Under ultra-supercritical pressure, the heat transfer characteristics of water in vertical upward 4- head internally ribbed tubes with a diameter of 28.65mm and thickness of 8mm were experimentally studied. The experi...Under ultra-supercritical pressure, the heat transfer characteristics of water in vertical upward 4- head internally ribbed tubes with a diameter of 28.65mm and thickness of 8mm were experimentally studied. The experiments were performed at P = 25- 34MPa, G = 450- 1800kg/（m^2·s） and q = 200 600kW/m^2. The results show that the pressure has only a moderate effect on the heat transfer of uhra-supercritical water when the water temperature is below the pseudocritical point. Sharp rise of the wall temperature near the pesudocritical region occurs earlier at a higher pressure. Increasing the mass velocity improves the heat transfer with a much stronger effect below the pesudocritical point than that above the pesudocritical point. For given pressure and mass velocity, the inner wall heat flux also shows a significant effect on the inner wall temperature, with a higher inner wall heat flux leading to a higher inner wall temperature. Increasing of inner wall heat flux leads to an early occurrence of sharp rise of the wall temperature. Correlations of heat transfer coefficients are also presented for vertical upward internally ribbed tubes.展开更多
By using two-parallel conductance probes,the instantaneous film thickness of gas-liquidtwo-phase flow within a horizontal plexiglass pipe of 50mm inner diameter was experimentallymeasured.The pipe was 6680mm long.Seve...By using two-parallel conductance probes,the instantaneous film thickness of gas-liquidtwo-phase flow within a horizontal plexiglass pipe of 50mm inner diameter was experimentallymeasured.The pipe was 6680mm long.Several wave patterns were distinguished through statisticalanalysis of signals of film thicknesses.Wave pattern maps were obtained and compared with resultsof former studies.The characteristics of the interfacial waves,such as time-averaged film thickness,wave height,wave propagation speed,wavelength and wave frequency,were systematically investigated.The effect of the exit structure of the test section on interfacial waves was experimentally examined.展开更多
We present a facile synthetic strategy to create mesoporous Cu_(2)O nanocrystals with tunable pore structures and surface functional groups of amine derivatives for efficient and preferable electrochemical conversion ...We present a facile synthetic strategy to create mesoporous Cu_(2)O nanocrystals with tunable pore structures and surface functional groups of amine derivatives for efficient and preferable electrochemical conversion of CO_(2) into ethylene.The structural characteristics of theseCu_(2)O nanocrystals can be manipulated using a set of amine derivatives,such as pyridine,4,4'-bipyridine,and hexamethylenetetramine,during the oxidative etching process of Cu nanocrystals by bubbling gaseous oxygen in N,N-dimethylformamide solution.These amine derivatives not only serve as surface functional groups but also significantly affect the resulting pore structures.The synergistic effect of pore structure confinement and surface amine functionalization leads to the superb Faradaic efficiency(FE)of 51.9% for C_(2)H_(4),respectively,together with the C_(2)H_(4) partial current density of -209.4 mA·cm^(-2) at -0.8 V vs.reversible hydrogen electrode(RHE).The relatively high selectivity towards C_(2)H_(4) was investigated using DFT simulations,where 4,4'-bipyridine functionalized Cu_(2)O seemed to favor the C_(2)H_(4) formation with the low free energy of the intermediates.This study provides a feasible strategy to manipulate the pore structure and surface functionalization of mesoporous Cu_(2)O nanocrystals by regulating the oxidative etching process,which sheds light on the rational preparation of high-performance CO_(2)RR electrocatalysts.展开更多
基金Supported by the High Technology Research and Development Programme of China （No. 2002AA526012 ）and the National Natural Science Foundation of China （No. 50323001）.
文摘Under ultra-supercritical pressure, the heat transfer characteristics of water in vertical upward 4- head internally ribbed tubes with a diameter of 28.65mm and thickness of 8mm were experimentally studied. The experiments were performed at P = 25- 34MPa, G = 450- 1800kg/（m^2·s） and q = 200 600kW/m^2. The results show that the pressure has only a moderate effect on the heat transfer of uhra-supercritical water when the water temperature is below the pseudocritical point. Sharp rise of the wall temperature near the pesudocritical region occurs earlier at a higher pressure. Increasing the mass velocity improves the heat transfer with a much stronger effect below the pesudocritical point than that above the pesudocritical point. For given pressure and mass velocity, the inner wall heat flux also shows a significant effect on the inner wall temperature, with a higher inner wall heat flux leading to a higher inner wall temperature. Increasing of inner wall heat flux leads to an early occurrence of sharp rise of the wall temperature. Correlations of heat transfer coefficients are also presented for vertical upward internally ribbed tubes.
基金Supported by the National Natural Science Foundation of China.
文摘By using two-parallel conductance probes,the instantaneous film thickness of gas-liquidtwo-phase flow within a horizontal plexiglass pipe of 50mm inner diameter was experimentallymeasured.The pipe was 6680mm long.Several wave patterns were distinguished through statisticalanalysis of signals of film thicknesses.Wave pattern maps were obtained and compared with resultsof former studies.The characteristics of the interfacial waves,such as time-averaged film thickness,wave height,wave propagation speed,wavelength and wave frequency,were systematically investigated.The effect of the exit structure of the test section on interfacial waves was experimentally examined.
基金financially supported by Shandong Provincial Natural Science Foundation(No.ZR2022MB120&ZR2020MB048)the University Feature Laboratory for Energy Conversion and Nanocatalysis of Shandong ProvinceHundred Outstanding Talent Program of Jining University(No.2020ZYRC05).
文摘We present a facile synthetic strategy to create mesoporous Cu_(2)O nanocrystals with tunable pore structures and surface functional groups of amine derivatives for efficient and preferable electrochemical conversion of CO_(2) into ethylene.The structural characteristics of theseCu_(2)O nanocrystals can be manipulated using a set of amine derivatives,such as pyridine,4,4'-bipyridine,and hexamethylenetetramine,during the oxidative etching process of Cu nanocrystals by bubbling gaseous oxygen in N,N-dimethylformamide solution.These amine derivatives not only serve as surface functional groups but also significantly affect the resulting pore structures.The synergistic effect of pore structure confinement and surface amine functionalization leads to the superb Faradaic efficiency(FE)of 51.9% for C_(2)H_(4),respectively,together with the C_(2)H_(4) partial current density of -209.4 mA·cm^(-2) at -0.8 V vs.reversible hydrogen electrode(RHE).The relatively high selectivity towards C_(2)H_(4) was investigated using DFT simulations,where 4,4'-bipyridine functionalized Cu_(2)O seemed to favor the C_(2)H_(4) formation with the low free energy of the intermediates.This study provides a feasible strategy to manipulate the pore structure and surface functionalization of mesoporous Cu_(2)O nanocrystals by regulating the oxidative etching process,which sheds light on the rational preparation of high-performance CO_(2)RR electrocatalysts.
