The ice phenology of alpine lakes on the Tibetan Plateau(TP)is a rapid and direct responder to climate changes,and the variations in lake ice exhibit high temporal frequency characteristics.MODIS and passive microwave...The ice phenology of alpine lakes on the Tibetan Plateau(TP)is a rapid and direct responder to climate changes,and the variations in lake ice exhibit high temporal frequency characteristics.MODIS and passive microwave data are widely used to monitor lake ice changes with high temporal resolution.However,the low spatial resolutions make it difficult to effectively quantify the freeze-melt dynamics of lakes.This work used Sentinel-1 synthetic aperture radar(SAR)data to derive high-resolution ice maps(about 6 days),then with the aid of Sentinel-2 optical images to quantify freeze-melt processes in three typical lakes on the TP(e.g.Selin Co,Ayakekumu Lake,and Nam Co).The results showed that three lakes had an average annual ice period of 125-157 days and a complete ice cover period of 72-115 days,from 2018 to 2022.They exhibit different ice phenology patterns.Nam Co is characterized by repeated episodes of freezing,melting,and refreezing,resulting in a prolonged freeze-up period.Meanwhile,the break-up period of Nam Co lasts for a longer duration(about 19 days),and the break-up exhibits a smooth process.Similarly,Ayakekumu Lake showed more significant inter-annual fluctuations in the freeze-up period,with deviations of up to 28 days observed among different years.Compared to the other two lakes,Selin Co experienced a relatively short freeze-up and break-up period.In short,Sentinel-1 SAR data can effectively monitor the weekly and seasonal variations in lake ice on the TP.Particularly,this data facilitates quantification of the freeze-melt dynamics.展开更多
The title complexes(NH4)[Ag(dpe)(H2bptc)](1) and Ag2(bpy)(ox)·7H2O(2) were synthesized via slow evaporation at room temperature,and characterized by elemental analysis and infrared spectra.The crystal of 1 crysta...The title complexes(NH4)[Ag(dpe)(H2bptc)](1) and Ag2(bpy)(ox)·7H2O(2) were synthesized via slow evaporation at room temperature,and characterized by elemental analysis and infrared spectra.The crystal of 1 crystallizes in triclinic,space group P1 with a = 8.3959(7),b = 11.8088(12),c = 12.8175(13) ,α = 85.507(2),β = 79.245(1),γ = 84.174(2)o,V = 1239.7(2) 3,Z = 2,C28H22AgN3O8,Mr = 636.36,Dc = 1.705 g/cm3,F(000) = 644 and μ(MoKα) = 0.874 mm-1.The final R = 0.0479 and wR = 0.1426 for 3632 observed reflections with I > 2σ(I) and R = 0.0559 and wR = 0.1503 for all data.The crystal of 2 crystallizes in orthorhombic,space group Pnna with a = 17.2291(17),b = 7.5289(6),c = 21.369(2),V = 2771.9(4) 3,Z = 4,C22H30Ag2N4O11,Mr = 742.24,Dc = 1.779 g/cm3,F(000) = 1488 and μ(MoKα) = 1.476 mm-1.The final R = 0.0648 and wR = 0.2058 for 1996 observed reflections with I > 2σ(I) and R = 0.0769 and wR = 0.2192 for all data.X-ray diffraction reveals that in complexes 1 and 2,both 1,2-di(4-pyridyl)ethylene and 4,4'-bipyridine act as typical bidentate N-donor ligands to link two Ag centers.3,3'4,4'-Biphenyltetracarboxylate and oxalate anions play the role of organic linkers and counter-ions to balance the cationic charge of AgI.The rich hydrogen-bonding interactions and ligand-unsupported Ag…Ag interactions as well as π-π stacking interactions contribute to the construction of three-dimensional sandwich-like frameworks.展开更多
Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of ...Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of phase change wallboard (PCW). The PCW room was established,and some contrast analysis of the storage and exchange thermal characteristic of PCW room and ordinary wall room were made under different conditions. The results show that the fluctuation of indoor air temperature in PCW room is smaller than that in ordinary room obviously. The exchange energy of PCM room with outdoor is less than that of ordinary wall room. In the winter condition,PCW room utilizes valley period electricity to storage energy in the night,while releases at peak period electricity in daytime,which can divert 40% of peak load. In the summer condition,PCW room can reduce the peak cooling load by 25% compared with ordinary wall room.展开更多
A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were c...A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were calculated by the mathematical model.The solution content first increases and then decreases along the solution flow direction.At y/Hr=0.98(where Hr is the height of regenerator),air humidity increases from 1.99% to 2.348% firstly and then decreases.The experimental results were used to validate mathematical model.It is indicated that the simulation results agree with experimental data well.The results not only show that the mathematical model can be used to predict the performance of regenerator,but also has great value in the design and improvement of evaporative condensing regenerator.展开更多
In the performance experiment of organic Rankine cycle power generation experimental system, the loadresistance-regulation method is one of the most important regulation methods. However, the regulation law has not be...In the performance experiment of organic Rankine cycle power generation experimental system, the loadresistance-regulation method is one of the most important regulation methods. However, the regulation law has not been clear enough to guide the experiment, which is unfavorable to the experimental research on organic Rankine cycle. In this paper the regulation law of turbine and generator by the load-resistance-regulation method is studied theoretically and experimentally. The results show that when the thermal cycle parameters keep constant, the turbine speed increases with the increase of load resistance and there is a maximum value of transmission-generator efficiency with the variation of the turbine speed; when the turbine speed and generator speed keep constant, the transmissiongenerator efficiency decreases and gradually tends to zero with the increase of load resistance.展开更多
When the wind speed changes significantly in a permanent magnet synchronous wind power generation system,the maximum power point cannot be easily determined in a timely manner.This study proposes a maximum power refer...When the wind speed changes significantly in a permanent magnet synchronous wind power generation system,the maximum power point cannot be easily determined in a timely manner.This study proposes a maximum power reference signal search method based on fuzzy control,which is an improvement to the climbing search method.A neural network-based parameter regulator is proposed to address external wind speed fluctuations,where the parameters of a proportional-integral controller is adjusted to accurately monitor the maximum power point under different wind speed conditions.Finally,the effectiveness of this method is verified via Simulink simulation.展开更多
The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated pha...The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated phase change material(MEPCM) suspension,a heat transfer performance experimental facility of the PHP was established.The heat transfer characteristic with MEPCM suspension of different mass concentrations(0.5% and 1.0%) and ultra-pure water were compared experimentally.It was found that when the PHP uses MEPCM suspension as its working fluid,operating stability is impoverished under lower heating power and the operating stability is better under higher heating power.At the inclination angle of 90°,the temperature at heating side decreases compared to ultra-pure water and the temperature at heating side decreases with the raising of MEPCM suspension mass concentration.The heat transfer characteristic of the PHP is positively correlated with the inclination angle and the 90° is optimum.The unfavorable effect of the inclination angle decreases with heating power increasing.When the inclination angle is 90°,the PHP with MEPCM suspension at 1.0% of mass concentration has the lowest thermal transfer resistance and followed by ultra-pure water and MEPCM suspension at 0.5% of mass concentration has the highest thermal transfer resistance.When the inclination angles are 60° and30°,the effect of gravity on the flow direction is reduced to 86.6% and 50% of that on the inclination angle of 90°,respectively,and the promoting effect of gravity on the working fluid is further weakened as the inclination angle further decreases.Due to the high viscosity of MEPCM suspension,the PHP with ultra-pure water has the lowest heat transfer resistance.When the inclination angles is 60°,the thermal resistance with MEPCM suspension at0.5% of the mass concentration is lower than that at 1.0% at the heating power below 230 W.The thermal resistance of MEPCM suspension tends to be similar for heating power of 230-250 W.At the heating power above 270 W,the thermal resistance with MEPCM suspension at 1.0% of the mass concentration is lower than that at 0.5%.展开更多
More and more attention was paid to phase change energy storage in air conditioning domain and construction energy conservation,and became the focus of the international research. Through the test and analysis of the ...More and more attention was paid to phase change energy storage in air conditioning domain and construction energy conservation,and became the focus of the international research. Through the test and analysis of the parameters of the indoor thermal property in phase change wallboard room and ordinary room,the effects of using phase change wallboards on indoor temperature in summer and air conditioning are obtained. The combination of construct enclosure and phase change materials can stabilize indoor temperature,improve indoor thermal comfort,reduce the frequency of the operation of air conditioning facility,cut the initial investment and operation expense,and meanwhile play an practical role in "the power balancing between the peak period and the valley period" policy. Through the experiment and the test of the effects exerted by phase change wallboard room and ordinary room on the indoor thermal environment,it is obtained that the phase change wallboard can reduce the fluctuation range of indoor temperature and the heat flow from the outside into indoor environment in summer. According to the study,it is found that the effect of cool-storing for 5 h is obvious. Through the analysis of the phase change wallboard without air conditioning in daytime,it is obtained that the frequency of the operation of air conditioning in phase change wallboard room is smaller than that in the ordinary room,which can prolong the lifetime of the facility and reduce operation expense.展开更多
Objective To comparatively study the toxicity of four metal-containing nanoparticles(MNPs) and their chemical counterparts to the air-blood barrier(ABB) permeability using an in vitro model.Methods ABB model, which wa...Objective To comparatively study the toxicity of four metal-containing nanoparticles(MNPs) and their chemical counterparts to the air-blood barrier(ABB) permeability using an in vitro model.Methods ABB model, which was developed via the co-culturing of A549 and pulmonary capillary endothelium, was exposed to spherical CuO-NPs(divided into CuO-40, CuO-80, and CuO-100 based on particle size), nano-Al2O3(sheet and short-rod-shaped), nano-ZnO, nano-Pb S, CuSO4, Al2(SO4)3, Zn(CH3COO)2, and Pb(NO3)2 for 60 min.Every 10 min following exposure, the cumulative cleared volume(ΔTCL) of Lucifer yellow by the model was calculated.A clearance curve was established using linear regression analysis of ΔTCL versus time.Permeability coefficient(P) was calculated based on the slope of the curve to represent the degree of change in the ABB permeability.Results The results found the increased P values of CuO-40, CuO-80, sheet, and short-rod-shaped nano-Al2O3, Al2(SO4)3, and Pb(NO3)2.Among them, small CuO-40 and CuO-80 were stronger than CuO-100 and CuSO4;no difference was observed between Al2(SO4)3 and sheet and short-rod-shaped nano-Al2O3;and nano-Pb S was slightly weaker than Pb(NO3)2.So clearly the MNPs possess diverse toxicity.Conclusion ABB permeability abnormality means pulmonary toxicity potential.More studies are warranted to understand MNPs toxicity and ultimately control the health hazards.展开更多
Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash...Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash deposition was performed from the analogous objective of a 410 t/h boiler economizer to verify the rationality and reliability of the ash-deposition-monitoring model presented in order to increase the security and economy in economizer running. The analog experiment platform is a tube-shell exchanger that conforms well to the conditions of a self-modeling area. The analog flue gas in the shell side is the heated air mixed with ash, and in the tube side the fluid is water heated by the flue gas. The fluid state in the water side and the flue gas side follows the second self-modeling area. A 4-factor-3-level orthogonal table was used to schedule 9 operation conditions of orthogonal experiment, with the 4 factors being heat power, flue gas velocity, ashes grain diameter and adding ashes quantity while the three levels are different values due to different position classes in every factor. The ash deposition thermal resistances is calculated by the model with the measure parameters of temperature and pressure drop. It shows that the values of the ash deposition thermal resistances gradually increase up to a stable state. And the experimental results are reliable by F testing method at α= 0.001. Therefore, the model can be applied in online monitoring of ash deposition in a boiler economizers in power plants and provides scientific decision on ash deposition prediction and sootblowing.展开更多
In this paper, a carbon dioxide trans-critical refrigerating system which is different from a conventional subcritical refrigerating cycle was studied. The trans-critical carbon dioxide refrigerating systems are based...In this paper, a carbon dioxide trans-critical refrigerating system which is different from a conventional subcritical refrigerating cycle was studied. The trans-critical carbon dioxide refrigerating systems are based on the Gustav Lorntzen cycle. Emphasis was focused on how to determine the optimal discharge pressure of compressor in CO2 trans-critical cycle. The factors related with the optimal discharge pressure were analyzed. A formula was developed based on cycle simulation, which could be used to predict the optimal discharge pressure of a basic CO2 trans-critical cycle. After further studies on CO2 trans-critical cycles with a regenerator or expander, two more formulas were also developed. These formulas could provide an access to improve the COP of CO2 trans-critical cycle.展开更多
This paper studied on the removal of toxic substance from river water using O3-GAC process. The result of GC/MS analysis indicated that the number of organic compound species was decreased by 55.1%. The species of tox...This paper studied on the removal of toxic substance from river water using O3-GAC process. The result of GC/MS analysis indicated that the number of organic compound species was decreased by 55.1%. The species of toxic substance of raw water also decreased from 16 to 5. The total removal rate of CODMn andUV254 were 45%～72% and 60%～80% following O3-GAC treatment. It reflected that this process had a good effective on removing unsaturation organic which absorb UV and toxic organic containing nitrogen. The results of Ames test indicated that raw water had a relatively strong mutagicity on TA 98. The O3-GAC process had a good ability in removing mutagen in water. The effluent water’s mutagicity is minus. The results of the study indicated that the effluent of the O3-GAC process was meet the demand of drinking water.展开更多
Building energy modeling(BEM)has become increasingly used in building energy conservation research.Prototype building models are developed to represent the typical urban building characteristics of a specific building...Building energy modeling(BEM)has become increasingly used in building energy conservation research.Prototype building models are developed to represent the typical urban building characteristics of a specific building type,meteorological conditions,and construction year.This study included four residential buildings and 11 commercial buildings to represent nationwide building types in China.With consideration of five climate zones and different construction years corresponding to national standards,a total of 151 prototype building models were developed.The building envelope properties,occupancy and energy-related behaviors,and heating,ventilation,and air-conditioning(HVAC)system characteristics were defined according to the corresponding building energy efficiency design standards,HVAC design standards,and through other sources,such as questionnaire surveys,on-site measurements,and literature,which reflect the real situation of existing buildings in China.Based on the developed prototype buildings,a large database of 9225 models in 270 cities was further developed to facilitate users to simulate building energy in different cities.In conclusion,the developed prototype building models can represent realistic building characteristics and construction practices of the most common residential and commercial buildings in China,serving as an important foundation for BEM.The models can be used for analyses related to building energy conservation research on typical individual buildings,including energy-saving technologies,advanced controls,and new policies,and providing a reference for the development of building energy codes and standards.展开更多
Building energy simulation analysis plays an important supporting role in the conservation of building energy.Since the early 1980s,researchers have focused on the development and validation of building energy modelin...Building energy simulation analysis plays an important supporting role in the conservation of building energy.Since the early 1980s,researchers have focused on the development and validation of building energy modeling programs(BEMPs)and have basically formed a set of systematic validation methods for BEMPs,mainly including analytical,comparative,and empirical methods.Based on related papers in this field,this study systematically analyzed the application status of validation methods for BEMPs from three aspects,namely,sources of validation cases,comparison parameters,and evaluation indicators.The applicability and characteristics of the three methods in different validation fields and different development stages of BEMPs were summarized.Guidance were proposed for researchers to choose more suitable validation methods and evaluation indicators.In addition,the current development trend of BEMPs and the challenges faced by validation methods were investigated,as well as the existing progress of current validation methods under this trend was analyzed.Subsequently,the development direction of the validation method was clarified.展开更多
The parameter study of sinter waste heat recovery in vertical tank was conducted numerically by using energy and exergy analysis,and the experimental data obtained from a homemade experimental apparatus was applied to...The parameter study of sinter waste heat recovery in vertical tank was conducted numerically by using energy and exergy analysis,and the experimental data obtained from a homemade experimental apparatus was applied to verify the reliability of numerical model.Based on the first and second laws of thermodynamics,the effects of flow rate of cooling air(FRCA)and inlet temperature of cooling air(ITCA),as well as the inner diameter of cooling section(IDCS)and height of cooling section(HCS),on the sinter cooling process were analyzed in detail.The results show that the average deviation between the experimental data and calculation values is 4.93%,and the model reliability is verified.The enthalpy exergy of outlet air tends to increase first and then decrease with increasing the FRCA and ITCA,while increasing the IDCS only leads to the increase in enthalpy exergy of outlet air.For a given operational condition,the enthalpy exergy of outlet air can reach a maximum value with increasing the HCS.The vertical tank could obtain the maximum enthalpy exergy of outlet air through the adjustments of FRCA and ITCA,as well as the HCS.展开更多
With integration of renewable energy and use of non-linear loads in power systems,the power quality problem is increasingly attracting attention of researchers.In China,standards for individual power quality indexes a...With integration of renewable energy and use of non-linear loads in power systems,the power quality problem is increasingly attracting attention of researchers.In China,standards for individual power quality indexes are set.However,when evaluating power quality in practice,individual indexes cannot directly reflect a comprehensive level of power quality.In this paper,a comprehensive analysis of various indexes is conducted to obtain a unified parameter for describing the characteristics of power quality from an overall perspective.First,weight values of power quality indexes are calculated by combining the subjective and objective weight.Then,based on the principal components of the projection method,projection values of boundary data and data to be evaluated are obtained.Finally,using these projection values,a grade range for power quality data is located.A practical case study is presented to show the validity of the proposed method for evaluating power quality.展开更多
Using ethanol or acetone as the working fluid, the performance of starting up and heat transfer of closed-loop plate oscillating heat pipe with parallel channels(POHP-PC) were experimentally investigated by varying fi...Using ethanol or acetone as the working fluid, the performance of starting up and heat transfer of closed-loop plate oscillating heat pipe with parallel channels(POHP-PC) were experimentally investigated by varying filling ratio, inclination, working fluids and heating power. The performance of the tested pulsating heat pipe was mainly evaluated by thermal resistance and wall temperature. Heating copper block and cold water bath were adopted in the experimental investigations. It was found that oscillating heat pipe with filling ratio of 50% started up earlier than that with 70% when heating input was 159.4 W, however, it has similar starting up performance with filling ratio of 50% as compared to 70% on the condition of heat input of 205.4 W. And heat pipe with filling ratio of 10% could not start up but directly transit to dry burning. A reasonable filling ratio range of 35%-70% was needed in order to achieve better performance, and there are different optimal filling ratios with different heating inputs- the more heating input, the higher optimal filling ratio, and vice versa. However, the dry burning appeared easily with low filling ratio, especially at very low filling ratio, such as 10%. And higher filling ratio, such as 70%, resulted in higher heat transfer( dry burning) limit. With filling ratio of 70% and inclination of 75°, oscillating heat pipe with acetone started up with heating input of just 24 W, but for ethanol, it needed to be achieved 68 W, Furthermore, the start time with acetone was similar as compared to that with ethanol. For steady operating state, the heating input with acetone was about 80 W, but it transited to dry burning state when heating input was greater than 160 W. However, for ethanol, the heating input was in vicinity of 160 W. Furthermore, thermal resistance with acetone was lower than that with ethanol at the same heating input of 120 W.展开更多
Switchable multi-layer ethylene tetra-fluoro-ethylene(ETFE)cushion controls the natural light and heat flux passing through the cushion with varying outdoor conditions by dynamically modifying its properties.In this p...Switchable multi-layer ethylene tetra-fluoro-ethylene(ETFE)cushion controls the natural light and heat flux passing through the cushion with varying outdoor conditions by dynamically modifying its properties.In this paper,the switchable ETFE cushions with ink printing of different optical and thermal properties were adopted as the window in a typical office model,and the indoor daylight and energy consumption were simulated by using Grasshopper software.Experimental model was built to validate the numerical model.Five locations representing five climate zones in China were selected to analyze the feasibility of the switchable ETFE cushion in different climates.The hourly indoor daylight and heat gain in a single day revealed the effects of the dynamic mechanism of ETFE cushion in improving indoor natural light and thermal environment.In addition,the annual daylight performance at the working area(1.5 m from the window)was simulated.ETFE cushion with printing of the lowest transmittance(ETFE1)was the optimal option for most cities and window-to-wall ratios,with the percentage of annual useful daylight hours up to 78.6%,except for the cases where the window-to-wall ratio(WWR)was 0.35 in Harbin,Beijing,and Hefei.The distribution of useful daylight hours revealed that ETFE cushions with low,medium,and high printing transmittance were suitable for offices where people work in the front,medium,and back region of the room,respectively.Energy consumption calculation revealed that ETFE1 showed advantages over other windows in most cities except for cities highly dominated by heating.ETFE1 delivered up to 33%of energy saving over a year in Kunming compared with the conventional double glazing but was not superior in cities with high heating and low cooling demands,such as Harbin.展开更多
Low critical temperature limits the application of CO_2 trans-critical power cycle.The binary mixture of R290/CO_2has higher critical temperature.Using mixture fluid may solve the problem that subcritical CO_2 is hard...Low critical temperature limits the application of CO_2 trans-critical power cycle.The binary mixture of R290/CO_2has higher critical temperature.Using mixture fluid may solve the problem that subcritical CO_2 is hardly condensed by conventional cooling water.In this article,theoretical analysis is executed to study the performance of the zeotropic mixture for trans-critical power cycle using low-grade liquid heat source with temperature of200℃.The results indicated that the problem that CO_2 can't be condensed in power cycle by conventional cooling water can be solved by mixing R290 to CO_2.Variation trend of outlet temperature of thermal oil in supercritical heater with heating pressure is determined by the composition of the mixture fluid.Gliding temperature causes the maximum outlet temperature of cooling water with the increase of mass fraction of R290.There are the maximum values for cycle thermal efficiency and net power output with the increase of supercritical heating pressure.展开更多
基金supported financially by the National Nature Science Foundation of China(No.41901129)the University Natural Sciences Research Project of Anhui Educational committee(KJ2020JD06)DUAN Zheng acknowledges the support from the Joint China-Sweden Mobility Grant funded by NSFC and STINT(CH2019-8250).
文摘The ice phenology of alpine lakes on the Tibetan Plateau(TP)is a rapid and direct responder to climate changes,and the variations in lake ice exhibit high temporal frequency characteristics.MODIS and passive microwave data are widely used to monitor lake ice changes with high temporal resolution.However,the low spatial resolutions make it difficult to effectively quantify the freeze-melt dynamics of lakes.This work used Sentinel-1 synthetic aperture radar(SAR)data to derive high-resolution ice maps(about 6 days),then with the aid of Sentinel-2 optical images to quantify freeze-melt processes in three typical lakes on the TP(e.g.Selin Co,Ayakekumu Lake,and Nam Co).The results showed that three lakes had an average annual ice period of 125-157 days and a complete ice cover period of 72-115 days,from 2018 to 2022.They exhibit different ice phenology patterns.Nam Co is characterized by repeated episodes of freezing,melting,and refreezing,resulting in a prolonged freeze-up period.Meanwhile,the break-up period of Nam Co lasts for a longer duration(about 19 days),and the break-up exhibits a smooth process.Similarly,Ayakekumu Lake showed more significant inter-annual fluctuations in the freeze-up period,with deviations of up to 28 days observed among different years.Compared to the other two lakes,Selin Co experienced a relatively short freeze-up and break-up period.In short,Sentinel-1 SAR data can effectively monitor the weekly and seasonal variations in lake ice on the TP.Particularly,this data facilitates quantification of the freeze-melt dynamics.
基金Supported by the National Natural Science Foundation of China (No. 20875007)Funding Project for Academic Human Resources Development in Institutions of Higher Learning under the Jurisdiction of Beijing Municipality (No. PHR201008372 and PHR201106124)the Research Fund of Beijing University of Civil Engineering and Architecture (No. 100902602)
文摘The title complexes(NH4)[Ag(dpe)(H2bptc)](1) and Ag2(bpy)(ox)·7H2O(2) were synthesized via slow evaporation at room temperature,and characterized by elemental analysis and infrared spectra.The crystal of 1 crystallizes in triclinic,space group P1 with a = 8.3959(7),b = 11.8088(12),c = 12.8175(13) ,α = 85.507(2),β = 79.245(1),γ = 84.174(2)o,V = 1239.7(2) 3,Z = 2,C28H22AgN3O8,Mr = 636.36,Dc = 1.705 g/cm3,F(000) = 644 and μ(MoKα) = 0.874 mm-1.The final R = 0.0479 and wR = 0.1426 for 3632 observed reflections with I > 2σ(I) and R = 0.0559 and wR = 0.1503 for all data.The crystal of 2 crystallizes in orthorhombic,space group Pnna with a = 17.2291(17),b = 7.5289(6),c = 21.369(2),V = 2771.9(4) 3,Z = 4,C22H30Ag2N4O11,Mr = 742.24,Dc = 1.779 g/cm3,F(000) = 1488 and μ(MoKα) = 1.476 mm-1.The final R = 0.0648 and wR = 0.2058 for 1996 observed reflections with I > 2σ(I) and R = 0.0769 and wR = 0.2192 for all data.X-ray diffraction reveals that in complexes 1 and 2,both 1,2-di(4-pyridyl)ethylene and 4,4'-bipyridine act as typical bidentate N-donor ligands to link two Ag centers.3,3'4,4'-Biphenyltetracarboxylate and oxalate anions play the role of organic linkers and counter-ions to balance the cationic charge of AgI.The rich hydrogen-bonding interactions and ligand-unsupported Ag…Ag interactions as well as π-π stacking interactions contribute to the construction of three-dimensional sandwich-like frameworks.
基金Project(50878133) supported by the National Natural Science Foundation of ChinaProject (2007R37) supported by Excellent Talents in Liaoning Province+1 种基金Project (2008S193) supported by the Key Laboratory Fund of Education Department in Liaoning ProvinceProject(1071211-1-00) supported by the Scientific and Technical Fund Project Subsidy of Shenyang Province
文摘Based on the phase change material (PCM) thermal characteristic,some testing methods such as differential scanning calorimeter (DSC) etc were used to select the low melting mixture of capric and lauric acid as PCM of phase change wallboard (PCW). The PCW room was established,and some contrast analysis of the storage and exchange thermal characteristic of PCW room and ordinary wall room were made under different conditions. The results show that the fluctuation of indoor air temperature in PCW room is smaller than that in ordinary room obviously. The exchange energy of PCM room with outdoor is less than that of ordinary wall room. In the winter condition,PCW room utilizes valley period electricity to storage energy in the night,while releases at peak period electricity in daytime,which can divert 40% of peak load. In the summer condition,PCW room can reduce the peak cooling load by 25% compared with ordinary wall room.
基金Project(PHR201007127) supported by Academic Human Resources Development Fund of Institutions of Higher Learning under the Jurisdiction of Beijing Municipality, China Project(bsbe2010-05) supported by the Opening Funds of State Key Laboratory of Building Safety and Built Environment, China Project supported by the Doctoral Startup Foundation of Beijing University of Civil Engineering and Architecture, China
文摘A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were calculated by the mathematical model.The solution content first increases and then decreases along the solution flow direction.At y/Hr=0.98(where Hr is the height of regenerator),air humidity increases from 1.99% to 2.348% firstly and then decreases.The experimental results were used to validate mathematical model.It is indicated that the simulation results agree with experimental data well.The results not only show that the mathematical model can be used to predict the performance of regenerator,but also has great value in the design and improvement of evaporative condensing regenerator.
基金Supported by the National Natural Science Foundation of China(No.51306198)the Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20110032110046)
文摘In the performance experiment of organic Rankine cycle power generation experimental system, the loadresistance-regulation method is one of the most important regulation methods. However, the regulation law has not been clear enough to guide the experiment, which is unfavorable to the experimental research on organic Rankine cycle. In this paper the regulation law of turbine and generator by the load-resistance-regulation method is studied theoretically and experimentally. The results show that when the thermal cycle parameters keep constant, the turbine speed increases with the increase of load resistance and there is a maximum value of transmission-generator efficiency with the variation of the turbine speed; when the turbine speed and generator speed keep constant, the transmissiongenerator efficiency decreases and gradually tends to zero with the increase of load resistance.
基金supported partially by the National Natural Science Foundation of China under Grant 61503348the Hubei Provincial Natural Science Foundation of China under Grant 2015CFA010the 111 project under Grant B17040
文摘When the wind speed changes significantly in a permanent magnet synchronous wind power generation system,the maximum power point cannot be easily determined in a timely manner.This study proposes a maximum power reference signal search method based on fuzzy control,which is an improvement to the climbing search method.A neural network-based parameter regulator is proposed to address external wind speed fluctuations,where the parameters of a proportional-integral controller is adjusted to accurately monitor the maximum power point under different wind speed conditions.Finally,the effectiveness of this method is verified via Simulink simulation.
基金financially supported by National Natural Science Foundation of China (Grant No.52000008)supported by R&D Program of Beijing Municipal Education Commission(Grant No.KM202310016008)+1 种基金Beijing Natural Science Foundation (Grant No.3192042)the Fundamental Research Funds for Beijing University of Civil Engineering and Architecture (Grant No.X20058)。
文摘The specific heat capacity of working fluid is an important influence factor on heat transfer characteristic of the pulsating heat pipe(PHP).Due to the relatively large specific heat capacity of micro encapsulated phase change material(MEPCM) suspension,a heat transfer performance experimental facility of the PHP was established.The heat transfer characteristic with MEPCM suspension of different mass concentrations(0.5% and 1.0%) and ultra-pure water were compared experimentally.It was found that when the PHP uses MEPCM suspension as its working fluid,operating stability is impoverished under lower heating power and the operating stability is better under higher heating power.At the inclination angle of 90°,the temperature at heating side decreases compared to ultra-pure water and the temperature at heating side decreases with the raising of MEPCM suspension mass concentration.The heat transfer characteristic of the PHP is positively correlated with the inclination angle and the 90° is optimum.The unfavorable effect of the inclination angle decreases with heating power increasing.When the inclination angle is 90°,the PHP with MEPCM suspension at 1.0% of mass concentration has the lowest thermal transfer resistance and followed by ultra-pure water and MEPCM suspension at 0.5% of mass concentration has the highest thermal transfer resistance.When the inclination angles are 60° and30°,the effect of gravity on the flow direction is reduced to 86.6% and 50% of that on the inclination angle of 90°,respectively,and the promoting effect of gravity on the working fluid is further weakened as the inclination angle further decreases.Due to the high viscosity of MEPCM suspension,the PHP with ultra-pure water has the lowest heat transfer resistance.When the inclination angles is 60°,the thermal resistance with MEPCM suspension at0.5% of the mass concentration is lower than that at 1.0% at the heating power below 230 W.The thermal resistance of MEPCM suspension tends to be similar for heating power of 230-250 W.At the heating power above 270 W,the thermal resistance with MEPCM suspension at 1.0% of the mass concentration is lower than that at 0.5%.
基金Project(50878133) supported by the National Natural Science Foundation of ChinaProject(2007R37) supported by the Program Supporting Excellent Talents of Liaoning Province,China+1 种基金Project(2008S193) supported by the Key Laboratory Fund of Education Department of Liaoning Province,ChinaProject(1071211-1-00) supported by the Scientific and Technical Fund Project Subsidy of Shenyang,China
文摘More and more attention was paid to phase change energy storage in air conditioning domain and construction energy conservation,and became the focus of the international research. Through the test and analysis of the parameters of the indoor thermal property in phase change wallboard room and ordinary room,the effects of using phase change wallboards on indoor temperature in summer and air conditioning are obtained. The combination of construct enclosure and phase change materials can stabilize indoor temperature,improve indoor thermal comfort,reduce the frequency of the operation of air conditioning facility,cut the initial investment and operation expense,and meanwhile play an practical role in "the power balancing between the peak period and the valley period" policy. Through the experiment and the test of the effects exerted by phase change wallboard room and ordinary room on the indoor thermal environment,it is obtained that the phase change wallboard can reduce the fluctuation range of indoor temperature and the heat flow from the outside into indoor environment in summer. According to the study,it is found that the effect of cool-storing for 5 h is obvious. Through the analysis of the phase change wallboard without air conditioning in daytime,it is obtained that the frequency of the operation of air conditioning in phase change wallboard room is smaller than that in the ordinary room,which can prolong the lifetime of the facility and reduce operation expense.
基金sponsored by the National Natural Science Foundation of China [No.81372949]the Young Scholar Scientific Research Foundation of China CDC [No.2016A206]
文摘Objective To comparatively study the toxicity of four metal-containing nanoparticles(MNPs) and their chemical counterparts to the air-blood barrier(ABB) permeability using an in vitro model.Methods ABB model, which was developed via the co-culturing of A549 and pulmonary capillary endothelium, was exposed to spherical CuO-NPs(divided into CuO-40, CuO-80, and CuO-100 based on particle size), nano-Al2O3(sheet and short-rod-shaped), nano-ZnO, nano-Pb S, CuSO4, Al2(SO4)3, Zn(CH3COO)2, and Pb(NO3)2 for 60 min.Every 10 min following exposure, the cumulative cleared volume(ΔTCL) of Lucifer yellow by the model was calculated.A clearance curve was established using linear regression analysis of ΔTCL versus time.Permeability coefficient(P) was calculated based on the slope of the curve to represent the degree of change in the ABB permeability.Results The results found the increased P values of CuO-40, CuO-80, sheet, and short-rod-shaped nano-Al2O3, Al2(SO4)3, and Pb(NO3)2.Among them, small CuO-40 and CuO-80 were stronger than CuO-100 and CuSO4;no difference was observed between Al2(SO4)3 and sheet and short-rod-shaped nano-Al2O3;and nano-Pb S was slightly weaker than Pb(NO3)2.So clearly the MNPs possess diverse toxicity.Conclusion ABB permeability abnormality means pulmonary toxicity potential.More studies are warranted to understand MNPs toxicity and ultimately control the health hazards.
文摘Ash deposition is a form of particulate fouling, and appears usually in boiler economizers. The ash deposition increases capital expenditure, energy input and maintenance costs. An analog experiment for monitoring ash deposition was performed from the analogous objective of a 410 t/h boiler economizer to verify the rationality and reliability of the ash-deposition-monitoring model presented in order to increase the security and economy in economizer running. The analog experiment platform is a tube-shell exchanger that conforms well to the conditions of a self-modeling area. The analog flue gas in the shell side is the heated air mixed with ash, and in the tube side the fluid is water heated by the flue gas. The fluid state in the water side and the flue gas side follows the second self-modeling area. A 4-factor-3-level orthogonal table was used to schedule 9 operation conditions of orthogonal experiment, with the 4 factors being heat power, flue gas velocity, ashes grain diameter and adding ashes quantity while the three levels are different values due to different position classes in every factor. The ash deposition thermal resistances is calculated by the model with the measure parameters of temperature and pressure drop. It shows that the values of the ash deposition thermal resistances gradually increase up to a stable state. And the experimental results are reliable by F testing method at α= 0.001. Therefore, the model can be applied in online monitoring of ash deposition in a boiler economizers in power plants and provides scientific decision on ash deposition prediction and sootblowing.
基金This work was supported by Beijing Foundation for Academic Human Resources Development in Institution and the Beijing Foundation for Natural Science
文摘In this paper, a carbon dioxide trans-critical refrigerating system which is different from a conventional subcritical refrigerating cycle was studied. The trans-critical carbon dioxide refrigerating systems are based on the Gustav Lorntzen cycle. Emphasis was focused on how to determine the optimal discharge pressure of compressor in CO2 trans-critical cycle. The factors related with the optimal discharge pressure were analyzed. A formula was developed based on cycle simulation, which could be used to predict the optimal discharge pressure of a basic CO2 trans-critical cycle. After further studies on CO2 trans-critical cycles with a regenerator or expander, two more formulas were also developed. These formulas could provide an access to improve the COP of CO2 trans-critical cycle.
文摘This paper studied on the removal of toxic substance from river water using O3-GAC process. The result of GC/MS analysis indicated that the number of organic compound species was decreased by 55.1%. The species of toxic substance of raw water also decreased from 16 to 5. The total removal rate of CODMn andUV254 were 45%～72% and 60%～80% following O3-GAC treatment. It reflected that this process had a good effective on removing unsaturation organic which absorb UV and toxic organic containing nitrogen. The results of Ames test indicated that raw water had a relatively strong mutagicity on TA 98. The O3-GAC process had a good ability in removing mutagen in water. The effluent water’s mutagicity is minus. The results of the study indicated that the effluent of the O3-GAC process was meet the demand of drinking water.
基金supported by the National Natural Science Foundation of China (No.52108068)the Beijing Municipal Natural Science Foundation of China (No.8222019)the National Natural Science Foundation of China (No.52225801).
文摘Building energy modeling(BEM)has become increasingly used in building energy conservation research.Prototype building models are developed to represent the typical urban building characteristics of a specific building type,meteorological conditions,and construction year.This study included four residential buildings and 11 commercial buildings to represent nationwide building types in China.With consideration of five climate zones and different construction years corresponding to national standards,a total of 151 prototype building models were developed.The building envelope properties,occupancy and energy-related behaviors,and heating,ventilation,and air-conditioning(HVAC)system characteristics were defined according to the corresponding building energy efficiency design standards,HVAC design standards,and through other sources,such as questionnaire surveys,on-site measurements,and literature,which reflect the real situation of existing buildings in China.Based on the developed prototype buildings,a large database of 9225 models in 270 cities was further developed to facilitate users to simulate building energy in different cities.In conclusion,the developed prototype building models can represent realistic building characteristics and construction practices of the most common residential and commercial buildings in China,serving as an important foundation for BEM.The models can be used for analyses related to building energy conservation research on typical individual buildings,including energy-saving technologies,advanced controls,and new policies,and providing a reference for the development of building energy codes and standards.
基金This work was supported by the National Natural Science Foundation of China(52078117)the National Natural Science Foundation of China(52108068)+1 种基金the National Natural Science Foundation of China(52225801)the“Zhishan”Scholars Programs of Southeast University(2242021R41145).
文摘Building energy simulation analysis plays an important supporting role in the conservation of building energy.Since the early 1980s,researchers have focused on the development and validation of building energy modeling programs(BEMPs)and have basically formed a set of systematic validation methods for BEMPs,mainly including analytical,comparative,and empirical methods.Based on related papers in this field,this study systematically analyzed the application status of validation methods for BEMPs from three aspects,namely,sources of validation cases,comparison parameters,and evaluation indicators.The applicability and characteristics of the three methods in different validation fields and different development stages of BEMPs were summarized.Guidance were proposed for researchers to choose more suitable validation methods and evaluation indicators.In addition,the current development trend of BEMPs and the challenges faced by validation methods were investigated,as well as the existing progress of current validation methods under this trend was analyzed.Subsequently,the development direction of the validation method was clarified.
基金The authors wish to thank the financial support for this work provided by the National Natural Science Foundation of China(51974087)China Postdoctoral Science Foundation(2018M642538)+1 种基金Fundamental Research Funds for the Central Universities(WK2090130025)Anhui Provincial Natural Science Foundation(19O8O85QE2O3).
文摘The parameter study of sinter waste heat recovery in vertical tank was conducted numerically by using energy and exergy analysis,and the experimental data obtained from a homemade experimental apparatus was applied to verify the reliability of numerical model.Based on the first and second laws of thermodynamics,the effects of flow rate of cooling air(FRCA)and inlet temperature of cooling air(ITCA),as well as the inner diameter of cooling section(IDCS)and height of cooling section(HCS),on the sinter cooling process were analyzed in detail.The results show that the average deviation between the experimental data and calculation values is 4.93%,and the model reliability is verified.The enthalpy exergy of outlet air tends to increase first and then decrease with increasing the FRCA and ITCA,while increasing the IDCS only leads to the increase in enthalpy exergy of outlet air.For a given operational condition,the enthalpy exergy of outlet air can reach a maximum value with increasing the HCS.The vertical tank could obtain the maximum enthalpy exergy of outlet air through the adjustments of FRCA and ITCA,as well as the HCS.
基金supported by National Natural Science Foundation of China(NSFC)(51477111)National Key Research and Development Program of China(2016YFB0901104).
文摘With integration of renewable energy and use of non-linear loads in power systems,the power quality problem is increasingly attracting attention of researchers.In China,standards for individual power quality indexes are set.However,when evaluating power quality in practice,individual indexes cannot directly reflect a comprehensive level of power quality.In this paper,a comprehensive analysis of various indexes is conducted to obtain a unified parameter for describing the characteristics of power quality from an overall perspective.First,weight values of power quality indexes are calculated by combining the subjective and objective weight.Then,based on the principal components of the projection method,projection values of boundary data and data to be evaluated are obtained.Finally,using these projection values,a grade range for power quality data is located.A practical case study is presented to show the validity of the proposed method for evaluating power quality.
基金Project 51306198 supported by National Natural Science Foundation of ChinaProject 00921915023 supported by Organization Department of Beijing+1 种基金Project NR2013K07 supported by Beijing Key Lab of Heating,Gas Supply,Ventilating and Air Conditioning EngineeringProject 331614013 supported by Beijing University of Civil Engineering and Architecture
文摘Using ethanol or acetone as the working fluid, the performance of starting up and heat transfer of closed-loop plate oscillating heat pipe with parallel channels(POHP-PC) were experimentally investigated by varying filling ratio, inclination, working fluids and heating power. The performance of the tested pulsating heat pipe was mainly evaluated by thermal resistance and wall temperature. Heating copper block and cold water bath were adopted in the experimental investigations. It was found that oscillating heat pipe with filling ratio of 50% started up earlier than that with 70% when heating input was 159.4 W, however, it has similar starting up performance with filling ratio of 50% as compared to 70% on the condition of heat input of 205.4 W. And heat pipe with filling ratio of 10% could not start up but directly transit to dry burning. A reasonable filling ratio range of 35%-70% was needed in order to achieve better performance, and there are different optimal filling ratios with different heating inputs- the more heating input, the higher optimal filling ratio, and vice versa. However, the dry burning appeared easily with low filling ratio, especially at very low filling ratio, such as 10%. And higher filling ratio, such as 70%, resulted in higher heat transfer( dry burning) limit. With filling ratio of 70% and inclination of 75°, oscillating heat pipe with acetone started up with heating input of just 24 W, but for ethanol, it needed to be achieved 68 W, Furthermore, the start time with acetone was similar as compared to that with ethanol. For steady operating state, the heating input with acetone was about 80 W, but it transited to dry burning state when heating input was greater than 160 W. However, for ethanol, the heating input was in vicinity of 160 W. Furthermore, thermal resistance with acetone was lower than that with ethanol at the same heating input of 120 W.
基金supported by grants from the Key Research and Development Program of Anhui Province(No.S202004a07020029)National Natural Science Foundation of China(No.51908174)Anhui Provincial Natural Science Foundation(No.1908085QE206).
文摘Switchable multi-layer ethylene tetra-fluoro-ethylene(ETFE)cushion controls the natural light and heat flux passing through the cushion with varying outdoor conditions by dynamically modifying its properties.In this paper,the switchable ETFE cushions with ink printing of different optical and thermal properties were adopted as the window in a typical office model,and the indoor daylight and energy consumption were simulated by using Grasshopper software.Experimental model was built to validate the numerical model.Five locations representing five climate zones in China were selected to analyze the feasibility of the switchable ETFE cushion in different climates.The hourly indoor daylight and heat gain in a single day revealed the effects of the dynamic mechanism of ETFE cushion in improving indoor natural light and thermal environment.In addition,the annual daylight performance at the working area(1.5 m from the window)was simulated.ETFE cushion with printing of the lowest transmittance(ETFE1)was the optimal option for most cities and window-to-wall ratios,with the percentage of annual useful daylight hours up to 78.6%,except for the cases where the window-to-wall ratio(WWR)was 0.35 in Harbin,Beijing,and Hefei.The distribution of useful daylight hours revealed that ETFE cushions with low,medium,and high printing transmittance were suitable for offices where people work in the front,medium,and back region of the room,respectively.Energy consumption calculation revealed that ETFE1 showed advantages over other windows in most cities except for cities highly dominated by heating.ETFE1 delivered up to 33%of energy saving over a year in Kunming compared with the conventional double glazing but was not superior in cities with high heating and low cooling demands,such as Harbin.
基金Project 51306198 supported by the National Natural Science Foundation of China
文摘Low critical temperature limits the application of CO_2 trans-critical power cycle.The binary mixture of R290/CO_2has higher critical temperature.Using mixture fluid may solve the problem that subcritical CO_2 is hardly condensed by conventional cooling water.In this article,theoretical analysis is executed to study the performance of the zeotropic mixture for trans-critical power cycle using low-grade liquid heat source with temperature of200℃.The results indicated that the problem that CO_2 can't be condensed in power cycle by conventional cooling water can be solved by mixing R290 to CO_2.Variation trend of outlet temperature of thermal oil in supercritical heater with heating pressure is determined by the composition of the mixture fluid.Gliding temperature causes the maximum outlet temperature of cooling water with the increase of mass fraction of R290.There are the maximum values for cycle thermal efficiency and net power output with the increase of supercritical heating pressure.
