A new one-dimensional molecule based on the linkage of [Mo7024] clusters and [BiL] （L = pyridine-2,6-dicarboxylic acid） assembles under ambient conditions. The title compound was characterized by X-ray powder diffra...A new one-dimensional molecule based on the linkage of [Mo7024] clusters and [BiL] （L = pyridine-2,6-dicarboxylic acid） assembles under ambient conditions. The title compound was characterized by X-ray powder diffraction, IR and UV spectra, thermogravimetric analysis, and single-crystal X-ray diffraction. Crystal data： C7H38BiMo7N5037, Mr = 1664.95, monoclinic, space group C2/c, a = 24.312（2）, b = 21.4869（18）, c = 18.5423（16） A, β = 111.6490（10）°, V = 9002.9（13） A3, Z = 8, μ = 5.883 mm-1, F（000） = 6304, GOF = 1.045, R = 0.0365 and wR = 0.1062.展开更多
A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu（phen）（en）} {Cu（phen）} {Cu3（phen）3（α-AsW9033）}]（OH）·3H2O （1, en = ethylene-diamine, 1,10-phen = 1,10-phe...A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu（phen）（en）} {Cu（phen）} {Cu3（phen）3（α-AsW9033）}]（OH）·3H2O （1, en = ethylene-diamine, 1,10-phen = 1,10-phenanthroline） has been synthesized by controlling the reaction process and characterized by infrared （IR） spectroscopy, elemental analysis, and thermogravimetric （TG） analysis. Crystal data for 1： C62H56AsCusN12O37W9, Mr=3608.46, monoclinic, space group P21/n, a = 13.245（4）, b = 25.692（9）, c = 24.670（8） A, fl = 99.251（6）°, V= 8286（5） A3, Z = 4, GOOF = 1.103, R = 0.0560, wR = 0.1285. In 1, the vacant sites of the trivacant Keggin anion [α-AsW9O33]9- are occupied by three same copper coordination cations [Cu（phen）]2＋. Meanwhile, the lacunary anion [α-AsWgO33]9-, is capped by two kinds of copper coordination cations [Cu（phen）]2＋ and [Cu（Dhen）（en）]2＋, resulting in an unorecedented Dolvcation structure with Cs svmmetrv.展开更多
基金supported by the NNSFC and the NSF from Henan Province(No.21171048,122300410126,and 13A150058)
文摘A new one-dimensional molecule based on the linkage of [Mo7024] clusters and [BiL] （L = pyridine-2,6-dicarboxylic acid） assembles under ambient conditions. The title compound was characterized by X-ray powder diffraction, IR and UV spectra, thermogravimetric analysis, and single-crystal X-ray diffraction. Crystal data： C7H38BiMo7N5037, Mr = 1664.95, monoclinic, space group C2/c, a = 24.312（2）, b = 21.4869（18）, c = 18.5423（16） A, β = 111.6490（10）°, V = 9002.9（13） A3, Z = 8, μ = 5.883 mm-1, F（000） = 6304, GOF = 1.045, R = 0.0365 and wR = 0.1062.
基金supported by the Foundation of Education Department of Henan Province(14A150028)
文摘A new organic-inorganic hybrid copper-substituted arsenatotungstate complex formulated as [{Cu（phen）（en）} {Cu（phen）} {Cu3（phen）3（α-AsW9033）}]（OH）·3H2O （1, en = ethylene-diamine, 1,10-phen = 1,10-phenanthroline） has been synthesized by controlling the reaction process and characterized by infrared （IR） spectroscopy, elemental analysis, and thermogravimetric （TG） analysis. Crystal data for 1： C62H56AsCusN12O37W9, Mr=3608.46, monoclinic, space group P21/n, a = 13.245（4）, b = 25.692（9）, c = 24.670（8） A, fl = 99.251（6）°, V= 8286（5） A3, Z = 4, GOOF = 1.103, R = 0.0560, wR = 0.1285. In 1, the vacant sites of the trivacant Keggin anion [α-AsW9O33]9- are occupied by three same copper coordination cations [Cu（phen）]2＋. Meanwhile, the lacunary anion [α-AsWgO33]9-, is capped by two kinds of copper coordination cations [Cu（phen）]2＋ and [Cu（Dhen）（en）]2＋, resulting in an unorecedented Dolvcation structure with Cs svmmetrv.
