Understanding the differences in mechanical properties and damage characteristics of granitoid under high temperatures is crucial for exploring deep geothermal resources.This study analyzes the evolution of the acoust...Understanding the differences in mechanical properties and damage characteristics of granitoid under high temperatures is crucial for exploring deep geothermal resources.This study analyzes the evolution of the acoustic emission(AE)characteristics and mechanical parameters of granodiorite and granite after heating and water cooling by uniaxial compression and variable-angle shear tests under different temperature gradients.We identify their changes in mesostructure and mineral composition with electron probe microanalysis and scanning electron microscopy.Results show that these two hot dry rocks have similar diagenetic minerals and microstructure,but show significantly different mechanical and acoustic characteristics,and even opposing evolution trends in a certain temperature range.At the temperatures ranging from 100℃to 500℃,the compressive and shear mechanical properties of granodiorite switch repeatedly between weakening and strengthening,and those of granite show a continuous weakening trend.At 600℃,both rocks exhibit a deterioration of mechanical properties.The damage mode of granite is characterized by initiating at low stress,exponential evolutionary activity,and intensified energy release.In contrast,granodiorite exhibits the characteristics of initiating at high stress,volatile evolutionary activity,and intermittent energy release,due to its more stable microstructure and fewer thermal defects compared to granite.As the temperature increases,the initiation and propagation of secondary cracks in granodiorite are suppressed to a certain extent,and the seismicity and brittleness are enhanced.The subtle differences in grain size,microscopic heterogeneity,and mineral composition of the two hot dry rocks determine the different acoustic-mechanical characteristics under heating and cooling,and the evolution trends with temperature.These findings are of great significance for the scientific and efficient construction of rock mass engineering by rationally utilizing different rock strata properties.展开更多
The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of...The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of Advanced Geochemistry has effectively stimulated students’interest in learning and further improved their scientific thinking and research innovation skills through the implementation of“Guiding Interactive”teaching reform measures,which has important theoretical significance and practical value.展开更多
Well-preserved graptolites of the genus Kiaerograptus are first reported from the upper Tremadocian Yinchupu Formation in the Nanba section,Yiyang,Hunan Province,South China,including four species,i.e.,Kiaerograptus l...Well-preserved graptolites of the genus Kiaerograptus are first reported from the upper Tremadocian Yinchupu Formation in the Nanba section,Yiyang,Hunan Province,South China,including four species,i.e.,Kiaerograptus lauzonensis(Erdtmann,1966),Kiaerograptus stoermeri(Erdtmann,1965),Kiaerograptus cf.supremus?Lindholm,1991,and Kiaerograptus sp.,which are robust in form.Based on these new specimens,the Kiaerograptus biozone is established for the first time in South China,increasing the late Tremadoc graptolite biozones in South China from four to five,in ascending order as follows:the Adelograptus tenellus biozone,the Aorograptus victoriae biozone,the Kiaerograptus biozone,the Sagenograptus murrayi biozone,and the Hunnegraptus copiosus biozone.A review of the occurrence records for robust Kiaerograptus species worldwide reveals that the distribution is restricted to the Aorograptus victoriae biozone and Kiaerograptus biozone in the late Tremadocian.This limited stratigraphical distribution makes Kiaerograptus a valuable taxon for precise biostratigraphical correlation at both the regional and global scales.展开更多
Geodetic functional models,stochastic models,and model parameter estimation theory are fundamental for geodetic data processing.In the past five years,through the unremitting efforts of Chinese scholars in the field o...Geodetic functional models,stochastic models,and model parameter estimation theory are fundamental for geodetic data processing.In the past five years,through the unremitting efforts of Chinese scholars in the field of geodetic data processing,according to the application and practice of geodesy,they have made significant contributions in the fields of hypothesis testing theory,un-modeled error,outlier detection,and robust estimation,variance component estimation,complex least squares,and ill-posed problems treatment.Many functional models such as the nonlinear adjustment model,EIV model,and mixed additive and multiplicative random error model are also constructed and improved.Geodetic data inversion is an important part of geodetic data processing,and Chinese scholars have done a lot of work in geodetic data inversion in the past five years,such as seismic slide distribution inversion,intelligent inversion algorithm,multi-source data joint inversion,water reserve change and satellite gravity inversion.This paper introduces the achievements of Chinese scholars in the field of geodetic data processing in the past five years,analyzes the methods used by scholars and the problems solved,and looks forward to the unsolved problems in geodetic data processing and the direction that needs further research in the future.展开更多
The Suizhou meteorite is a heavily shocked and melted vein-containing L6 chondrite.It contains a minor amount of diopside with a(Ca_(0.419)Mg_(0.466)Fe_(0.088))SiO_(3)composition,and a shock-metamorphosed diopside gra...The Suizhou meteorite is a heavily shocked and melted vein-containing L6 chondrite.It contains a minor amount of diopside with a(Ca_(0.419)Mg_(0.466)Fe_(0.088))SiO_(3)composition,and a shock-metamorphosed diopside grain associated with ringwoodite and lingunite was found in a melt vein of this meteorite.Our electron microprobe,transmission electron microscopic and Raman spectroscopic analyses revealed four silicate phases with different compositions and structures inside this shock-metamorphosed diopside grain,termed phase A,B,C and D in this paper.Phase A is identified as orthorhombic(Ca_(0.663)-Mg_(0.314))SiO_(3)-perovskite which is closely associated with phase B,the vitrified(Mg_(0.642)Ca_(0.290)Fe_(0.098))SiO_(3)perovskite.Phase D is assigned to be(Mg_(0.578)Ca_(0.414))SiO_(3)majorite which is associated with phase C,the vetrified Carich Mg-perovskite with a(Mg_(0.853)Ca_(0.167))SiO_(3)composition.Based on high-pressure and high-temperature experiments,the diopside grain in the melt vein of the Suizhou meteorite would have experienced a P–T regime of 20–24GPa and 1800–>2000℃.Such P–T conditions are high enough for the decomposition of the diopside and the formation of four different silicate phases.The orthorhombic(Ca_(0.663)Mg_(0.314))SiO_(3)perovskite found in the Suizhou L6 chondrite might be considered as the third lower-mantle silicate mineral after bridgmanite and davemaoite after the detailed analyses of its crystal structure and physical properties being completed.展开更多
Sentinel-1A/B data are crucial for retrieving numerical information about surface phenomena and processes.Coregistration of terrain observation by progressive scans(TOPS)data is a critical step in its application.TOPS...Sentinel-1A/B data are crucial for retrieving numerical information about surface phenomena and processes.Coregistration of terrain observation by progressive scans(TOPS)data is a critical step in its application.TOPS data must be fundamentally co-registered with an accuracy of 0.001 pixels.However,various decorrelation factors due to natural vegetation and seasonal effects affect the coregistration accuracy of TOPS data.This paper proposed an enhanced spectral diversity coregistration method for dual-polarimetric(PolESD)Sentinel-1A/B TOPS data.The PolESD method suppresses speckle noise based on a unified non-local framework in dual-pol Synthetic Aperture Radar(SAR),and extracts the phase of the optimal polarization channel from the denoised polarimetric interferometric coherency matrix.Compared with the traditional ESD method developed for single-polarization data,the PolESD method can obtain more accurate coherence and phase and get more pixels for azimuth-offset estimation.In bare areas covered with low vegetation,the number of pixels selected by PolESD is more than the Boxcar method.It can also correct misregistration more effectively and eliminate phase jumps in the burst edge.Therefore,PolESD will help improve the application of TOPS data in low-coherence scenarios.展开更多
We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact stru...We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase.展开更多
Fluidic oscillators(FOs)can be used as an efficient fluidic vibration tool to solve high friction problems in extended-reach wells.However,the complex mechanism of FOs makes the design challenging,and the dynamic eros...Fluidic oscillators(FOs)can be used as an efficient fluidic vibration tool to solve high friction problems in extended-reach wells.However,the complex mechanism of FOs makes the design challenging,and the dynamic erosion behavior inside FOs is still unclear.In this paper,new FOs are proposed and the working characteristics under the influence of periodic particle-laden jets are investigated.Firstly,the results reveal the working mechanism of new FOs,showing that the generation of pressure pulses is closely connected with periodic jet switching and the development of vortices.Secondly,the important performance parameters,i.e.,pressure pulse and oscillation frequency,are extensively studied through numerical simulation and experimental verification.It is found that the performance can be optimized by adjusting the tool structure according to different engineering requirements.Finally,the oscillating solid-liquid two-phase flow inside FO is studied.It is demonstrated that the accumulation of particles leads to a significant reduction in performance.The results also reveal five locations that are susceptible to erosion and the erosion behavior of these locations are studied.It has been shown that the periodic jet causes fluctuations in the amount of erosion at the outlet and splitter.This research can provide valuable references for the design and optimization of vibration friction-reduction tools.展开更多
The Neoproterozoic evolution of the Jiangnan Orogen is important for understanding the tectonic history of South China.As a volcanic-sedimentary sequence developed in the Nanhua rift,the Banxi Group preserves the reco...The Neoproterozoic evolution of the Jiangnan Orogen is important for understanding the tectonic history of South China.As a volcanic-sedimentary sequence developed in the Nanhua rift,the Banxi Group preserves the records of important magmatic and tectonic events linked to the assembly and breakup of the Rodinia supercontinent.In this study,we report the results from whole-rock major-and trace-element concentrations,with zircon LA-(MC)-ICP-MS U-Pb ages,trace elements and Lu-Hf isotopic compositions of sandstones from the Banxi Group.The rocks are characterized by high SiO_(2)(65.88%–82.76%,with an average of 75.50%)contents,moderate(Fe_(2)O_(3)^(T)+MgO)(1.81%–7.78%,mean:3.79%)and TiO_(2)(0.39%–0.54%,mean:0.48%),low K_(2)O/Na_(2)O(0.03–0.40,mean:0.10)ratios and low Al_2O_(3)/SiO_(2)(0.11–0.24,mean:0.15)ratios.The sandstones have highΣREE contents(mean:179.1 ppm),with chondrite-normalized REE patterns similar to the upper crust and PAAS,showing enriched LREE((La/Yb)_N mean:14.85),sub-horizontal HREE curves and mild Eu(Eu/Eu^(*):0.75–0.89,mean:0.81)negative anomalies.Their geochemical characteristics resemble those of passive continental margin sandstones.Most of the zircons are magmatic in origin and yield a U-Pb age distribution with three peaks:a major age peak at 805 Ma and two subordinate age peaks at 1990 Ma and 2470 Ma,implying three major magmatic sources.The Neoproterozoic zircons haveε_(Hf)(t)values ranging from-47.4 to 12.4(mostly-20 to 0),suggesting a mixture of some juvenile arc-derived material and middle Paleoproterozoic heterogeneous crustal sources.The Hf model ages of middle Paleoproterozoic zircons(~1990 Ma)with negativeε_(Hf)(t)values(-12.65 to-6.21,Ave.=-9.8)concentrated around the Meso-Paleoarchean(mean T_(DM)^(C)=3.3–3.1 Ga).For late Neoarchean detrital zircons(~2470 Ma),ε_(Hf)(t)values are divided into two groups,one with negative values(-9.16 to-0.6)with model ages of 3.5–2.9 Ga,the other featuring positive values(1.0 to 3.9)with model ages of 2.9–2.7 Ga,recording a crustal growth event at~2.5 Ga.Neoproterozoic zircons show volcanic arc affinities with partly intraplate magmatic features.We propose that the Banxi Group formed in a rift basin within a passive continental margin setting,which derived detritus from felsic to intermediate rocks from the Yangtze Block and a small amount of arc volcanic rocks.The middle Paleoproterozoic detrital zircon data suggest Columbia-aged basement lies beneath the western Jiangnan orogen.展开更多
Mantle conductivity imaging is one of the scientific goals of the forthcoming Macao Science Satellite-1(MSS-1).To achieve this goal,we develop a data analysis and inversion scheme for satellite magnetic data to probe ...Mantle conductivity imaging is one of the scientific goals of the forthcoming Macao Science Satellite-1(MSS-1).To achieve this goal,we develop a data analysis and inversion scheme for satellite magnetic data to probe global one-dimensional(1D)mantle conductivity structures.Using this scheme,we present a new global mantle conductivity model by analyzing over 8 years of Swarm satellite magnetic data.First,after sophisticated data selection procedures and the removal of core and crustal fields,the inducing and induced spherical harmonic coefficients of magnetic potential due to the magnetospheric ring current are derived.Second,satellite Cresponses are estimated from the time series of these coefficients.Finally,the observed responses are inverted for both smooth and threejump conductivity models using a quasi-Newton algorithm.The obtained conductivity models are in general agreement with previous global mantle conductivity models.A comparison of our conductivity model with the laboratory conductivity model suggests the mean state of the upper mantle and transition zone is relatively dry.This scheme can be used to process the forthcoming Macao Science Satellite-1 magnetic data.展开更多
Global electromagnetic induction provides an efficient way to probe the electrical conductivity in the Earth’s deep interior.Owing to the increasing geomagnetic data especially from high-accuracy geomagnetic satellit...Global electromagnetic induction provides an efficient way to probe the electrical conductivity in the Earth’s deep interior.Owing to the increasing geomagnetic data especially from high-accuracy geomagnetic satellites,inverting the Earth’s three-dimensional conductivity distribution on a global scale becomes attainable.A key requirement in the global conductivity inversion is to have a forward solver with high-accuracy and efficiency.In this study,a finite volume method for global electromagnetic induction forward modeling is developed based on unstructured grids.Arbitrary polyhedral grids are supported in our algorithms to obtain high geometric adaptability.We employ a cell-centered collocated variable arrangement which allows convenient discretization for complex geometries and straightforward implementation of multigrid technique.To validate the method,we test our code with two synthetic models and compare our finite volume results with an analytical solution and a finite element numerical solution.Good agreements are observed between our solution and other results,indicating acceptable accuracy of the proposed method.展开更多
Timely response to earthquake characterization can facilitate earthquake emergency rescue and further scientific investigations.On June 1,2022,M_(W) 5.9 earthquake occurred in the southern area of the Longmenshan faul...Timely response to earthquake characterization can facilitate earthquake emergency rescue and further scientific investigations.On June 1,2022,M_(W) 5.9 earthquake occurred in the southern area of the Longmenshan fault zone.This event also happened at the south end of the Dayi seismic gap and is the largest earthquake that has occurred in this seismic gap since the 1970 M 6.2 event.The slip-distribution model constrained by the seismic waveforms suggests a thrust-dominated faulting mechanism.The main slip occurs at a depth of~14 km,and the cumulative energy is released in the first 6 s.The variations of Coulomb stress caused by the mainshock show a positive change in the southwest area of the Dayi seismic gap,indicating possible activation of future earthquakes.In addition,we emphasize the importance of rapid estimation of deformation for near-field hazard delineation,especially when interferometric radar fails to image coseismic deformation in a high relief terrain.展开更多
The ore types of the Zhaokalong Fe-Cu deposit are divided into two categories: sulfide-type and oxide-type. The sulfide-type ore include siderite ore, galena-sphalerite ore and chalcopyrite ore, whereas the oxide-type...The ore types of the Zhaokalong Fe-Cu deposit are divided into two categories: sulfide-type and oxide-type. The sulfide-type ore include siderite ore, galena-sphalerite ore and chalcopyrite ore, whereas the oxide-type ore include magnetite ore and hematite ore. The ore textures and structures indicate that the Zhaokalong deposit is of the sedimentary-exhalative mineralization type. Geochemical analyses show that the two ore types have a high As, Sb, Mn, Co and Ni content. The REE patterns reveal an enrichment of the LREE compared to the HREE. Isotopic analysis of siderite ore reveal that the δ13CPDB ranges from 2.01 to 3.34 (‰) whereas the δ18O SMOW ranges from 6.96 to 18.95 (‰). The fluid inclusion microthermometry results indicate that homogenization temperatures of fluid inclusions in quartz range from 131 to 181℃, with salinity values of 1.06 to 8.04 wt% NaCl eq. The mineralizing fluid therefore belongs to the low temperature - low salinity system, with a mineralizing solution of a CO2-Ca2+(Na+, K+)-SO42-(F-, Cl-)-H2O system. The geochemical results and fluid inclusion data provide additional evidence that the Zhaokalong deposit is a sedex-type deposit that experienced two stages of mineralization. The sulfide mineralization probably occurred first, during the sedimentary exhalative process, as exhibited by the abundance of marine materials associated with the sulfide ores, indicating a higher temperature and relatively deoxidized oceanic depositional environment. After the main exhalative stage, hydrothermal activity was superimposed to the sulfide mineralization. The later stage oxide mineralization occurred in a low temperature and relatively oxidized environment, in which magmatic fluid circulation was dominant.展开更多
Mesozoic granitic intrusions are widely distributed in the Nanling region,South China.Yanshanian granites are closely connected with the formation of tungsten deposits.The Xihuashan granite is a typical representative...Mesozoic granitic intrusions are widely distributed in the Nanling region,South China.Yanshanian granites are closely connected with the formation of tungsten deposits.The Xihuashan granite is a typical representative of tungsten-bearing granite.The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite,medium-grained biotite granite and fine-grained two-mica granite,which correspond to LA-ICP-MS zircon U-Pb ages of 155.5±0.4 Ma,153.0±0.6 Ma and 152.8±0.9 Ma,respectively.Rocks from the Xihuashan mining area displays high SiO2(73.85% to 76.49%) and Na2O+K2O contents(8.09% to 9.43%),belonging to high-K calc-alkaline series.They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 1.06.All granites in this study area are rich in Rb,Th,U and Pb,and depleted in Ba,Sr,P,Ti,Nb and Eu,especially depleted in medium-grained biotite granite and fine-grained two-mica granite.The medium-grained porphyritic biotite granites usually have high LREE concentrations,whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents.Our geochemical data reveal that the studied rocks are highly fractionated I-type granite.The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity,which may explain the formation of three types of distinct granites.Variations of Rb,Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar.Fractional crystallization of monazite,allanite and apatite resulted in LREE changes in granite,and formation of garnet mainly caused HREE changes.Granites from the Xihuashan mining area have relatively high εNd(t) values(-9.77 to -11.46),indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantle-derived magmas.展开更多
The general regression neural network(GRNN) model was proposed to model and predict the length of day(LOD) change, which has very complicated time-varying characteristics. Meanwhile, considering that the axial atmosph...The general regression neural network(GRNN) model was proposed to model and predict the length of day(LOD) change, which has very complicated time-varying characteristics. Meanwhile, considering that the axial atmospheric angular momentum(AAM) function is tightly correlated with the LOD changes, it was introduced into the GRNN prediction model to further improve the accuracy of prediction. Experiments with the observational data of LOD changes show that the prediction accuracy of the GRNN model is 6.1% higher than that of BP network, and after introducing AAM function, the improvement of prediction accuracy further increases to 14.7%. The results show that the GRNN with AAM function is an effective prediction method for LOD changes.展开更多
The Kendekeke polymetallic deposit, located in the middle part of the magmatic arc belt of Qimantag on the southwestern margin of the Qaidam Basin, is a polygenetic compound deposit in the Qimantag metallogenic belt o...The Kendekeke polymetallic deposit, located in the middle part of the magmatic arc belt of Qimantag on the southwestern margin of the Qaidam Basin, is a polygenetic compound deposit in the Qimantag metallogenic belt of Qinghai Province. Multi-periodic ore-forming processes occurred in this deposit, including early-stage iron mineralization and lead-zinc-gold-polymetallic mineralization which was controlled by later hydrothermal process. The characteristics of the ore-forming fluids and mineralization were discussed by using the fluid inclusion petrography, Laser Raman Spectrum and micro-thermometry methods. Three stages, namely, S1-stage(copper-iron-sulfide stage), S2-stage(lead-zinc-sulfide stage) and C-stage(carbonate stage) were included in the hydrothermal process as indicated by the results of this study. The fluid inclusions are in three types: aqueous inclusion(type I), CO2-aqueous inclusion(type II) and pure CO2 inclusion(type III). Type I inclusions were observed in the S1-stage, having homogenization temperature at 240–320oC, and salinities ranging from 19.8% to 25.0%(wt % NaCl equiv.). All three types of inclusions, existing as immiscible inclusion assemblages, were presented in the S2-stage, with the lowest homogenization temperature ranging from 175 oC to 295oC, which represents the metallogenic temperature of the S2-stage. The salinities of these inclusions are in the range of 1.5% to 16%. The fluid inclusions in the C-stage belong to types I, II and III, having homogenization temperatures at 120–210oC, and salinities ranging from 0.9% to 14.5%. These observations indicate that the ore-forming fluids evolved from high-temperature to lowtemperature, from high-salinity to low-salinity, from homogenization to immiscible separation. Results of Laser Raman Spectroscopy show that high density of CO2 and CH4 were found as gas compositions in the inclusions. CO2, worked as the pH buffer of ore-forming fluids, together with reduction of organic gases(i.e. CH4, etc), affected the transport and sediment of the minerals. The fluid system alternated between open and close systems, namely, between lithostatic pressure and hydrostatic pressure systems. The calculated metallogenic pressures are in the range of 30 to 87 Mpa corresponding to 3 km mineralization depth. Under the influence of tectonic movements, immiscible separation occurred in the original ore-forming fluids, which were derived from the previous highsalinity, high-temperature magmatic fluids. The separation of CO2 changed the physicochemical properties and composition of the original fluids, and then diluted by mixing with extraneous fluids such as meteoric water and groundwater, and metallogenic materials in the fluids such as lead, zinc and gold were precipitated.展开更多
The absorbing boundary is the key in numerical simulation of borehole radar.Perfect match layer(PML) was chosen as the absorbing boundary in numerical simulation of GPR.But CPML(convolutional perfect match layer) appr...The absorbing boundary is the key in numerical simulation of borehole radar.Perfect match layer(PML) was chosen as the absorbing boundary in numerical simulation of GPR.But CPML(convolutional perfect match layer) approach that we have chosen has the advantage of being media independent.Beginning with the Maxwell equations in a two-dimensional structure,numerical formulas of finite-difference time-domain(FDTD) method with CPML boundary condition for transverse electric(TE) or transverse magnetic(TM) wave are presented in details.Also,there are three models for borehole-GPR simulation.By analyzing the simulation results,the features of targets in GPR are obtained,which can provide a better interpretation of real radar data.The results show that CPML is well suited for the simulation of borehole-GPR.展开更多
Rare metals including Lithium(Li),Beryllium(Be),Rubidium(Rb),Cesium(Cs),Zirconium(Zr),Hafnium(Hf),Niobium(Nb),Tantalum(Ta),Tungsten(W)and Tin(Sn)are important critical mineral resources.In China,rare metal mineral dep...Rare metals including Lithium(Li),Beryllium(Be),Rubidium(Rb),Cesium(Cs),Zirconium(Zr),Hafnium(Hf),Niobium(Nb),Tantalum(Ta),Tungsten(W)and Tin(Sn)are important critical mineral resources.In China,rare metal mineral deposits are spatially distributed mainly in the Altay and Southern Great Xingán Range regions in the Central Asian orogenic belt;in the Middle Qilian,South Qinling and East Qinling mountains regions in the Qilian-Qinling-Dabie orogenic belt;in the Western Sichuan and Bailongshan-Dahongliutan regions in the Kunlun-Songpan-Garze orogenic belt,and in the Northeastern Jiangxi,Northwestern Jiangxi,and Southern Hunan regions in South China.Major ore-forming epochs include Indosinian(mostly 200-240 Ma,in particular in western China)and the Yanshanian(mostly 120-160 Ma,in particular in South China).In addition,Bayan Obo,Inner Mongolia,northeastern China,with a complex formation history,hosts the largest REE and Nb deposits in China.There are six major rare metal mineral deposit types in China:Highly fractionated granite;Pegmatite;Alkaline granite;Carbonatite and alkaline rock;Volcanic;and Hydrothermal types.Two further types,namely the Leptynite type and Breccia pipe type,have recently been discovered in China,and are represented by the Yushishan Nb-Ta-(Zr-Hf-REE)and the Weilasituo Li-Rb-Sn-W-Zn-Pb deposits.Several most important controlling factors for rare metal mineral deposits are discussed,including geochemical behaviors and sources of the rare metals,highly evolved magmatic fractionation,and structural controls such as the metamorphic core complex setting,with a revised conceptual model for the latter.展开更多
基金The authors would like to acknowledge the financial support from the National Natural Science Foundation of China(Grant No.52104112)the Research Foundation of the Department of Natural Resources of Hunan Province,China(Grant No.20230101DZ)the Natural Science Foundation of Hunan Province,China(Grant No.2023JJ20062).
文摘Understanding the differences in mechanical properties and damage characteristics of granitoid under high temperatures is crucial for exploring deep geothermal resources.This study analyzes the evolution of the acoustic emission(AE)characteristics and mechanical parameters of granodiorite and granite after heating and water cooling by uniaxial compression and variable-angle shear tests under different temperature gradients.We identify their changes in mesostructure and mineral composition with electron probe microanalysis and scanning electron microscopy.Results show that these two hot dry rocks have similar diagenetic minerals and microstructure,but show significantly different mechanical and acoustic characteristics,and even opposing evolution trends in a certain temperature range.At the temperatures ranging from 100℃to 500℃,the compressive and shear mechanical properties of granodiorite switch repeatedly between weakening and strengthening,and those of granite show a continuous weakening trend.At 600℃,both rocks exhibit a deterioration of mechanical properties.The damage mode of granite is characterized by initiating at low stress,exponential evolutionary activity,and intensified energy release.In contrast,granodiorite exhibits the characteristics of initiating at high stress,volatile evolutionary activity,and intermittent energy release,due to its more stable microstructure and fewer thermal defects compared to granite.As the temperature increases,the initiation and propagation of secondary cracks in granodiorite are suppressed to a certain extent,and the seismicity and brittleness are enhanced.The subtle differences in grain size,microscopic heterogeneity,and mineral composition of the two hot dry rocks determine the different acoustic-mechanical characteristics under heating and cooling,and the evolution trends with temperature.These findings are of great significance for the scientific and efficient construction of rock mass engineering by rationally utilizing different rock strata properties.
基金Project(42130810)supported by the National Natural Science Foundation of ChinaProject(2022JJ20057)supported by the Natural Science Foundation for Excellent Young Scholars of Hunan Province,China+1 种基金Project(2023CXQD063)supported by Central South University Innovation-Driven Research Programme,ChinaProject(2022-01)supported by Natural Resources Science and Technology Project of Hunan Province,China。
基金This article is the research result of the Education and Teaching Reform Research Project(No.2022JGB038)of Central South University and supported by the Scientific Research Fund of Hunan Provincial Education Department(No.23B0953).
文摘The construction of geochemical disciplines has brought new vitality to the development of traditional geology.In the new round of“Double First-Class”discipline construction at Central South University,the course of Advanced Geochemistry has effectively stimulated students’interest in learning and further improved their scientific thinking and research innovation skills through the implementation of“Guiding Interactive”teaching reform measures,which has important theoretical significance and practical value.
基金supported in part by the National Key Research and Development Program(Grant Nos.2022YFF0800302)the Natural Science Foundation of China(Grant Nos.42072005,42172035)+2 种基金the China Geological Survey Project(Grant Nos.DD20221649)UNESCO:IUGS IGCP project 735“Rocks and the Rise of Ordovician Life:Filling knowledge gaps in the Early Palaeozoic Biodiversification”the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB26000000)。
文摘Well-preserved graptolites of the genus Kiaerograptus are first reported from the upper Tremadocian Yinchupu Formation in the Nanba section,Yiyang,Hunan Province,South China,including four species,i.e.,Kiaerograptus lauzonensis(Erdtmann,1966),Kiaerograptus stoermeri(Erdtmann,1965),Kiaerograptus cf.supremus?Lindholm,1991,and Kiaerograptus sp.,which are robust in form.Based on these new specimens,the Kiaerograptus biozone is established for the first time in South China,increasing the late Tremadoc graptolite biozones in South China from four to five,in ascending order as follows:the Adelograptus tenellus biozone,the Aorograptus victoriae biozone,the Kiaerograptus biozone,the Sagenograptus murrayi biozone,and the Hunnegraptus copiosus biozone.A review of the occurrence records for robust Kiaerograptus species worldwide reveals that the distribution is restricted to the Aorograptus victoriae biozone and Kiaerograptus biozone in the late Tremadocian.This limited stratigraphical distribution makes Kiaerograptus a valuable taxon for precise biostratigraphical correlation at both the regional and global scales.
基金National Natural Science Foundation of China(No.42174011)。
文摘Geodetic functional models,stochastic models,and model parameter estimation theory are fundamental for geodetic data processing.In the past five years,through the unremitting efforts of Chinese scholars in the field of geodetic data processing,according to the application and practice of geodesy,they have made significant contributions in the fields of hypothesis testing theory,un-modeled error,outlier detection,and robust estimation,variance component estimation,complex least squares,and ill-posed problems treatment.Many functional models such as the nonlinear adjustment model,EIV model,and mixed additive and multiplicative random error model are also constructed and improved.Geodetic data inversion is an important part of geodetic data processing,and Chinese scholars have done a lot of work in geodetic data inversion in the past five years,such as seismic slide distribution inversion,intelligent inversion algorithm,multi-source data joint inversion,water reserve change and satellite gravity inversion.This paper introduces the achievements of Chinese scholars in the field of geodetic data processing in the past five years,analyzes the methods used by scholars and the problems solved,and looks forward to the unsolved problems in geodetic data processing and the direction that needs further research in the future.
文摘The Suizhou meteorite is a heavily shocked and melted vein-containing L6 chondrite.It contains a minor amount of diopside with a(Ca_(0.419)Mg_(0.466)Fe_(0.088))SiO_(3)composition,and a shock-metamorphosed diopside grain associated with ringwoodite and lingunite was found in a melt vein of this meteorite.Our electron microprobe,transmission electron microscopic and Raman spectroscopic analyses revealed four silicate phases with different compositions and structures inside this shock-metamorphosed diopside grain,termed phase A,B,C and D in this paper.Phase A is identified as orthorhombic(Ca_(0.663)-Mg_(0.314))SiO_(3)-perovskite which is closely associated with phase B,the vitrified(Mg_(0.642)Ca_(0.290)Fe_(0.098))SiO_(3)perovskite.Phase D is assigned to be(Mg_(0.578)Ca_(0.414))SiO_(3)majorite which is associated with phase C,the vetrified Carich Mg-perovskite with a(Mg_(0.853)Ca_(0.167))SiO_(3)composition.Based on high-pressure and high-temperature experiments,the diopside grain in the melt vein of the Suizhou meteorite would have experienced a P–T regime of 20–24GPa and 1800–>2000℃.Such P–T conditions are high enough for the decomposition of the diopside and the formation of four different silicate phases.The orthorhombic(Ca_(0.663)Mg_(0.314))SiO_(3)perovskite found in the Suizhou L6 chondrite might be considered as the third lower-mantle silicate mineral after bridgmanite and davemaoite after the detailed analyses of its crystal structure and physical properties being completed.
基金supported by Jilin Changbaishan Volcano National Observation and Research Station(Project No.NORSCBS20-04)National Natural Science Foundation of China(42174023)the Fundamental Research Fund for the Central Universities of Central South University(No.506021722).
文摘Sentinel-1A/B data are crucial for retrieving numerical information about surface phenomena and processes.Coregistration of terrain observation by progressive scans(TOPS)data is a critical step in its application.TOPS data must be fundamentally co-registered with an accuracy of 0.001 pixels.However,various decorrelation factors due to natural vegetation and seasonal effects affect the coregistration accuracy of TOPS data.This paper proposed an enhanced spectral diversity coregistration method for dual-polarimetric(PolESD)Sentinel-1A/B TOPS data.The PolESD method suppresses speckle noise based on a unified non-local framework in dual-pol Synthetic Aperture Radar(SAR),and extracts the phase of the optimal polarization channel from the denoised polarimetric interferometric coherency matrix.Compared with the traditional ESD method developed for single-polarization data,the PolESD method can obtain more accurate coherence and phase and get more pixels for azimuth-offset estimation.In bare areas covered with low vegetation,the number of pixels selected by PolESD is more than the Boxcar method.It can also correct misregistration more effectively and eliminate phase jumps in the burst edge.Therefore,PolESD will help improve the application of TOPS data in low-coherence scenarios.
文摘We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase.
基金funded by the National Key Research and Development Program of China under grant number 2020YFC1807200the National Natural Science Foundation of China under grant number 41872186the National Natural Science Foundation of China(Grant number 51978674)。
文摘Fluidic oscillators(FOs)can be used as an efficient fluidic vibration tool to solve high friction problems in extended-reach wells.However,the complex mechanism of FOs makes the design challenging,and the dynamic erosion behavior inside FOs is still unclear.In this paper,new FOs are proposed and the working characteristics under the influence of periodic particle-laden jets are investigated.Firstly,the results reveal the working mechanism of new FOs,showing that the generation of pressure pulses is closely connected with periodic jet switching and the development of vortices.Secondly,the important performance parameters,i.e.,pressure pulse and oscillation frequency,are extensively studied through numerical simulation and experimental verification.It is found that the performance can be optimized by adjusting the tool structure according to different engineering requirements.Finally,the oscillating solid-liquid two-phase flow inside FO is studied.It is demonstrated that the accumulation of particles leads to a significant reduction in performance.The results also reveal five locations that are susceptible to erosion and the erosion behavior of these locations are studied.It has been shown that the periodic jet causes fluctuations in the amount of erosion at the outlet and splitter.This research can provide valuable references for the design and optimization of vibration friction-reduction tools.
基金financially supported by the Natural Science Foundation of China(Grant No.41972198)the Cooperation Foundation of the Key Laboratory of Mineralogy and Metallogeny,Chinese Academy of Sciences(Grant No.KLMM20180201)the Scientific Research Starting Foundation of Central South University。
文摘The Neoproterozoic evolution of the Jiangnan Orogen is important for understanding the tectonic history of South China.As a volcanic-sedimentary sequence developed in the Nanhua rift,the Banxi Group preserves the records of important magmatic and tectonic events linked to the assembly and breakup of the Rodinia supercontinent.In this study,we report the results from whole-rock major-and trace-element concentrations,with zircon LA-(MC)-ICP-MS U-Pb ages,trace elements and Lu-Hf isotopic compositions of sandstones from the Banxi Group.The rocks are characterized by high SiO_(2)(65.88%–82.76%,with an average of 75.50%)contents,moderate(Fe_(2)O_(3)^(T)+MgO)(1.81%–7.78%,mean:3.79%)and TiO_(2)(0.39%–0.54%,mean:0.48%),low K_(2)O/Na_(2)O(0.03–0.40,mean:0.10)ratios and low Al_2O_(3)/SiO_(2)(0.11–0.24,mean:0.15)ratios.The sandstones have highΣREE contents(mean:179.1 ppm),with chondrite-normalized REE patterns similar to the upper crust and PAAS,showing enriched LREE((La/Yb)_N mean:14.85),sub-horizontal HREE curves and mild Eu(Eu/Eu^(*):0.75–0.89,mean:0.81)negative anomalies.Their geochemical characteristics resemble those of passive continental margin sandstones.Most of the zircons are magmatic in origin and yield a U-Pb age distribution with three peaks:a major age peak at 805 Ma and two subordinate age peaks at 1990 Ma and 2470 Ma,implying three major magmatic sources.The Neoproterozoic zircons haveε_(Hf)(t)values ranging from-47.4 to 12.4(mostly-20 to 0),suggesting a mixture of some juvenile arc-derived material and middle Paleoproterozoic heterogeneous crustal sources.The Hf model ages of middle Paleoproterozoic zircons(~1990 Ma)with negativeε_(Hf)(t)values(-12.65 to-6.21,Ave.=-9.8)concentrated around the Meso-Paleoarchean(mean T_(DM)^(C)=3.3–3.1 Ga).For late Neoarchean detrital zircons(~2470 Ma),ε_(Hf)(t)values are divided into two groups,one with negative values(-9.16 to-0.6)with model ages of 3.5–2.9 Ga,the other featuring positive values(1.0 to 3.9)with model ages of 2.9–2.7 Ga,recording a crustal growth event at~2.5 Ga.Neoproterozoic zircons show volcanic arc affinities with partly intraplate magmatic features.We propose that the Banxi Group formed in a rift basin within a passive continental margin setting,which derived detritus from felsic to intermediate rocks from the Yangtze Block and a small amount of arc volcanic rocks.The middle Paleoproterozoic detrital zircon data suggest Columbia-aged basement lies beneath the western Jiangnan orogen.
基金financially supported by the National Natural Science Foundation of China(41922027,41830107,42142034,41874086)Innovation-Driven Project of Central South University(2020CX012)+4 种基金Macao FoundationMacao Science and Technology Development Fund(0001/2019/A1)the Pre-research Project on Civil Aerospace Technologies funded by China National Space Administration(D020303)the Hunan Provincial Innovation Foundation for Postgraduate(CX20210277)the Fundamental Research Funds for the Central Universities of Central South University(2021zzts0259)。
文摘Mantle conductivity imaging is one of the scientific goals of the forthcoming Macao Science Satellite-1(MSS-1).To achieve this goal,we develop a data analysis and inversion scheme for satellite magnetic data to probe global one-dimensional(1D)mantle conductivity structures.Using this scheme,we present a new global mantle conductivity model by analyzing over 8 years of Swarm satellite magnetic data.First,after sophisticated data selection procedures and the removal of core and crustal fields,the inducing and induced spherical harmonic coefficients of magnetic potential due to the magnetospheric ring current are derived.Second,satellite Cresponses are estimated from the time series of these coefficients.Finally,the observed responses are inverted for both smooth and threejump conductivity models using a quasi-Newton algorithm.The obtained conductivity models are in general agreement with previous global mantle conductivity models.A comparison of our conductivity model with the laboratory conductivity model suggests the mean state of the upper mantle and transition zone is relatively dry.This scheme can be used to process the forthcoming Macao Science Satellite-1 magnetic data.
基金supported by the National Natural Science Foundation of China(41922027,4214200052)by the Macao Foundation+1 种基金by the Pre-research Project on Civil Aerospace Technologies No.D020308/D020303 funded by China National Space Administrationby the Macao Science and Technology Development Fund,grant No.0001/2019/A1。
文摘Global electromagnetic induction provides an efficient way to probe the electrical conductivity in the Earth’s deep interior.Owing to the increasing geomagnetic data especially from high-accuracy geomagnetic satellites,inverting the Earth’s three-dimensional conductivity distribution on a global scale becomes attainable.A key requirement in the global conductivity inversion is to have a forward solver with high-accuracy and efficiency.In this study,a finite volume method for global electromagnetic induction forward modeling is developed based on unstructured grids.Arbitrary polyhedral grids are supported in our algorithms to obtain high geometric adaptability.We employ a cell-centered collocated variable arrangement which allows convenient discretization for complex geometries and straightforward implementation of multigrid technique.To validate the method,we test our code with two synthetic models and compare our finite volume results with an analytical solution and a finite element numerical solution.Good agreements are observed between our solution and other results,indicating acceptable accuracy of the proposed method.
基金the National Natural Science Foundation of China(No.42174023)。
文摘Timely response to earthquake characterization can facilitate earthquake emergency rescue and further scientific investigations.On June 1,2022,M_(W) 5.9 earthquake occurred in the southern area of the Longmenshan fault zone.This event also happened at the south end of the Dayi seismic gap and is the largest earthquake that has occurred in this seismic gap since the 1970 M 6.2 event.The slip-distribution model constrained by the seismic waveforms suggests a thrust-dominated faulting mechanism.The main slip occurs at a depth of~14 km,and the cumulative energy is released in the first 6 s.The variations of Coulomb stress caused by the mainshock show a positive change in the southwest area of the Dayi seismic gap,indicating possible activation of future earthquakes.In addition,we emphasize the importance of rapid estimation of deformation for near-field hazard delineation,especially when interferometric radar fails to image coseismic deformation in a high relief terrain.
基金supported by the China Schorlarship Council (CSC)the Global Center of Excellence (GCOE) in Novel Carbon Resource Sciences, Kyushu Universitysupported by the Zhaokalong Mine, Qinghai, China
文摘The ore types of the Zhaokalong Fe-Cu deposit are divided into two categories: sulfide-type and oxide-type. The sulfide-type ore include siderite ore, galena-sphalerite ore and chalcopyrite ore, whereas the oxide-type ore include magnetite ore and hematite ore. The ore textures and structures indicate that the Zhaokalong deposit is of the sedimentary-exhalative mineralization type. Geochemical analyses show that the two ore types have a high As, Sb, Mn, Co and Ni content. The REE patterns reveal an enrichment of the LREE compared to the HREE. Isotopic analysis of siderite ore reveal that the δ13CPDB ranges from 2.01 to 3.34 (‰) whereas the δ18O SMOW ranges from 6.96 to 18.95 (‰). The fluid inclusion microthermometry results indicate that homogenization temperatures of fluid inclusions in quartz range from 131 to 181℃, with salinity values of 1.06 to 8.04 wt% NaCl eq. The mineralizing fluid therefore belongs to the low temperature - low salinity system, with a mineralizing solution of a CO2-Ca2+(Na+, K+)-SO42-(F-, Cl-)-H2O system. The geochemical results and fluid inclusion data provide additional evidence that the Zhaokalong deposit is a sedex-type deposit that experienced two stages of mineralization. The sulfide mineralization probably occurred first, during the sedimentary exhalative process, as exhibited by the abundance of marine materials associated with the sulfide ores, indicating a higher temperature and relatively deoxidized oceanic depositional environment. After the main exhalative stage, hydrothermal activity was superimposed to the sulfide mineralization. The later stage oxide mineralization occurred in a low temperature and relatively oxidized environment, in which magmatic fluid circulation was dominant.
基金supported by the National Key Basic Research Program(2012CB416700,2007CB411408),a special fund managed by the State Key Laboratory of Ore Deposit Geochemistry,Institute of Geochemistry,Chinese Academy of Sciences,and the State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences in Wuhan
文摘Mesozoic granitic intrusions are widely distributed in the Nanling region,South China.Yanshanian granites are closely connected with the formation of tungsten deposits.The Xihuashan granite is a typical representative of tungsten-bearing granite.The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite,medium-grained biotite granite and fine-grained two-mica granite,which correspond to LA-ICP-MS zircon U-Pb ages of 155.5±0.4 Ma,153.0±0.6 Ma and 152.8±0.9 Ma,respectively.Rocks from the Xihuashan mining area displays high SiO2(73.85% to 76.49%) and Na2O+K2O contents(8.09% to 9.43%),belonging to high-K calc-alkaline series.They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 1.06.All granites in this study area are rich in Rb,Th,U and Pb,and depleted in Ba,Sr,P,Ti,Nb and Eu,especially depleted in medium-grained biotite granite and fine-grained two-mica granite.The medium-grained porphyritic biotite granites usually have high LREE concentrations,whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents.Our geochemical data reveal that the studied rocks are highly fractionated I-type granite.The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity,which may explain the formation of three types of distinct granites.Variations of Rb,Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar.Fractional crystallization of monazite,allanite and apatite resulted in LREE changes in granite,and formation of garnet mainly caused HREE changes.Granites from the Xihuashan mining area have relatively high εNd(t) values(-9.77 to -11.46),indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantle-derived magmas.
基金Projects(U1231105,10878026)supported by the National Natural Science Foundation of China
文摘The general regression neural network(GRNN) model was proposed to model and predict the length of day(LOD) change, which has very complicated time-varying characteristics. Meanwhile, considering that the axial atmospheric angular momentum(AAM) function is tightly correlated with the LOD changes, it was introduced into the GRNN prediction model to further improve the accuracy of prediction. Experiments with the observational data of LOD changes show that the prediction accuracy of the GRNN model is 6.1% higher than that of BP network, and after introducing AAM function, the improvement of prediction accuracy further increases to 14.7%. The results show that the GRNN with AAM function is an effective prediction method for LOD changes.
基金supported by the China Geological Survey Investigation Programs (No. 2008-21-03 and No. 20110301-64)
文摘The Kendekeke polymetallic deposit, located in the middle part of the magmatic arc belt of Qimantag on the southwestern margin of the Qaidam Basin, is a polygenetic compound deposit in the Qimantag metallogenic belt of Qinghai Province. Multi-periodic ore-forming processes occurred in this deposit, including early-stage iron mineralization and lead-zinc-gold-polymetallic mineralization which was controlled by later hydrothermal process. The characteristics of the ore-forming fluids and mineralization were discussed by using the fluid inclusion petrography, Laser Raman Spectrum and micro-thermometry methods. Three stages, namely, S1-stage(copper-iron-sulfide stage), S2-stage(lead-zinc-sulfide stage) and C-stage(carbonate stage) were included in the hydrothermal process as indicated by the results of this study. The fluid inclusions are in three types: aqueous inclusion(type I), CO2-aqueous inclusion(type II) and pure CO2 inclusion(type III). Type I inclusions were observed in the S1-stage, having homogenization temperature at 240–320oC, and salinities ranging from 19.8% to 25.0%(wt % NaCl equiv.). All three types of inclusions, existing as immiscible inclusion assemblages, were presented in the S2-stage, with the lowest homogenization temperature ranging from 175 oC to 295oC, which represents the metallogenic temperature of the S2-stage. The salinities of these inclusions are in the range of 1.5% to 16%. The fluid inclusions in the C-stage belong to types I, II and III, having homogenization temperatures at 120–210oC, and salinities ranging from 0.9% to 14.5%. These observations indicate that the ore-forming fluids evolved from high-temperature to lowtemperature, from high-salinity to low-salinity, from homogenization to immiscible separation. Results of Laser Raman Spectroscopy show that high density of CO2 and CH4 were found as gas compositions in the inclusions. CO2, worked as the pH buffer of ore-forming fluids, together with reduction of organic gases(i.e. CH4, etc), affected the transport and sediment of the minerals. The fluid system alternated between open and close systems, namely, between lithostatic pressure and hydrostatic pressure systems. The calculated metallogenic pressures are in the range of 30 to 87 Mpa corresponding to 3 km mineralization depth. Under the influence of tectonic movements, immiscible separation occurred in the original ore-forming fluids, which were derived from the previous highsalinity, high-temperature magmatic fluids. The separation of CO2 changed the physicochemical properties and composition of the original fluids, and then diluted by mixing with extraneous fluids such as meteoric water and groundwater, and metallogenic materials in the fluids such as lead, zinc and gold were precipitated.
基金Project(41174061) supported by the National Natural Science Foundation of ChinaProject(2011QNZT011) supported by the Free Exploration Program of Central South University,China
文摘The absorbing boundary is the key in numerical simulation of borehole radar.Perfect match layer(PML) was chosen as the absorbing boundary in numerical simulation of GPR.But CPML(convolutional perfect match layer) approach that we have chosen has the advantage of being media independent.Beginning with the Maxwell equations in a two-dimensional structure,numerical formulas of finite-difference time-domain(FDTD) method with CPML boundary condition for transverse electric(TE) or transverse magnetic(TM) wave are presented in details.Also,there are three models for borehole-GPR simulation.By analyzing the simulation results,the features of targets in GPR are obtained,which can provide a better interpretation of real radar data.The results show that CPML is well suited for the simulation of borehole-GPR.
基金financially supported by the National Key R&D Program of China(grant no.2017YFC0602405)the National Natural Science Foundation of China(grant no.42030811)。
文摘Rare metals including Lithium(Li),Beryllium(Be),Rubidium(Rb),Cesium(Cs),Zirconium(Zr),Hafnium(Hf),Niobium(Nb),Tantalum(Ta),Tungsten(W)and Tin(Sn)are important critical mineral resources.In China,rare metal mineral deposits are spatially distributed mainly in the Altay and Southern Great Xingán Range regions in the Central Asian orogenic belt;in the Middle Qilian,South Qinling and East Qinling mountains regions in the Qilian-Qinling-Dabie orogenic belt;in the Western Sichuan and Bailongshan-Dahongliutan regions in the Kunlun-Songpan-Garze orogenic belt,and in the Northeastern Jiangxi,Northwestern Jiangxi,and Southern Hunan regions in South China.Major ore-forming epochs include Indosinian(mostly 200-240 Ma,in particular in western China)and the Yanshanian(mostly 120-160 Ma,in particular in South China).In addition,Bayan Obo,Inner Mongolia,northeastern China,with a complex formation history,hosts the largest REE and Nb deposits in China.There are six major rare metal mineral deposit types in China:Highly fractionated granite;Pegmatite;Alkaline granite;Carbonatite and alkaline rock;Volcanic;and Hydrothermal types.Two further types,namely the Leptynite type and Breccia pipe type,have recently been discovered in China,and are represented by the Yushishan Nb-Ta-(Zr-Hf-REE)and the Weilasituo Li-Rb-Sn-W-Zn-Pb deposits.Several most important controlling factors for rare metal mineral deposits are discussed,including geochemical behaviors and sources of the rare metals,highly evolved magmatic fractionation,and structural controls such as the metamorphic core complex setting,with a revised conceptual model for the latter.
