Eu3+ doped SiO2 nano-crystalline glasses were prepared by sol-gel method. The broad peak of XRD pattern indicates an amorphous SiO2 matrix. The affection of anneal time and anneal temperatures on photoluminescence (PL...Eu3+ doped SiO2 nano-crystalline glasses were prepared by sol-gel method. The broad peak of XRD pattern indicates an amorphous SiO2 matrix. The affection of anneal time and anneal temperatures on photoluminescence (PL) properties of SiO2 glass under different Eu doping concentration were studied systematically. It is found that the optimized anneal time is about 3 h. The excitation spectra of 2% Eu3+ doped SiO2 glass powder were measured under various anneal temperatures, and the optimized anneal temperature is observed around 700℃. The fluorescence-quenching effect can be observed in the emission spectra when the annealing temperature exceeds 700℃. The emission spectra of different molar ratio dopants were measured at an annealed temperature of 500℃, and the concentration-quenching phenomenon has also been observed in SiO2 glass powder when the molar ratio of Eu3+ ion exceeds 3% . The result shows that the PL intensity approaches its maximum when the molar ratio of Eu3+ ions in the sample is about 3% . In addition, a comparatively stronger emission spectrum at wavelength of 703 nm which is corresponding to the energy transition 5D0→7F4 of Eu ions is also obtained.展开更多
An improved sol-gel method was employed to prepare Eu3+ ions doped SiO2-Y2O3 nanocomposites.Systematic study was carried out on the effect of post-annealing treatment on photoluminescence(PL) properties of the samples...An improved sol-gel method was employed to prepare Eu3+ ions doped SiO2-Y2O3 nanocomposites.Systematic study was carried out on the effect of post-annealing treatment on photoluminescence(PL) properties of the samples under various europium ions doping concentrations.X-ray diffraction(XRD) patterns indicated that the samples showed an amorphous matrix structure,and the scanning electron microscopy(SEM) pictures showed that the samples presented a nano size(from 21 to 42 nm) granular-stack structure after hi...展开更多
基金Project supported by the National Natural Science Foundation of China (50272063)
文摘Eu3+ doped SiO2 nano-crystalline glasses were prepared by sol-gel method. The broad peak of XRD pattern indicates an amorphous SiO2 matrix. The affection of anneal time and anneal temperatures on photoluminescence (PL) properties of SiO2 glass under different Eu doping concentration were studied systematically. It is found that the optimized anneal time is about 3 h. The excitation spectra of 2% Eu3+ doped SiO2 glass powder were measured under various anneal temperatures, and the optimized anneal temperature is observed around 700℃. The fluorescence-quenching effect can be observed in the emission spectra when the annealing temperature exceeds 700℃. The emission spectra of different molar ratio dopants were measured at an annealed temperature of 500℃, and the concentration-quenching phenomenon has also been observed in SiO2 glass powder when the molar ratio of Eu3+ ion exceeds 3% . The result shows that the PL intensity approaches its maximum when the molar ratio of Eu3+ ions in the sample is about 3% . In addition, a comparatively stronger emission spectrum at wavelength of 703 nm which is corresponding to the energy transition 5D0→7F4 of Eu ions is also obtained.
基金supported by the Guangdong Province (2007-173)Jiangmen City (2009-217)
文摘An improved sol-gel method was employed to prepare Eu3+ ions doped SiO2-Y2O3 nanocomposites.Systematic study was carried out on the effect of post-annealing treatment on photoluminescence(PL) properties of the samples under various europium ions doping concentrations.X-ray diffraction(XRD) patterns indicated that the samples showed an amorphous matrix structure,and the scanning electron microscopy(SEM) pictures showed that the samples presented a nano size(from 21 to 42 nm) granular-stack structure after hi...
