Iron-rich electrolytic manganese residue(IREMR)is an industrial waste produced during the processing of electrolytic metal manganese,and it contains certain amounts of Fe and Mn resources and other heavy metals.In thi...Iron-rich electrolytic manganese residue(IREMR)is an industrial waste produced during the processing of electrolytic metal manganese,and it contains certain amounts of Fe and Mn resources and other heavy metals.In this study,the slurry electrolysis technique was used to recover high-purity Fe powder from IREMR.The effects of IREMR and H2SO4 mass ratio,current density,reaction temper-ature,and electrolytic time on the leaching and current efficiencies of Fe were studied.According to the results,high-purity Fe powder can be recovered from the cathode plate,and the slurry electrolyte can be recycled.The leaching efficiency,current efficiency,and purity of Fe reached 92.58%,80.65%,and 98.72wt%,respectively,at a 1:2.5 mass ratio of H2SO4 and IREMR,reaction temperature of 60℃,electric current density of 30 mA/cm^(2),and reaction time of 8 h.In addition,vibrating sample magnetometer(VSM)analysis showed that the coercivity of electrolytic iron powder was 54.5 A/m,which reached the advanced magnetic grade of electrical pure-iron powder(DT4A coercivity standard).The slurry electrolytic method provides fundamental support for the industrial application of Fe resource recovery in IRMER.展开更多
The concept of zero waste is an ideal situation that will require different solutions for different categories of waste.Electronic waste(E-waste),the fastest growing category of solid hazardous waste presents various ...The concept of zero waste is an ideal situation that will require different solutions for different categories of waste.Electronic waste(E-waste),the fastest growing category of solid hazardous waste presents various unique challenges.Electronic product repair,reuse and remanufacture(3re)are crucial for effective source reduction of E-waste and the integration of the electronics industry into a circular or zero-waste economy framework.Increasingly,3re implementation is restricted by regulatory difficulties,particularly the invocation of copyright laws.Here,we use the examples of electronic printer cartridges and restored compact discs(CDs)to identify the challenges and to explore solutions for managing the risks associated with E-waste through circular economy and the opportunities presented by innovative Blockchain solutions.A set of international consensuses on judicial definitions,such as 3re,refurbish fake/counterfeit product and copyright exhaustion,are proposed to accelerate source reduction in E-waste management toward the goal of zero waste.展开更多
基金supported by the Key Research and Development Program of Guangxi Province,China (No.AB23075174)the National Natural Science Foundation of China (No.52174386)the Science and Technology Plan Project of Sichuan Province,China (No.2022YFS0459).
文摘Iron-rich electrolytic manganese residue(IREMR)is an industrial waste produced during the processing of electrolytic metal manganese,and it contains certain amounts of Fe and Mn resources and other heavy metals.In this study,the slurry electrolysis technique was used to recover high-purity Fe powder from IREMR.The effects of IREMR and H2SO4 mass ratio,current density,reaction temper-ature,and electrolytic time on the leaching and current efficiencies of Fe were studied.According to the results,high-purity Fe powder can be recovered from the cathode plate,and the slurry electrolyte can be recycled.The leaching efficiency,current efficiency,and purity of Fe reached 92.58%,80.65%,and 98.72wt%,respectively,at a 1:2.5 mass ratio of H2SO4 and IREMR,reaction temperature of 60℃,electric current density of 30 mA/cm^(2),and reaction time of 8 h.In addition,vibrating sample magnetometer(VSM)analysis showed that the coercivity of electrolytic iron powder was 54.5 A/m,which reached the advanced magnetic grade of electrical pure-iron powder(DT4A coercivity standard).The slurry electrolytic method provides fundamental support for the industrial application of Fe resource recovery in IRMER.
基金supported by a grant from the National Natural Science Foundation of China(Grant No.51974262)the Science&Technology Pillar Program of Sichuan Province(No.2019YFS0450)support from the Lincoln Dynamic Foundation’s World Institute for Sustainable Development of Materials(WISDOM).
文摘The concept of zero waste is an ideal situation that will require different solutions for different categories of waste.Electronic waste(E-waste),the fastest growing category of solid hazardous waste presents various unique challenges.Electronic product repair,reuse and remanufacture(3re)are crucial for effective source reduction of E-waste and the integration of the electronics industry into a circular or zero-waste economy framework.Increasingly,3re implementation is restricted by regulatory difficulties,particularly the invocation of copyright laws.Here,we use the examples of electronic printer cartridges and restored compact discs(CDs)to identify the challenges and to explore solutions for managing the risks associated with E-waste through circular economy and the opportunities presented by innovative Blockchain solutions.A set of international consensuses on judicial definitions,such as 3re,refurbish fake/counterfeit product and copyright exhaustion,are proposed to accelerate source reduction in E-waste management toward the goal of zero waste.
