Groundwater is an important source of drinking water.Groundwater pollution severely endangers drinking water safety and sustainable social development.In the case of groundwater pollution,the top priority is to identi...Groundwater is an important source of drinking water.Groundwater pollution severely endangers drinking water safety and sustainable social development.In the case of groundwater pollution,the top priority is to identify pollution sources,and accurate information on pollution sources is the premise of efficient remediation.Then,an appropriate pollution remediation scheme should be developed according to information on pollution sources,site conditions,and economic costs.The methods for identifying pollution sources mainly include geophysical exploration,geochemistry,isotopic tracing,and numerical modeling.Among these identification methods,only the numerical modeling can recognize various information on pollution sources,while other methods can only identify a certain aspect of pollution sources.The remediation technologies of groundwater can be divided into in-situ and ex-situ remediation technologies according to the remediation location.The in-situ remediation technologies enjoy low costs and a wide remediation range,but their remediation performance is prone to be affected by environmental conditions and cause secondary pollution.The ex-situ remediation technologies boast high remediation efficiency,high processing capacity,and high treatment concentration but suffer high costs.Different methods for pollution source identification and remediation technologies are applicable to different conditions.To achieve the expected identification and remediation results,it is feasible to combine several methods and technologies according to the actual hydrogeological conditions of contaminated sites and the nature of pollutants.Additionally,detailed knowledge about the hydrogeological conditions and stratigraphic structure of the contaminated site is the basis of all work regardless of the adopted identification methods or remediation technologies.展开更多
Rock thermal physical properties play a crucial role in understanding deep thermal conditions,modeling the thermal structure of the lithosphere,and discovering the evolutionary history of sedimentary basins.Recent adv...Rock thermal physical properties play a crucial role in understanding deep thermal conditions,modeling the thermal structure of the lithosphere,and discovering the evolutionary history of sedimentary basins.Recent advancements in geothermal exploration,particularly the identification of high-temperature geothermal resources in Datong Basin,Shanxi,China,have opened new possibilities.This study aims to characterize the thermal properties of rocks and explore factors influencing thermal conductivity in basins hosting high-temperature geothermal resources.A total of 70 groups of rock samples were collected from outcrops in and around Datong Basin,Shanxi Province.Thermal property tests were carried out to analyze the rock properties,and the influencing factors of thermal conductivity were studied through experiments at different temperature and water-filled states.The results indicate that the thermal conductivity of rocks in Datong,Shanxi Province,typically ranges from 0.690 W/(m·K)to 6.460 W/(m·K),the thermal diffusion coefficient ranges from 0.441 mm^(2)/s to 2.023 mm^(2)/s,and the specific heat capacity of the rocks ranges from 0.569 KJ/(kg·℃)to 1.117 KJ/(kg·°C).Experimental results reveal the impact of temperature and water saturation on the thermal conductivity of the rock.The thermal conductivity decreases with increasing temperature and rises with high water saturation.A temperature correction formula for the thermal conductivity of different lithologies in the area is proposed through linear fitting.The findings from this study provide essential parameters for the assessment and prediction,development,and utilization of geothermal resources in the region and other basins with typical high-temperature geothermal resource.展开更多
Underground Thermal Energy Storage(UTES)store unstable and non-continuous energy underground,releasing stable heat energy on demand.This effectively improve energy utilization and optimize energy allocation.As UTES te...Underground Thermal Energy Storage(UTES)store unstable and non-continuous energy underground,releasing stable heat energy on demand.This effectively improve energy utilization and optimize energy allocation.As UTES technology advances,accommodating greater depth,higher temperature and multi-energy complementarity,new research challenges emerge.This paper comprehensively provides a systematic summary of the current research status of UTES.It categorized different types of UTES systems,analyzes the applicability of key technologies of UTES,and evaluate their economic and environmental benefits.Moreover,this paper identifies existing issues with UTES,such as injection blockage,wellbore scaling and corrosion,seepage and heat transfer in cracks,etc.It suggests deepening the research on blockage formation mechanism and plugging prevention technology,improving the study of anticorrosive materials and water treatment technology,and enhancing the investigation of reservoir fracture network characterization technology and seepage heat transfer.These recommendations serve as valuable references for promoting the high-quality development of UTES.展开更多
Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the stu...Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the study area, ensure the safety of local crops and the health of local residents, and provide a basis for the subsequent environmental restoration and the prevention and control of environmental pollution. Based on the analysis of the heavy metal concentrations in local soils and crops, the study investigated the spatial distribution, pollution degrees, and potential ecological risks of heavy metals in the farmland of a mining area in the southeastern Nanyang Basin, Henan province, China explored the sources of heavy metals and assessed the health risks caused by crop intake. The results of this study are as follows. The root soils of crops in the study area suffered heavy metal pollution to varying degrees. The degree of heavy metal pollution in maize fields is higher than that in wheat fields, and both types of fields suffer the most severe Cd pollution. Moreover, the root soils of different crops suffer compound pollution.The root soils in the maize fields suffer severe compound pollution at some sampling positions, whose distribution is similar to that of the mining area. Cd poses the highest potential ecological risks among all heavy metals, and the study area mainly suffers low and moderate comprehensive potential ecological risks. The principal component analysis(PCA) shows that the distribution of Zn, Cd, Pb, and As in soils of the study area is mainly affected by anthropogenic factors such as local mining activities;the distribution of Cr and Ni is primarily controlled by the local geological background;the distribution of Hg is mainly affected by local vehicle exhaust emissions, and the distribution of Cu is influenced by both human activities and the geological background. Different cereal crops in the study area are polluted with heavy metals dominated by Cd and Ni to varying degrees, especially wheat. As indicated by the health risk assessment results, the intake of maize in the study area does not pose significant human health risks;however, Cu has high risks to human health, and the compound heavy metal pollution caused by the intake of wheat in the study area poses risks to the health of both adults and children. Overall, the soils and crops in the study area suffer a high degree of heavy metal pollution, for which mining activities may be the main reason.展开更多
Groundwater,as a critical component of the hydrological cycle,is essential for sustainable ecosystem development.To clarify the current status of domestic and overseas research,and to identify hotspots,frontier and fu...Groundwater,as a critical component of the hydrological cycle,is essential for sustainable ecosystem development.To clarify the current status of domestic and overseas research,and to identify hotspots,frontier and future trends of groundwater and ecology research,this study utilizes bibliometric methods and CiteSpace software to examine relevant published articles in the Web of Science(WOS)and CNKI databases from 1978 to 2022.Specifically,this study analyzes(1)the annual number of published papers;(2)research institutions;(3)keywords;and(4)evolution of research hotspots.The findings reveal that the United States,China,and Germany are the top three countries in groundwater and ecology research.International research hotspots mainly focus on microbial ecology,climate change,groundwater-surface water interactions in the hyporheic zone,biodiversity,and submarine groundwater discharge,while domestic research hotspots mainly focus on ecological water conveyance,ecological flow,groundwater development and utilization,groundwater pollution,and groundwater and ecological protection.Both domestic and international research hotspots exhibit interdisciplinary features with diverse research objects and assessment methods.Future research in this area is expected to focus on topics such as contamination,groundwater quality,framework,mechanism,spatial distribution,and dissolved organic matter.Additionally,the study of ecological recharge,ecological flow,ecological protection,water intake and use will continue to be the hot topics domestically.展开更多
Landslide is a serious natural disaster next only to earthquake and flood,which will cause a great threat to people’s lives and property safety.The traditional research of landslide disaster based on experience-drive...Landslide is a serious natural disaster next only to earthquake and flood,which will cause a great threat to people’s lives and property safety.The traditional research of landslide disaster based on experience-driven or statistical model and its assessment results are subjective,difficult to quantify,and no pertinence.As a new research method for landslide susceptibility assessment,machine learning can greatly improve the landslide susceptibility model’s accuracy by constructing statistical models.Taking Western Henan for example,the study selected 16 landslide influencing factors such as topography,geological environment,hydrological conditions,and human activities,and 11 landslide factors with the most significant influence on the landslide were selected by the recursive feature elimination(RFE)method.Five machine learning methods[Support Vector Machines(SVM),Logistic Regression(LR),Random Forest(RF),Extreme Gradient Boosting(XGBoost),and Linear Discriminant Analysis(LDA)]were used to construct the spatial distribution model of landslide susceptibility.The models were evaluated by the receiver operating characteristic curve and statistical index.After analysis and comparison,the XGBoost model(AUC 0.8759)performed the best and was suitable for dealing with regression problems.The model had a high adaptability to landslide data.According to the landslide susceptibility map of the five models,the overall distribution can be observed.The extremely high and high susceptibility areas are distributed in the Funiu Mountain range in the southwest,the Xiaoshan Mountain range in the west,and the Yellow River Basin in the north.These areas have large terrain fluctuations,complicated geological structural environments and frequent human engineering activities.The extremely high and highly prone areas were 12043.3 km^(2)and 3087.45 km^(2),accounting for 47.61%and 12.20%of the total area of the study area,respectively.Our study reflects the distribution of landslide susceptibility in western Henan Province,which provides a scientific basis for regional disaster warning,prediction,and resource protection.The study has important practical significance for subsequent landslide disaster management.展开更多
As typical carbonate geothermal reservoirs with low porosity in northern China,the Jixianian System in the Xiong’an New Area is the main target for geothermal fluid exploration.The Jixianian System comprises the Gaoy...As typical carbonate geothermal reservoirs with low porosity in northern China,the Jixianian System in the Xiong’an New Area is the main target for geothermal fluid exploration.The Jixianian System comprises the Gaoyuzhuang,Yangzhuang,Wumishan,Hongshuizhuang,and Tieling formations.The characteristics,formation periods,and controlling factors of reservoir tectonic fractures have been determined based on analyses of outcrops,cores,thin sections,and image logs.The results show that unfilled fractures account for over 87% and most tectonic fractures are high-angle shear fractures with angles concentrated at 40°to 70°and the fracture porosity increases linearly with an increased fracture aperture.Within the same tectonic setting and stress field,the lithology and layer thickness are the dominant factors governing the development of tectonic fractures,which are the most developed in dolomites and thin layers.Tectonic fractures were most likely formed in regions near faults or areas with larger stress gradients.The tectonic fractures in the carbonate geothermal reservoirs are roughly divided into four sets:NNW-SSE and NNE-SSW oriented‘X’-conjugated shear fractures formed from the Paleozoic to the pre-Yanshanian Movement;NE-SW-oriented shear fractures,formed in episode B of the Yanshanian Movement,occurred at the Early Cretaceous;nearly E-W-oriented tensional fractures formed in the late Yanshanian Movement at the Late Cretaceous to Paleogene,and NEE-SW-oriented shear fractures formed during the Himalayan movement.展开更多
1. Objectives Ophiolites from the oceanic crust are important indicators for identifying tectonic suture zones. Recently, a continuous ophiolite belt was found near the Guola Mountain in the Nujiang tectonic belt. Due...1. Objectives Ophiolites from the oceanic crust are important indicators for identifying tectonic suture zones. Recently, a continuous ophiolite belt was found near the Guola Mountain in the Nujiang tectonic belt. Due to intensive hydrothermal alteration during tectonic evolution, clayey altered ophiolite with special engineering geological characteristics was formed, which has an extremely adverse impact on engineering stability. However, the adverse properties of clayey altered ophiolite are still not well understood in engineering practices(Zhang YS, et al., 2011).展开更多
1,4-dioxane pollution is characterized by its early identification, widespread sources and extensive distribution. The pollutant is highly mobile and persistent in the water environment and is classified as a B2(proba...1,4-dioxane pollution is characterized by its early identification, widespread sources and extensive distribution. The pollutant is highly mobile and persistent in the water environment and is classified as a B2(probable) human carcinogen. After reviewing recent researches on the pollution status,transport and transformation characteristics of 1,4-dioxane in the water environment, as well as the environmental pollution remediation and treatment technologies, and the status of environmental regulation,this paper addresses that the distribution of 1,4-dioxane in water bodies is significantly correlated with chlorinated hydrocarbon pollutants such as 1,1,1-trichloroethane(1,1,1-TCA) and trichloroethylene(TCE).It is noteworthy that 1,4-dioxane often occurs in symbiosis with 1,1,1-TCA and has a similarity contamination plume distribution to 1,1,1-TCA. The natural attenuation of 1,4-dioxane in groundwater environment is weak, but there is a certain degree of biological oxidation attenuation. Current methods for treating 1,4-dioxane pollution mainly include extraction-treatment technology, advanced oxidation treatment technology, modified biological treatment technology and phytoremediation technology, all of which have their limitations in practical application. Currently, there is no environmental regulation available for the 1,4-dioxane pollution worldwide, and no enforceable standard established for defining the health trigger levels of 1,4-dioxane in drinking water. Research on this contaminant in China is generally limited to the site or laboratory scale, and there are no studies on the environmental risk and quality standards for 1,4-dioxane in the water environment.展开更多
The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significa...The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster.展开更多
The effective recovery of water level is a crucial measure of the success of comprehensive groundwater over-exploitation management actions in North China.However,traditional evaluation method do not directly capture ...The effective recovery of water level is a crucial measure of the success of comprehensive groundwater over-exploitation management actions in North China.However,traditional evaluation method do not directly capture the relationship between mining and other equilibrium elements.This study presents an innovative evaluation method to assess the water level recovery resulting from mining reduction based on the relationship between variation in exploitation and recharge.Firstly,the recharge variability of source and sink terms for both the base year and evaluation year is calculated and the coefficient of recharge variationβis introduced,which is then used to calculate the effective mining reduction and solve the water level recovery value caused by the effective mining reduction,and finally the water level recovery contribution by mining reduction is calculated by combining with the actual volume of mining reduction in the evaluation area.This research focuses on Baoding and Shijiazhuang Plain area,which share similar hydrogeological conditions but vary in groundwater exploitation and utilization.As the effect of groundwater level recovery with mining reduction was evaluated in these two areas as case study.In 2018,the results showed an effective water level recovery of 0.17 m and 0.13 m in the shallow groundwater of Shijiazhuang and Baoding Plain areas,respectively.The contributions of recovery from mining reduction were 76%and 57.98%for these two areas,respectively.It was notable that the water level recovery was most prominent in the foothill plain regions.From the evaluation results,it is evident that water level recovery depends not only on the intensity of groundwater mining reduction,but also on its effectiveness.The value of water level recovery alone cannot accurately indicate the intensity of mining reduction,as recharge variation significantly influences water level changes.Therefore,in practice,it is crucial to comprehensively assess the impact of mining reduction on water level recovery by combining the coefficient of recharge variation with the contribution of water level recovery from mining reduction.This integrated approach provide a more reasonable and scientifically supported basis,offering essential data support for groundwater management and conservation.To improve the accuracy and reliability of evaluation results,future work will focus on the standardizing and normalizing raw data processing.展开更多
The source area of the Yellow River(SAYR),located above the Huangheyan hydrological station,is important for ecological preservation and water source conservation in the Yellow River Basin.In this area,the impact of w...The source area of the Yellow River(SAYR),located above the Huangheyan hydrological station,is important for ecological preservation and water source conservation in the Yellow River Basin.In this area,the impact of water conservation projects on the hydrology and the ecological environment is pivotal in protecting water resources and alpine vegetation ecosystems.This study investigates the impact of the Yellow River Source Hydropower Station on the runoff and ecological evolution of the SAYR,along with the underlying mechanism,using extensive datasets encompassing long-term meteorological,hydrological and remote sensing data from various time periods.Results show that,over the long term,precipitation is the primary factor driving runoff variations in the SAYR.Nevertheless,from 1990 to 2020,there is a notably inconsistent relationship between precipitation and runoff.After the completion of the Yellow River Source Hydropower Station in 2001,the water level of Eling Lake experienced and elevation of 2–3 m,leading to a gradual recovery of runoff.In addition,the basin's water balance shifted from a negative to a positive equilibrium,oscillating with changes in lake water levels.Consequently,the overflow zone of the Tangchama alluvial–proluvial fan in the upper reaches of the lakeshore shifted by 500 m,and marsh wetlands expanded by 20.78 km^(2).The increased storage of lakes and groundwater in the SAYR is the key controlling factor for the runoff recovery,changes in the basin's water balance,and enhancements in lakeshore vegetation ecology.Under the geological background of the Qinghai–Tibet Plateau's upliftment and intensified upstream river erosion,the basin experienced a substantial water imbalance due to declining discharge base levels,which is the most critical factor behind runoff attenuation in the SAYR towards the end of the 20th century.The construction of the hydropower station objectively raised the drainage base level of the basin,thereby positively contributing to the preservation of water balance,runoff stability,and the enhancement of swamps and wetlands along the lakeshore.展开更多
The changes of development and utilization of karst groundwater in Sangu Spring Basin have made the original groundwater resource evaluation unable to meet the needs of future economic development.Based on analysis of...The changes of development and utilization of karst groundwater in Sangu Spring Basin have made the original groundwater resource evaluation unable to meet the needs of future economic development.Based on analysis of existing data,combined with the characteristics of supplement,runoff and draining of regional karst groundwater,the Visual Modelflow software was used to build a numerical simulation model of Sangu spring Basin.The amount of karst groundwater resource and groundwater environment of the Basin were evaluated under different exploitation schemes,and the changes of karst groundwater environment in the future ten years were also predicted.The fitting error which is less than 0.5 m between the calculated value and measured value of the water level in the fitted borehole accounts for 93%.For the lithologically and structurally complex Sangu Spring Basin,the fitting effect of numerical simulation model was ideal.On the basis of the current mining amount of 111.80 million m3/a,the total redistributed exploited amount in the spring region was 61.79 million m3/a.Under the condition that the quantity of recoverable resources reached 173.59 million m3/a and under different precipitation schemes,all constraint conditions were satisfied,such as regional water level drawdown,maximum allowable water level drawdown in every simulated water source area and the flow rate of Guobi Spring.The results will provide a scientific basis for the rational development and utilization of karst groundwater in Sangu Spring Basin.展开更多
The groundwater in the research area is characterized by alkalescence,generally over-high EC value,and relatively low dissolved oxygen and oxidation-reduction potential.The pollution is presented by abnormal acid-base...The groundwater in the research area is characterized by alkalescence,generally over-high EC value,and relatively low dissolved oxygen and oxidation-reduction potential.The pollution is presented by abnormal acid-base,dissolved oxygen reduction,and conductivity rise.The overall situation of groundwater chemical field is controlled by natural conditions,the hydrochemical type has obvious zoning feature and changes from single type to multiple types from the river bank of the Yellow River to both sides,and the local abnormality is closely related to the intensity of human activities.The pollution scope and degree of inorganic toxicological indexes and organic indexes are strongly correlated with land utilization type,pollution source distribution,urbanization,and pollutant disposal of the city,the pollution in the petrochemical industrial area is the most serious,and the organic pollution tends to escalate and diffuse to the downstream.展开更多
A much improved understanding of how farmyard manure application may affect carbonate rock dissolution is needed in order to predict possible feedbacks between the rock carbon cycle and the global climate system. Two ...A much improved understanding of how farmyard manure application may affect carbonate rock dissolution is needed in order to predict possible feedbacks between the rock carbon cycle and the global climate system. Two carbonate mineral rock tablets; dolomite and limestone were buried at six depths between 0 and 110 cm in a soil typical of the subtropical karst area in Guiyang City, Guizhou Province. The extent of tablet dissolution, soil CO2, soil p H, soil water content, soil mineral and chemical composition, and chemical composition of soil water were tested in order to assess the degree of dissolution under manure application over the course of one year. The results show that manure addition decreases the dissolution rate of carbonate rocks; limestone and dolomite by between 11.7%-116.9% and 25.0%-65.69% respectively, with the dissolution rate of limestone consistently exceeding that of dolomite under the same conditions. Our data indicates that the rate of pedogenesis of the dolomite and limestone rocks is decreased as much as 35.77% and 59.41% respectively, as a result of manure application. Moreover, the results suggest that manure application accelerated the generation of soil CO2, with soil CO2 concentration increasing on average by 93.94%, and the CO2 flux increasing by 67.64% compared with the control profile. Finally, the data also indicates that manure decreases CO2 uptake by dissolution of carbonate rocks by 25.50%-39.45% on a Guiyang city scale. The counteraction of the CO2 sink contributed by karst water due to farmyard manure utilization in general karst area（both dolomite and limestone） however was 59.41%-62.72%, indicating the application of manure successfully reduces both dissolution and CO2 release to the atmosphere.展开更多
To provide information on vegetation patterns and altitudinal distributions of pollen assemblage in surface soil layers,their complicated relationships in a dryland mountain-basin system in northwestern China and a re...To provide information on vegetation patterns and altitudinal distributions of pollen assemblage in surface soil layers,their complicated relationships in a dryland mountain-basin system in northwestern China and a realistic basis for paleovegetational reconstruction,we investigated 86 vegetation quadrats and analyzed 80 soil samples from the surface soil layers along an altitudinal transect on the north slope of the Middle Tianshan Mountains from alpine cushion vegetation at 3,510 m near glacier to desert vegetation at 460 m in the Gurbantunggut Desert.According to surface pollen assemblages and the results of the detrended correspondence analysis,the transect can be divided into six major altitudinal pollen zones as alpine cushion vegetation,alpine and subalpine meadows,montane Picea forest,forest-steppe ecotone,Artemisia desert and typical desert,which basically reflect the characteristics of the mountainous vegetation patterns on the north slope of the Middle Tianshan Mountains.However,Picea pollen also exists outside the spruce forest,Chenopodiaceae and Artemisia pollen appeared above the elevation of 1,300 m,indicating that most of them might be introduced from lower elevations by upslope winds.Airborne pollen researches from three regions at different elevations further suggest that a high-frequency northwest anabatic wind has a remarkable influence on the transportation and dispersion of surface pollen in the area.展开更多
Lithium separation technique for three reference materials has been established together with precise determination of lithium isotope using a Neptune multi collector-inductively coupled plasma mass spectrometry (MC-I...Lithium separation technique for three reference materials has been established together with precise determination of lithium isotope using a Neptune multi collector-inductively coupled plasma mass spectrometry (MC-ICP-MS). The solutions of lithium element standard reference materials, potassium, calcium, sodium, magnesium and iron single element, were used to evaluate analytical methods applied. Three separate stages of ion-exchange chromatography were carried out using organic cation-exchange resin (AG 50W-X8). Lithium was enriched for the three stages using different eluants, which are 2.8 M HCl, 0.15 M HCl and 0.5 M HCl in 30% ethanol, respectively. The columns for the first and second stages are made of polypropylene, and those for the third stage are made of quartz. Total reagent volume for the entire chemical process was 35 mL for three reference materials. The recovery yielded for the three stages is 98.9-101.2% with an average of 100.0%, 97.6- 101.9% with an average of 99.9%, and 99.8-103.3% with an average of 100.6%, respectively. The precision of this technique is conservatively estimated to be ±0.72-1.04‰ (2σ population), which is similar to the precision obtained by different authors in different laboratories with MC-ICP-MS. The δ 7 Li values ( 7 Li/ 6 Li relative to the IRMM-016 standard) determined for andesite (AGV-2) and basalt (BHVO-2) are 5.68‰ (n=18), 4.33‰ (n=18), respectively. The δ 7 Li value ( 7 Li/ 6 Li relative to the L-SVEC standard) determined for IRMM-016 is -0.01‰ (n=15). All these analytical results are in good agreement with those previously reported. In addition, the results for the same kinds of samples analyzed at the MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, are consistent with those obtained at the Plasma Laboratory, University of Maryland, within analytical uncertainty. According to these experiment results, it is concluded that this proposed procedure is a suitable method for determining the lithium isotopic composition of natural samples.展开更多
Geothermal energy plays an important role in urban construction of the Xiong’an New Area. Geothermal reservoir fracture distribution of the Mesoproterozoic Jixianian Wumishan Formation(Fm.) carbonate reservoir in the...Geothermal energy plays an important role in urban construction of the Xiong’an New Area. Geothermal reservoir fracture distribution of the Mesoproterozoic Jixianian Wumishan Formation(Fm.) carbonate reservoir in the Rongcheng geothermal field are evaluated based on FMI log from Wells D19 and D21. The results show carbonate reservoir fracture density of Well D19 is 15.2/100 m, greater than that of Well D21 with a value of 9.2/100 m. Reservoir porosity and permeability of Well D19 are better than that of Well D21, and the water saturation is bimodally distributed. The movable fluid volume ratio(BVM) of Well D19 is 2% to 8% with some zones exceeding 20%, while the value of Well D21 is less than 4%. Therefore, reservoir fractures in Well D19 are more conducive to fluid flow. Reservoir fractures have a similar occurrence to normal faults, indicating that the tensile stress field controlled the formation of such fractures. Developed reservoir fractures provide a good channel for groundwater convection. The circulation of regional groundwater and the heat exchange between water and rock and the multiple heat accumulation patterns form a stable and high potential heat reservoir in the Rongcheng geothermal field.展开更多
We present the first systematic hydrogeological analysis to grain insights on the evolution of the Gonghe Basin in North China. Two hundred and forty seven water samples were collected from the Gonghe East Basin, Gong...We present the first systematic hydrogeological analysis to grain insights on the evolution of the Gonghe Basin in North China. Two hundred and forty seven water samples were collected from the Gonghe East Basin, Gonghe West Basin and Chaka Basin. The three groundwater systems of Gonghe Basin from west to east display different geochemical signatures. Based on Na/Cl ratios and Langelier-Ludwig diagram, it is inferred that the groundwater recharge potential of the Gonghe East Basin is much prosperous than the other areas. The renewability of the aquifers in alluvial-proluvial fan of Wahonghe and Gonghe East Basin margin is much faster than in the other basins. The groundwater quality in Chaka Salt Lake,Shazhuyu and Qiabuqia River Valley plains is low due to strong evaporation and cation exchange. The groundwater quality of the phreatic aquifers in the Qiabuqia River Valley plain is further deteriorated by mixing of high-arsenic and high-mineralization water from the deep fault structures.展开更多
基金funded by the National Natural Science Foundation of China(41907175)the Open Fund of Key Laboratory(WSRCR-2023-01)the project of the China Geological Survey(DD20230459).
文摘Groundwater is an important source of drinking water.Groundwater pollution severely endangers drinking water safety and sustainable social development.In the case of groundwater pollution,the top priority is to identify pollution sources,and accurate information on pollution sources is the premise of efficient remediation.Then,an appropriate pollution remediation scheme should be developed according to information on pollution sources,site conditions,and economic costs.The methods for identifying pollution sources mainly include geophysical exploration,geochemistry,isotopic tracing,and numerical modeling.Among these identification methods,only the numerical modeling can recognize various information on pollution sources,while other methods can only identify a certain aspect of pollution sources.The remediation technologies of groundwater can be divided into in-situ and ex-situ remediation technologies according to the remediation location.The in-situ remediation technologies enjoy low costs and a wide remediation range,but their remediation performance is prone to be affected by environmental conditions and cause secondary pollution.The ex-situ remediation technologies boast high remediation efficiency,high processing capacity,and high treatment concentration but suffer high costs.Different methods for pollution source identification and remediation technologies are applicable to different conditions.To achieve the expected identification and remediation results,it is feasible to combine several methods and technologies according to the actual hydrogeological conditions of contaminated sites and the nature of pollutants.Additionally,detailed knowledge about the hydrogeological conditions and stratigraphic structure of the contaminated site is the basis of all work regardless of the adopted identification methods or remediation technologies.
基金supported by the Geothermal Survey Project of the China Geological Survey(Grant No.DD20221676)the Shanxi Geoscience Think Tank Development Fund 2023–001 and Basic Research Operations Project of the Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological Sciences(SK202212).
文摘Rock thermal physical properties play a crucial role in understanding deep thermal conditions,modeling the thermal structure of the lithosphere,and discovering the evolutionary history of sedimentary basins.Recent advancements in geothermal exploration,particularly the identification of high-temperature geothermal resources in Datong Basin,Shanxi,China,have opened new possibilities.This study aims to characterize the thermal properties of rocks and explore factors influencing thermal conductivity in basins hosting high-temperature geothermal resources.A total of 70 groups of rock samples were collected from outcrops in and around Datong Basin,Shanxi Province.Thermal property tests were carried out to analyze the rock properties,and the influencing factors of thermal conductivity were studied through experiments at different temperature and water-filled states.The results indicate that the thermal conductivity of rocks in Datong,Shanxi Province,typically ranges from 0.690 W/(m·K)to 6.460 W/(m·K),the thermal diffusion coefficient ranges from 0.441 mm^(2)/s to 2.023 mm^(2)/s,and the specific heat capacity of the rocks ranges from 0.569 KJ/(kg·℃)to 1.117 KJ/(kg·°C).Experimental results reveal the impact of temperature and water saturation on the thermal conductivity of the rock.The thermal conductivity decreases with increasing temperature and rises with high water saturation.A temperature correction formula for the thermal conductivity of different lithologies in the area is proposed through linear fitting.The findings from this study provide essential parameters for the assessment and prediction,development,and utilization of geothermal resources in the region and other basins with typical high-temperature geothermal resource.
基金supported by the National Nature Science Foundation of China under grant No.42272350the Foundation of Shanxi Key Laboratory for Exploration and Exploitation of Geothermal Resources under grant No.SX202202.
文摘Underground Thermal Energy Storage(UTES)store unstable and non-continuous energy underground,releasing stable heat energy on demand.This effectively improve energy utilization and optimize energy allocation.As UTES technology advances,accommodating greater depth,higher temperature and multi-energy complementarity,new research challenges emerge.This paper comprehensively provides a systematic summary of the current research status of UTES.It categorized different types of UTES systems,analyzes the applicability of key technologies of UTES,and evaluate their economic and environmental benefits.Moreover,this paper identifies existing issues with UTES,such as injection blockage,wellbore scaling and corrosion,seepage and heat transfer in cracks,etc.It suggests deepening the research on blockage formation mechanism and plugging prevention technology,improving the study of anticorrosive materials and water treatment technology,and enhancing the investigation of reservoir fracture network characterization technology and seepage heat transfer.These recommendations serve as valuable references for promoting the high-quality development of UTES.
基金jointly funded by National Natural Science Foundation of China (41877398)project of the China Geological Survey (DD20221773)。
文摘Heavy metal distribution in mining areas has always been a hot research topic due to the special environment of these areas. This study aims to explore the impact of heavy metal pollution on soils and crops in the study area, ensure the safety of local crops and the health of local residents, and provide a basis for the subsequent environmental restoration and the prevention and control of environmental pollution. Based on the analysis of the heavy metal concentrations in local soils and crops, the study investigated the spatial distribution, pollution degrees, and potential ecological risks of heavy metals in the farmland of a mining area in the southeastern Nanyang Basin, Henan province, China explored the sources of heavy metals and assessed the health risks caused by crop intake. The results of this study are as follows. The root soils of crops in the study area suffered heavy metal pollution to varying degrees. The degree of heavy metal pollution in maize fields is higher than that in wheat fields, and both types of fields suffer the most severe Cd pollution. Moreover, the root soils of different crops suffer compound pollution.The root soils in the maize fields suffer severe compound pollution at some sampling positions, whose distribution is similar to that of the mining area. Cd poses the highest potential ecological risks among all heavy metals, and the study area mainly suffers low and moderate comprehensive potential ecological risks. The principal component analysis(PCA) shows that the distribution of Zn, Cd, Pb, and As in soils of the study area is mainly affected by anthropogenic factors such as local mining activities;the distribution of Cr and Ni is primarily controlled by the local geological background;the distribution of Hg is mainly affected by local vehicle exhaust emissions, and the distribution of Cu is influenced by both human activities and the geological background. Different cereal crops in the study area are polluted with heavy metals dominated by Cd and Ni to varying degrees, especially wheat. As indicated by the health risk assessment results, the intake of maize in the study area does not pose significant human health risks;however, Cu has high risks to human health, and the compound heavy metal pollution caused by the intake of wheat in the study area poses risks to the health of both adults and children. Overall, the soils and crops in the study area suffer a high degree of heavy metal pollution, for which mining activities may be the main reason.
基金the basic scientific research expense of the Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological Sciences(SK202119).
文摘Groundwater,as a critical component of the hydrological cycle,is essential for sustainable ecosystem development.To clarify the current status of domestic and overseas research,and to identify hotspots,frontier and future trends of groundwater and ecology research,this study utilizes bibliometric methods and CiteSpace software to examine relevant published articles in the Web of Science(WOS)and CNKI databases from 1978 to 2022.Specifically,this study analyzes(1)the annual number of published papers;(2)research institutions;(3)keywords;and(4)evolution of research hotspots.The findings reveal that the United States,China,and Germany are the top three countries in groundwater and ecology research.International research hotspots mainly focus on microbial ecology,climate change,groundwater-surface water interactions in the hyporheic zone,biodiversity,and submarine groundwater discharge,while domestic research hotspots mainly focus on ecological water conveyance,ecological flow,groundwater development and utilization,groundwater pollution,and groundwater and ecological protection.Both domestic and international research hotspots exhibit interdisciplinary features with diverse research objects and assessment methods.Future research in this area is expected to focus on topics such as contamination,groundwater quality,framework,mechanism,spatial distribution,and dissolved organic matter.Additionally,the study of ecological recharge,ecological flow,ecological protection,water intake and use will continue to be the hot topics domestically.
基金This work was financially supported by National Natural Science Foundation of China(41972262)Hebei Natural Science Foundation for Excellent Young Scholars(D2020504032)+1 种基金Central Plains Science and technology innovation leader Project(214200510030)Key research and development Project of Henan province(221111321500).
文摘Landslide is a serious natural disaster next only to earthquake and flood,which will cause a great threat to people’s lives and property safety.The traditional research of landslide disaster based on experience-driven or statistical model and its assessment results are subjective,difficult to quantify,and no pertinence.As a new research method for landslide susceptibility assessment,machine learning can greatly improve the landslide susceptibility model’s accuracy by constructing statistical models.Taking Western Henan for example,the study selected 16 landslide influencing factors such as topography,geological environment,hydrological conditions,and human activities,and 11 landslide factors with the most significant influence on the landslide were selected by the recursive feature elimination(RFE)method.Five machine learning methods[Support Vector Machines(SVM),Logistic Regression(LR),Random Forest(RF),Extreme Gradient Boosting(XGBoost),and Linear Discriminant Analysis(LDA)]were used to construct the spatial distribution model of landslide susceptibility.The models were evaluated by the receiver operating characteristic curve and statistical index.After analysis and comparison,the XGBoost model(AUC 0.8759)performed the best and was suitable for dealing with regression problems.The model had a high adaptability to landslide data.According to the landslide susceptibility map of the five models,the overall distribution can be observed.The extremely high and high susceptibility areas are distributed in the Funiu Mountain range in the southwest,the Xiaoshan Mountain range in the west,and the Yellow River Basin in the north.These areas have large terrain fluctuations,complicated geological structural environments and frequent human engineering activities.The extremely high and highly prone areas were 12043.3 km^(2)and 3087.45 km^(2),accounting for 47.61%and 12.20%of the total area of the study area,respectively.Our study reflects the distribution of landslide susceptibility in western Henan Province,which provides a scientific basis for regional disaster warning,prediction,and resource protection.The study has important practical significance for subsequent landslide disaster management.
基金funded by the National Key Research and Development Program of China(Grant No.2019YFB1504101)the Natural Science Foundation of Hebei Province,China(Grant No.D2021504041)。
文摘As typical carbonate geothermal reservoirs with low porosity in northern China,the Jixianian System in the Xiong’an New Area is the main target for geothermal fluid exploration.The Jixianian System comprises the Gaoyuzhuang,Yangzhuang,Wumishan,Hongshuizhuang,and Tieling formations.The characteristics,formation periods,and controlling factors of reservoir tectonic fractures have been determined based on analyses of outcrops,cores,thin sections,and image logs.The results show that unfilled fractures account for over 87% and most tectonic fractures are high-angle shear fractures with angles concentrated at 40°to 70°and the fracture porosity increases linearly with an increased fracture aperture.Within the same tectonic setting and stress field,the lithology and layer thickness are the dominant factors governing the development of tectonic fractures,which are the most developed in dolomites and thin layers.Tectonic fractures were most likely formed in regions near faults or areas with larger stress gradients.The tectonic fractures in the carbonate geothermal reservoirs are roughly divided into four sets:NNW-SSE and NNE-SSW oriented‘X’-conjugated shear fractures formed from the Paleozoic to the pre-Yanshanian Movement;NE-SW-oriented shear fractures,formed in episode B of the Yanshanian Movement,occurred at the Early Cretaceous;nearly E-W-oriented tensional fractures formed in the late Yanshanian Movement at the Late Cretaceous to Paleogene,and NEE-SW-oriented shear fractures formed during the Himalayan movement.
基金Supported by the National Natural Science Foundation of China (41941017)the Fundamental Research Funds for the Central Public Research Institutes (SK202109)。
文摘1. Objectives Ophiolites from the oceanic crust are important indicators for identifying tectonic suture zones. Recently, a continuous ophiolite belt was found near the Guola Mountain in the Nujiang tectonic belt. Due to intensive hydrothermal alteration during tectonic evolution, clayey altered ophiolite with special engineering geological characteristics was formed, which has an extremely adverse impact on engineering stability. However, the adverse properties of clayey altered ophiolite are still not well understood in engineering practices(Zhang YS, et al., 2011).
文摘1,4-dioxane pollution is characterized by its early identification, widespread sources and extensive distribution. The pollutant is highly mobile and persistent in the water environment and is classified as a B2(probable) human carcinogen. After reviewing recent researches on the pollution status,transport and transformation characteristics of 1,4-dioxane in the water environment, as well as the environmental pollution remediation and treatment technologies, and the status of environmental regulation,this paper addresses that the distribution of 1,4-dioxane in water bodies is significantly correlated with chlorinated hydrocarbon pollutants such as 1,1,1-trichloroethane(1,1,1-TCA) and trichloroethylene(TCE).It is noteworthy that 1,4-dioxane often occurs in symbiosis with 1,1,1-TCA and has a similarity contamination plume distribution to 1,1,1-TCA. The natural attenuation of 1,4-dioxane in groundwater environment is weak, but there is a certain degree of biological oxidation attenuation. Current methods for treating 1,4-dioxane pollution mainly include extraction-treatment technology, advanced oxidation treatment technology, modified biological treatment technology and phytoremediation technology, all of which have their limitations in practical application. Currently, there is no environmental regulation available for the 1,4-dioxane pollution worldwide, and no enforceable standard established for defining the health trigger levels of 1,4-dioxane in drinking water. Research on this contaminant in China is generally limited to the site or laboratory scale, and there are no studies on the environmental risk and quality standards for 1,4-dioxane in the water environment.
基金supported by National Natural Science Foundation(No.41272301 and No.42007171)Nature Fund of Hebei(No.D2021504034)Chinese Academy of Geological Sciences(No.YYWF201628).
文摘The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster.
基金supported by National Natural Science Foundation of China(41972262)Hebei Natural Science Foundation for Excellent Young Scholars(D2020504032).
文摘The effective recovery of water level is a crucial measure of the success of comprehensive groundwater over-exploitation management actions in North China.However,traditional evaluation method do not directly capture the relationship between mining and other equilibrium elements.This study presents an innovative evaluation method to assess the water level recovery resulting from mining reduction based on the relationship between variation in exploitation and recharge.Firstly,the recharge variability of source and sink terms for both the base year and evaluation year is calculated and the coefficient of recharge variationβis introduced,which is then used to calculate the effective mining reduction and solve the water level recovery value caused by the effective mining reduction,and finally the water level recovery contribution by mining reduction is calculated by combining with the actual volume of mining reduction in the evaluation area.This research focuses on Baoding and Shijiazhuang Plain area,which share similar hydrogeological conditions but vary in groundwater exploitation and utilization.As the effect of groundwater level recovery with mining reduction was evaluated in these two areas as case study.In 2018,the results showed an effective water level recovery of 0.17 m and 0.13 m in the shallow groundwater of Shijiazhuang and Baoding Plain areas,respectively.The contributions of recovery from mining reduction were 76%and 57.98%for these two areas,respectively.It was notable that the water level recovery was most prominent in the foothill plain regions.From the evaluation results,it is evident that water level recovery depends not only on the intensity of groundwater mining reduction,but also on its effectiveness.The value of water level recovery alone cannot accurately indicate the intensity of mining reduction,as recharge variation significantly influences water level changes.Therefore,in practice,it is crucial to comprehensively assess the impact of mining reduction on water level recovery by combining the coefficient of recharge variation with the contribution of water level recovery from mining reduction.This integrated approach provide a more reasonable and scientifically supported basis,offering essential data support for groundwater management and conservation.To improve the accuracy and reliability of evaluation results,future work will focus on the standardizing and normalizing raw data processing.
基金funded by China Geological Survey Program(DD20230422)and Chinese Academy of Geological Sciences Basic Research Fund Program(SK202214).
文摘The source area of the Yellow River(SAYR),located above the Huangheyan hydrological station,is important for ecological preservation and water source conservation in the Yellow River Basin.In this area,the impact of water conservation projects on the hydrology and the ecological environment is pivotal in protecting water resources and alpine vegetation ecosystems.This study investigates the impact of the Yellow River Source Hydropower Station on the runoff and ecological evolution of the SAYR,along with the underlying mechanism,using extensive datasets encompassing long-term meteorological,hydrological and remote sensing data from various time periods.Results show that,over the long term,precipitation is the primary factor driving runoff variations in the SAYR.Nevertheless,from 1990 to 2020,there is a notably inconsistent relationship between precipitation and runoff.After the completion of the Yellow River Source Hydropower Station in 2001,the water level of Eling Lake experienced and elevation of 2–3 m,leading to a gradual recovery of runoff.In addition,the basin's water balance shifted from a negative to a positive equilibrium,oscillating with changes in lake water levels.Consequently,the overflow zone of the Tangchama alluvial–proluvial fan in the upper reaches of the lakeshore shifted by 500 m,and marsh wetlands expanded by 20.78 km^(2).The increased storage of lakes and groundwater in the SAYR is the key controlling factor for the runoff recovery,changes in the basin's water balance,and enhancements in lakeshore vegetation ecology.Under the geological background of the Qinghai–Tibet Plateau's upliftment and intensified upstream river erosion,the basin experienced a substantial water imbalance due to declining discharge base levels,which is the most critical factor behind runoff attenuation in the SAYR towards the end of the 20th century.The construction of the hydropower station objectively raised the drainage base level of the basin,thereby positively contributing to the preservation of water balance,runoff stability,and the enhancement of swamps and wetlands along the lakeshore.
基金This work was supported by the Fundamental Research Funds for the Chinese Academy of Geosciences(No.JYYWF20180401)the China Geological Survey project(No.DD20160296,DD20201123).
文摘The changes of development and utilization of karst groundwater in Sangu Spring Basin have made the original groundwater resource evaluation unable to meet the needs of future economic development.Based on analysis of existing data,combined with the characteristics of supplement,runoff and draining of regional karst groundwater,the Visual Modelflow software was used to build a numerical simulation model of Sangu spring Basin.The amount of karst groundwater resource and groundwater environment of the Basin were evaluated under different exploitation schemes,and the changes of karst groundwater environment in the future ten years were also predicted.The fitting error which is less than 0.5 m between the calculated value and measured value of the water level in the fitted borehole accounts for 93%.For the lithologically and structurally complex Sangu Spring Basin,the fitting effect of numerical simulation model was ideal.On the basis of the current mining amount of 111.80 million m3/a,the total redistributed exploited amount in the spring region was 61.79 million m3/a.Under the condition that the quantity of recoverable resources reached 173.59 million m3/a and under different precipitation schemes,all constraint conditions were satisfied,such as regional water level drawdown,maximum allowable water level drawdown in every simulated water source area and the flow rate of Guobi Spring.The results will provide a scientific basis for the rational development and utilization of karst groundwater in Sangu Spring Basin.
文摘The groundwater in the research area is characterized by alkalescence,generally over-high EC value,and relatively low dissolved oxygen and oxidation-reduction potential.The pollution is presented by abnormal acid-base,dissolved oxygen reduction,and conductivity rise.The overall situation of groundwater chemical field is controlled by natural conditions,the hydrochemical type has obvious zoning feature and changes from single type to multiple types from the river bank of the Yellow River to both sides,and the local abnormality is closely related to the intensity of human activities.The pollution scope and degree of inorganic toxicological indexes and organic indexes are strongly correlated with land utilization type,pollution source distribution,urbanization,and pollutant disposal of the city,the pollution in the petrochemical industrial area is the most serious,and the organic pollution tends to escalate and diffuse to the downstream.
文摘A much improved understanding of how farmyard manure application may affect carbonate rock dissolution is needed in order to predict possible feedbacks between the rock carbon cycle and the global climate system. Two carbonate mineral rock tablets; dolomite and limestone were buried at six depths between 0 and 110 cm in a soil typical of the subtropical karst area in Guiyang City, Guizhou Province. The extent of tablet dissolution, soil CO2, soil p H, soil water content, soil mineral and chemical composition, and chemical composition of soil water were tested in order to assess the degree of dissolution under manure application over the course of one year. The results show that manure addition decreases the dissolution rate of carbonate rocks; limestone and dolomite by between 11.7%-116.9% and 25.0%-65.69% respectively, with the dissolution rate of limestone consistently exceeding that of dolomite under the same conditions. Our data indicates that the rate of pedogenesis of the dolomite and limestone rocks is decreased as much as 35.77% and 59.41% respectively, as a result of manure application. Moreover, the results suggest that manure application accelerated the generation of soil CO2, with soil CO2 concentration increasing on average by 93.94%, and the CO2 flux increasing by 67.64% compared with the control profile. Finally, the data also indicates that manure decreases CO2 uptake by dissolution of carbonate rocks by 25.50%-39.45% on a Guiyang city scale. The counteraction of the CO2 sink contributed by karst water due to farmyard manure utilization in general karst area（both dolomite and limestone） however was 59.41%-62.72%, indicating the application of manure successfully reduces both dissolution and CO2 release to the atmosphere.
基金jointly funded by the National Natural Science Foundation of China (40972212,41272386,41572331,90102009,31590822)the Scientific Research Foundation for the Young Scientists of State Key Laboratory of Vegetation and Environmental Change,Institute of Botany,Chinese Academy of Sciences and the Returned Overseas Chinese Scholars,Ministry of Education of the People’s Republic of China and the National Postdoc Science Foundation of China (2003033253)
文摘To provide information on vegetation patterns and altitudinal distributions of pollen assemblage in surface soil layers,their complicated relationships in a dryland mountain-basin system in northwestern China and a realistic basis for paleovegetational reconstruction,we investigated 86 vegetation quadrats and analyzed 80 soil samples from the surface soil layers along an altitudinal transect on the north slope of the Middle Tianshan Mountains from alpine cushion vegetation at 3,510 m near glacier to desert vegetation at 460 m in the Gurbantunggut Desert.According to surface pollen assemblages and the results of the detrended correspondence analysis,the transect can be divided into six major altitudinal pollen zones as alpine cushion vegetation,alpine and subalpine meadows,montane Picea forest,forest-steppe ecotone,Artemisia desert and typical desert,which basically reflect the characteristics of the mountainous vegetation patterns on the north slope of the Middle Tianshan Mountains.However,Picea pollen also exists outside the spruce forest,Chenopodiaceae and Artemisia pollen appeared above the elevation of 1,300 m,indicating that most of them might be introduced from lower elevations by upslope winds.Airborne pollen researches from three regions at different elevations further suggest that a high-frequency northwest anabatic wind has a remarkable influence on the transportation and dispersion of surface pollen in the area.
基金supported by grants from the Natural Science Foundation of China (no. 40973013,41173003)the Ministry of Land and Resources (no.201011027)+2 种基金China Geological Survey (no.1212011120298, 1212010816027)the Ministry of Science and Technology (no. K0802)the Open Foundation of Chinese Academy of Geological Sciences (no. 2009-SYS-06)
文摘Lithium separation technique for three reference materials has been established together with precise determination of lithium isotope using a Neptune multi collector-inductively coupled plasma mass spectrometry (MC-ICP-MS). The solutions of lithium element standard reference materials, potassium, calcium, sodium, magnesium and iron single element, were used to evaluate analytical methods applied. Three separate stages of ion-exchange chromatography were carried out using organic cation-exchange resin (AG 50W-X8). Lithium was enriched for the three stages using different eluants, which are 2.8 M HCl, 0.15 M HCl and 0.5 M HCl in 30% ethanol, respectively. The columns for the first and second stages are made of polypropylene, and those for the third stage are made of quartz. Total reagent volume for the entire chemical process was 35 mL for three reference materials. The recovery yielded for the three stages is 98.9-101.2% with an average of 100.0%, 97.6- 101.9% with an average of 99.9%, and 99.8-103.3% with an average of 100.6%, respectively. The precision of this technique is conservatively estimated to be ±0.72-1.04‰ (2σ population), which is similar to the precision obtained by different authors in different laboratories with MC-ICP-MS. The δ 7 Li values ( 7 Li/ 6 Li relative to the IRMM-016 standard) determined for andesite (AGV-2) and basalt (BHVO-2) are 5.68‰ (n=18), 4.33‰ (n=18), respectively. The δ 7 Li value ( 7 Li/ 6 Li relative to the L-SVEC standard) determined for IRMM-016 is -0.01‰ (n=15). All these analytical results are in good agreement with those previously reported. In addition, the results for the same kinds of samples analyzed at the MLR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, are consistent with those obtained at the Plasma Laboratory, University of Maryland, within analytical uncertainty. According to these experiment results, it is concluded that this proposed procedure is a suitable method for determining the lithium isotopic composition of natural samples.
基金funded by the National Key R&D Program of China(Grant No.2019YFB1504101)the China Postdoctoral Science Foundation(Grant No.2019M663087)the National Natural Science Foundation of China(Grant No.42002189)。
文摘Geothermal energy plays an important role in urban construction of the Xiong’an New Area. Geothermal reservoir fracture distribution of the Mesoproterozoic Jixianian Wumishan Formation(Fm.) carbonate reservoir in the Rongcheng geothermal field are evaluated based on FMI log from Wells D19 and D21. The results show carbonate reservoir fracture density of Well D19 is 15.2/100 m, greater than that of Well D21 with a value of 9.2/100 m. Reservoir porosity and permeability of Well D19 are better than that of Well D21, and the water saturation is bimodally distributed. The movable fluid volume ratio(BVM) of Well D19 is 2% to 8% with some zones exceeding 20%, while the value of Well D21 is less than 4%. Therefore, reservoir fractures in Well D19 are more conducive to fluid flow. Reservoir fractures have a similar occurrence to normal faults, indicating that the tensile stress field controlled the formation of such fractures. Developed reservoir fractures provide a good channel for groundwater convection. The circulation of regional groundwater and the heat exchange between water and rock and the multiple heat accumulation patterns form a stable and high potential heat reservoir in the Rongcheng geothermal field.
基金supported by National Natural Science Foundation of China(No. 41402234 and No. 41372243)the Fundamental Research Funds for Chinese Academy of Geological Sciences (No.YYWF201502)
文摘We present the first systematic hydrogeological analysis to grain insights on the evolution of the Gonghe Basin in North China. Two hundred and forty seven water samples were collected from the Gonghe East Basin, Gonghe West Basin and Chaka Basin. The three groundwater systems of Gonghe Basin from west to east display different geochemical signatures. Based on Na/Cl ratios and Langelier-Ludwig diagram, it is inferred that the groundwater recharge potential of the Gonghe East Basin is much prosperous than the other areas. The renewability of the aquifers in alluvial-proluvial fan of Wahonghe and Gonghe East Basin margin is much faster than in the other basins. The groundwater quality in Chaka Salt Lake,Shazhuyu and Qiabuqia River Valley plains is low due to strong evaporation and cation exchange. The groundwater quality of the phreatic aquifers in the Qiabuqia River Valley plain is further deteriorated by mixing of high-arsenic and high-mineralization water from the deep fault structures.
