To investigate the influence of confining pressures and temperatures on the seepage characteristics of fractured rocks, seepage tests were conducted on a fractured silty mudstone using a self-developed experimental sy...To investigate the influence of confining pressures and temperatures on the seepage characteristics of fractured rocks, seepage tests were conducted on a fractured silty mudstone using a self-developed experimental system, and the effects of different factors on coefficient of permeability were discussed. The results showed that the increasing confining pressure will gradually decrease the coefficient of permeability, and this process is divided into two stages: 1) the fast decrease stage, which corresponds to a confining pressure less than 30 kPa, and 2) the slow decrease stage, which corresponds to a confining pressure larger than 30 kPa. Unlike confining pressure, an increase in temperature will increase the coefficient of permeability. It is noted that fracture surface roughness will also affect the variation of coefficient of permeability to a certain extent. Among the three examined factors, the effect of confining pressure increases is dominant on fracture permeability coefficient. The relationship between the confining pressure and coefficient of permeability can be quantified by an exponential function.展开更多
In this work,the effects of Co doping on the magnetostructural coupling transformation of Ni_(50-x)Co_(x)Mn_(50-y)Ti_(y)(x=0-15,y=12.5-15)Heusler alloys were systematically investigated through the first-princi-ples c...In this work,the effects of Co doping on the magnetostructural coupling transformation of Ni_(50-x)Co_(x)Mn_(50-y)Ti_(y)(x=0-15,y=12.5-15)Heusler alloys were systematically investigated through the first-princi-ples calculations and experimental verification.The cal-culation result indicates that the doped Co atoms prefer to occupy the Ni sublattice.The Co atoms tend to flock together in terms of the lowest energy principle.Since the formation energy of the austenite is higher than that of the martensite,the alloys will undergo martensitic transfor-mation for the Ni_(50-x)Co_(x)Mn_(37.5)Ti_(12.5)alloys(x=0-12.5).The magnetostructural coupling point of Ni_(50-x)Co_(x)Mn_(37.5)Ti_(12.5)alloys is predicted in the vicinity of x=11-12.Based on the computational composition Ni_(37.5)Co_(12.5)Mn_(37.5)Ti_(12.5),the Ni_(36)Co_(14)Mn_(36)Ti_(14)alloy with magnetostructural coupling near room temperature was experimentally developed by simultaneously increasing the Ti and Co contents.The largest magnetization change(ΔM)and magnetic entropy changes(ΔS_(m))obtained under magnetic field of 5 T for the martensitic transformation in the Ni_(36)Co_(14)Mn_(36)Ti_(14) alloy are about 87.6 A·m^(2)·kg^(-1)and 21 J·kg^(-1)·K^(-1),respectively.The fracture strength and strain for non-textured polycrystalline Ni_(36)Co_(14)Mn_(36)Ti_(14)alloy reach 953 MPa and 12.3%,respectively.The results show that the alloy not only possesses a large magne-tocaloric effect but also has excellent mechanical proper-ties.In addition,the 6 M modulated martensite is evidenced in the Ni-Co-Mn-Ti alloys via transmission electron microscopy technique.展开更多
基金Projects(51838001, 51878070, 51908073, 51908069) supported by the National Natural Science Foundation of ChinaProject(2019SK2171) supported by the Key Research and Development Program of Hunan Province, China+2 种基金Project(kq1905043) supported by the Training Program for Excellent Young Innovators of Changsha, ChinaProject(2019IC04) supported by Double First-class Scientific Research International Cooperation Expansion Project of Changsha University of Science & Technology, ChinaProject(CX20200811) supported by Postgraduate Research and Innovation Key Project of Hunan Province, China。
文摘To investigate the influence of confining pressures and temperatures on the seepage characteristics of fractured rocks, seepage tests were conducted on a fractured silty mudstone using a self-developed experimental system, and the effects of different factors on coefficient of permeability were discussed. The results showed that the increasing confining pressure will gradually decrease the coefficient of permeability, and this process is divided into two stages: 1) the fast decrease stage, which corresponds to a confining pressure less than 30 kPa, and 2) the slow decrease stage, which corresponds to a confining pressure larger than 30 kPa. Unlike confining pressure, an increase in temperature will increase the coefficient of permeability. It is noted that fracture surface roughness will also affect the variation of coefficient of permeability to a certain extent. Among the three examined factors, the effect of confining pressure increases is dominant on fracture permeability coefficient. The relationship between the confining pressure and coefficient of permeability can be quantified by an exponential function.
基金financially supported by the National Natural Science Foundation of China (No.51771044)the Natural Science Foundation of Hebei Province (No.E2019501061)+2 种基金the Fundamental Research Funds for the Central Universities (No. N2023027)Program of Introducing Talents of Discipline Innovation to Universities 2.0 (No.BP0719037)LiaoNing Revitalization Talents Program (No.XLYC1802023)
文摘In this work,the effects of Co doping on the magnetostructural coupling transformation of Ni_(50-x)Co_(x)Mn_(50-y)Ti_(y)(x=0-15,y=12.5-15)Heusler alloys were systematically investigated through the first-princi-ples calculations and experimental verification.The cal-culation result indicates that the doped Co atoms prefer to occupy the Ni sublattice.The Co atoms tend to flock together in terms of the lowest energy principle.Since the formation energy of the austenite is higher than that of the martensite,the alloys will undergo martensitic transfor-mation for the Ni_(50-x)Co_(x)Mn_(37.5)Ti_(12.5)alloys(x=0-12.5).The magnetostructural coupling point of Ni_(50-x)Co_(x)Mn_(37.5)Ti_(12.5)alloys is predicted in the vicinity of x=11-12.Based on the computational composition Ni_(37.5)Co_(12.5)Mn_(37.5)Ti_(12.5),the Ni_(36)Co_(14)Mn_(36)Ti_(14)alloy with magnetostructural coupling near room temperature was experimentally developed by simultaneously increasing the Ti and Co contents.The largest magnetization change(ΔM)and magnetic entropy changes(ΔS_(m))obtained under magnetic field of 5 T for the martensitic transformation in the Ni_(36)Co_(14)Mn_(36)Ti_(14) alloy are about 87.6 A·m^(2)·kg^(-1)and 21 J·kg^(-1)·K^(-1),respectively.The fracture strength and strain for non-textured polycrystalline Ni_(36)Co_(14)Mn_(36)Ti_(14)alloy reach 953 MPa and 12.3%,respectively.The results show that the alloy not only possesses a large magne-tocaloric effect but also has excellent mechanical proper-ties.In addition,the 6 M modulated martensite is evidenced in the Ni-Co-Mn-Ti alloys via transmission electron microscopy technique.
