Six new high precision U-Pb zircon ID-TIMS ages plus thirteen in situ high spatial resolution U-Pb zircon LA-MC-ICPMS ages are reported from Jurassic plutonic(metaluminous to weakly peraluminous biotite granites)and J...Six new high precision U-Pb zircon ID-TIMS ages plus thirteen in situ high spatial resolution U-Pb zircon LA-MC-ICPMS ages are reported from Jurassic plutonic(metaluminous to weakly peraluminous biotite granites)and Jurassic to Cretaceous hypabyssal(dacites)rocks from Macao.Despite its relatively small area(~30 km^2),the new ages tightly constrain the Macao granitic magmatism to two periods ranging from 164.5±0.6 Ma to 162.9±0.7 Ma and 156.6±0.2 Ma to 155.5±0.8 Ma,separated by ca.6 Ma.Inherited zircons point to the existence of a basement with ages up to Paleo-Proterozoic and late Archean in the region.In addition,younger dacitic rocks were dated at 150.6±0.6 Ma and<120 Ma.U-Pb zircon ages and whole-rock REE data of Macao granites indicate that the first pulse is also represented in Hong Kong and Southeast(SE)China,while magmatism with the chemical characteristics of the second pulse seems to not be represented outside Macao.The two granitic magmatic pulses have distinct mineralogical and geochemical features that support their discrete nature rather than a continuum of comagmatic activity and suggest that the Macao granitic suite was incrementally assembled during a period of ca.9 Ma,a hypothesis also extendable to the neighboring Hong Kong region for a time lapse of ca.24 Ma.In Macao,the transition from granitic magmatism(Middle to Upper Jurassic)to the younger dacite dykes(Upper Jurassic to Lower Cretaceous)most likely corresponds to a change in the regional tectonic setting,from an extensional regime related with foundering of the subducting paleoPacific plate during the Early Yanshanian period to the reestablishment of a normal subduction system in SE China during the Late Yanshanian period.展开更多
The Anti-Atlas belt of southern Morocco is situated on the northern edge of the West African craton(WAC).It corresponds to a broad anticlinorium some 800 km long and 200 km wide,trending ENE-WSW,parallel to the
We present a new tracksite with multiple dinosaur tracks from the lowermost Barremian (Lower Cretaceous) of the Cape Espichel (Sesimbra, Portugal). The tracks are localized on three beds on the top carbonate beds of t...We present a new tracksite with multiple dinosaur tracks from the lowermost Barremian (Lower Cretaceous) of the Cape Espichel (Sesimbra, Portugal). The tracks are localized on three beds on the top carbonate beds of the Areia do Mastro Formation. Those bioclastic, nodular limestones were deposited in a very shallow subtidal-intertidal, restricted lagoon environment. The track surfaces are very dinoturbated, with a substantial number of tracks. Several tracks assign to sauropods, ornithopods and theropods dinosaurs were recorded. Due to heavy bioturbation and the preservation conditions, it is not possible to define trackways;some preliminary work done on the tracks could disclose some behaviours of their producers. Several species of carnivore and herbivore dinosaurs crossed that large area at different times. Herbivores may have used the lagoon margin as passage between feeding spots, while carnivores frequented the area to hunt in groups or individually.展开更多
Maritime transportation, widely used both in international transport of goods and touristic purposes, has been identified as a significant source of ultrafine particles (UFP). In-land passenger ferry is a source of UF...Maritime transportation, widely used both in international transport of goods and touristic purposes, has been identified as a significant source of ultrafine particles (UFP). In-land passenger ferry is a source of UFP far less addressed;however, in locations with relatively high frequency of this transportation mode, it is expected that they contribute to an increase of their concentration. Moreover, the negative effects of UFP on human health and environment are known and therefore, monitoring UFP produced by ferries is vital to assess the degree of exposure of who work or live close to ferries’ terminals or downwind to their cruising path. This work aims to study the influence of in-land ferries activities on UFP in the urban/suburban areas near ferries’ terminals and downwind across the cruising path. The UFP monitoring campaign was carried out from September to December 2018 for 19 non-consecutive periods. The sampling sites were chosen in order to maximize measurements under downwind conditions and allow the association between ferry operation and UFP concentration response. Based on data collected, correlation analysis was performed between ferry’s traffic and particle number counting (PNC) of UFP, and also with meteorological variables. Results show an increase in PNC ranging from 25 to 197% during the third minute around a ferry movement and are moderate to positive significant correlations between PNC values and the number of ferry operations (r = 0.79 to r = 0.94), showing that UFP emitted by in-land ferries contributes to PNC increase. Moreover, negative correlations (r = -0.85 to r = -0.93) between PNC and wind intensity were also found.展开更多
Home Energy Management Systems(HEMS)are increasingly relevant for demand-side management at the residential level by collecting data(energy,weather,electricity prices)and controlling home appliances or storage systems...Home Energy Management Systems(HEMS)are increasingly relevant for demand-side management at the residential level by collecting data(energy,weather,electricity prices)and controlling home appliances or storage systems.This control can be performed with classical models that find optimal solutions,with high real-time computational cost,or data-driven approaches,like Reinforcement Learning,that find good and flexible solutions,but depend on the availability of load and generation data and demand high computational resources for training.In this work,a novel HEMS is proposed for the optimization of an electric battery operation in a real,online and data-driven environment that integrates state-of-the-art load forecasting combining CNN and LSTM neural networks to increase the robustness of decisions.Several Reinforcement Learning agents are trained with different algorithms(Double DQN,Dueling DQN,Rainbow and Proximal Policy Optimization)in order to minimize the cost of electricity purchase and to maximize photovoltaic self-consumption for a PV-Battery residential system.Results show that the best Reinforcement Learning agent achieves a 35%reduction in total cost when compared with an optimization-based agent.展开更多
In this study,we identified the moisture sources for the precipitation associated with tropical cyclones(TCs)during the rapid intensification(RI)process from 1980 to 2018 by applying a Lagrangian moisture source diagnos...In this study,we identified the moisture sources for the precipitation associated with tropical cyclones(TCs)during the rapid intensification(RI)process from 1980 to 2018 by applying a Lagrangian moisture source diagnostic method.We detected sixteen regions on a global scale for RI events distributed as follows:four in the North Atlantic(NATL),two in the Central and East Pacific Ocean(NEPAC),the North Indian Ocean(NIO)and South Indian Ocean(SIO),and three in the South Pacific Ocean(SPO)and the Western North Pacific Ocean(WNP).The moisture uptake(MU)mostly was from the regions where TCs underwent RI.The Western NATL,tropical NATL,Caribbean Sea,the Gulf of Mexico and the Central America and Mexico landmass supported~85.4%of the precipitating moisture in the NATL,while the latter source and the eastern North Pacific Ocean provided the higher amount of moisture in NEPAC(~84.3%).The Arabian Sea,the Bay of Bengal and the Indian Peninsula were the major moisture sources in NIO,contributing approximately 81.3%.The eastern and western parts of the Indian Ocean supplied most of the atmospheric humidity in SIO(~83.8%).The combined contributions(~87.9%)from the western and central SPO and the Coral Sea were notably higher in SPO.Meanwhile,TCs in the WNP basin mostly received moisture from the western North Pacific Ocean,the Philippine Sea and the China Sea,accounting for 80.1%.The remaining moisture support in each basin came from the summed contributions of the remote sources.Overall,RI TCs gained more moisture up to 2500 km from the cyclone centre than those slow intensification(SI)and the total MU was approximately three times higher during RI than SI.Finally,the patterns of the MU differences respond to the typical pathways of moisture transport in each basin.展开更多
Standardized Precipitation Index(SPI)and Standardized Precipitation Evapotranspiration Index(SPEI),traditionally derived at a monthly scale,are widely used drought indices.To overcome temporalresolution limitations,we...Standardized Precipitation Index(SPI)and Standardized Precipitation Evapotranspiration Index(SPEI),traditionally derived at a monthly scale,are widely used drought indices.To overcome temporalresolution limitations,we have previously developed and published a well-validated daily SPI/SPEI in situ dataset.Although having a high temporal resolution,this in situ dataset presents low spatial resolution due to the scarcity of stations.Therefore,based on the China Meteorological Forcing Dataset,which is composed of data from more than 1,000 ground-based observation sites and multiple remote sensing grid meteorological dataset,we present the first high spatiotemporal-resolution daily SPI/SPEI raster datasets over China.It spans from 1979 to 2018,with a spatial resolution of 0.1°×0.1°,a temporal resolution of 1-day,and the timescales of 30-,90-,and 360-days.Results show that the spatial distributions of drought event characteristics detected by the daily SPI/SPEI are consistent with the monthly SPI/SPEI.The correlation between the daily value of the 12-month scale and the monthly value of SPI/SPEI is the strongest,with linear correlation,Nash-Sutcliffe coefficient,and normalized root mean square error of 0.98,0.97,and 0.04,respectively.The daily SPI/SPEI is shown to be more sensitive to flash drought than the monthly SPI/SPEI.Our improved SPI/SPEI shows high accuracy and credibility,presenting enhanced results when compared to the monthly SPI/SPEI.The total data volume is up to 150 GB,compressed to 91 GB in Network Common Data Form(NetCDF).It can be available from Figshare(https://doi.org/10.6084/m9.figshare.c.5823533)and ScienceDB(https://doi.org/10.57760/sciencedb.j00076.00103).展开更多
3D city models associate a database of a city to a rigorous geospatial representation that is close to the visible reality by combining appearance, geometry, and semantics. As such, these models may include tools that...3D city models associate a database of a city to a rigorous geospatial representation that is close to the visible reality by combining appearance, geometry, and semantics. As such, these models may include tools that convey attribute analysis, not only at the statistical level but also in terms of visual appearance of the objects, thus allowing the generation of new knowledge about a phenomenon or its effects. Lisbon is a city with a moderate level of seismic risk, and has been hit in the past by strong earthquakes. Several seismic vulnerability studies of buildings have been carried out in Lisbon. These studies generate different scenarios that consider the magnitude and source location of potential earthquakes. The results of these studies were presented as maps obtained from crossing information contained in 2D layers and presented in a GIS environment. In the present study a seismic vulnerability assessment of Lisbon's buildings held in 2D is extended to the third dimension, which refines the resolution and the set of parameters and explores the gains of spatial analysis in 3D representations. The numerous parameters that contribute to assess seismic vulnerability of buildings may be analyzed individually or simultaneously as well as in multiple seismic scenarios. Although covering all residential buildings in Lisbon, the application of the 3Dcity model is demonstrated with more detail in three pilot areas.展开更多
The widespread W-(Mo)-Sn-Nb-Ta polymetallic mineralization in Southeast(SE)China is genetically associated with Mesozoic highly fractionated granitic rocks.Such rocks have enigmatic mineralogical and geochemical featu...The widespread W-(Mo)-Sn-Nb-Ta polymetallic mineralization in Southeast(SE)China is genetically associated with Mesozoic highly fractionated granitic rocks.Such rocks have enigmatic mineralogical and geochemical features,making its petrogenesis an intensely debated topic.To better understand the underlying magma evolution processes,petrography,garnet chemistry and whole-rock major and trace element data are reported for Jurassic highly fractionated granitic rocks and associated microgranite and aplitepegmatite dikes from Macao and compared with coeval similar granitic rocks from nearby areas in SE China.Despite the fact that the most evolved rocks in Macao are garnet-bearing aplite-pegmatite dikes,the existence of coeval two-mica and garnet-bearing biotite and muscovite granites displaying more evolved compositions(e.g.,lower Zr/Hf ratios)indicates that the differentiation sequence reached higher degrees of fractionation at a regional scale.Although crystal fractionation played an important role,late-stage fluid/melt interactions,involving F-rich fluids,imparted specific geochemical characteristics to Macao and SE China highly fractionated granitic rocks such as the non-CHARAC(CHArge-and-RAdius-Controlled)behavior of trace elements,leading,for example,to non-chondritic Zr/Hf ratios,Rare Earth Elements(REE)tetrad effects and Nb-Ta enrichment and fractionation.Such process contributed to the late-stage crystallization of accessory phases only found in these highly evolved facies.Among the latter,two populations of garnet were identified in MGI(Macao GroupⅠ)highly fractionated granitic rocks:small grossular-poor euhedral grains and large grossular-rich skeletal garnet grains with quartz inclusions.The first group was mainly formed through precipitation from highly evolved Mn-rich slightly peraluminous melts under low-pressure and relatively low temperature(~700℃)conditions.Assimilation of upper crust metasedimentary materials may have contributed as a source of Mn and Al to the formation of garnet.The second group has a metasomatic origin related to the interaction of magmatic fluids with previously crystallized mineral phases and,possibly,with assimilated metasedimentary enclaves or surrounding metasedimentary strata.The highly fractionated granitic rocks in Macao represent the first stage in the development of granite-related W-(Mo)-Sn-Nb-Ta mineralization associated with coeval more evolved lithotypes in SE China.展开更多
Due to climate change,growing urbanization,and population migration the social and economic impacts of natural hazards have been increasing worldwide.The challenge for risk science,both methodologically and conceptual...Due to climate change,growing urbanization,and population migration the social and economic impacts of natural hazards have been increasing worldwide.The challenge for risk science,both methodologically and conceptually,is to integrate robust multi-hazard evaluation models with展开更多
基金supported by the Macao Science and Technology Development Fund (FDCT 043/2014/A1)support of FCT (Portugal) through UID/GEO/ 50019/2013 to Instituto Dom Luiz,Universidade de Lisboa
文摘Six new high precision U-Pb zircon ID-TIMS ages plus thirteen in situ high spatial resolution U-Pb zircon LA-MC-ICPMS ages are reported from Jurassic plutonic(metaluminous to weakly peraluminous biotite granites)and Jurassic to Cretaceous hypabyssal(dacites)rocks from Macao.Despite its relatively small area(~30 km^2),the new ages tightly constrain the Macao granitic magmatism to two periods ranging from 164.5±0.6 Ma to 162.9±0.7 Ma and 156.6±0.2 Ma to 155.5±0.8 Ma,separated by ca.6 Ma.Inherited zircons point to the existence of a basement with ages up to Paleo-Proterozoic and late Archean in the region.In addition,younger dacitic rocks were dated at 150.6±0.6 Ma and<120 Ma.U-Pb zircon ages and whole-rock REE data of Macao granites indicate that the first pulse is also represented in Hong Kong and Southeast(SE)China,while magmatism with the chemical characteristics of the second pulse seems to not be represented outside Macao.The two granitic magmatic pulses have distinct mineralogical and geochemical features that support their discrete nature rather than a continuum of comagmatic activity and suggest that the Macao granitic suite was incrementally assembled during a period of ca.9 Ma,a hypothesis also extendable to the neighboring Hong Kong region for a time lapse of ca.24 Ma.In Macao,the transition from granitic magmatism(Middle to Upper Jurassic)to the younger dacite dykes(Upper Jurassic to Lower Cretaceous)most likely corresponds to a change in the regional tectonic setting,from an extensional regime related with foundering of the subducting paleoPacific plate during the Early Yanshanian period to the reestablishment of a normal subduction system in SE China during the Late Yanshanian period.
文摘The Anti-Atlas belt of southern Morocco is situated on the northern edge of the West African craton(WAC).It corresponds to a broad anticlinorium some 800 km long and 200 km wide,trending ENE-WSW,parallel to the
文摘We present a new tracksite with multiple dinosaur tracks from the lowermost Barremian (Lower Cretaceous) of the Cape Espichel (Sesimbra, Portugal). The tracks are localized on three beds on the top carbonate beds of the Areia do Mastro Formation. Those bioclastic, nodular limestones were deposited in a very shallow subtidal-intertidal, restricted lagoon environment. The track surfaces are very dinoturbated, with a substantial number of tracks. Several tracks assign to sauropods, ornithopods and theropods dinosaurs were recorded. Due to heavy bioturbation and the preservation conditions, it is not possible to define trackways;some preliminary work done on the tracks could disclose some behaviours of their producers. Several species of carnivore and herbivore dinosaurs crossed that large area at different times. Herbivores may have used the lagoon margin as passage between feeding spots, while carnivores frequented the area to hunt in groups or individually.
文摘Maritime transportation, widely used both in international transport of goods and touristic purposes, has been identified as a significant source of ultrafine particles (UFP). In-land passenger ferry is a source of UFP far less addressed;however, in locations with relatively high frequency of this transportation mode, it is expected that they contribute to an increase of their concentration. Moreover, the negative effects of UFP on human health and environment are known and therefore, monitoring UFP produced by ferries is vital to assess the degree of exposure of who work or live close to ferries’ terminals or downwind to their cruising path. This work aims to study the influence of in-land ferries activities on UFP in the urban/suburban areas near ferries’ terminals and downwind across the cruising path. The UFP monitoring campaign was carried out from September to December 2018 for 19 non-consecutive periods. The sampling sites were chosen in order to maximize measurements under downwind conditions and allow the association between ferry operation and UFP concentration response. Based on data collected, correlation analysis was performed between ferry’s traffic and particle number counting (PNC) of UFP, and also with meteorological variables. Results show an increase in PNC ranging from 25 to 197% during the third minute around a ferry movement and are moderate to positive significant correlations between PNC values and the number of ferry operations (r = 0.79 to r = 0.94), showing that UFP emitted by in-land ferries contributes to PNC increase. Moreover, negative correlations (r = -0.85 to r = -0.93) between PNC and wind intensity were also found.
基金funded by the Portuguese Portuguese Fundação para a Ciência e a Tecnologia(FCT)I.P./MCTES through IDMEC under LAETA,Project:UIDB/50022/2020(https://doi.org/10.54499/UIDB/50022/2020),UIDP/50022/2020(https://doi.org/10.54499/UIDP/50022/2020)and through national funds(PIDDAC),through IDL–UIDB/50019/2020 https://doi.org/10.54499/UIDB/50019/2020),UIDP/50019/2020(https://doi.org/10.54499/UIDP/50019/2020)and LA/P/0068/2020(https://doi.org/10.54499/LA/P/0068/2020)and the FCT Studentship 2021.06299.BD(G Pontes Luz)。
文摘Home Energy Management Systems(HEMS)are increasingly relevant for demand-side management at the residential level by collecting data(energy,weather,electricity prices)and controlling home appliances or storage systems.This control can be performed with classical models that find optimal solutions,with high real-time computational cost,or data-driven approaches,like Reinforcement Learning,that find good and flexible solutions,but depend on the availability of load and generation data and demand high computational resources for training.In this work,a novel HEMS is proposed for the optimization of an electric battery operation in a real,online and data-driven environment that integrates state-of-the-art load forecasting combining CNN and LSTM neural networks to increase the robustness of decisions.Several Reinforcement Learning agents are trained with different algorithms(Double DQN,Dueling DQN,Rainbow and Proximal Policy Optimization)in order to minimize the cost of electricity purchase and to maximize photovoltaic self-consumption for a PV-Battery residential system.Results show that the best Reinforcement Learning agent achieves a 35%reduction in total cost when compared with an optimization-based agent.
基金support from the Xunta de Galicia(Consellería de Cultura,Educacion e Universidade)under grant No.´ED481A2020/193.R.M.T was supported by the Portuguese Science Foundation(FCT)through the project AMOTHEC(https://doi.org/10.54499/DRI/India/0098/2020)EPhysLab members are supported by the SETESTRELO project(grant no.PID2021-122314OB-I00)funded by the Ministerio de Ciencia+4 种基金Innovacion y Universidades,Spain(MICIU/AEI/´10.13039/501100011033)Xunta de Galicia under the Project ED431C2021/44(Programa de Consolidacion e Estructuraci´on´de Unidades de Investigacion Competitivas(Grupos de Ref-´erencia Competitiva)Consellería de Cultura,Educacion e´Universidade)by the European Union‘ERDF A way of making Europe’support provided by CESGA(Centro de Supercomputacion de Galicia)and RES´(Red Espanola de Supercomputaci˜on)。
文摘In this study,we identified the moisture sources for the precipitation associated with tropical cyclones(TCs)during the rapid intensification(RI)process from 1980 to 2018 by applying a Lagrangian moisture source diagnostic method.We detected sixteen regions on a global scale for RI events distributed as follows:four in the North Atlantic(NATL),two in the Central and East Pacific Ocean(NEPAC),the North Indian Ocean(NIO)and South Indian Ocean(SIO),and three in the South Pacific Ocean(SPO)and the Western North Pacific Ocean(WNP).The moisture uptake(MU)mostly was from the regions where TCs underwent RI.The Western NATL,tropical NATL,Caribbean Sea,the Gulf of Mexico and the Central America and Mexico landmass supported~85.4%of the precipitating moisture in the NATL,while the latter source and the eastern North Pacific Ocean provided the higher amount of moisture in NEPAC(~84.3%).The Arabian Sea,the Bay of Bengal and the Indian Peninsula were the major moisture sources in NIO,contributing approximately 81.3%.The eastern and western parts of the Indian Ocean supplied most of the atmospheric humidity in SIO(~83.8%).The combined contributions(~87.9%)from the western and central SPO and the Coral Sea were notably higher in SPO.Meanwhile,TCs in the WNP basin mostly received moisture from the western North Pacific Ocean,the Philippine Sea and the China Sea,accounting for 80.1%.The remaining moisture support in each basin came from the summed contributions of the remote sources.Overall,RI TCs gained more moisture up to 2500 km from the cyclone centre than those slow intensification(SI)and the total MU was approximately three times higher during RI than SI.Finally,the patterns of the MU differences respond to the typical pathways of moisture transport in each basin.
基金the China meteorological forcing dataset.Thanks to the Natural Science Foundation of Fujian Province(No.2021J01627,No.2020J01465)the National Natural Science Foundation of China(No.41601562,No.32071776)for their financial support.
文摘Standardized Precipitation Index(SPI)and Standardized Precipitation Evapotranspiration Index(SPEI),traditionally derived at a monthly scale,are widely used drought indices.To overcome temporalresolution limitations,we have previously developed and published a well-validated daily SPI/SPEI in situ dataset.Although having a high temporal resolution,this in situ dataset presents low spatial resolution due to the scarcity of stations.Therefore,based on the China Meteorological Forcing Dataset,which is composed of data from more than 1,000 ground-based observation sites and multiple remote sensing grid meteorological dataset,we present the first high spatiotemporal-resolution daily SPI/SPEI raster datasets over China.It spans from 1979 to 2018,with a spatial resolution of 0.1°×0.1°,a temporal resolution of 1-day,and the timescales of 30-,90-,and 360-days.Results show that the spatial distributions of drought event characteristics detected by the daily SPI/SPEI are consistent with the monthly SPI/SPEI.The correlation between the daily value of the 12-month scale and the monthly value of SPI/SPEI is the strongest,with linear correlation,Nash-Sutcliffe coefficient,and normalized root mean square error of 0.98,0.97,and 0.04,respectively.The daily SPI/SPEI is shown to be more sensitive to flash drought than the monthly SPI/SPEI.Our improved SPI/SPEI shows high accuracy and credibility,presenting enhanced results when compared to the monthly SPI/SPEI.The total data volume is up to 150 GB,compressed to 91 GB in Network Common Data Form(NetCDF).It can be available from Figshare(https://doi.org/10.6084/m9.figshare.c.5823533)and ScienceDB(https://doi.org/10.57760/sciencedb.j00076.00103).
基金partially supported by the Project FCT UID/GEO/50019/2013-Instituto Dom Luiz
文摘3D city models associate a database of a city to a rigorous geospatial representation that is close to the visible reality by combining appearance, geometry, and semantics. As such, these models may include tools that convey attribute analysis, not only at the statistical level but also in terms of visual appearance of the objects, thus allowing the generation of new knowledge about a phenomenon or its effects. Lisbon is a city with a moderate level of seismic risk, and has been hit in the past by strong earthquakes. Several seismic vulnerability studies of buildings have been carried out in Lisbon. These studies generate different scenarios that consider the magnitude and source location of potential earthquakes. The results of these studies were presented as maps obtained from crossing information contained in 2D layers and presented in a GIS environment. In the present study a seismic vulnerability assessment of Lisbon's buildings held in 2D is extended to the third dimension, which refines the resolution and the set of parameters and explores the gains of spatial analysis in 3D representations. The numerous parameters that contribute to assess seismic vulnerability of buildings may be analyzed individually or simultaneously as well as in multiple seismic scenarios. Although covering all residential buildings in Lisbon, the application of the 3Dcity model is demonstrated with more detail in three pilot areas.
基金supported by the Macao Science and Technology Development Fund(No.FDCT 043/2014/A1)the financial FCT support(No.UIDB/50019/2020–IDL)。
文摘The widespread W-(Mo)-Sn-Nb-Ta polymetallic mineralization in Southeast(SE)China is genetically associated with Mesozoic highly fractionated granitic rocks.Such rocks have enigmatic mineralogical and geochemical features,making its petrogenesis an intensely debated topic.To better understand the underlying magma evolution processes,petrography,garnet chemistry and whole-rock major and trace element data are reported for Jurassic highly fractionated granitic rocks and associated microgranite and aplitepegmatite dikes from Macao and compared with coeval similar granitic rocks from nearby areas in SE China.Despite the fact that the most evolved rocks in Macao are garnet-bearing aplite-pegmatite dikes,the existence of coeval two-mica and garnet-bearing biotite and muscovite granites displaying more evolved compositions(e.g.,lower Zr/Hf ratios)indicates that the differentiation sequence reached higher degrees of fractionation at a regional scale.Although crystal fractionation played an important role,late-stage fluid/melt interactions,involving F-rich fluids,imparted specific geochemical characteristics to Macao and SE China highly fractionated granitic rocks such as the non-CHARAC(CHArge-and-RAdius-Controlled)behavior of trace elements,leading,for example,to non-chondritic Zr/Hf ratios,Rare Earth Elements(REE)tetrad effects and Nb-Ta enrichment and fractionation.Such process contributed to the late-stage crystallization of accessory phases only found in these highly evolved facies.Among the latter,two populations of garnet were identified in MGI(Macao GroupⅠ)highly fractionated granitic rocks:small grossular-poor euhedral grains and large grossular-rich skeletal garnet grains with quartz inclusions.The first group was mainly formed through precipitation from highly evolved Mn-rich slightly peraluminous melts under low-pressure and relatively low temperature(~700℃)conditions.Assimilation of upper crust metasedimentary materials may have contributed as a source of Mn and Al to the formation of garnet.The second group has a metasomatic origin related to the interaction of magmatic fluids with previously crystallized mineral phases and,possibly,with assimilated metasedimentary enclaves or surrounding metasedimentary strata.The highly fractionated granitic rocks in Macao represent the first stage in the development of granite-related W-(Mo)-Sn-Nb-Ta mineralization associated with coeval more evolved lithotypes in SE China.
文摘Due to climate change,growing urbanization,and population migration the social and economic impacts of natural hazards have been increasing worldwide.The challenge for risk science,both methodologically and conceptually,is to integrate robust multi-hazard evaluation models with
