Carbonates have been known to act as hydrocarbon source rocks, but their basic geochemical and associated hydrocarbon generation characteristics remain not well understood as they occur with argillaceous source rocks ...Carbonates have been known to act as hydrocarbon source rocks, but their basic geochemical and associated hydrocarbon generation characteristics remain not well understood as they occur with argillaceous source rocks in most cases, and the hydrocarbon generation from each rock type is di cult to distinguish, forming one of puzzling issues within the field of petroleum geology and geochemistry. To improve the understanding of this critical issue, this paper reviews recent advances in this field and provides a summary of key areas that can be studied in future. Results show that carbonate source rocks are generally associated with high-salinity environments with low amounts of terrestrial inputs and low dissolved oxygen contents. Petrographically, these source rocks are dark gray or black, fine-grained, stratified, and contain bacterial and algal bioprecursors along with some other impurities. They generally have low organic matter contents, although these can vary significantly in di erent cases(e.g., the total organic carbon contents of marine and lacustrine carbonate source rocks in China are generally 0.1%–1.0% and 0.4%–4.0%, respectively). These rocks contain type I and type II kerogen, meaning there is a lack of vitrinites. This means that assessment of the maturity of the organic matter in these sediments needs to use non-traditional techniques rather than vitrinite reflectance. In terms of molecular geochemistry, carbonate source rocks have typical characteristics indicative of generally reducing and saline environments and lower organism-dominated bioprecursors of organic matter, e.g., high contents of sulfur compounds, low Pr/Ph ratios, and dominance of n-alkanes. Most of the carbonate source rocks are typically dominated by D-type organic facies in an oxidized shallow water mass, although high-quality source rocks generally contain A-and B-type organic facies in saline lacustrine and marine-reducing environments, respectively. The hydrocarbon generation model for the carbonate source rocks can involve early, middle, and late stages, with a diversity of hydrocarbons within these rocks, which can be aggregated, adsorbed, enclosed within minerals, or present as inclusions. This in turn implies that the large-scale hydrocarbon expulsion from these rocks is reliant on brittle deformation caused by external forces. Finally, a number of aspects of these source rocks remain unclear and need further study, including the e ectiveness of carbonates as hydrocarbon source rocks, bioprecursors, and hydrocarbon generation models of carbonate source rock, and the di erences between marine and lacustrine carbonate source rocks.展开更多
Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carb...Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carbon dioxide utilization and sequestration,but it also alleviates the environmental burden.However,significant challenges exist in assessment of CO_(2)footprint and water-rock interactions,due to complex geochemical processes.Herein this study conducts a three-dimensional,multicomponent reactive transport model(RTM)of a field-scale CO_(2)and O_(2)ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin,China.Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas(CO_(2))footprint and environmental impact(SO_(4)^(2–))of the CO_(2)and O_(2)ISL,considering the potential chemical reaction network for uranium recovery at the field scale.RTM results demonstrate that the fate of the CO_(2)could be summarized as injected CO_(2)dissolution,dissolved CO_(2)mineralization and storage of CO_(2)as a gas phase during the CO_(2)and O_(2)ISL process.Furthermore,compared to acid ISL,CO_(2)and O_(2)ISL has a potentially smaller environmental footprint,with 20%of SO_(4)^(2–)concentration in the aquifer.The findings improve our fundamental understanding of carbon utilization in a long-term CO_(2)and O_(2)ISL system and provide important environmental implications when considering complex geochemical processes.展开更多
Shales are a major sink for K into seawater delivered from continental weathering,and are potential recorders of K cycling.High precision K isotope analyses reveal a[0.6%variation in δ^41K values(41K/39K relative to ...Shales are a major sink for K into seawater delivered from continental weathering,and are potential recorders of K cycling.High precision K isotope analyses reveal a[0.6%variation in δ^41K values(41K/39K relative to NIST SRM 3141a)from a set of well characterized postArchean Australian shale(PAAS)samples.By contrast,loess samples have relatively homogenous δ^41K values(-0.5±0.1%),which may represent the average K composition of upper continental crust.Most of the shales analyzed in this study have experienced K enrichment relative to average continental crust,and the majority of them define a trend of decreasing δ^41K value(from-0.5to-0.7%)with increasing K content and K/Na ratio,indicating cation exchange in clays minerals is accompanied by K isotope fractionation.Several shale samples do not follow the trend and have elevated δ^41K values up to-0.1%,and these samples are characterized by variable Fe isotope compositions,which reflect post-depositional processes.The K isotope variability observed in shales,in combination with recent findings about K isotope fractionation during continental weathering,indicates that K isotopes fractionate during cycling of K between different reservoirs,and K isotopes in sediments may be used to trace geological cycling of K.展开更多
Co(Ⅱ)and Ni(Ⅱ)are two common toxic heavy metals,and may simultaneously exist in contaminated water,soil,and sediment systems in Earth’s surface environment.Under this circumstance,competitive adsorption between the...Co(Ⅱ)and Ni(Ⅱ)are two common toxic heavy metals,and may simultaneously exist in contaminated water,soil,and sediment systems in Earth’s surface environment.Under this circumstance,competitive adsorption between the two metals may influence their migration,toxicity,and bioavailability.In this research,the competitive sorption of Co(Ⅱ)and Ni(Ⅱ)on γ-Al_2O_3was studied using both macroscopic sorption experiments and extended X-ray absorption fine structure(EXAFS)spectroscopy.Results suggest that Ni(Ⅱ)reduced the amount of Co(Ⅱ)sorption in a binary-solute system at pH 6.0.This is because both Co(Ⅱ)and Ni(Ⅱ)form inner-sphere surface complexes during sorption on γ-Al_2O_3and compete for the surface reactive sites.However,Co(Ⅱ)exhibited a negligible influence on sorption amount of Ni(Ⅱ)under the same conditions,which suggests Ni(Ⅱ)has a stronger affinity to alumina surface.At pH 7.5,Co(Ⅱ)and Ni(Ⅱ)sorption density were much higher than that at pH 6.0,but there no mutual competitive effect was observed.EXAFS analysis further revealed that formation of layered double-hydrated precipitates was the dominant sorption mechanism for both Co(Ⅱ)and Ni(Ⅱ)at pH 7.5.Because this type of sorption does not rely on surface reactive sites,there was no competition between Co(Ⅱ)and Ni(Ⅱ).This finding sheds light on risk assessment and remediation of Ni/Co pollution.展开更多
Geophysical methods have been applied to a wide range of hydrogeological problems. With improvement in geophysical inversion algorithms and measurement tools, significant achievements have been made in the characteriz...Geophysical methods have been applied to a wide range of hydrogeological problems. With improvement in geophysical inversion algorithms and measurement tools, significant achievements have been made in the characterization of subsurface architecture, time-lapse monitoring of hydrogeological process and contaminant plumes delineation. In this paper, we summarize the geophysical methods that are most widely used in hydrogeology including Electrical Resistivity Tomography(ERT), Induced Polarization(IP), Ground Penetrating Radar(GPR) and Electromagnetic Induction(EMI). Three examples including lab and field works are used to demonstrate current application of geophysical methods for characterizing subsurface architecture and contaminant plumes. Though great progress has been made in hydrogeohysics over the last few decades at home and abroad, challenges still remain in practical applications. More recently, hydrogeophysics continues to develop in the areas of establishment of hydrogeophysical models, large-scale architecture characterization, uncertainty analysis, biogeochemical process monitoring and ecosystem science.展开更多
CO_(2)+O_(2) in-situ leaching(ISL)of sandstonetype uranium ore represents the third generation of solution mining in China.In this study,reactive transport modeling of the interaction between hydrodynamic and geochemi...CO_(2)+O_(2) in-situ leaching(ISL)of sandstonetype uranium ore represents the third generation of solution mining in China.In this study,reactive transport modeling of the interaction between hydrodynamic and geochemical reactions is performed to enable better prediction and regulation of the CO_(2)+O_(2) in-situ leaching process of uranium.Geochemical reactions between mining solutions and rock,and the kinetic uranium dissolution controlled by O_(2)(aq)and bicarbonate(HCO_(3)-)are considered in the CO_(2)+O_(2) ISL reactive transport model of a typical sandstone-hosted uranium ore deposit in northern China.The reactive leaching of uranium is most sensitive to the spatial distribution of the mineralogical properties of the uranium deposit.Stochastic geostatistical models are used to represent the uncertainty on the spatial distribution of mineral grades.A Monte Carlo analysis was also performed to simulate the uranium production variability over an entire set of geostatistical realizations.The ISL stochastic simulation performed with the selected geostatistical realizations approximates the uranium production variability well.The simulation results of the ISL reactive transport model show that the extent of the uranium plume is highly dependent on mineralogical heterogeneity.The uncertainty analysis suggests the effect of uranium grade heterogeneity was found to be important to improve the accurate capture of the uncertainty.This study provides guidance for the accurate simulation and dynamic regulation of the CO_(2)+O_(2) leaching process of uranium at the scale of large mining areas.展开更多
This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the...This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the hydrogeological parameters of the aquifer in the study area, the model was calibrated and validated using the observed heads through the integrated trial-and-error and automated techniques. Also, the sensitivity analysis of the model was performed to evaluate the uncertainty associated with the calibrated model. According to the mine construction plan at different mining levels of-500 m,-600 m, and-700 m, the calibrated model was then applied to predict the water yields dependent on the different mining levels. As indicated by the prediction results, the numerical simulation model can systematically describe the groundwater system in the mining area and determine the source of water inrush in this iron mine. In conclusion, numerical analyses carried out in this study can provide guidance to decision-makers in balancing the iron ore mining and mine dewatering in the future.展开更多
The formation of manganese oxides in nature is commonly mediated by microorganisms.In this study,the mineralization of biogenic manganese oxidation mediated by Pseudomanas putida has been experimentally investigated b...The formation of manganese oxides in nature is commonly mediated by microorganisms.In this study,the mineralization of biogenic manganese oxidation mediated by Pseudomanas putida has been experimentally investigated by employing various characterization techniques,including SEM,FESEM,TEM,XRD,and STXM-NEXAFS.The results indicate that Mn^(2+) ions can be oxidized into Mn(Ⅳ) minerals(birnessite and pyrolusite) and Mn(Ⅲ) minerals(hausmannite and feitknechtite),successively.The primary products(birnessite and pyrolusite) further transformed into hausmannite and feitknechtite under Mn^(2+) ion-enriched conditions.However,birnessite and pyrolusite are the endproducts of the continuous microbial oxidation processes.These biogenic Mn oxides are poorly crystallized,which provides them with a high potential for usage in environmental restoration of contaminated soils and waters contaminated with heavy metals.The approaches employed in this study will also enrich genesis research of biological oxidation of Mn(Ⅱ) species in nature.展开更多
This paper focused on nitrate fate in the vadose zone(VZ)and its implications for groundwater vulnerability under different soil types in the agricultural area of Huaihe River Basin,China.Isotopic compositions of nitr...This paper focused on nitrate fate in the vadose zone(VZ)and its implications for groundwater vulnerability under different soil types in the agricultural area of Huaihe River Basin,China.Isotopic compositions of nitrate(δ15N andδ18O)along with NO3-and Cl-concentrations were determined in the VZ-shallow groundwater continuum beneath silty-loam and silty-clay-loam,which are distinctive in texture and organic carbon(OC).In the soil zone(<1 m in depth),measuredδ18O-NO3-suggested the ubiquitous of nitrification regardless of soil types.In the subsoil zone(>1 m in depth),however,the concurrent enrichment ofδ15N-NO3-andδ18O-NO3-indicated the occurrence of denitrification,which showed a dependence on subsoil properties.Specifically,during wheat and maize land uses,denitrification removed as much as 76%-88%of the total nitrate where the subsoil was dominated by stratified OC-rich silty-clay-loam.In contrast,only 0%-28%of the nitrate was degraded via denitrification where the subsoil was composed of uniform,OC-depleted silty-loam.Furthermore,inactive denitrification and higher permeability in the silty-loam VZ implied higher groundwater vulnerability.This observation was consistent with the fact that groundwater NO3--N concentration beneath silty-loam(11.24 mg L-1)was over two times higher than that of the silty-clay-loam(5.32 mg L-1),where stricter fertilization management and conservation strategies should be applied to protect groundwater quality.展开更多
The mineralogy of mare basalts reflects the chemical composition of the magma source, as well as the physical and chemical environment of the rocks' formation. This is significant for understanding the thermal evo...The mineralogy of mare basalts reflects the chemical composition of the magma source, as well as the physical and chemical environment of the rocks' formation. This is significant for understanding the thermal evolution of the Moon. In this study, the spatial distribution of mineralogy on the lunar northern nearside basalts was mapped using the Moon Mineralogy Mapper(M^3) data. The study area, which is an elongated mare, Mare Frigoris and northern Mare Imbrium, was mapped and characterized into 27 units based on multi-source data, including spectrum, terrain and element abundance. We extracted 177 M^3 spectra from fresh craters. Spectral parameters such as absorption center and band area ratio(BAR)were obtained through data processing. The variation of mafic minerals in this region was acquired by analyzing these parameters. The basaltic units in eastern Mare Frigoris, which are older, have been found to be dominated by clinopyroxene with lower CaO compared to the returned lunar samples; this is similar to older basaltic units in Mare Imbrium. The basaltic units of western Mare Frigoris and Sinus Roris which are younger have been found to be rich in olivine. The late-stage basalts in Oceanus Procellarum and Mare Imbrium show the same feature. These widespread olivine-rich basalts suggest uniqueness in the evolution of the Moon. Geographically speaking, Mare Frigoris is an individual mare, but the magma source region has connections with surrounding maria in consideration of mineral differences between western and eastern Frigoris, as well as mineral similarities with maria at the same location.展开更多
The characteristics,formation time,and origin of the sucrosic dolomite reservoirs in the Permian Qixia Formation of northwestern Sichuan Basin are analyzed.Core and outcrop description and microscopic analysis of the ...The characteristics,formation time,and origin of the sucrosic dolomite reservoirs in the Permian Qixia Formation of northwestern Sichuan Basin are analyzed.Core and outcrop description and microscopic analysis of the sucrosic dolomite samples are carried out.It is found that the dolomite has typical features different from other kinds of dolomites:(1)This dolomite is generally medium-coarse in crystal size,and often associated with very finely to finely crystalline dolomite and cave-filling dolomite.(2)Typical identification marks of eogenetic karstification are developed at the top of the upward-shallowing sequence.(3)The medium-coarse crystalline sucrosic dolomite is cut by the early diagenetic karst fabric,and is characterized by dolomite with dissolution edge,dolomite vadose silt in pores,and transgression clay filling between the medium-coarse dolomite crystals.The medium-coarse crystalline sucrosic dolomite was formed earlier than the eogenetic karstification.The sucrosic dolomite with occasional cloudy core and clear rim has bright cathodoluminescence,high inclusions temperature,significant negative skewness carbon and oxygen isotopic compositions,and rare-earth element(REE)pattern similar to seawater,indicating it experienced two periods of dolomitization,evaporative concentration reflux-infiltration and penecontemporaneous seawater circulation hydrothermal fluid dolomitization.The study results not only update the understanding on the dolomitization time of Qixia Formation,demonstrate that the sucrosic dolomite can be formed in the penecontemporaneous stage when seawater reflux superimposed with hydrothermal fluid effects,but also show that the taphorogenesis in the Dongwu period began in the Early Permian.Moreover,the dolomite controlled by the grain bank migration and terrain in the slope break appears in bands of large scale,this knowledge provides basis for expanding the exploration field of this type of reservoirs.展开更多
Here we present(^(234)U/^(238)U)data from river sediments collected on the Tibetan Plateau.The(^(234)U/^(238)U)ratios of a specific grain size fraction show good correlation with erosion rates,which were determined by...Here we present(^(234)U/^(238)U)data from river sediments collected on the Tibetan Plateau.The(^(234)U/^(238)U)ratios of a specific grain size fraction show good correlation with erosion rates,which were determined by in-situ–produced cosmogenic nuclides.This correlation has previously been observed in a wide range of geomorphic settings,suggesting that(^(234)U/^(238)U)ratios of fluvial sediments have great potential to quantify erosion rates.展开更多
Evaluating the hydrocarbon generation potential of highly mature organic matter is a key and critically challenging area of research in petroleum geochemistry. To explore this issue, we used negative ion electrospray ...Evaluating the hydrocarbon generation potential of highly mature organic matter is a key and critically challenging area of research in petroleum geochemistry. To explore this issue, we used negative ion electrospray ionization-Fourier transform-ion cyclotron resonance-mass spectrometry to investigate the molecular evolution of N-containing compounds in Carboniferous-lower Permian source rocks with a range of maturities in the northwestern Junggar Basin, China. The N1compounds formed from on-fluorescent chlorophyll catabolites(NCCs), which record the characteristics of the residual soluble organic matter. These components remain in the source rocks after hydrocarbon generation and expulsion, and enable evaluation of the hydrocarbon generation potential. The newly defined indexes of molecular evolution, which are the polymerization index P1([DBE 18+DBE 15]/[DBE 12+DBE 9]_N1) and alkylation index R1(RC_(6–35)/RC_(0–5)), combined with the vitrinite reflectance(VR_(o)) and paleo-salinity index(β-carotane/n Cmax), can identify the factors that control the evolution of highly mature organic matter. The main factor for source rocks deposited in a weakly saline environment is the maturity, but for a highly saline environment both the maturity and salinity are key factors. The high salinity inhibits the molecular polymerization of organic matter and extends the oil generation peak. Given the differences in the bio-precursors in saline source rocks, we propose a new model for hydrocarbon generation that can be used to determine the oil generation potential of highly mature organic matter.展开更多
Climate conditions have long been acknowledged as a pivotal factor shaping regional productivity and influencing available resources,consequently playing an important role in driving social changes throughout human hi...Climate conditions have long been acknowledged as a pivotal factor shaping regional productivity and influencing available resources,consequently playing an important role in driving social changes throughout human history[1–3].In ancient East Asia,the Chinese agrarian civilization emerged around 4000 years ago in northern China,the region termed the“Central Plains”.This region faced recurrent episodes of large-scale social unrest,profoundly impacting the societal structure and dynastic cycles[4].These episodes were marked by extended civil peasant uprisings and/or incursions from northern nomadic tribes,often spanning decades to centuries[5].Both the agrarian societies in the Central Plains and the husbandry-based nomadic tribes in the vast northern grasslands,characterized by semi-arid and semi-humid climates,were notably sensitive to climate variations[6].展开更多
Groundwater system is a complex and open system, which is affected by natural conditions and human activities. Natural hydrological processes is conceptualized through relatively simple flow governing equations in gro...Groundwater system is a complex and open system, which is affected by natural conditions and human activities. Natural hydrological processes is conceptualized through relatively simple flow governing equations in groundwater models. Moreover, observation data is always limited in field hydrogeological conditions. Therefore, the predictive results of groundwater simulation often deviate from true values, which is attribute to the uncertainty of groundwater numerical simulation. According to the process of system simulation, the uncertainty sources of groundwater numerical simulation can be divided into model parameters, conceptual model and observation data uncertainties. In addition, the uncertainty stemmed from boundary conditions is sometimes refered as scenario uncertainty. In this paper, the origination and category of groundwater modeling uncertainty are analyzed. The recent progresses on the methods of groundwater modeling uncertainty analysis are reivewed. Furthermore, the researches on the comprehensive analysis of uncertainty sources, and the predictive uncertainty of model outputs are discussed. Finally, several prospects on the deveolpment of groundwater modeling uncetainty analysis are proposed.展开更多
Deciphering the eolian sources is critical to understand the paleo-significance of the Quaternary eolian deposits(the Xiashu loess)in the lower reaches of the Yangtze River.Both a local source from the fluvial sedimen...Deciphering the eolian sources is critical to understand the paleo-significance of the Quaternary eolian deposits(the Xiashu loess)in the lower reaches of the Yangtze River.Both a local source from the fluvial sediments of the Yangtze River and a distal source from the northern deserts similar to that of the loess on the Chinese Loess Plateau(CLP)have been proposed.Recent researches show great advantages of detrital zircon ages as a source tracer for Asian dust based on the laser ablation U-Pb isotopic dating technique.This work presents the U-Pb ages of zircon grains extracted from the Xiashu loess.The results indicate that the Xiashu loess has a very different age distribution of zircon grains from that of the loess on the CLP as well as the materials in the arid lands of the Asian Interior.Instead,the zircon ages of the Xiashu loess are indistinguishable from the fluvial sediments of the Yangtze River,indicating the dominance of proximal dust source.Proximal source of the Xiashu loess implies that extensive eolian processes might have existed in the currently wet South China,possibly in response to the full glacial conditions after the middle Pleistocene transition of global climate.展开更多
Significant uncertainties remain regarding the temporal evolution of natural vegetation during the Quaternary, and drivers of past vegetation change, on the Chinese Loess Plateau(CLP). This study presents analyses of ...Significant uncertainties remain regarding the temporal evolution of natural vegetation during the Quaternary, and drivers of past vegetation change, on the Chinese Loess Plateau(CLP). This study presents analyses of total organic carbon isotopic composition(TOC) and n-alkane ratios(C31/C27) from the Lingtai loess-palaeosol sequence on the central CLP over the last 450 kyr. The results demonstrate that the vegetation in this region comprised a mix of C_3 and C_4 plants of herb and woody growth-form. C_3 plants dominated for most of the last 450 kyr, but this did not lead to extensive forest. C_3 woody plants were more abundant in MIS9(S3 period) and MIS5(S1 period) during warm and humid climate conditions. Herbs increased in the region since 130 kyr, possibly as a result of increased aridity. On the orbital timescales, there was a reduction of C_3 herbal plants in MIS11(S4) than in MIS12(L5), and in Holocene than in the last glacial period. Our isotope and n-alkane proxy records are in agreement with Artemisia pollen changes in the region, which is/was the dominant species in this area and varying due to different heat and water conditions between glacial and interglacial periods. Though the climate in MIS1(S0) was similar to that in MIS11(S4), a significant increase in woody plants during the Holocene suggests the impact of human activities and ecological effects of changes in fire activity.展开更多
Mineral dust released from the desert is one of the important components of atmospheric aerosols. Arid and semi-arid deserts, sandy lands in northern China and their adjacent Gobi Desert lands in northern China and ne...Mineral dust released from the desert is one of the important components of atmospheric aerosols. Arid and semi-arid deserts, sandy lands in northern China and their adjacent Gobi Desert lands in northern China and neighboring Mongolia(hereinafter referred to as Gobi) are potential sources of mineral dust in Asia. However, there is currently a lack of systematic studies on the characteristics of major elements in the potential mineral dust source area. This study investigates the major elements of 310 surficial sand samples in the stabilized and semi-stabilized dune fields from 12 deserts/sandy land and Gobi in northern China and southern Mongolian Gobi and compiles published data. We identify four regions with distinct geochemical characteristics:(1) Taklimakan, Kumtag and Qaidam deserts in western China;(2) Badain Jaran, Tengger, Hobq, and Mu Us deserts in the central and western regions of northern China;(3) Hulun Buir, Onqin Daga and Horqin sandy lands in northeast China;and(4) Gobi and Gurbantunggut deserts. The spatial distributions of the SiO2 and CaO contents in Chinese deserts are highly variable. The average content of SiO2 generally reflects an increasing trend from west to east, while the average content of CaO shows a decreasing trend from west to east. We demonstrate that the spatial variation of major elements is likely controlled by two key scenarios: the composition of source rocks and the mineral maturity caused by the supply of fresh materials. The SiO2/(Al2O3+K2O+Na2O) ratio of desert sediments is relatively lower in western China and may be caused by high ferricmagnesia and high carbonate minerals;this ratio is relatively higher in the northeast sandy lands and may be linked to a lack of fresh material supply and the presence of high K-feldspar minerals in source rocks. The deserts can be further distinguished by ternary diagrams with SiO2/10-CaO-Al2O3,(K2O+Na2O)-CaO-Fe2O3 and CaO-Na2O-K2O. The comparison of major elements between desert sediments and loess suggests that the western and/or central deserts in China may be the potential provenances of loess on the Loess Plateau.展开更多
The sorption of cadmium(Cd) is one of the most important chemical processes in soil, affecting its fate and mobility in both soil and water and ultimately controlling its bioavailability. In order to fundamentally und...The sorption of cadmium(Cd) is one of the most important chemical processes in soil, affecting its fate and mobility in both soil and water and ultimately controlling its bioavailability. In order to fundamentally understand the sorption/desorption of Cd in soil systems, X-ray absorption fine structure spectroscopy(XAFS) has been applied in numerous studies to provide molecular-level information that can be used to characterize the surface adsorption and precipitation reactions that Cd can undergo. This information greatly improves our current knowledge of the possible chemical reactions of Cd in soil. This paper critically reviews the mechanisms of Cd sorption/desorption at the mineral-water interface based on XAFS studies performed over the past twenty years. An introduction to the basic concepts of sorption processes is provided, followed by a detailed interpretation of XAFS theory and experimental data collection and processing,ending finally with a discussion of the atomic/molecular-scale Cd sorption mechanisms that occur at the soil mineral-water interface. Particular emphasis is placed on literature that discusses Cd adsorption and speciation when associated with iron, manganese, and aluminum oxides and aluminosilicate minerals.Multiple sorption mechanisms by which Cd is sorbed by these minerals have been found, spanning from outer-sphere to inner-sphere to surface precipitation,depending on mineral type, surface loading, and pH. In addition, the application of complementary techniques(e.g.,113 Cd nuclear magnetic resonance(NMR) and molecular dynamics simulation) for probing Cd sorption mechanisms is discussed. This review can help to develop appropriate strategies for the environmental remediation of Cd-contaminated soils.展开更多
This study examines the effects of hydrologic sorting and mixing of sources on the Sr-Nd isotopic compositions of suspended sediments at different water depths. The samples were collected from three layers (surface, m...This study examines the effects of hydrologic sorting and mixing of sources on the Sr-Nd isotopic compositions of suspended sediments at different water depths. The samples were collected from three layers (surface, middle and bottom) at Datong hydrological station of Yangtze River during the flood season of 2010. Our results show that, 87 Sr/ 86 Sr values decrease from surface to bottom, ranging from 0.730332 to 0.720857. ε Nd (0) values range from 14.75 to 10.09, with surface sediments being the most negative. The isotope composition at the middle layer can best represent the mean isotopic composition of the total suspended sediments transported by a river. It is believed that the stratification of Sr-Nd isotope is attributable to mixing of sediments from different sources due to hydrological sorting. Sediments from the upper stream are found to be coarser, and tend to contribute more to the lower water column. Although Sr-Nd isotope is a well acknowledged tool to trace sediment provenance, the current study suggests that the grain size of the samples and the sampling locations should be taken into consideration when applying this method to provenance study.展开更多
基金jointly funded by the National Science and Technology Major Project of China (Grant No. 2016ZX05003-005)National Natural Science Foundation of China (Grant Nos. 41472100 and 41322017)
文摘Carbonates have been known to act as hydrocarbon source rocks, but their basic geochemical and associated hydrocarbon generation characteristics remain not well understood as they occur with argillaceous source rocks in most cases, and the hydrocarbon generation from each rock type is di cult to distinguish, forming one of puzzling issues within the field of petroleum geology and geochemistry. To improve the understanding of this critical issue, this paper reviews recent advances in this field and provides a summary of key areas that can be studied in future. Results show that carbonate source rocks are generally associated with high-salinity environments with low amounts of terrestrial inputs and low dissolved oxygen contents. Petrographically, these source rocks are dark gray or black, fine-grained, stratified, and contain bacterial and algal bioprecursors along with some other impurities. They generally have low organic matter contents, although these can vary significantly in di erent cases(e.g., the total organic carbon contents of marine and lacustrine carbonate source rocks in China are generally 0.1%–1.0% and 0.4%–4.0%, respectively). These rocks contain type I and type II kerogen, meaning there is a lack of vitrinites. This means that assessment of the maturity of the organic matter in these sediments needs to use non-traditional techniques rather than vitrinite reflectance. In terms of molecular geochemistry, carbonate source rocks have typical characteristics indicative of generally reducing and saline environments and lower organism-dominated bioprecursors of organic matter, e.g., high contents of sulfur compounds, low Pr/Ph ratios, and dominance of n-alkanes. Most of the carbonate source rocks are typically dominated by D-type organic facies in an oxidized shallow water mass, although high-quality source rocks generally contain A-and B-type organic facies in saline lacustrine and marine-reducing environments, respectively. The hydrocarbon generation model for the carbonate source rocks can involve early, middle, and late stages, with a diversity of hydrocarbons within these rocks, which can be aggregated, adsorbed, enclosed within minerals, or present as inclusions. This in turn implies that the large-scale hydrocarbon expulsion from these rocks is reliant on brittle deformation caused by external forces. Finally, a number of aspects of these source rocks remain unclear and need further study, including the e ectiveness of carbonates as hydrocarbon source rocks, bioprecursors, and hydrocarbon generation models of carbonate source rock, and the di erences between marine and lacustrine carbonate source rocks.
基金supported by the National Natural Science Foundation of China(Grant No.U2167212)。
文摘Under the new development philosophy of carbon peaking and carbon neutrality,CO_(2)and O_(2)in situ leaching(ISL)has been identified as a promising technique for uranium mining in China,not only because it solves carbon dioxide utilization and sequestration,but it also alleviates the environmental burden.However,significant challenges exist in assessment of CO_(2)footprint and water-rock interactions,due to complex geochemical processes.Herein this study conducts a three-dimensional,multicomponent reactive transport model(RTM)of a field-scale CO_(2)and O_(2)ISL process at a typical sandstone-hosted uranium deposit in Songliao Basin,China.Numerical simulations are performed to provide new insight into quantitative interpretation of the greenhouse gas(CO_(2))footprint and environmental impact(SO_(4)^(2–))of the CO_(2)and O_(2)ISL,considering the potential chemical reaction network for uranium recovery at the field scale.RTM results demonstrate that the fate of the CO_(2)could be summarized as injected CO_(2)dissolution,dissolved CO_(2)mineralization and storage of CO_(2)as a gas phase during the CO_(2)and O_(2)ISL process.Furthermore,compared to acid ISL,CO_(2)and O_(2)ISL has a potentially smaller environmental footprint,with 20%of SO_(4)^(2–)concentration in the aquifer.The findings improve our fundamental understanding of carbon utilization in a long-term CO_(2)and O_(2)ISL system and provide important environmental implications when considering complex geochemical processes.
基金supported by the National Key R&D Program of China (Project No. 2017YFC0602801)National Science Foundation of China (Grant Nos. 41622301, 41873004)+1 种基金supported by the NASA Astrobiology Institute (NNA13AA94A to BLB)the National Science Foundation (1741048-EAR to BLB)
文摘Shales are a major sink for K into seawater delivered from continental weathering,and are potential recorders of K cycling.High precision K isotope analyses reveal a[0.6%variation in δ^41K values(41K/39K relative to NIST SRM 3141a)from a set of well characterized postArchean Australian shale(PAAS)samples.By contrast,loess samples have relatively homogenous δ^41K values(-0.5±0.1%),which may represent the average K composition of upper continental crust.Most of the shales analyzed in this study have experienced K enrichment relative to average continental crust,and the majority of them define a trend of decreasing δ^41K value(from-0.5to-0.7%)with increasing K content and K/Na ratio,indicating cation exchange in clays minerals is accompanied by K isotope fractionation.Several shale samples do not follow the trend and have elevated δ^41K values up to-0.1%,and these samples are characterized by variable Fe isotope compositions,which reflect post-depositional processes.The K isotope variability observed in shales,in combination with recent findings about K isotope fractionation during continental weathering,indicates that K isotopes fractionate during cycling of K between different reservoirs,and K isotopes in sediments may be used to trace geological cycling of K.
基金co-funded by the National Natural Science Foundation of China(No.41473084)the Project of China Geological Survey(No.12120114092001)the 1000 Youth Talent program
文摘Co(Ⅱ)and Ni(Ⅱ)are two common toxic heavy metals,and may simultaneously exist in contaminated water,soil,and sediment systems in Earth’s surface environment.Under this circumstance,competitive adsorption between the two metals may influence their migration,toxicity,and bioavailability.In this research,the competitive sorption of Co(Ⅱ)and Ni(Ⅱ)on γ-Al_2O_3was studied using both macroscopic sorption experiments and extended X-ray absorption fine structure(EXAFS)spectroscopy.Results suggest that Ni(Ⅱ)reduced the amount of Co(Ⅱ)sorption in a binary-solute system at pH 6.0.This is because both Co(Ⅱ)and Ni(Ⅱ)form inner-sphere surface complexes during sorption on γ-Al_2O_3and compete for the surface reactive sites.However,Co(Ⅱ)exhibited a negligible influence on sorption amount of Ni(Ⅱ)under the same conditions,which suggests Ni(Ⅱ)has a stronger affinity to alumina surface.At pH 7.5,Co(Ⅱ)and Ni(Ⅱ)sorption density were much higher than that at pH 6.0,but there no mutual competitive effect was observed.EXAFS analysis further revealed that formation of layered double-hydrated precipitates was the dominant sorption mechanism for both Co(Ⅱ)and Ni(Ⅱ)at pH 7.5.Because this type of sorption does not rely on surface reactive sites,there was no competition between Co(Ⅱ)and Ni(Ⅱ).This finding sheds light on risk assessment and remediation of Ni/Co pollution.
基金funded by the National Natural Science Fund of China (NSFC)-Xinjiang No.U1503282the NSFC No.41030746,41672229 and 41172206
文摘Geophysical methods have been applied to a wide range of hydrogeological problems. With improvement in geophysical inversion algorithms and measurement tools, significant achievements have been made in the characterization of subsurface architecture, time-lapse monitoring of hydrogeological process and contaminant plumes delineation. In this paper, we summarize the geophysical methods that are most widely used in hydrogeology including Electrical Resistivity Tomography(ERT), Induced Polarization(IP), Ground Penetrating Radar(GPR) and Electromagnetic Induction(EMI). Three examples including lab and field works are used to demonstrate current application of geophysical methods for characterizing subsurface architecture and contaminant plumes. Though great progress has been made in hydrogeohysics over the last few decades at home and abroad, challenges still remain in practical applications. More recently, hydrogeophysics continues to develop in the areas of establishment of hydrogeophysical models, large-scale architecture characterization, uncertainty analysis, biogeochemical process monitoring and ecosystem science.
基金jointly supported by the National Key Research and Development Program of China(No.2019YFC1804304)the National Natural Science Foundation of China(Nos.2167212,41772254)。
文摘CO_(2)+O_(2) in-situ leaching(ISL)of sandstonetype uranium ore represents the third generation of solution mining in China.In this study,reactive transport modeling of the interaction between hydrodynamic and geochemical reactions is performed to enable better prediction and regulation of the CO_(2)+O_(2) in-situ leaching process of uranium.Geochemical reactions between mining solutions and rock,and the kinetic uranium dissolution controlled by O_(2)(aq)and bicarbonate(HCO_(3)-)are considered in the CO_(2)+O_(2) ISL reactive transport model of a typical sandstone-hosted uranium ore deposit in northern China.The reactive leaching of uranium is most sensitive to the spatial distribution of the mineralogical properties of the uranium deposit.Stochastic geostatistical models are used to represent the uncertainty on the spatial distribution of mineral grades.A Monte Carlo analysis was also performed to simulate the uranium production variability over an entire set of geostatistical realizations.The ISL stochastic simulation performed with the selected geostatistical realizations approximates the uranium production variability well.The simulation results of the ISL reactive transport model show that the extent of the uranium plume is highly dependent on mineralogical heterogeneity.The uncertainty analysis suggests the effect of uranium grade heterogeneity was found to be important to improve the accurate capture of the uncertainty.This study provides guidance for the accurate simulation and dynamic regulation of the CO_(2)+O_(2) leaching process of uranium at the scale of large mining areas.
基金financially supported by the National Natural Science Foundation of China(No.41402198 and 41372235)Jiangsu Natural Science Fund-Youth Fund(No.BK20131009)the Fundamental Research Funds for the Central Universities(No.2014B03614)
文摘This study develops a three-dimensional heterogeneous numerical model to simulate the water inrush process and predict the water yield for mineral exploration in Yangzhuang Iron Mine in Anhui Province. To identify the hydrogeological parameters of the aquifer in the study area, the model was calibrated and validated using the observed heads through the integrated trial-and-error and automated techniques. Also, the sensitivity analysis of the model was performed to evaluate the uncertainty associated with the calibrated model. According to the mine construction plan at different mining levels of-500 m,-600 m, and-700 m, the calibrated model was then applied to predict the water yields dependent on the different mining levels. As indicated by the prediction results, the numerical simulation model can systematically describe the groundwater system in the mining area and determine the source of water inrush in this iron mine. In conclusion, numerical analyses carried out in this study can provide guidance to decision-makers in balancing the iron ore mining and mine dewatering in the future.
基金financial supported by the National Basic Research Program of China(No.2014CB846004)National Natural Science Foundation of China(Grant Nos.41425009 and 41272056)
文摘The formation of manganese oxides in nature is commonly mediated by microorganisms.In this study,the mineralization of biogenic manganese oxidation mediated by Pseudomanas putida has been experimentally investigated by employing various characterization techniques,including SEM,FESEM,TEM,XRD,and STXM-NEXAFS.The results indicate that Mn^(2+) ions can be oxidized into Mn(Ⅳ) minerals(birnessite and pyrolusite) and Mn(Ⅲ) minerals(hausmannite and feitknechtite),successively.The primary products(birnessite and pyrolusite) further transformed into hausmannite and feitknechtite under Mn^(2+) ion-enriched conditions.However,birnessite and pyrolusite are the endproducts of the continuous microbial oxidation processes.These biogenic Mn oxides are poorly crystallized,which provides them with a high potential for usage in environmental restoration of contaminated soils and waters contaminated with heavy metals.The approaches employed in this study will also enrich genesis research of biological oxidation of Mn(Ⅱ) species in nature.
基金This work was supported by the Key Program of the National Natural Science Foundation of China(41230640)Major Science and Technology Program for Water Pollution Control and Treatment(2017ZX07602003).
文摘This paper focused on nitrate fate in the vadose zone(VZ)and its implications for groundwater vulnerability under different soil types in the agricultural area of Huaihe River Basin,China.Isotopic compositions of nitrate(δ15N andδ18O)along with NO3-and Cl-concentrations were determined in the VZ-shallow groundwater continuum beneath silty-loam and silty-clay-loam,which are distinctive in texture and organic carbon(OC).In the soil zone(<1 m in depth),measuredδ18O-NO3-suggested the ubiquitous of nitrification regardless of soil types.In the subsoil zone(>1 m in depth),however,the concurrent enrichment ofδ15N-NO3-andδ18O-NO3-indicated the occurrence of denitrification,which showed a dependence on subsoil properties.Specifically,during wheat and maize land uses,denitrification removed as much as 76%-88%of the total nitrate where the subsoil was dominated by stratified OC-rich silty-clay-loam.In contrast,only 0%-28%of the nitrate was degraded via denitrification where the subsoil was composed of uniform,OC-depleted silty-loam.Furthermore,inactive denitrification and higher permeability in the silty-loam VZ implied higher groundwater vulnerability.This observation was consistent with the fact that groundwater NO3--N concentration beneath silty-loam(11.24 mg L-1)was over two times higher than that of the silty-clay-loam(5.32 mg L-1),where stricter fertilization management and conservation strategies should be applied to protect groundwater quality.
基金supported by the Key Research Program of the Chinese Academy of Sciences (No. XDPB11)the National Natural Science Foundation of China (No. 11773087)+2 种基金the Macao Science and Technology Development Fund (103/2017/A and 0042/2018/A2)the Strategic Priority Research Program on Space Science, the Chinese Academy of Sciences (No. XDA15020302)the Minor Planet Foundation of Purple Mountain Observatory
文摘The mineralogy of mare basalts reflects the chemical composition of the magma source, as well as the physical and chemical environment of the rocks' formation. This is significant for understanding the thermal evolution of the Moon. In this study, the spatial distribution of mineralogy on the lunar northern nearside basalts was mapped using the Moon Mineralogy Mapper(M^3) data. The study area, which is an elongated mare, Mare Frigoris and northern Mare Imbrium, was mapped and characterized into 27 units based on multi-source data, including spectrum, terrain and element abundance. We extracted 177 M^3 spectra from fresh craters. Spectral parameters such as absorption center and band area ratio(BAR)were obtained through data processing. The variation of mafic minerals in this region was acquired by analyzing these parameters. The basaltic units in eastern Mare Frigoris, which are older, have been found to be dominated by clinopyroxene with lower CaO compared to the returned lunar samples; this is similar to older basaltic units in Mare Imbrium. The basaltic units of western Mare Frigoris and Sinus Roris which are younger have been found to be rich in olivine. The late-stage basalts in Oceanus Procellarum and Mare Imbrium show the same feature. These widespread olivine-rich basalts suggest uniqueness in the evolution of the Moon. Geographically speaking, Mare Frigoris is an individual mare, but the magma source region has connections with surrounding maria in consideration of mineral differences between western and eastern Frigoris, as well as mineral similarities with maria at the same location.
基金Supported by the National Science&Technology Major Project of China(2016ZX05004002-001)Natural Science Foundation(41802147)Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance
文摘The characteristics,formation time,and origin of the sucrosic dolomite reservoirs in the Permian Qixia Formation of northwestern Sichuan Basin are analyzed.Core and outcrop description and microscopic analysis of the sucrosic dolomite samples are carried out.It is found that the dolomite has typical features different from other kinds of dolomites:(1)This dolomite is generally medium-coarse in crystal size,and often associated with very finely to finely crystalline dolomite and cave-filling dolomite.(2)Typical identification marks of eogenetic karstification are developed at the top of the upward-shallowing sequence.(3)The medium-coarse crystalline sucrosic dolomite is cut by the early diagenetic karst fabric,and is characterized by dolomite with dissolution edge,dolomite vadose silt in pores,and transgression clay filling between the medium-coarse dolomite crystals.The medium-coarse crystalline sucrosic dolomite was formed earlier than the eogenetic karstification.The sucrosic dolomite with occasional cloudy core and clear rim has bright cathodoluminescence,high inclusions temperature,significant negative skewness carbon and oxygen isotopic compositions,and rare-earth element(REE)pattern similar to seawater,indicating it experienced two periods of dolomitization,evaporative concentration reflux-infiltration and penecontemporaneous seawater circulation hydrothermal fluid dolomitization.The study results not only update the understanding on the dolomitization time of Qixia Formation,demonstrate that the sucrosic dolomite can be formed in the penecontemporaneous stage when seawater reflux superimposed with hydrothermal fluid effects,but also show that the taphorogenesis in the Dongwu period began in the Early Permian.Moreover,the dolomite controlled by the grain bank migration and terrain in the slope break appears in bands of large scale,this knowledge provides basis for expanding the exploration field of this type of reservoirs.
基金supported by National Science Foundation of China(Grant No.41422205)
文摘Here we present(^(234)U/^(238)U)data from river sediments collected on the Tibetan Plateau.The(^(234)U/^(238)U)ratios of a specific grain size fraction show good correlation with erosion rates,which were determined by in-situ–produced cosmogenic nuclides.This correlation has previously been observed in a wide range of geomorphic settings,suggesting that(^(234)U/^(238)U)ratios of fluvial sediments have great potential to quantify erosion rates.
基金supported by the National Natural Science Foundation of China(Grant Nos.42230808 and 42102148)China Postdoctoral Science Foundation(Grant No.2021M691497)。
文摘Evaluating the hydrocarbon generation potential of highly mature organic matter is a key and critically challenging area of research in petroleum geochemistry. To explore this issue, we used negative ion electrospray ionization-Fourier transform-ion cyclotron resonance-mass spectrometry to investigate the molecular evolution of N-containing compounds in Carboniferous-lower Permian source rocks with a range of maturities in the northwestern Junggar Basin, China. The N1compounds formed from on-fluorescent chlorophyll catabolites(NCCs), which record the characteristics of the residual soluble organic matter. These components remain in the source rocks after hydrocarbon generation and expulsion, and enable evaluation of the hydrocarbon generation potential. The newly defined indexes of molecular evolution, which are the polymerization index P1([DBE 18+DBE 15]/[DBE 12+DBE 9]_N1) and alkylation index R1(RC_(6–35)/RC_(0–5)), combined with the vitrinite reflectance(VR_(o)) and paleo-salinity index(β-carotane/n Cmax), can identify the factors that control the evolution of highly mature organic matter. The main factor for source rocks deposited in a weakly saline environment is the maturity, but for a highly saline environment both the maturity and salinity are key factors. The high salinity inhibits the molecular polymerization of organic matter and extends the oil generation peak. Given the differences in the bio-precursors in saline source rocks, we propose a new model for hydrocarbon generation that can be used to determine the oil generation potential of highly mature organic matter.
基金This work was supported by the National Natural Science Foundation of China(42025707 and 41888101)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB 40010200)+1 种基金the Science and Technology Planning Project of Nanjing Institute of Geography and Limnology,Chinese Academy of Sciences(NIGLAS2022TJ11)the Key Laboratory of Surficial Geochemistry,Ministry of Education,Nanjing University.
文摘Climate conditions have long been acknowledged as a pivotal factor shaping regional productivity and influencing available resources,consequently playing an important role in driving social changes throughout human history[1–3].In ancient East Asia,the Chinese agrarian civilization emerged around 4000 years ago in northern China,the region termed the“Central Plains”.This region faced recurrent episodes of large-scale social unrest,profoundly impacting the societal structure and dynastic cycles[4].These episodes were marked by extended civil peasant uprisings and/or incursions from northern nomadic tribes,often spanning decades to centuries[5].Both the agrarian societies in the Central Plains and the husbandry-based nomadic tribes in the vast northern grasslands,characterized by semi-arid and semi-humid climates,were notably sensitive to climate variations[6].
基金supported by the National Natural Science Fundation of China (41172207, 41071018, 41030746, 40725010 and 40730635)
文摘Groundwater system is a complex and open system, which is affected by natural conditions and human activities. Natural hydrological processes is conceptualized through relatively simple flow governing equations in groundwater models. Moreover, observation data is always limited in field hydrogeological conditions. Therefore, the predictive results of groundwater simulation often deviate from true values, which is attribute to the uncertainty of groundwater numerical simulation. According to the process of system simulation, the uncertainty sources of groundwater numerical simulation can be divided into model parameters, conceptual model and observation data uncertainties. In addition, the uncertainty stemmed from boundary conditions is sometimes refered as scenario uncertainty. In this paper, the origination and category of groundwater modeling uncertainty are analyzed. The recent progresses on the methods of groundwater modeling uncertainty analysis are reivewed. Furthermore, the researches on the comprehensive analysis of uncertainty sources, and the predictive uncertainty of model outputs are discussed. Finally, several prospects on the deveolpment of groundwater modeling uncetainty analysis are proposed.
基金supported by the National Natural Science Foundation of China(41102103,41173105 and 41321062)
文摘Deciphering the eolian sources is critical to understand the paleo-significance of the Quaternary eolian deposits(the Xiashu loess)in the lower reaches of the Yangtze River.Both a local source from the fluvial sediments of the Yangtze River and a distal source from the northern deserts similar to that of the loess on the Chinese Loess Plateau(CLP)have been proposed.Recent researches show great advantages of detrital zircon ages as a source tracer for Asian dust based on the laser ablation U-Pb isotopic dating technique.This work presents the U-Pb ages of zircon grains extracted from the Xiashu loess.The results indicate that the Xiashu loess has a very different age distribution of zircon grains from that of the loess on the CLP as well as the materials in the arid lands of the Asian Interior.Instead,the zircon ages of the Xiashu loess are indistinguishable from the fluvial sediments of the Yangtze River,indicating the dominance of proximal dust source.Proximal source of the Xiashu loess implies that extensive eolian processes might have existed in the currently wet South China,possibly in response to the full glacial conditions after the middle Pleistocene transition of global climate.
基金supported by the National Natural Science Foundation of China(Grant No.41172149)the Science Fund for Creative Research Groups of NSFC(Grant No.41321062)the National Key Basic Research Program of China(Grant No.2015CB953804)
文摘Significant uncertainties remain regarding the temporal evolution of natural vegetation during the Quaternary, and drivers of past vegetation change, on the Chinese Loess Plateau(CLP). This study presents analyses of total organic carbon isotopic composition(TOC) and n-alkane ratios(C31/C27) from the Lingtai loess-palaeosol sequence on the central CLP over the last 450 kyr. The results demonstrate that the vegetation in this region comprised a mix of C_3 and C_4 plants of herb and woody growth-form. C_3 plants dominated for most of the last 450 kyr, but this did not lead to extensive forest. C_3 woody plants were more abundant in MIS9(S3 period) and MIS5(S1 period) during warm and humid climate conditions. Herbs increased in the region since 130 kyr, possibly as a result of increased aridity. On the orbital timescales, there was a reduction of C_3 herbal plants in MIS11(S4) than in MIS12(L5), and in Holocene than in the last glacial period. Our isotope and n-alkane proxy records are in agreement with Artemisia pollen changes in the region, which is/was the dominant species in this area and varying due to different heat and water conditions between glacial and interglacial periods. Though the climate in MIS1(S0) was similar to that in MIS11(S4), a significant increase in woody plants during the Holocene suggests the impact of human activities and ecological effects of changes in fire activity.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41673095, 41230526, 41690111 & 41877369)the Fundamental Research Funds for the Central Universities (Grant No. Swu118203)
文摘Mineral dust released from the desert is one of the important components of atmospheric aerosols. Arid and semi-arid deserts, sandy lands in northern China and their adjacent Gobi Desert lands in northern China and neighboring Mongolia(hereinafter referred to as Gobi) are potential sources of mineral dust in Asia. However, there is currently a lack of systematic studies on the characteristics of major elements in the potential mineral dust source area. This study investigates the major elements of 310 surficial sand samples in the stabilized and semi-stabilized dune fields from 12 deserts/sandy land and Gobi in northern China and southern Mongolian Gobi and compiles published data. We identify four regions with distinct geochemical characteristics:(1) Taklimakan, Kumtag and Qaidam deserts in western China;(2) Badain Jaran, Tengger, Hobq, and Mu Us deserts in the central and western regions of northern China;(3) Hulun Buir, Onqin Daga and Horqin sandy lands in northeast China;and(4) Gobi and Gurbantunggut deserts. The spatial distributions of the SiO2 and CaO contents in Chinese deserts are highly variable. The average content of SiO2 generally reflects an increasing trend from west to east, while the average content of CaO shows a decreasing trend from west to east. We demonstrate that the spatial variation of major elements is likely controlled by two key scenarios: the composition of source rocks and the mineral maturity caused by the supply of fresh materials. The SiO2/(Al2O3+K2O+Na2O) ratio of desert sediments is relatively lower in western China and may be caused by high ferricmagnesia and high carbonate minerals;this ratio is relatively higher in the northeast sandy lands and may be linked to a lack of fresh material supply and the presence of high K-feldspar minerals in source rocks. The deserts can be further distinguished by ternary diagrams with SiO2/10-CaO-Al2O3,(K2O+Na2O)-CaO-Fe2O3 and CaO-Na2O-K2O. The comparison of major elements between desert sediments and loess suggests that the western and/or central deserts in China may be the potential provenances of loess on the Loess Plateau.
基金funded by the National Natural Science Foundation of China (Nos. 41722303, 41977267, and 41473084)the National Key R&D Program of China (No. 2017YFD0800303)+1 种基金the financial support of the Opening Fund of State Key Laboratory of Environmental Geochemistry (No. SKLEG2019712)the National 1 000 Youth Talent Program of China。
文摘The sorption of cadmium(Cd) is one of the most important chemical processes in soil, affecting its fate and mobility in both soil and water and ultimately controlling its bioavailability. In order to fundamentally understand the sorption/desorption of Cd in soil systems, X-ray absorption fine structure spectroscopy(XAFS) has been applied in numerous studies to provide molecular-level information that can be used to characterize the surface adsorption and precipitation reactions that Cd can undergo. This information greatly improves our current knowledge of the possible chemical reactions of Cd in soil. This paper critically reviews the mechanisms of Cd sorption/desorption at the mineral-water interface based on XAFS studies performed over the past twenty years. An introduction to the basic concepts of sorption processes is provided, followed by a detailed interpretation of XAFS theory and experimental data collection and processing,ending finally with a discussion of the atomic/molecular-scale Cd sorption mechanisms that occur at the soil mineral-water interface. Particular emphasis is placed on literature that discusses Cd adsorption and speciation when associated with iron, manganese, and aluminum oxides and aluminosilicate minerals.Multiple sorption mechanisms by which Cd is sorbed by these minerals have been found, spanning from outer-sphere to inner-sphere to surface precipitation,depending on mineral type, surface loading, and pH. In addition, the application of complementary techniques(e.g.,113 Cd nuclear magnetic resonance(NMR) and molecular dynamics simulation) for probing Cd sorption mechanisms is discussed. This review can help to develop appropriate strategies for the environmental remediation of Cd-contaminated soils.
基金supported by the State Key Program of National Natural Science of China (40830107)the Key Program for International S&T Cooperation Projects of China (2010DFA24480)the Geological Survey Program of China (water (2010) mineral assessment 03-07-08)
文摘This study examines the effects of hydrologic sorting and mixing of sources on the Sr-Nd isotopic compositions of suspended sediments at different water depths. The samples were collected from three layers (surface, middle and bottom) at Datong hydrological station of Yangtze River during the flood season of 2010. Our results show that, 87 Sr/ 86 Sr values decrease from surface to bottom, ranging from 0.730332 to 0.720857. ε Nd (0) values range from 14.75 to 10.09, with surface sediments being the most negative. The isotope composition at the middle layer can best represent the mean isotopic composition of the total suspended sediments transported by a river. It is believed that the stratification of Sr-Nd isotope is attributable to mixing of sediments from different sources due to hydrological sorting. Sediments from the upper stream are found to be coarser, and tend to contribute more to the lower water column. Although Sr-Nd isotope is a well acknowledged tool to trace sediment provenance, the current study suggests that the grain size of the samples and the sampling locations should be taken into consideration when applying this method to provenance study.
