks allows a better understanding of the nature of the subsurface rocks and aids seismic interpretation.In this study,we characterise the discontinuity network of the Balmuccia peridotite(BP)in the IvreaeVerbano Zone(IVZ),northwestern Italy.This geological body is the focus of the Drilling the Ivrea eVerbano zonE(DIVE),an international continental scientific drilling project,and two active seismic surveys,SEismic imaging of the Ivrea ZonE(SEIZE)and high-resolution SEIZE(Hi-SEIZE),which aim to resolve the subsurface structure of the DIVE drilling target through high-resolution seismic imaging.For fracture characterisation,we developed two drone-based digital outcrop models(DOMs)at two different resolutions(10^(-3)-10 m and 10^(-1)-10^(3)m),which allowed us to quantitatively characterise the orientation,size,and intensity of the main rock discontinuities.These properties affect the seismic velocity and consequently the interpretation of the seismic data.We found that(i)the outcropping BP discontinuity network is represented by three more sets of fractures with respect to those reported in the literature;(ii)the discontinuity sizes follow a power-law distribution,indicating similarity across scales,and(iii)discontinuity intensity is not uniformly distributed along the outcrop.Our results help to explain the seismic behaviour of the BP detected by the SEIZE survey,suggesting that the low P-wave velocities observed can be related to the discontinuity network,and provide the basic topological parameters(orientation,density,distribution,and aperture)of the fracture network unique to the BP.These,in turn,can be used for interpretation of the Hi-SEIZE seismic survey and forward modelling of the seismic response.展开更多
Development and production from fractured reservoirs require extensive knowledge about the reservoir structures and in situ stress regimes.For this,this paper investigates fractures and the parameters(aperture and den...Development and production from fractured reservoirs require extensive knowledge about the reservoir structures and in situ stress regimes.For this,this paper investigates fractures and the parameters(aperture and density)through a combination of wellbore data and geomechanical laboratory testing in three separate wells in the Asmari reservoir,Zagros Belt,Iran.The Asmari reservoir(Oligo-Miocene)consists mainly of calcitic and dolomitic rocks in depths of 2000e3000 m.Based on the observation of features in several wellbores,the orientation and magnitude of the in situ stresses along with their influence on reservoir-scale geological structures and neotectonics were determined.The study identifies two regional tectonic fracture settings in the reservoir:one set associated with longitudinal and diagonal wrinkling,and the other related to faulting.The former,which is mainly of open fractures with a large aperture,is dominant and generally oriented in the N45°-90°W direction while the latter is obliquely oriented relative to the bedding and characterized by N45°-90°E.The largest aperture is found in open fractures that are longitudinal and developed in the dolomitic zones within a complex stress regime.Moreover,analysis of drilling-induced fractures(DIFs)and borehole breakouts(BBs)from the image logs revealed that the maximum horizontal stress(SHmax)orientation in these three wells is consistent with the NE-SW regional trend of the SHmax(maximum principal horizontal stress)in the Zagros Belt.Likewise,the stress magnitude obtained from geomechanical testing and poroelastic equations confirmed a variation in stress regime from normal to reverse,which changes in regard to active faults in the study area.Finally,a relationship between the development degree of open fractures and in situ stress regime was found.This means that in areas where the stress regime is complex and reverse,fractures would exhibit higher density,dip angle,and larger apertures.展开更多
The Atlantic Meridional Overturning Circulation(AMOC)is a crucial component of the Earth’s climate system due to its fundamental role in heat distribution,carbon and oxygen transport,and the weather.Other climate com...The Atlantic Meridional Overturning Circulation(AMOC)is a crucial component of the Earth’s climate system due to its fundamental role in heat distribution,carbon and oxygen transport,and the weather.Other climate components,such as the atmosphere and sea ice,influence the AMOC.Evaluating the physical mechanisms of those interactions is paramount to increasing knowledge about AMOC’s functioning.In this study,the authors used outputs from the Community Earth System Model version 2 and observational data to investigate changes in theAMOC and the associated physical processes.Two DECK experiments were evaluated:piControl and 1pctCO_(2),with an annual increase of 1%of atmospheric CO_(2).The analysis revealed a significant decrease in the AMOC,associated with changes in mixed layer depth and buoyancy in high latitudes of the North Atlantic,resulting in the shutdown of deep convection and potentially affecting the formation of North Atlantic Deep Water and Antarctic Bottom Water.A vital aspect observed in this study is the association between increased runoff and reduced water evaporation,giving rise to a positive feedback process.Consequently,the rates of freshwater spreading have intensified during this period,which could lead to an accelerated disruption of the AMOC beyond the projections of existing models.展开更多
Understanding the nature of parental melts for pyroxenite veins in supra-subduction zone(SSZ)ophiolites provides vibrant constraints on melt infiltration processes operating in subduction zones.The Zedang ophiolitic m...Understanding the nature of parental melts for pyroxenite veins in supra-subduction zone(SSZ)ophiolites provides vibrant constraints on melt infiltration processes operating in subduction zones.The Zedang ophiolitic massif in the eastern Yarlung–Zangbo suture zone in Tibet consists of mantle peridotites and a crustal section of gabbro,diabase,and basalt.Veins of two pyroxenite varieties cut the southern part of the Zedang massif.These pyroxenite rocks have different geochemical characteristics,where the first variety(type-I)has relatively higher contents of SiO_(2)(51.82–53.08 wt%),MgO(20.08–23.23 wt%),andΣPGE(3.42–13.97 ppb),and lower Al_(2)O_(3)(1.59–2.28 wt%)andΣREE(1.63–2.94 ppm).The second pyroxenite variety(type-II)is characterized by SiO_(2)(45.44–49.61 wt%),Mg O(16.68–19.78 wt%),Al_(2)O_(3)(4.24–8.77 wt%),ΣPGE(14.46–322.06 ppb),andΣREE(5.82–7.44 ppm).Pyroxenite type-I shows N-MORB-like chondritenormalized REE patterns.Zircon U-Pb ages of pyroxenite type-I(194±10 Ma),associated ophiolitic gabbro(135.3±2.0 Ma),and plagiogranite(124.2±2.3 Ma)evidently imply episodic evolution of the Zedang ophiolites.The mineralogical and geochemical characteristics of the investigated pyroxenites can be explained by subduction-initiated hydrous melting of metasomatized sub-arc mantle,later overprinted by sub-slab mantle melting triggered by upwelling asthenosphere during the Jurassic–Early Cretaceous times.The geochemical variations in pyroxenite vein composition,coupled with age differences amongst the other ophiolite units,may correspond to intermittent emplacement of pyroxenite dikes and isotropic gabbroic intrusions where the geodynamic setting progressed from arc maturation and slab rollback to slab tearing and delamination.展开更多
Hydraulic fracturing facilitates the development and exploitation of unconventional reservoirs.In this study,the injected hydraulic fracturing fluid(HFF)and flowback and produced water(FPW)in tight oil reservoirs of t...Hydraulic fracturing facilitates the development and exploitation of unconventional reservoirs.In this study,the injected hydraulic fracturing fluid(HFF)and flowback and produced water(FPW)in tight oil reservoirs of the Lucaogou Formation in the Junggar Basin are temporally sampled from day 1 to day 64.Freshwater is used for fracturing,and HFF is obtained.The chemical and isotopic parameters(including the water type,total salinity,total dissolved solids(TDS),pH,concentrations of Na^(+),Cl^(-),Ba^(+),K^(+),Fe^(2+)+Fe^(3+),and CO_(3)^(2-),dD,and δ^(18)O)are experimentally obtained,and their variations with time are systematically analyzed based on the flowback water.The results show that the water type,Na/Cl ratio,total salinity,and TDS of the FPW change periodically primarily due to the HFF mixing with formation water,thus causing δD and δ^(18)O to deviate from the meteoric water line of Xinjiang.Because of watererock interaction(WRI),the concentrations of Fe^(2+)+Fe^(3+)and CO_(3)^(2-)of the FPW increase over time,with the solution pH becoming more alkaline.Furthermore,based on the significant changes observed in the geochemistry of the FPW,three separate time intervals of flowback time are identified:Stage Ⅰ(<10 days),where the FPW is dominated by the HFF and the changes in ions and isotopes are mainly caused by the WRI;Stage Ⅱ(10-37 days),where the FPW is dominated by the addition of formation water to the HFF and the WRI is weakened;and finally,Stage Ⅲ(>37 days),where the FPW is dominated by the chemistry of the formation water.The methodology implemented in this study can provide critical support for the source identification of formation water.展开更多
Some problems of groundwater development in the Niger Delta ranging from negligence to geological peculiarities are examined to highlight the importance and application of geologic knowledge and research for decision ...Some problems of groundwater development in the Niger Delta ranging from negligence to geological peculiarities are examined to highlight the importance and application of geologic knowledge and research for decision making and averting failure in groundwater development for provisional use. Although the geology and hydrogeologic properties of the aquifer system in the Niger Delta immensely favors groundwater development, there are several recorded cases of failed groundwater development projects poor water quality, dry boreholes and boreholes with surprisingly low yield which could have been avoided. This is due to the perception that since groundwater is prolific, geologic and locational peculiarities can be ignored. This research has highlighted the importance of the knowledge of the hydrogeology of the different geologic units as significant factor in the success of groundwater projects through the correlation of past research of geologic units and groundwater potentials, quality and challenges with the present projects implemented in some of the locations. Cases where groundwater projects are executed with wrong exploration options and without consideration of the peculiarity of the geologic units of the project area, including engagement of incompetent contractors, and negligence to the existing regulatory framework for groundwater development in Nigeria are presented. In order to promote sustainable groundwater development and management in the Niger Delta, this research highlights and recommends the pragmatic use of geologic information including various technical, institutional, regulatory and management measures which have the capacity to avert challenges in groundwater development for provisional use.展开更多
Modification signs in extreme weather events may be directly related to alterations in the thermodynamic panorama of the atmosphere that need to be better understood. This study aimed to make a first interconnection b...Modification signs in extreme weather events may be directly related to alterations in the thermodynamic panorama of the atmosphere that need to be better understood. This study aimed to make a first interconnection between climate extremes and thermodynamic patterns in the city of Rio de Janeiro. Maximum and minimum air temperature and precipitation extreme indices from two surface meteorological stations (ABOV and STCZ) and instability indices based on temperature and humidity from radiosonde observations (SBGL) were employed to investigate changes in the periods 1964-1980 (P1), 1981-2000 (P2), and 2001-2020 (P3). Statistical tests were adopted to determine the significance and magnitude of trends. The frequency of warm (cold) days and warm (cold) nights are increasing (decreasing) in the city. Cold (Warm) extremes are changing with greater magnitude in ABOV (STCZ) than in STCZ (ABOV). In ABOV, there is a significant increase of +84 mm/decade in the rainfall volume associated with severe precipitation (above the 95<sup>th</sup> percentile) and most extreme precipitation indices show an increase in frequency and intensity. In STCZ, there is a decrease in extreme precipitation until the 1990s, and from there, an increase, showing a wetter climate in the most recent years. It is also verified in SBGL that there is a statistically significant increase (decrease) in air temperature of +0.1°C/decade (-0.2°C/decade) and relative humidity of +1.2%/decade (-3%/decade) at the low and middle (high) troposphere. There is a visible rising trend in most of the evaluated instability indices over the last few decades. The increasing trends of some extreme precipitation indices are probably allied to the precipitable water increasing trend of +1.2 mm/decade.展开更多
The Plio-Quaternary deformation pattern of the northern Aegean and south Balkan regions is interpreted as an effect of the interaction between the Anatolian-Aegean-Pelagonian system (Tethyan belt), undergoing westward...The Plio-Quaternary deformation pattern of the northern Aegean and south Balkan regions is interpreted as an effect of the interaction between the Anatolian-Aegean-Pelagonian system (Tethyan belt), undergoing westward extrusion and strong deformation, and the surrounding plates (Nubia, Europe and Adriatic). Since the middle-late Miocene, the collision of the Tethyan belt with the continental Adriatic domain has caused strong E-W shortening in the outer Hellenides and Albanides, also involving the southward extrusion of the Peloponnesus wedge, at the expense of the Ionian oceanic domain. The roughly E-W extension recognized in the western South Balkan zones (Macedonia and eastern Albania) is related to the divergence between the Pelagonian belt (Albanides and Hellenides) and the Rhodope-Moesia domain. Stressed by the westward displacement of the central Anatolian plateau and by the southward bowing of the Cycladic Arc, the northern Aegean zone has contemporaneously undergone E-W compression and N-S extension, which has generated a series of dextral shear faults, delimiting a number of slats. The westward displacement and deformation of such slats can explain the morphological features of the northern Aegean zone. During this phase, the push of the central Anatolian plateau also caused the separation of the Rhodope massif from the Moesian European domain, with the consequent formation of the upper Thrace basin. This hypothesis can explain the Plio-Quaternary compressional deformations recognized in a sector of the North Anatolian fault system, the Ganos-Gelibolu zone. The proposed geodynamic/tectonic interpretation may help to explain some features of the time-space distribution of major earthquakes in the study area.展开更多
Sand excavations in river beds have compromised the safety of several bridges in recent years. Large scale sand mining from river beds is now common in the Niger Delta, due to the necessity of reclaiming land for deve...Sand excavations in river beds have compromised the safety of several bridges in recent years. Large scale sand mining from river beds is now common in the Niger Delta, due to the necessity of reclaiming land for development purposes and to meet construction needs in the region. There is currently no regulation as to where sand can be mined in river channels because of the lack of adequate understanding of the risks to coastal infrastructure involved with its abstraction. The phenomenon of bridge Abutment and bank failure induced by excessive dredging of sand river bed is considered. Two types of instability were distinguished, one relating to the equilibrium slope of the riverbed and the other riverbank instability. An empirical relationship in the form X<sub>s</sub> = 3Htan(90 - α) has been developed through analysis, supported by examples that a minimum distance of 94 m (for sand river beds) from a bridge should be observed for sand abstraction in order to guaranty the safety of bridge foundation. For clay riverbeds, slightly shorter minimum distances can be considered safe. The study further shows that the capacity of sand borrowing in river channels to generate bank instability is dependent on the composition and stratigraphy beneath the river bed.展开更多
Soil conductivity is responsible for its aggressive behavior to metallic objects either in contact or buried in the ground. Rapid deterioration and eventual rupture of pipelines leading ultimately to crude oil spillag...Soil conductivity is responsible for its aggressive behavior to metallic objects either in contact or buried in the ground. Rapid deterioration and eventual rupture of pipelines leading ultimately to crude oil spillages have been of economic as well as environmental concern. Although many factors contribute to soil resistivity, these relationships have hardly been quantitatively expressed. This paper explores the factors affecting soil resistivity firstly by matching the spatial regional distribution with each of the identified factors of influence, including ground elevation soil type, depth to water table and undrained strength. 183 Vertical Electrical Sounding VES with the ABEM SAS 1000, using Schlumberger electrode configuration were carried out along a pipeline route to generate resistivity distribution across a linear alignment that traverses three geomorphic sub-environments in the Niger Delta Region. The apparent resistivity values averaged over depths of 3 m and 10 m were plotted against the co-ordinates using Surfer-16 and overlaid on Google earth Pro to produce a spatial distribution with enhanced location visibility. The results show that apparent resistivity is influenced by depth to water table with lower values in areas of shallow water table occurrence. Furthermore, it is shown that changes in resistivity below the water table are more due to variation in soil type. Within a soil type above the water table, soil resistivity increases monotonically with depth until the depth of probe extends to a different soil horizon. Results of this study provide guidance as to what ground resistivity to expect in different part of the delta as well as provide valuable information to assess the risks to assets either as a means of prioritizing maintenance or of improving design for new installations in the Niger Delta Region.展开更多
Eclogite lenses in marbles from the Dabie-Sulu ultrahigh-pressure （UHP） terrane are deeply subducted meta-sedimentary rocks. Zircons in these rocks have been used to constrain the ages of prograde and UHP metamorphi...Eclogite lenses in marbles from the Dabie-Sulu ultrahigh-pressure （UHP） terrane are deeply subducted meta-sedimentary rocks. Zircons in these rocks have been used to constrain the ages of prograde and UHP metamorphism during subduction, and later retrograde metamorphism during exhumation. Inherited （detrital） and metamorphic zircons were distinguished on the basis of transmitted light microscopy, cathodoluminescence （CL） imaging, trace element contents and mineral inclusions. The distribution of mineral inclusions combined with CL imaging of the metamorphic zircon make it possible to relate zircon zones （domains） to different metamorphic stages. Domain 1 consists of rounded, oblong and spindly cores with dark-luminescent images, and contains quartz eclogite facies mineral inclusion assemblages, indicating formation under high-pressure （HP） metamorphic conditions of T = 571-668℃ and P =1.7-2.02 GPa. Domain 2 always surrounds domain 1 or occurs as rounded and spindly cores with white-luminescent images. It contains coesite eclogite facies mineral inclusion assemblages, indicating formation under UHP metamorphic conditions of T = 782-849℃ and P 〉 5.5 GPa. Domain 3, with gray-luminescent images, always surrounds domain 2 and occurs as the outermost zircon rim. It is characterized by low-pressure mineral inclusion assemblages, which are related to regional amphibolite facies retrograde metamorphism of T = 600- 710℃ and P = 0.7-1.2 GPa. The three metamorphic zircon domains have distinct ages; sample H1 from the Dabie terrane yielded SHRIMP ages of 245 ± 4 Ma for domain 1, 235 ± 3 Ma for domain 2 and 215± 6 Ma for domain 3, whereas sample H2 from the Sulu terrane yielded similar ages of 244 ± 4 Ma, 233 ± 4 Ma and 214 ± 5 Ma for Domains 1, 2 and 3, respectively. The mean ages of these zones suggest that subduction to UHP depths took place over 10-11 Ma and exhumation of the rocks occurred over a period of 19-20 Ma. Thus, subduction from - 55 km to 〉 160 km deep mantle depth took place at rates of approximately 9.5-10.5 km/Ma and exhumation from depths 〉160 km to the base of the crust at -30 km occurred at approximately 6.5 km/Ma. We propose a model for these rocks involving deep subduction of continental margin lithosphere followed by ultrafast exhumation driven by buoyancy forces after break-off of the UHP slab deep within the mantle.展开更多
In deep mineral exploration, the acquisition of audio magnetotelluric （AMT） data is severely affected by ambient noise near the observation sites; This near-field noise restricts investigation depths. Mathematical m...In deep mineral exploration, the acquisition of audio magnetotelluric （AMT） data is severely affected by ambient noise near the observation sites; This near-field noise restricts investigation depths. Mathematical morphological filtering （MMF） proved effective in suppressing large-scale strong and variably shaped noise, typically low-frequency noise, but can not deal with pulse noise of AMT data. We combine compressive sensing and MMF. First we use MMF to suppress the large-scale strong ambient noise; second, we use the improved orthogonal match pursuit （IOMP） algorithm to remove the residual pulse noise. To remove the noise and protect the useful AMT signal, a redundant dictionary that matches with spikes and is insensitive to the useful signal is designed. Synthetic and field data from the Luzong field suggest that the proposed method suppresses the near-source noise and preserves the signal well; thus, better results are obtained that improve the output of either MMF or IOMP.展开更多
Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to ...Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to reddish–orange to colorless. The grains are all 100–300 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm-1 and 1333 cm-1, mostly at 1331.51 cm-1 or 1326.96 cm-1. This investigation extends the occurrence of diamond and moissanite to the Bulqiza chromitites in the Eastern Mirdita Ophiolite. Integration of the mineralogical, petrological and geochemical data of the Bulqiza chromitites suggests their multi–stage formation. Magnesiochromite grains and perhaps small bodies of chromitite formed at various depths in the upper mantle, and encapsulated the ultra–high pressure, highly reduced and crustal minerals. Some oceanic crustal slabs containing the magnesiochromite and their inclusion were later trapped in suprasubduction zones, where they were modified by tholeiitic and boninitic arc magmas, thus changing the magnesiochromite compositions and depositing chromitite ores in melt channels.展开更多
The Early Paleozoic evolution of the northern margin of Gondwana is characterized by several episodes of bimodal magmatism intruded or outpoured within thick sedimentary basins. These processes are well recorded in th...The Early Paleozoic evolution of the northern margin of Gondwana is characterized by several episodes of bimodal magmatism intruded or outpoured within thick sedimentary basins. These processes are well recorded in the Variscan blocks incorporated in the Ligurian Alps because they experienced low temperature Alpine metamorphism. During the Paleozoic, these blocks, together with the other Alpine basements, were placed between the Corsica-Sardinia and the Bohemian Massif along the northern margin of Gondwana. In this framework, they host several a variegated lithostratigraphy forming two main complexes(Complexs I and II) that can be distinguished by both the protoliths and their crosscutting relationships, which indicate that the acidic and mafic intrusives of Complex II cut an already folded sequence made of sediments, basalts and granitoids of Complex I. Both complexes were involved in the Variscan orogenic phases as highlighted by the pervasive eclogite-amphibolite facies schistosity(foliation II). However, rare relicts of a metamorphic foliation at amphibolite facies conditions(foliation I)is locally preserved only in the rocks of Complex I. It is debatable if this schistosity was produced during the early folding event e occurred between the emplacement of Complex I and II e rather than during an early stage of the Variscan metamorphic cycle.New SHRIMP and LA ICP-MS Ue Pb zircon dating integrated with literature data, provide emplacement ages of the several volcanic or intrusive bodies of both complexes. The igneous activity of Complex I is dated between 507 ± 15 Ma and 494 ± 5 Ma, while Complex II between 467 ± 12 Ma and 445.5 ± 12 Ma.The folding event recorded only by the Complex I should therefore have occurred between 494 ± 5 Ma and 467 ± 12 Ma. The Variscan eclogite-amphibolite facies metamorphism is instead constrained between ~420 Ma and ~300 Ma. These ages and the geochemical signature of these rocks allow constraining the Early Paleozoic tectono-magmatic evolution of the Ligurian blocks, from a middleeupper Cambrian rifting stage, through the formation of an Early Ordovician volcanic arc during the Rheic Ocean subduction, until a Late Ordovician extension related to the arc collapse and subsequent rifting of the PaleoThetys. Furthermore, the ~420-350 Ma ages from zircon rims testify to thermal perturbations that may be associated with the Silurian rifting-related magmatism, followed by the subduction-collisional phases of the Variscan orogeny.展开更多
This paper presents preliminary results of three-dimensional thermomechanical finite-element models of a parameter study to compute the current temperature and stress distribution in the subduction zone of the central...This paper presents preliminary results of three-dimensional thermomechanical finite-element models of a parameter study to compute the current temperature and stress distribution in the subduction zone of the central Andes （16°S-26°S） up to a depth of 400 km, the bottom of the asthenosphere. For this purpose a simulation running over c. 50,000 years will be realized based on the geometry of a generic subduction zone and an elasto-viscoplastic Drucker-Prager rheology. The kinematic and thermal boundary conditions as well as the rheological parameters represent the current state of the study area. In future works the model will be refined using a systematic study of physical parameters in order to estimate the influence of the main parameters （e.g. viscosity, fault friction, velocity, shear heating） on the results of the reference model presented here. The reference model is kept as simple as possible to be able to estimate the influence of the parameters in future studies in the best possible way, whilst minimizing comnutational time.展开更多
The spatial occurrence of iron in kaolinite of coal measures west of Beijing was studied by using the Mossbauer spectroscopy technique and a step-by-step method of fitting. The results show that there are three kinds ...The spatial occurrence of iron in kaolinite of coal measures west of Beijing was studied by using the Mossbauer spectroscopy technique and a step-by-step method of fitting. The results show that there are three kinds of spatial occurrence in kaolinites： tetra-coordination Fe（3＋） in Si-O tetrahedrons, sexa-coordination Fe（3＋） in A1--O octahedrons and sexa-coordination Fe（2＋） in A1-O octahedrons, respectively occupying 51.72 %, 37.25 % and 11.03 %, Neither foreign matter of magnetic Fe mineral nor superparamagnetic goethite exists in kaolin concentrates. Fe in kaolin concentrates cannot be removed by conventional methods, which is significant for both theoretical research on kaolinite minerology and practical use of the kaolinites of coal measures west of Beijing.The research also illustrates that the Mossbauer spectroscopy is an effective method in studying the micro-superfine Fe in kaolin.展开更多
The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime.Volcanism produced a wide range ...The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime.Volcanism produced a wide range of intermediate-silicic magmas including medium-to high-K calc-alkaline andesites,dacites,and rhyolites.A thick late Palaeozoic succession is well exposed in the four most representative Sardinian continental basins(Nurra,Perdasdefogu,Escalaplano,and Seui-Seulo),and contains substantial stratigraphic,geochemical,and geochronological evidence of the area's complex geological evolution from the latest Carboniferous to the beginning of the Triassic.Based on major and trace element data and LA-ICP-MS U-Pb zircon dating,it is possible to reconstruct the timing of postVariscan volcanism.This volcanism records active tectonism between the latest Carboniferous and Permian,and post-dates the unroofing and erosion of nappes in this segment of the southern Variscides.In particular,igneous zircon grains from calc-alkaline silicic volcanic rocks yielded ages between299±1 and 288±3 Ma,thereby constraining the development of continental strike-slip faulting from south(Escalaplano Basin)to north(Nurra Basin).Notably,andesites emplaced in medium-grade metamorphic basement(Mt.Cobingius,Ogliastra)show a cluster of older ages at 332±12 Ma.Despite the large uncertainty,this age constrains the onset of igneous activity in the mid-crust.These new radiometric ages constitute:(1)a consistent dataset for different volcanic events;(2)a precise chronostratigraphic constraint which fits well with the biostratigraphic data and(3)insights into the plate reorganization between Laurussia and Gondwana during the late Palaeozoic evolution of the Variscan chain.展开更多
Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM+ images were used for th...Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM+ images were used for this study. Digital elevation models derived from ASTER GDEM and SRTM were also utilized. Visible, infrared and thermal infrared channels were utilized in order to get accurate glacier change maps. Three methods were tried to map this debris-covered glacier in this research. The glacier has been mapped successfully and the changes in the glacier terminus from 1978 to 2011 have been calculated. Manual, semi-automatic and thermal methods were found to give similar results. It was found that the glacier has undergone serious ablation during this period despite of the fact that many of the larger glaciers in the Hindu Kush and Karakoram mountain regions in the Upper Indus Basin were reported to be expanding. The terminus has been moved back about 600 meters during this period and there was an abrupt change in the glacier terminus during 1990-2002. We propose that debris thickness is not the only factor that influences the glacier ablation but the altitude of the debris-covered glacier as well. Many glaciers in the Karakoram region reported to be expanding were having higher altitudes compared to the study area.展开更多
Four different varieties of charnockitic rocks, with different modes of formation, from the Mesoproterozoic Natal belt are described and new C isotope data presented. Excellent coastal exposures in a number of quarrie...Four different varieties of charnockitic rocks, with different modes of formation, from the Mesoproterozoic Natal belt are described and new C isotope data presented. Excellent coastal exposures in a number of quarries and river sections make this part of the Natal belt a good location for observing charnockitic field relationships. Whereas there has been much debate on genesis of charnockites and the use of the term charnockite, it is generally recognized that the stabilization of orthopyroxene relative to biotite in granitoid rocks is a function of low aH2O （-- high CO2）, high temperature, and composition （especially Fe/（Fe ＋Mg））. From the Natal belt exposures, it is evident that syn-emplacement, magmatic crystallization of charnockite can arise from mantle-derived differentiated melts that are inherently hot and dry （as in the Oribi Gorge granites and Munster enderbite）, as well as from wet granitic melts that have been affected through interaction with dry country rock to produce localized charnockitic marginal facies in plutons （as in the Portobello Granite）. Two varieties of post-emplacement sub-solidus charnock- ites are also evident. These include charnockitic aureoles developed in leucocratic, biotite, garnet granite adjacent to cross-cutting enderbitic veins that are attributed to metamorphic-metasomatic processes （as in the Nicholson＇s Point granite, a part of the Margate Granite Suite）, as well as nebulous, patchy charnocki- tic veins in the Margate Granite that are attributed to anatectic metamorphic processes under low-aH2O fluid conditions during a metamorphic event. These varieties of charnockite show that the required physical conditions of their genesis can be achieved through a number of geological processes, providing some important implications for the classification of charnockites, and for the interpretation of charnock- ite genesis in areas where poor exposure obscures field relationships.展开更多
The Bulqiza ultramafic massif, which is part of the eastern Mirdita ophiolite of northern Albania, is world renowned for its high-Cr chromitite deposits. High-Cr chromitites hosted in the mantle section are the crysta...The Bulqiza ultramafic massif, which is part of the eastern Mirdita ophiolite of northern Albania, is world renowned for its high-Cr chromitite deposits. High-Cr chromitites hosted in the mantle section are the crystallized products of boninitic melts in a supra-subduction zone(SSZ). However,economically important high-Al chromitites are also present in massive dunite of the mantle-crust transition zone(MTZ). Chromian-spinel in the high-Al chromitites and dunites of the MTZ have much lower Cr~# values(100 Cr/(Cr+Al))(47.7-55.1 and 46.5-51.7, respectively) than those in the high-Cr chromitites(78.2-80.4), harzburgites(72.6-77.9) and mantle dunites(79.4-84.3). The chemical differences in these two types of chromitites are reflected in the behaviors of their platinum-group elements(PGE).The high-Cr chromitites are rich in IPGE relative to PPGE with 0.10-0.45 PPGE/IPGE ratios, whereas the high-Al chromitites have relatively higher PPGE/IPGE ratios between 1.20 and 7.80. The calculated melts in equilibrium with the high-Cr chromitites are boninitic-like, and those associated with the high-Al chromitites are MORB-like but with hydrous, oxidized and TiO-poor features. We propose that the coexistence of both types of chromitites in the Bulqiza ultramafic massif may indicates a change in magma composition from MORB-like to boninitic-like in a proto-forearc setting during subduction initiation.展开更多
基金the Swiss National Science Foundation for the grant PP00P2_187199 of project OROG3NY.
文摘The presence of discontinuities(e.g.faults,fractures,veins,layering)in crystalline rocks can be challenging for seismic interpretations because the wide range of their size,orientation,and intensity,which controls the mechanical properties of the rock and elastic wave propagation,resulting in equally varying seismic responses at different scales.The geometrical characterisation of adjacent outcrop discontinuity networks allows a better understanding of the nature of the subsurface rocks and aids seismic interpretation.In this study,we characterise the discontinuity network of the Balmuccia peridotite(BP)in the IvreaeVerbano Zone(IVZ),northwestern Italy.This geological body is the focus of the Drilling the Ivrea eVerbano zonE(DIVE),an international continental scientific drilling project,and two active seismic surveys,SEismic imaging of the Ivrea ZonE(SEIZE)and high-resolution SEIZE(Hi-SEIZE),which aim to resolve the subsurface structure of the DIVE drilling target through high-resolution seismic imaging.For fracture characterisation,we developed two drone-based digital outcrop models(DOMs)at two different resolutions(10^(-3)-10 m and 10^(-1)-10^(3)m),which allowed us to quantitatively characterise the orientation,size,and intensity of the main rock discontinuities.These properties affect the seismic velocity and consequently the interpretation of the seismic data.We found that(i)the outcropping BP discontinuity network is represented by three more sets of fractures with respect to those reported in the literature;(ii)the discontinuity sizes follow a power-law distribution,indicating similarity across scales,and(iii)discontinuity intensity is not uniformly distributed along the outcrop.Our results help to explain the seismic behaviour of the BP detected by the SEIZE survey,suggesting that the low P-wave velocities observed can be related to the discontinuity network,and provide the basic topological parameters(orientation,density,distribution,and aperture)of the fracture network unique to the BP.These,in turn,can be used for interpretation of the Hi-SEIZE seismic survey and forward modelling of the seismic response.
文摘Development and production from fractured reservoirs require extensive knowledge about the reservoir structures and in situ stress regimes.For this,this paper investigates fractures and the parameters(aperture and density)through a combination of wellbore data and geomechanical laboratory testing in three separate wells in the Asmari reservoir,Zagros Belt,Iran.The Asmari reservoir(Oligo-Miocene)consists mainly of calcitic and dolomitic rocks in depths of 2000e3000 m.Based on the observation of features in several wellbores,the orientation and magnitude of the in situ stresses along with their influence on reservoir-scale geological structures and neotectonics were determined.The study identifies two regional tectonic fracture settings in the reservoir:one set associated with longitudinal and diagonal wrinkling,and the other related to faulting.The former,which is mainly of open fractures with a large aperture,is dominant and generally oriented in the N45°-90°W direction while the latter is obliquely oriented relative to the bedding and characterized by N45°-90°E.The largest aperture is found in open fractures that are longitudinal and developed in the dolomitic zones within a complex stress regime.Moreover,analysis of drilling-induced fractures(DIFs)and borehole breakouts(BBs)from the image logs revealed that the maximum horizontal stress(SHmax)orientation in these three wells is consistent with the NE-SW regional trend of the SHmax(maximum principal horizontal stress)in the Zagros Belt.Likewise,the stress magnitude obtained from geomechanical testing and poroelastic equations confirmed a variation in stress regime from normal to reverse,which changes in regard to active faults in the study area.Finally,a relationship between the development degree of open fractures and in situ stress regime was found.This means that in areas where the stress regime is complex and reverse,fractures would exhibit higher density,dip angle,and larger apertures.
基金This work was possible through the financing of PEC-20480 Project between Royal Dutch Shell(Shell)and the Laboratório de Métodos Computacionais em Engenharia(LAMCE)and through the doctoral fellowship funding by CNPq for Elisa Passos Case number 141819/2016-2the postdoctoral fellowship funding by FAPERJ E 10/2020-Edital Inteligência Artificial Case Number E-26/203.327/2022-Enrollment No.Scholarship 2015.08297.7 for Lívia Sancho.
文摘The Atlantic Meridional Overturning Circulation(AMOC)is a crucial component of the Earth’s climate system due to its fundamental role in heat distribution,carbon and oxygen transport,and the weather.Other climate components,such as the atmosphere and sea ice,influence the AMOC.Evaluating the physical mechanisms of those interactions is paramount to increasing knowledge about AMOC’s functioning.In this study,the authors used outputs from the Community Earth System Model version 2 and observational data to investigate changes in theAMOC and the associated physical processes.Two DECK experiments were evaluated:piControl and 1pctCO_(2),with an annual increase of 1%of atmospheric CO_(2).The analysis revealed a significant decrease in the AMOC,associated with changes in mixed layer depth and buoyancy in high latitudes of the North Atlantic,resulting in the shutdown of deep convection and potentially affecting the formation of North Atlantic Deep Water and Antarctic Bottom Water.A vital aspect observed in this study is the association between increased runoff and reduced water evaporation,giving rise to a positive feedback process.Consequently,the rates of freshwater spreading have intensified during this period,which could lead to an accelerated disruption of the AMOC beyond the projections of existing models.
基金co-supported by Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(No.GML2019ZD0201)the Second Tibetan Plateau Scientific Expedition and Research Program(No.2019QZKK0801)+3 种基金the National Natural Science Foundation of China(NNSFCProject Nos.42272048,41720104009,42172069,92062215)the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources Fund(No.J1901-28)the China Geological Survey(CGS,Project Nos.DD20230340,DD20221630)。
文摘Understanding the nature of parental melts for pyroxenite veins in supra-subduction zone(SSZ)ophiolites provides vibrant constraints on melt infiltration processes operating in subduction zones.The Zedang ophiolitic massif in the eastern Yarlung–Zangbo suture zone in Tibet consists of mantle peridotites and a crustal section of gabbro,diabase,and basalt.Veins of two pyroxenite varieties cut the southern part of the Zedang massif.These pyroxenite rocks have different geochemical characteristics,where the first variety(type-I)has relatively higher contents of SiO_(2)(51.82–53.08 wt%),MgO(20.08–23.23 wt%),andΣPGE(3.42–13.97 ppb),and lower Al_(2)O_(3)(1.59–2.28 wt%)andΣREE(1.63–2.94 ppm).The second pyroxenite variety(type-II)is characterized by SiO_(2)(45.44–49.61 wt%),Mg O(16.68–19.78 wt%),Al_(2)O_(3)(4.24–8.77 wt%),ΣPGE(14.46–322.06 ppb),andΣREE(5.82–7.44 ppm).Pyroxenite type-I shows N-MORB-like chondritenormalized REE patterns.Zircon U-Pb ages of pyroxenite type-I(194±10 Ma),associated ophiolitic gabbro(135.3±2.0 Ma),and plagiogranite(124.2±2.3 Ma)evidently imply episodic evolution of the Zedang ophiolites.The mineralogical and geochemical characteristics of the investigated pyroxenites can be explained by subduction-initiated hydrous melting of metasomatized sub-arc mantle,later overprinted by sub-slab mantle melting triggered by upwelling asthenosphere during the Jurassic–Early Cretaceous times.The geochemical variations in pyroxenite vein composition,coupled with age differences amongst the other ophiolite units,may correspond to intermittent emplacement of pyroxenite dikes and isotropic gabbroic intrusions where the geodynamic setting progressed from arc maturation and slab rollback to slab tearing and delamination.
基金supported by the National Natural Science Foundation of China(No.U2003102).
文摘Hydraulic fracturing facilitates the development and exploitation of unconventional reservoirs.In this study,the injected hydraulic fracturing fluid(HFF)and flowback and produced water(FPW)in tight oil reservoirs of the Lucaogou Formation in the Junggar Basin are temporally sampled from day 1 to day 64.Freshwater is used for fracturing,and HFF is obtained.The chemical and isotopic parameters(including the water type,total salinity,total dissolved solids(TDS),pH,concentrations of Na^(+),Cl^(-),Ba^(+),K^(+),Fe^(2+)+Fe^(3+),and CO_(3)^(2-),dD,and δ^(18)O)are experimentally obtained,and their variations with time are systematically analyzed based on the flowback water.The results show that the water type,Na/Cl ratio,total salinity,and TDS of the FPW change periodically primarily due to the HFF mixing with formation water,thus causing δD and δ^(18)O to deviate from the meteoric water line of Xinjiang.Because of watererock interaction(WRI),the concentrations of Fe^(2+)+Fe^(3+)and CO_(3)^(2-)of the FPW increase over time,with the solution pH becoming more alkaline.Furthermore,based on the significant changes observed in the geochemistry of the FPW,three separate time intervals of flowback time are identified:Stage Ⅰ(<10 days),where the FPW is dominated by the HFF and the changes in ions and isotopes are mainly caused by the WRI;Stage Ⅱ(10-37 days),where the FPW is dominated by the addition of formation water to the HFF and the WRI is weakened;and finally,Stage Ⅲ(>37 days),where the FPW is dominated by the chemistry of the formation water.The methodology implemented in this study can provide critical support for the source identification of formation water.
文摘Some problems of groundwater development in the Niger Delta ranging from negligence to geological peculiarities are examined to highlight the importance and application of geologic knowledge and research for decision making and averting failure in groundwater development for provisional use. Although the geology and hydrogeologic properties of the aquifer system in the Niger Delta immensely favors groundwater development, there are several recorded cases of failed groundwater development projects poor water quality, dry boreholes and boreholes with surprisingly low yield which could have been avoided. This is due to the perception that since groundwater is prolific, geologic and locational peculiarities can be ignored. This research has highlighted the importance of the knowledge of the hydrogeology of the different geologic units as significant factor in the success of groundwater projects through the correlation of past research of geologic units and groundwater potentials, quality and challenges with the present projects implemented in some of the locations. Cases where groundwater projects are executed with wrong exploration options and without consideration of the peculiarity of the geologic units of the project area, including engagement of incompetent contractors, and negligence to the existing regulatory framework for groundwater development in Nigeria are presented. In order to promote sustainable groundwater development and management in the Niger Delta, this research highlights and recommends the pragmatic use of geologic information including various technical, institutional, regulatory and management measures which have the capacity to avert challenges in groundwater development for provisional use.
文摘Modification signs in extreme weather events may be directly related to alterations in the thermodynamic panorama of the atmosphere that need to be better understood. This study aimed to make a first interconnection between climate extremes and thermodynamic patterns in the city of Rio de Janeiro. Maximum and minimum air temperature and precipitation extreme indices from two surface meteorological stations (ABOV and STCZ) and instability indices based on temperature and humidity from radiosonde observations (SBGL) were employed to investigate changes in the periods 1964-1980 (P1), 1981-2000 (P2), and 2001-2020 (P3). Statistical tests were adopted to determine the significance and magnitude of trends. The frequency of warm (cold) days and warm (cold) nights are increasing (decreasing) in the city. Cold (Warm) extremes are changing with greater magnitude in ABOV (STCZ) than in STCZ (ABOV). In ABOV, there is a significant increase of +84 mm/decade in the rainfall volume associated with severe precipitation (above the 95<sup>th</sup> percentile) and most extreme precipitation indices show an increase in frequency and intensity. In STCZ, there is a decrease in extreme precipitation until the 1990s, and from there, an increase, showing a wetter climate in the most recent years. It is also verified in SBGL that there is a statistically significant increase (decrease) in air temperature of +0.1°C/decade (-0.2°C/decade) and relative humidity of +1.2%/decade (-3%/decade) at the low and middle (high) troposphere. There is a visible rising trend in most of the evaluated instability indices over the last few decades. The increasing trends of some extreme precipitation indices are probably allied to the precipitable water increasing trend of +1.2 mm/decade.
文摘The Plio-Quaternary deformation pattern of the northern Aegean and south Balkan regions is interpreted as an effect of the interaction between the Anatolian-Aegean-Pelagonian system (Tethyan belt), undergoing westward extrusion and strong deformation, and the surrounding plates (Nubia, Europe and Adriatic). Since the middle-late Miocene, the collision of the Tethyan belt with the continental Adriatic domain has caused strong E-W shortening in the outer Hellenides and Albanides, also involving the southward extrusion of the Peloponnesus wedge, at the expense of the Ionian oceanic domain. The roughly E-W extension recognized in the western South Balkan zones (Macedonia and eastern Albania) is related to the divergence between the Pelagonian belt (Albanides and Hellenides) and the Rhodope-Moesia domain. Stressed by the westward displacement of the central Anatolian plateau and by the southward bowing of the Cycladic Arc, the northern Aegean zone has contemporaneously undergone E-W compression and N-S extension, which has generated a series of dextral shear faults, delimiting a number of slats. The westward displacement and deformation of such slats can explain the morphological features of the northern Aegean zone. During this phase, the push of the central Anatolian plateau also caused the separation of the Rhodope massif from the Moesian European domain, with the consequent formation of the upper Thrace basin. This hypothesis can explain the Plio-Quaternary compressional deformations recognized in a sector of the North Anatolian fault system, the Ganos-Gelibolu zone. The proposed geodynamic/tectonic interpretation may help to explain some features of the time-space distribution of major earthquakes in the study area.
文摘Sand excavations in river beds have compromised the safety of several bridges in recent years. Large scale sand mining from river beds is now common in the Niger Delta, due to the necessity of reclaiming land for development purposes and to meet construction needs in the region. There is currently no regulation as to where sand can be mined in river channels because of the lack of adequate understanding of the risks to coastal infrastructure involved with its abstraction. The phenomenon of bridge Abutment and bank failure induced by excessive dredging of sand river bed is considered. Two types of instability were distinguished, one relating to the equilibrium slope of the riverbed and the other riverbank instability. An empirical relationship in the form X<sub>s</sub> = 3Htan(90 - α) has been developed through analysis, supported by examples that a minimum distance of 94 m (for sand river beds) from a bridge should be observed for sand abstraction in order to guaranty the safety of bridge foundation. For clay riverbeds, slightly shorter minimum distances can be considered safe. The study further shows that the capacity of sand borrowing in river channels to generate bank instability is dependent on the composition and stratigraphy beneath the river bed.
文摘Soil conductivity is responsible for its aggressive behavior to metallic objects either in contact or buried in the ground. Rapid deterioration and eventual rupture of pipelines leading ultimately to crude oil spillages have been of economic as well as environmental concern. Although many factors contribute to soil resistivity, these relationships have hardly been quantitatively expressed. This paper explores the factors affecting soil resistivity firstly by matching the spatial regional distribution with each of the identified factors of influence, including ground elevation soil type, depth to water table and undrained strength. 183 Vertical Electrical Sounding VES with the ABEM SAS 1000, using Schlumberger electrode configuration were carried out along a pipeline route to generate resistivity distribution across a linear alignment that traverses three geomorphic sub-environments in the Niger Delta Region. The apparent resistivity values averaged over depths of 3 m and 10 m were plotted against the co-ordinates using Surfer-16 and overlaid on Google earth Pro to produce a spatial distribution with enhanced location visibility. The results show that apparent resistivity is influenced by depth to water table with lower values in areas of shallow water table occurrence. Furthermore, it is shown that changes in resistivity below the water table are more due to variation in soil type. Within a soil type above the water table, soil resistivity increases monotonically with depth until the depth of probe extends to a different soil horizon. Results of this study provide guidance as to what ground resistivity to expect in different part of the delta as well as provide valuable information to assess the risks to assets either as a means of prioritizing maintenance or of improving design for new installations in the Niger Delta Region.
基金the National 973 Project of Chinese Ministry of Science and Technology （Grant No. 2003CB716502） the Natural Science Foundation of China （Grant No. 40399143） +1 种基金 the German Science Foundation （DFG grant No. GE 1152/2-2 , WE2850/3- 1）.
文摘Eclogite lenses in marbles from the Dabie-Sulu ultrahigh-pressure （UHP） terrane are deeply subducted meta-sedimentary rocks. Zircons in these rocks have been used to constrain the ages of prograde and UHP metamorphism during subduction, and later retrograde metamorphism during exhumation. Inherited （detrital） and metamorphic zircons were distinguished on the basis of transmitted light microscopy, cathodoluminescence （CL） imaging, trace element contents and mineral inclusions. The distribution of mineral inclusions combined with CL imaging of the metamorphic zircon make it possible to relate zircon zones （domains） to different metamorphic stages. Domain 1 consists of rounded, oblong and spindly cores with dark-luminescent images, and contains quartz eclogite facies mineral inclusion assemblages, indicating formation under high-pressure （HP） metamorphic conditions of T = 571-668℃ and P =1.7-2.02 GPa. Domain 2 always surrounds domain 1 or occurs as rounded and spindly cores with white-luminescent images. It contains coesite eclogite facies mineral inclusion assemblages, indicating formation under UHP metamorphic conditions of T = 782-849℃ and P 〉 5.5 GPa. Domain 3, with gray-luminescent images, always surrounds domain 2 and occurs as the outermost zircon rim. It is characterized by low-pressure mineral inclusion assemblages, which are related to regional amphibolite facies retrograde metamorphism of T = 600- 710℃ and P = 0.7-1.2 GPa. The three metamorphic zircon domains have distinct ages; sample H1 from the Dabie terrane yielded SHRIMP ages of 245 ± 4 Ma for domain 1, 235 ± 3 Ma for domain 2 and 215± 6 Ma for domain 3, whereas sample H2 from the Sulu terrane yielded similar ages of 244 ± 4 Ma, 233 ± 4 Ma and 214 ± 5 Ma for Domains 1, 2 and 3, respectively. The mean ages of these zones suggest that subduction to UHP depths took place over 10-11 Ma and exhumation of the rocks occurred over a period of 19-20 Ma. Thus, subduction from - 55 km to 〉 160 km deep mantle depth took place at rates of approximately 9.5-10.5 km/Ma and exhumation from depths 〉160 km to the base of the crust at -30 km occurred at approximately 6.5 km/Ma. We propose a model for these rocks involving deep subduction of continental margin lithosphere followed by ultrafast exhumation driven by buoyancy forces after break-off of the UHP slab deep within the mantle.
基金supported by the National High Technology Research and Development Program of China(No.2014AA06A602)National Natural Science Foundation of China(No.41404111)Natural Science Foundation of Hunan Province(No.2015JJ3088)
文摘In deep mineral exploration, the acquisition of audio magnetotelluric （AMT） data is severely affected by ambient noise near the observation sites; This near-field noise restricts investigation depths. Mathematical morphological filtering （MMF） proved effective in suppressing large-scale strong and variably shaped noise, typically low-frequency noise, but can not deal with pulse noise of AMT data. We combine compressive sensing and MMF. First we use MMF to suppress the large-scale strong ambient noise; second, we use the improved orthogonal match pursuit （IOMP） algorithm to remove the residual pulse noise. To remove the noise and protect the useful AMT signal, a redundant dictionary that matches with spikes and is insensitive to the useful signal is designed. Synthetic and field data from the Luzong field suggest that the proposed method suppresses the near-source noise and preserves the signal well; thus, better results are obtained that improve the output of either MMF or IOMP.
基金funded by grants from the NSF China(Nos.41502062,41672046,41541017,41641015)the China Geological Survey(Nos.DD20160023-01,201511022)+2 种基金National Key Research and Development Project of China(2016YFC0600310)from the Institute of Geology,Chinese Academy of Geological Sciences(J1526)IGCP–649
文摘Various combinations of diamond, moissanite, zircon, corundum, rutile and titanitehave been recovered from the Bulqiza chromitites. More than 10 grains of diamond have been recovered, most of which are pale yellow to reddish–orange to colorless. The grains are all 100–300 μm in size and mostly anhedral, but with a range of morphologies including elongated, octahedral and subhedral varieties. Their identification was confirmed by a characteristic shift in the Raman spectra between 1325 cm-1 and 1333 cm-1, mostly at 1331.51 cm-1 or 1326.96 cm-1. This investigation extends the occurrence of diamond and moissanite to the Bulqiza chromitites in the Eastern Mirdita Ophiolite. Integration of the mineralogical, petrological and geochemical data of the Bulqiza chromitites suggests their multi–stage formation. Magnesiochromite grains and perhaps small bodies of chromitite formed at various depths in the upper mantle, and encapsulated the ultra–high pressure, highly reduced and crustal minerals. Some oceanic crustal slabs containing the magnesiochromite and their inclusion were later trapped in suprasubduction zones, where they were modified by tholeiitic and boninitic arc magmas, thus changing the magnesiochromite compositions and depositing chromitite ores in melt channels.
基金supported by Italian 1:50,000 Geological Mapping (CARGdR egione Liguria Project, University of Pavia grants)
文摘The Early Paleozoic evolution of the northern margin of Gondwana is characterized by several episodes of bimodal magmatism intruded or outpoured within thick sedimentary basins. These processes are well recorded in the Variscan blocks incorporated in the Ligurian Alps because they experienced low temperature Alpine metamorphism. During the Paleozoic, these blocks, together with the other Alpine basements, were placed between the Corsica-Sardinia and the Bohemian Massif along the northern margin of Gondwana. In this framework, they host several a variegated lithostratigraphy forming two main complexes(Complexs I and II) that can be distinguished by both the protoliths and their crosscutting relationships, which indicate that the acidic and mafic intrusives of Complex II cut an already folded sequence made of sediments, basalts and granitoids of Complex I. Both complexes were involved in the Variscan orogenic phases as highlighted by the pervasive eclogite-amphibolite facies schistosity(foliation II). However, rare relicts of a metamorphic foliation at amphibolite facies conditions(foliation I)is locally preserved only in the rocks of Complex I. It is debatable if this schistosity was produced during the early folding event e occurred between the emplacement of Complex I and II e rather than during an early stage of the Variscan metamorphic cycle.New SHRIMP and LA ICP-MS Ue Pb zircon dating integrated with literature data, provide emplacement ages of the several volcanic or intrusive bodies of both complexes. The igneous activity of Complex I is dated between 507 ± 15 Ma and 494 ± 5 Ma, while Complex II between 467 ± 12 Ma and 445.5 ± 12 Ma.The folding event recorded only by the Complex I should therefore have occurred between 494 ± 5 Ma and 467 ± 12 Ma. The Variscan eclogite-amphibolite facies metamorphism is instead constrained between ~420 Ma and ~300 Ma. These ages and the geochemical signature of these rocks allow constraining the Early Paleozoic tectono-magmatic evolution of the Ligurian blocks, from a middleeupper Cambrian rifting stage, through the formation of an Early Ordovician volcanic arc during the Rheic Ocean subduction, until a Late Ordovician extension related to the arc collapse and subsequent rifting of the PaleoThetys. Furthermore, the ~420-350 Ma ages from zircon rims testify to thermal perturbations that may be associated with the Silurian rifting-related magmatism, followed by the subduction-collisional phases of the Variscan orogeny.
文摘This paper presents preliminary results of three-dimensional thermomechanical finite-element models of a parameter study to compute the current temperature and stress distribution in the subduction zone of the central Andes （16°S-26°S） up to a depth of 400 km, the bottom of the asthenosphere. For this purpose a simulation running over c. 50,000 years will be realized based on the geometry of a generic subduction zone and an elasto-viscoplastic Drucker-Prager rheology. The kinematic and thermal boundary conditions as well as the rheological parameters represent the current state of the study area. In future works the model will be refined using a systematic study of physical parameters in order to estimate the influence of the main parameters （e.g. viscosity, fault friction, velocity, shear heating） on the results of the reference model presented here. The reference model is kept as simple as possible to be able to estimate the influence of the parameters in future studies in the best possible way, whilst minimizing comnutational time.
基金Project 3042013 supported by Natural Science Foundation of Beijing
文摘The spatial occurrence of iron in kaolinite of coal measures west of Beijing was studied by using the Mossbauer spectroscopy technique and a step-by-step method of fitting. The results show that there are three kinds of spatial occurrence in kaolinites： tetra-coordination Fe（3＋） in Si-O tetrahedrons, sexa-coordination Fe（3＋） in A1--O octahedrons and sexa-coordination Fe（2＋） in A1-O octahedrons, respectively occupying 51.72 %, 37.25 % and 11.03 %, Neither foreign matter of magnetic Fe mineral nor superparamagnetic goethite exists in kaolin concentrates. Fe in kaolin concentrates cannot be removed by conventional methods, which is significant for both theoretical research on kaolinite minerology and practical use of the kaolinites of coal measures west of Beijing.The research also illustrates that the Mossbauer spectroscopy is an effective method in studying the micro-superfine Fe in kaolin.
基金substantially supported by the University of Genova(PRA 2012 grant to Laura Gaggero)University of Pavia(PRIN 2008 to Ausonio Ronchi)
文摘The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime.Volcanism produced a wide range of intermediate-silicic magmas including medium-to high-K calc-alkaline andesites,dacites,and rhyolites.A thick late Palaeozoic succession is well exposed in the four most representative Sardinian continental basins(Nurra,Perdasdefogu,Escalaplano,and Seui-Seulo),and contains substantial stratigraphic,geochemical,and geochronological evidence of the area's complex geological evolution from the latest Carboniferous to the beginning of the Triassic.Based on major and trace element data and LA-ICP-MS U-Pb zircon dating,it is possible to reconstruct the timing of postVariscan volcanism.This volcanism records active tectonism between the latest Carboniferous and Permian,and post-dates the unroofing and erosion of nappes in this segment of the southern Variscides.In particular,igneous zircon grains from calc-alkaline silicic volcanic rocks yielded ages between299±1 and 288±3 Ma,thereby constraining the development of continental strike-slip faulting from south(Escalaplano Basin)to north(Nurra Basin).Notably,andesites emplaced in medium-grade metamorphic basement(Mt.Cobingius,Ogliastra)show a cluster of older ages at 332±12 Ma.Despite the large uncertainty,this age constrains the onset of igneous activity in the mid-crust.These new radiometric ages constitute:(1)a consistent dataset for different volcanic events;(2)a precise chronostratigraphic constraint which fits well with the biostratigraphic data and(3)insights into the plate reorganization between Laurussia and Gondwana during the late Palaeozoic evolution of the Variscan chain.
基金Rio Grande do Sul State Foundation for Research (FAPERGS), Brazil for financial support
文摘Recent changes occurred in terminus of the debris-covered Bilafond Glacier in the Karakoram Range in the Himalayas, Northern Pakistan was investigated in this research. Landsat MSS, TM and ETM+ images were used for this study. Digital elevation models derived from ASTER GDEM and SRTM were also utilized. Visible, infrared and thermal infrared channels were utilized in order to get accurate glacier change maps. Three methods were tried to map this debris-covered glacier in this research. The glacier has been mapped successfully and the changes in the glacier terminus from 1978 to 2011 have been calculated. Manual, semi-automatic and thermal methods were found to give similar results. It was found that the glacier has undergone serious ablation during this period despite of the fact that many of the larger glaciers in the Hindu Kush and Karakoram mountain regions in the Upper Indus Basin were reported to be expanding. The terminus has been moved back about 600 meters during this period and there was an abrupt change in the glacier terminus during 1990-2002. We propose that debris thickness is not the only factor that influences the glacier ablation but the altitude of the debris-covered glacier as well. Many glaciers in the Karakoram region reported to be expanding were having higher altitudes compared to the study area.
文摘Four different varieties of charnockitic rocks, with different modes of formation, from the Mesoproterozoic Natal belt are described and new C isotope data presented. Excellent coastal exposures in a number of quarries and river sections make this part of the Natal belt a good location for observing charnockitic field relationships. Whereas there has been much debate on genesis of charnockites and the use of the term charnockite, it is generally recognized that the stabilization of orthopyroxene relative to biotite in granitoid rocks is a function of low aH2O （-- high CO2）, high temperature, and composition （especially Fe/（Fe ＋Mg））. From the Natal belt exposures, it is evident that syn-emplacement, magmatic crystallization of charnockite can arise from mantle-derived differentiated melts that are inherently hot and dry （as in the Oribi Gorge granites and Munster enderbite）, as well as from wet granitic melts that have been affected through interaction with dry country rock to produce localized charnockitic marginal facies in plutons （as in the Portobello Granite）. Two varieties of post-emplacement sub-solidus charnock- ites are also evident. These include charnockitic aureoles developed in leucocratic, biotite, garnet granite adjacent to cross-cutting enderbitic veins that are attributed to metamorphic-metasomatic processes （as in the Nicholson＇s Point granite, a part of the Margate Granite Suite）, as well as nebulous, patchy charnocki- tic veins in the Margate Granite that are attributed to anatectic metamorphic processes under low-aH2O fluid conditions during a metamorphic event. These varieties of charnockite show that the required physical conditions of their genesis can be achieved through a number of geological processes, providing some important implications for the classification of charnockites, and for the interpretation of charnock- ite genesis in areas where poor exposure obscures field relationships.
基金financially supported by the National Natural Science Foundation of China (grants No. 41541017, 41641015, 41720104009)the China Geological Survey (grants No. DD20160023-01, 201511022)the Research funding from the Chinese Academy of Geological Sciences (grant No. YYWF201702)
文摘The Bulqiza ultramafic massif, which is part of the eastern Mirdita ophiolite of northern Albania, is world renowned for its high-Cr chromitite deposits. High-Cr chromitites hosted in the mantle section are the crystallized products of boninitic melts in a supra-subduction zone(SSZ). However,economically important high-Al chromitites are also present in massive dunite of the mantle-crust transition zone(MTZ). Chromian-spinel in the high-Al chromitites and dunites of the MTZ have much lower Cr~# values(100 Cr/(Cr+Al))(47.7-55.1 and 46.5-51.7, respectively) than those in the high-Cr chromitites(78.2-80.4), harzburgites(72.6-77.9) and mantle dunites(79.4-84.3). The chemical differences in these two types of chromitites are reflected in the behaviors of their platinum-group elements(PGE).The high-Cr chromitites are rich in IPGE relative to PPGE with 0.10-0.45 PPGE/IPGE ratios, whereas the high-Al chromitites have relatively higher PPGE/IPGE ratios between 1.20 and 7.80. The calculated melts in equilibrium with the high-Cr chromitites are boninitic-like, and those associated with the high-Al chromitites are MORB-like but with hydrous, oxidized and TiO-poor features. We propose that the coexistence of both types of chromitites in the Bulqiza ultramafic massif may indicates a change in magma composition from MORB-like to boninitic-like in a proto-forearc setting during subduction initiation.
