The power conversion efficiency for single-junction solar cells is limited by the Shockley-Quiesser limit.An effective approach to realize high efficiency is to develop multi-junction cells.These years have witnessed ...The power conversion efficiency for single-junction solar cells is limited by the Shockley-Quiesser limit.An effective approach to realize high efficiency is to develop multi-junction cells.These years have witnessed the rapid development of organic–inorganic perovskite solar cells.The excellent optoelectronic properties and tunable bandgaps of perovskite materials make them potential candidates for developing tandem solar cells,by combining with silicon,Cu(In,Ga)Se_(2)and organic solar cells.In this review,we present the recent progress of perovskite-based tandem solar cells,including perovskite/silicon,perovskite/perovskite,perovskite/Cu(In,Ga)Se_(2),and perovskite/organic cells.Finally,the challenges and opportunities for perovskite-based tandem solar cells are discussed.展开更多
Adsorptive separation of p-xylene(pX)from xylene isomers is a key process in chemical industry,but known adsorbents cannot simultaneously achieve high adsorption selectivity,capacity,and rate.Here,we demonstrate gatin...Adsorptive separation of p-xylene(pX)from xylene isomers is a key process in chemical industry,but known adsorbents cannot simultaneously achieve high adsorption selectivity,capacity,and rate.Here,we demonstrate gating ultramicropore as a solution for this challenge.Slight modification of the synthetic condition gives rise to isomeric metal-organic frameworksα-[Zn(pba)](MAF-88,H2pba=4-(1H-pyrazol-4-yl)benzoic acid)andβ-[Zn(pba)](MAF-89)possessing similar pillared-column structures,porosities,and high pX capacities of 2.0 mmol g^(−1),but very different framework/pore topologies,pore sizes,and pX selectivities.For binary and ternary mixtures of liquid xylene isomers,MAF-88 with narrow one-dimensional(1D)channels shows pX selectivity of 11 and 1.6,while MAF-89 with 3D-connected quasi-discrete pores shows pX selectivity up to 221 and 46,respectively.Thermogravimetry,differential scanning calorimetry,and time-dependent separation experiments reveal that the kinetic effects of the gating pores play more important roles than the thermodynamic effects,which is further confirmed by single-crystal X-ray diffraction and computational simulations.展开更多
All-perovskite tandem integrated photovoltaics (APTI-PVs),which maximize the light-harvesting in full-wavelength spectral range and combine the fascinating advantages of low-cost, solution-processability, and high-per...All-perovskite tandem integrated photovoltaics (APTI-PVs),which maximize the light-harvesting in full-wavelength spectral range and combine the fascinating advantages of low-cost, solution-processability, and high-performance, are regarded as one of the most promising solutions for new-generation PV technology[1]. Encouragingly, the power conversion efficiency (PCE) of twoterminal APTI-PV device now has been surpassed the single-junction PSCs and reached a high level of exceeding 28%[2].展开更多
基金the National Natural Science Foundation of China(51773045,21772030,51922032,and 21961160720)for financial support。
文摘The power conversion efficiency for single-junction solar cells is limited by the Shockley-Quiesser limit.An effective approach to realize high efficiency is to develop multi-junction cells.These years have witnessed the rapid development of organic–inorganic perovskite solar cells.The excellent optoelectronic properties and tunable bandgaps of perovskite materials make them potential candidates for developing tandem solar cells,by combining with silicon,Cu(In,Ga)Se_(2)and organic solar cells.In this review,we present the recent progress of perovskite-based tandem solar cells,including perovskite/silicon,perovskite/perovskite,perovskite/Cu(In,Ga)Se_(2),and perovskite/organic cells.Finally,the challenges and opportunities for perovskite-based tandem solar cells are discussed.
基金supported by the National Natural Science Foundation of China(21731007,22090061,21821003,22161021)the support of Jiangxi Province(jxsq2018106041)the“Young Elite Scientists Sponsorship Program”by CAST。
文摘Adsorptive separation of p-xylene(pX)from xylene isomers is a key process in chemical industry,but known adsorbents cannot simultaneously achieve high adsorption selectivity,capacity,and rate.Here,we demonstrate gating ultramicropore as a solution for this challenge.Slight modification of the synthetic condition gives rise to isomeric metal-organic frameworksα-[Zn(pba)](MAF-88,H2pba=4-(1H-pyrazol-4-yl)benzoic acid)andβ-[Zn(pba)](MAF-89)possessing similar pillared-column structures,porosities,and high pX capacities of 2.0 mmol g^(−1),but very different framework/pore topologies,pore sizes,and pX selectivities.For binary and ternary mixtures of liquid xylene isomers,MAF-88 with narrow one-dimensional(1D)channels shows pX selectivity of 11 and 1.6,while MAF-89 with 3D-connected quasi-discrete pores shows pX selectivity up to 221 and 46,respectively.Thermogravimetry,differential scanning calorimetry,and time-dependent separation experiments reveal that the kinetic effects of the gating pores play more important roles than the thermodynamic effects,which is further confirmed by single-crystal X-ray diffraction and computational simulations.
基金supported by the National Natural Science Foundation of China (22005355)Guangdong Basic and Applied Basic Research Foundation (2022A1515010282)the Fundamental Research Funds for the Central Universities,Sun Yat-sen University(22qntd2305)。
文摘All-perovskite tandem integrated photovoltaics (APTI-PVs),which maximize the light-harvesting in full-wavelength spectral range and combine the fascinating advantages of low-cost, solution-processability, and high-performance, are regarded as one of the most promising solutions for new-generation PV technology[1]. Encouragingly, the power conversion efficiency (PCE) of twoterminal APTI-PV device now has been surpassed the single-junction PSCs and reached a high level of exceeding 28%[2].
