Two-dimensional materials with novel mechanical and thermal properties are available for sensors,photodetectors,thermoelectric,crystal diode and flexible nanodevices.In this investigation,the mechanical and thermal pr...Two-dimensional materials with novel mechanical and thermal properties are available for sensors,photodetectors,thermoelectric,crystal diode and flexible nanodevices.In this investigation,the mechanical and thermal properties of pristine SiC and GeC are explored by molecular dynamics simulations.First,the fracture strength and fracture strain behaviors are addressed in the zigzag and armchair directions at 300 K.The excellent toughness of SiC and GeC is demonstrated by the maximal fracture strain of 0.43 and 0.47 in the zigzag direction,respectively.The temperature-tunable tensile strength of SiC and GeC is also investigated.Then,using non-equilibrium molecular dynamics(NEMD)calculations,the thermal performances of SiC and GeC are explored.In particular,the thermal conductivity of SiC and GeC shows a pronounced size dependence and reaches up to 85.67 W·m^(-1)-K^(-1)and 34.37 W·m^(-1)-K^(-1),respectively.The goal of our work is to provide a theoretical framework that can be used in the near future.This will enable us to design an efficient thermal management scheme for two-dimensional materials in electronics and optoelectronics.展开更多
To understand the relationship between the process-microstructure-mechanical properties of the high-pressure die-casting(HPDC) AE44 magnesium alloy, 3D reconstruction and 2D characterization were carried out on the HP...To understand the relationship between the process-microstructure-mechanical properties of the high-pressure die-casting(HPDC) AE44 magnesium alloy, 3D reconstruction and 2D characterization were carried out on the HPDC castings produced with different process parameters(low slow-shot speed, fast slow-shot speed, solidification pressure). Microstructural characterization revealed that the formation of shrinkage pores are closely related to ESCs, which were mainly controlled by the low slow-shot speed in shot sleeve(ESCs growth time) and fast slow-shot speed into the die cavity(distribution of ESCs). In addition, solidification pressure can significantly reduce the shrinkage porosity in the center by improving the feeding capacity of liquid metal. Tensile fracture revealed that the tearing ridge is mainly evolved from the slip band of ESCs. The quantity and distribution of ESCs determine the fracture mode of castings. The relationship between mechanical properties of castings and the morphology of ESCs and porosity is also statistically discussed.展开更多
3D reconstruction and 2D observation were conducted to characterize the microstructure of the castings produced through high pressure die casting with different parameters.Our results indicate that shrinkage pores gen...3D reconstruction and 2D observation were conducted to characterize the microstructure of the castings produced through high pressure die casting with different parameters.Our results indicate that shrinkage pores generally co-existed with externally solidified crystals(ESCs).In specimen produced without fast slow shot speed,big net-shrinkage pores accompanied with ESCs were found in the center of the specimen.When the casting pressurization was introduced,the shrinkage pores gathered to the specimen center and became much less due to the optimization of melt feeding.Much more porosity was found near the gate rather than in the middle of the rod bar,especially gas pores.Thefilling process simulation reveals that the middle position of the bars wasfirstlyfilled and followed by the near gate position accompanied with one intense turbulentflow.展开更多
The microstructure characteristics and mechanical properties of 2024 wrought aluminum alloy produced by a new rheoforming technique under as-cast and optimized heat treatment conditions were investigated. The present ...The microstructure characteristics and mechanical properties of 2024 wrought aluminum alloy produced by a new rheoforming technique under as-cast and optimized heat treatment conditions were investigated. The present rheoforming combined the independently developed rheocasting process, named as LSPSF (low superheat pouring with a shear field) process, and the existing squeeze casting process. The experimental results show that LSPSF can be used to prepare sound semi-solid slurry within 25 s to fully meet the production rate of squeeze casting. The primary α(Al) presents in mean equivalent diameter of 69 μm and shape factor of 0.76, and features zero-entrapped eutectics. Compared with conventional squeeze casting, the present LSPSF rheoforming can improve the microstructures and mechanical properties. An optimized heat treatment results in substantial reduction of microsegregation and significant improvement of mechanical properties, such as yield strength of 321 MPa, ultimate tensile strength of 428 MPa and elongation of 12%.展开更多
New-type magnesium alloy with prominent solubility and mechanical property lays foundation for preparing fracturing part in petroleum extraction.Herein,Mg-xZn-Zr-SiC alloy is prepared with casting strategy.Electrochem...New-type magnesium alloy with prominent solubility and mechanical property lays foundation for preparing fracturing part in petroleum extraction.Herein,Mg-xZn-Zr-SiC alloy is prepared with casting strategy.Electrochemical and compression tests are conducted to assess the feasibility as decomposable material.Morphology,composition,phase and distribution are characterized to investigate decomposition mechanism.Results indicate that floccule,substrate component and reticulate secondary phase are formed on as-prepared surface.Sample also acts out enhanced compression strength to maintain pressure and guarantee stability in dissolution process.Furthermore,as decomposition time and zinc content increase,couple corrosion intensifies,resulting in gradually enhanced decomposition rate.Rapid sample decomposition is mainly due to basal anode dissolution,micro particle exfoliation and poor decomposition resistance of corroding product.Such work shows profound significance in preparing new-type accessible alloy to ensure rapid dissolution of fracturing part and guarantee stable compression strength in oil-gas reservoir exploitation.展开更多
A scheme is proposed to investigate the non-classical states generated by a quantum scissors device(QSD) operating on the the cavity mode of an optomechanical system. When the catalytic QSD acts on the cavity mode of ...A scheme is proposed to investigate the non-classical states generated by a quantum scissors device(QSD) operating on the the cavity mode of an optomechanical system. When the catalytic QSD acts on the cavity mode of the optomechanical system, the resulting state contains only the vacuum, single-photon and two-photon states depending upon the coupling parameter of the optomechanical system as well as the transmission coefficients of beam splitters(BSs). Especially, the output state is just a class of multicomponent cat state truncations at time t = 2π by choosing the appropriate value of coupling parameter. We discuss the success probability of such a state and the fidelity between the output state and input state via QSD. Then the linear entropy is used to investigate the entanglement between the two subsystems, finding that QSD operation can enhance their entanglement degree. Furthermore, we also derive the analytical expression of the Wigner function(WF) for the cavity mode via QSD and numerically analyze the WF distribution in phase space at time t =2π. These results show that the high non-classicality of output state can always be achieved by modulating the coupling parameter of the optomechanical system as well as the transmittance of BSs.展开更多
Mo fibers were added to RMC with different mass ratios of resin and hardener to improve its mechanical properties. The influences of fiber surface state and hardener content on interface bonding strength and mechanica...Mo fibers were added to RMC with different mass ratios of resin and hardener to improve its mechanical properties. The influences of fiber surface state and hardener content on interface bonding strength and mechanical properties of RMC were studied, respectively. Furthermore, strain values of typical measuring points on samples of Mo fiber reinforced RMC(MFRRMC) under different loads were obtained by experiments and finite element analysis. The experimental results prove that scrap Mo fibers can improve interface bonding strength and mechanical properties of RMC better than new smooth Mo fibers because of the discharge pits randomly distributed on the surface of scrap fibers. With the decrease of hardener content, not only interface bonding strength between fiber and matrix, but also compression and flexural strength of MFRRMC increase firstly and then decrease. The properties are best while the mass ratio of resin and hardener reaches 4:1. It is indicated that finite element calculation data basically agree with experimental data by comparison of strain values on typical measuring points, which can provide an important intuitive reference for successive study on other mechanical properties of MFRRMC, validating the correctness of simulation method as well.展开更多
2D MXenes are highly attractive for fabricating high-precision gas sensors operated at room temperature(RT)due to their high surface-to-volume ratio.However,the limited selectivity and low sensitivity are still long-s...2D MXenes are highly attractive for fabricating high-precision gas sensors operated at room temperature(RT)due to their high surface-to-volume ratio.However,the limited selectivity and low sensitivity are still long-standing challenges for their further applications.Herein,the self-assembly of 0D-2D heterostructure for highly sensitive NO_(2) detection was achieved by integrating ZnO nanoparticles on Ti_(3)C_(2)Tx MXene-derived TiO_(2) nanosheets(designated as ZnO@MTiO_(2)).ZnO nanoparticles can not only act as spacers to prevent the restacking of MTiO_(2) nanosheets and ensure effective transfer for gas molecules,but also enhance the sensitivity of the sensor the through trapping effect on electrons.Meanwhile,MTiO_(2) nanosheets facilitate gas diffusion for rapid sensor response.Benefiting from the synergistic effect of individual components,the ZnO@MTiO_(2)0D-2D heterostructure-based sensors revealed remarkable sensitivity and excellent selectivity to low concentration NO_(2) at RT.This work may facilitate the sensing application of MXene derivative and provide a new avenue for the development of high-performance gas sensors in safety assurance and environmental monitoring.展开更多
W-15Cu composite powders prepared by mechanical alloying(MA)of raw powders were consolidated by spark plasma sintering(SPS)process at temperature ranged 1 230-1 300℃for 10 min and under a pressure of 30 MPa.By using ...W-15Cu composite powders prepared by mechanical alloying(MA)of raw powders were consolidated by spark plasma sintering(SPS)process at temperature ranged 1 230-1 300℃for 10 min and under a pressure of 30 MPa.By using high energy milling,particles containing very fine tungsten grains embedded in copper,called composite particles,could be produced.The W grains were homogeneously dispersed in copper phase,which was very important to obtain W-Cu alloy with high mechanical properties, fine and homogeneous microstructure.The microstructure and properties of W-15Cu alloys prepared by SPS processes at different temperature were researched.The results show that W-15Cu alloys consolidated by SPS can reach 99.6%relative density,and transverse rupture strength(TRS)is 1 400.9 MPa,Rockwell C hardness (HRC)is 45.2,the thermal conductivity is 196 W/m·K at room temperature,the average grain size is less than 2 μm,and W-15Cu alloy with excellent properties,homogeneous and fine microstructure is obtained.展开更多
A new type of hybrid SiC foam-SiC particles-Al composites used as an electronic packaging substrate material were fabricated by squeeze casting technique. The mechanical properties and the fracture mechanism of the hy...A new type of hybrid SiC foam-SiC particles-Al composites used as an electronic packaging substrate material were fabricated by squeeze casting technique. The mechanical properties and the fracture mechanism of the hybrid composites were investigated. The influence of SiC particles and foam hybrid reinforcement on the behavior of the composites was studied. The results show that the interface bonding in the hybrid composites is good for the composites with the unique double interpenetrating structure. The compressive strength of the hybrid composite reinforced by the SiC with the volume fraction of 59.9% is 680 MPa,which is higher than that of any other composites with the same volume fraction of SiC particles reinforcement.展开更多
As the energy density of battery increases rapidly,lithium-ion batteries(LIBs)are facing serious safety issue with thermal runaway,which largely limits the large-scale applications of high-energy-density LIBs.It is ge...As the energy density of battery increases rapidly,lithium-ion batteries(LIBs)are facing serious safety issue with thermal runaway,which largely limits the large-scale applications of high-energy-density LIBs.It is generally agreed that the chemical crosstalk between the cathode and anode leads to thermal runaway of LIBs.Herein,a multifunctional high safety electrolyte is designed with synergistic construction of cathode electrolyte interphase and capture of reactive free radicals to limit the intrinsic pathway of thermal runaway.The cathode electrolyte interphase not only resists the gas attack from the anode but suppresses the parasitic side reactions induced by electrolyte.And the function of free radical capture has the ability of reducing heat release from thermal runaway of battery.The dual strategy improves the intrinsic safety of battery prominently that the triggering temperature of thermal runaway is increased by 24.4℃and the maximum temperature is reduced by 177.7℃.Simultaneously,the thermal runaway propagation in module can be self-quenched.Moreover,the electrolyte design balances the trade-off of electrochemical and safety performance of high-energy batteries.The capacity retention of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)|graphite pouch cell has been significantly increased from 53.85%to 97.05%with higher coulombic efficiency of 99.94%at operating voltage extended up to 4.5 V for 200 cycles.Therefore,this work suggests a feasible strategy to mitigate the safety risk of high-energy-density LIBs without sacrificing electrochemical performances.展开更多
Si3N4/TiC nanocomposite ceramics have been fabricated by hot pressing technique with AI2O3 and Y2O3 as additives.The results showed that well dispersed composite powder wascarried out by adding dispersant and adjustin...Si3N4/TiC nanocomposite ceramics have been fabricated by hot pressing technique with AI2O3 and Y2O3 as additives.The results showed that well dispersed composite powder wascarried out by adding dispersant and adjusting pH valuesof suspensions. Remarkable increase in flexural strength at room temperatures was obtained by adding nanoparticlesin Si3N4 matrix with 10% (wt pct) of nano-Si3N4 and 15% of nano-TiC. The flexural strength, fracture toughnessand hardness were 1025 MPa, 7.5 MPa·m1/2 and 15.6 GPa, respectively. The microstructures of materials wereanalyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), which indicated thatTiC nanoparticles distribute in the matrix and at the grain boundaries. According to the fracture form, low contentsof nano particles could refine matrix grains and lead to the track deflection as well as crack pinning. The multiplexmicrostructure was formed by mixing nano-Si3N4 particles. The crack trajectories exhibited crack deflection, rod-likegrain bridging and pull-out.展开更多
Spin qubits and superconducting qubits are promising candidates for realizing solid-state quantum information processors.Designing a hybrid architecture that combines the advantages of different qubits on the same chi...Spin qubits and superconducting qubits are promising candidates for realizing solid-state quantum information processors.Designing a hybrid architecture that combines the advantages of different qubits on the same chip is a highly desirable but challenging goal.Here we propose a hybrid architecture that utilizes a high-impedance SQUID array resonator as a quantum bus,thereby coherently coupling different solid-state qubits.We employ a resonant exchange spin qubit hosted in a triple quantum dot and a superconducting transmon qubit.Since this hybrid system is highly tunable,it can operate in a dispersive regime,where the interaction between the different qubits is mediated by virtual photons.By utilizing such interactions,entangling gate operations between different qubits can be realized in a short time of 30 ns with a fidelity of up to 96.5%under realistic parameter conditions.Further utilizing this interaction,remote entangled state between different qubits can be prepared and is robust to perturbations of various parameters.These results pave the way for exploring efficient fault-tolerant quantum computation on hybrid quantum architecture platforms.展开更多
An incipient mechanical fault detection method, combining multifractal theory and Mahalanobis-Taguchi system (MTS), which is based on statistical technology, is proposed in this paper. Multifractal features of vibrati...An incipient mechanical fault detection method, combining multifractal theory and Mahalanobis-Taguchi system (MTS), which is based on statistical technology, is proposed in this paper. Multifractal features of vibration signals obtained from machine state monitoring are extracted by multifractal spectrum analysis and generalized fractal dimensions. Considering the situation of mass samples of normal mechanical running state and few fault states, the feature parameters corresponding to different mechanical running states are further optimized by a statistical method, based on which incipient faults are subsequently identifi ed and diagnosed accurately. Experimental results proved that the method combining multifractal theory and MTS can be used for incipient fault state recognition effectively during the mechanical running process, and the accuracy of fault state identifi cation is improved.展开更多
The semi-solid slurry of wrought aluminum alloy 2024 was prepared by a well developed rheocasting process, low superheat pouring with shearing field(LSPSF). The appreciate combination of pouring temperature and rotati...The semi-solid slurry of wrought aluminum alloy 2024 was prepared by a well developed rheocasting process, low superheat pouring with shearing field(LSPSF). The appreciate combination of pouring temperature and rotation speed of barrel, can give rise to a transition of the growth morphology of primary α(Al) from coarse-dendritic to coarse-particle-like and further to fine-globular. The combined effects of both localized rapid cooling and vigorous mixing during the initial stage of solidification can enhance wall nucleation and nuclei survival, which leads to the formation of fine-globular primary α(Al). By using semi-solid slurry prepared by LSPSF, direct squeeze cast cup-shaped component with improved mechanical properties such as yield strength of 198 MPa, ultimate tensile strength of 306 MPa and elongation of 10.4%, can be obtained.展开更多
The perovskite samples La1-x (Sr1-yKy )xMnO3 (y = 0.0, 0.2, 04, 0.6, 0.8) were prepared by the solid-state reaction method with comparatively low sintering temperature and with comparatively short sintering time, and ...The perovskite samples La1-x (Sr1-yKy )xMnO3 (y = 0.0, 0.2, 04, 0.6, 0.8) were prepared by the solid-state reaction method with comparatively low sintering temperature and with comparatively short sintering time, and the electric transport property and temperature stability of MR of this system were studied. The q-T curves show the abnormal phenomenon that with the increase of K doping amount, resistivity increases, and the insulator-metal transition temperature decreases, which is because the influence of the occupation disorder degree of A-site ions σ2 on the electric transport property of perovskite manganites is larger than that of the radius of A-site ions<rA>. In the temperature range below 225 K, MR increases continuously with the decrease of temperature, which is the characteristic of low-field magnetoresistance; in the comparatively wide temperature range near 250 K, the MR-T curves of all the samples are comparatively flat, and the value of MR almost does not change with temperature, which shows the temperature stability of magnetoresistance, and can be explained by the competition between the low-field magnetoresistance induced by spin-dependent tunneling of surface phase and the intrinsic magnetoresistance of grain phase. The magnetoresistance value of the sample with y = 0.8 keeps at (7.92 ± 0.36) % in the very wide temperature range of 225-275 K, and this is a good reference for the preparation of this kind of sample with practical application value in the future.展开更多
The structural and electronic properties of bulk and (001) plane of TiC were investigated by the first-principles total-energy pseudopotential method based on density functional theory.The calculated bulk properties i...The structural and electronic properties of bulk and (001) plane of TiC were investigated by the first-principles total-energy pseudopotential method based on density functional theory.The calculated bulk properties indicate that bonding nature in TiC is a combination of ionicity,covalency and metallicity,in which the Ti-C covalent bonding is the predominate one.The calculated results of structural relaxation and surface energy for TiC(001) slab indicate that slab with 7 layers shows bulk-like characteristic interiors,and the changes of slab occur on the outmost three layers,which shows that the relaxation only influences the top three layers.Meanwhile,the strong Ti-C covalent bonding can be found in the distribution of charge density on the (110) and (001) planes.Ti-C covalent bonding is enhanced by the charge depletion and accumulation in the vacuum and the interlayer region between top two atomic layers.展开更多
Thermal error monitoring technology is the key technological support to solve the thermal error problem of heavy-duty CNC(computer numerical control) machine tools. Currently, there are many review literatures introdu...Thermal error monitoring technology is the key technological support to solve the thermal error problem of heavy-duty CNC(computer numerical control) machine tools. Currently, there are many review literatures introducing the thermal error research of CNC machine tools,but those mainly focus on the thermal issues in small and medium-sized CNC machine tools and seldom introduce thermal error monitoring technologies. This paper gives an overview of the research on the thermal error of CNC machine tools and emphasizes the study of thermal error of the heavy-duty CNC machine tool in three areas. These areas are the causes of thermal error of heavy-duty CNC machine tool and the issues with the temperature monitoring technology and thermal deformation monitoring technology. A new optical measurement technology called the ‘‘fiber Bragg grating(FBG) distributed sensing technology'' for heavy-duty CNC machine tools is introduced in detail. This technology forms an intelligent sensing and monitoring system for heavy-duty CNC machine tools.This paper fills in the blank of this kind of review articlesto guide the development of this industry field and opens up new areas of research on the heavy-duty CNC machine tool thermal error.展开更多
A series of the samples La_(1-x)(Sr_(1-y)Na_y)_xMnO_3(y=0.0,0.2,0.4,0.6,0.8,1.0) were prepared by the solid-state reaction method.Magnetoresistance enhancement and temperature stability of magnetoresistance in the sys...A series of the samples La_(1-x)(Sr_(1-y)Na_y)_xMnO_3(y=0.0,0.2,0.4,0.6,0.8,1.0) were prepared by the solid-state reaction method.Magnetoresistance enhancement and temperature stability of magnetoresistance in the system La_(1-x)(Sr_(1-y)Na_y)_xMnO_3 with unchanged Mn^(3+)/Mn^(4+) ratio through the doping of both monovalent and divalent elements at A site were studied through the measurements of X-ray diffraction(XRD) patterns,resistivity-temperature(ρ-T) curves and magnetoresistance-temperature(MR-T) curves.The results indicate that with the increase of Na doping amount,the peak value of MR increases,and it increases from 12.4% for y=0.2 to 50.6% for y=1.0 in the magnetic field B=0.8 T;ρ-T curves exhibit the double-peak phenomenon,which comes from the competition between the resistivity of surface phase and that of body phase;for the sample of y=0.8,MR increases slowly from 8.3% to 9.4% in the temperature range from 259 to 179 K,and MR is so stable in such a wide temperature range,which provides reference for the research on the temperature stability of MR.展开更多
This paper deals with the effects of codoped VC/Cr3C2 and sintering temperature on the magnetic and mechanical properties of ultra-fine grained WC-12%Co alloys. Results show that the synergistic action of doped VC/Cr3...This paper deals with the effects of codoped VC/Cr3C2 and sintering temperature on the magnetic and mechanical properties of ultra-fine grained WC-12%Co alloys. Results show that the synergistic action of doped VC/Cr3C2 in optimal proportion enhances both the hardness and transverse rupture strength (TRS) of the alloys, with more homogeneous microstructure. When the alloy is sintered at 1430°C and with 0.5% Cr3C2/0.2% VC, the TRS reaches 3786 MPa, the hardness is 91.7 HRA and the grain size smaller than 0.6 μm. The numerical analyses on grain growth during the sintering process show that both VC precipitating on the WC grain boundary and Cr3C2 dissolving in the Co phase decrease the solid/liquid interfacial energy γ, the process of dissolution and reprecipitation is greatly retarded and the coarsening of WC grains is inhibited.展开更多
基金support of the Natural Science Foundation of Jiangsu (Grant No. BK20220407)the National Natural Science Foundation of China (Grant Nos. 12102323, 11890674)+1 种基金the China Postdoctoral Science Foundation (Grant No. 2021M692574)the Fundamental Research Funds for the Central Universities (Grant No. sxzy012022024)
文摘Two-dimensional materials with novel mechanical and thermal properties are available for sensors,photodetectors,thermoelectric,crystal diode and flexible nanodevices.In this investigation,the mechanical and thermal properties of pristine SiC and GeC are explored by molecular dynamics simulations.First,the fracture strength and fracture strain behaviors are addressed in the zigzag and armchair directions at 300 K.The excellent toughness of SiC and GeC is demonstrated by the maximal fracture strain of 0.43 and 0.47 in the zigzag direction,respectively.The temperature-tunable tensile strength of SiC and GeC is also investigated.Then,using non-equilibrium molecular dynamics(NEMD)calculations,the thermal performances of SiC and GeC are explored.In particular,the thermal conductivity of SiC and GeC shows a pronounced size dependence and reaches up to 85.67 W·m^(-1)-K^(-1)and 34.37 W·m^(-1)-K^(-1),respectively.The goal of our work is to provide a theoretical framework that can be used in the near future.This will enable us to design an efficient thermal management scheme for two-dimensional materials in electronics and optoelectronics.
基金financially supported by the Fundamental Research Funds for the Central Universities (M22JBMC0060)the National Natural Science Foundation of China (No.52175284)the State Key Lab of Advanced Metals and Materials (No.2021-ZD08)。
文摘To understand the relationship between the process-microstructure-mechanical properties of the high-pressure die-casting(HPDC) AE44 magnesium alloy, 3D reconstruction and 2D characterization were carried out on the HPDC castings produced with different process parameters(low slow-shot speed, fast slow-shot speed, solidification pressure). Microstructural characterization revealed that the formation of shrinkage pores are closely related to ESCs, which were mainly controlled by the low slow-shot speed in shot sleeve(ESCs growth time) and fast slow-shot speed into the die cavity(distribution of ESCs). In addition, solidification pressure can significantly reduce the shrinkage porosity in the center by improving the feeding capacity of liquid metal. Tensile fracture revealed that the tearing ridge is mainly evolved from the slip band of ESCs. The quantity and distribution of ESCs determine the fracture mode of castings. The relationship between mechanical properties of castings and the morphology of ESCs and porosity is also statistically discussed.
基金financially supported by the National Natural Science Foundation of China (No. 52175284)the State Key Lab of Advanced Metals and Materials (2021-ZD08)technical support of BL13W1 Beamline in Shanghai Synchrotron Radiation Facility (SSRF) and Gaomi Xiangyu company
文摘3D reconstruction and 2D observation were conducted to characterize the microstructure of the castings produced through high pressure die casting with different parameters.Our results indicate that shrinkage pores generally co-existed with externally solidified crystals(ESCs).In specimen produced without fast slow shot speed,big net-shrinkage pores accompanied with ESCs were found in the center of the specimen.When the casting pressurization was introduced,the shrinkage pores gathered to the specimen center and became much less due to the optimization of melt feeding.Much more porosity was found near the gate rather than in the middle of the rod bar,especially gas pores.Thefilling process simulation reveals that the middle position of the bars wasfirstlyfilled and followed by the near gate position accompanied with one intense turbulentflow.
基金Project(50474007) supported by the National Natural Science Foundation of ChinaProject(0450050) supported by the Natural Science Foundation of Jiangxi Province, ChinaProject(GJJ 08006) supported by the Science & Technology Program of Education Department of Jiangxi Province, China
文摘The microstructure characteristics and mechanical properties of 2024 wrought aluminum alloy produced by a new rheoforming technique under as-cast and optimized heat treatment conditions were investigated. The present rheoforming combined the independently developed rheocasting process, named as LSPSF (low superheat pouring with a shear field) process, and the existing squeeze casting process. The experimental results show that LSPSF can be used to prepare sound semi-solid slurry within 25 s to fully meet the production rate of squeeze casting. The primary α(Al) presents in mean equivalent diameter of 69 μm and shape factor of 0.76, and features zero-entrapped eutectics. Compared with conventional squeeze casting, the present LSPSF rheoforming can improve the microstructures and mechanical properties. An optimized heat treatment results in substantial reduction of microsegregation and significant improvement of mechanical properties, such as yield strength of 321 MPa, ultimate tensile strength of 428 MPa and elongation of 12%.
基金supported by the National Natural Science Foundation of China(No.51905417)China Postdoctoral Science Foundation(No.2020M670306).
文摘New-type magnesium alloy with prominent solubility and mechanical property lays foundation for preparing fracturing part in petroleum extraction.Herein,Mg-xZn-Zr-SiC alloy is prepared with casting strategy.Electrochemical and compression tests are conducted to assess the feasibility as decomposable material.Morphology,composition,phase and distribution are characterized to investigate decomposition mechanism.Results indicate that floccule,substrate component and reticulate secondary phase are formed on as-prepared surface.Sample also acts out enhanced compression strength to maintain pressure and guarantee stability in dissolution process.Furthermore,as decomposition time and zinc content increase,couple corrosion intensifies,resulting in gradually enhanced decomposition rate.Rapid sample decomposition is mainly due to basal anode dissolution,micro particle exfoliation and poor decomposition resistance of corroding product.Such work shows profound significance in preparing new-type accessible alloy to ensure rapid dissolution of fracturing part and guarantee stable compression strength in oil-gas reservoir exploitation.
基金Project supported by the National Natural Science Foundation of China (Grant No.11704051)the Qinglan Project of the Jiangsu Education Department and the Research Foundation of Six Talents Peaks Project in Jiangsu Province,China (Grant No.XNY-093)。
文摘A scheme is proposed to investigate the non-classical states generated by a quantum scissors device(QSD) operating on the the cavity mode of an optomechanical system. When the catalytic QSD acts on the cavity mode of the optomechanical system, the resulting state contains only the vacuum, single-photon and two-photon states depending upon the coupling parameter of the optomechanical system as well as the transmission coefficients of beam splitters(BSs). Especially, the output state is just a class of multicomponent cat state truncations at time t = 2π by choosing the appropriate value of coupling parameter. We discuss the success probability of such a state and the fidelity between the output state and input state via QSD. Then the linear entropy is used to investigate the entanglement between the two subsystems, finding that QSD operation can enhance their entanglement degree. Furthermore, we also derive the analytical expression of the Wigner function(WF) for the cavity mode via QSD and numerically analyze the WF distribution in phase space at time t =2π. These results show that the high non-classicality of output state can always be achieved by modulating the coupling parameter of the optomechanical system as well as the transmittance of BSs.
基金Funded by the National Natural Science Foundation of China(No.5117 5308)the National Science and Technology Major Project of China(No.2012ZX04010032)
文摘Mo fibers were added to RMC with different mass ratios of resin and hardener to improve its mechanical properties. The influences of fiber surface state and hardener content on interface bonding strength and mechanical properties of RMC were studied, respectively. Furthermore, strain values of typical measuring points on samples of Mo fiber reinforced RMC(MFRRMC) under different loads were obtained by experiments and finite element analysis. The experimental results prove that scrap Mo fibers can improve interface bonding strength and mechanical properties of RMC better than new smooth Mo fibers because of the discharge pits randomly distributed on the surface of scrap fibers. With the decrease of hardener content, not only interface bonding strength between fiber and matrix, but also compression and flexural strength of MFRRMC increase firstly and then decrease. The properties are best while the mass ratio of resin and hardener reaches 4:1. It is indicated that finite element calculation data basically agree with experimental data by comparison of strain values on typical measuring points, which can provide an important intuitive reference for successive study on other mechanical properties of MFRRMC, validating the correctness of simulation method as well.
基金supported by the National Natural Science Foundation of China(No.52103308)the Natural Science Foundation of Jiangsu Province of China(No.BK20210826)+4 种基金Outstanding Youth Foundation of Jiangsu Province of China(No.BK20211548)National Key Research and Development Program of China(No.2017YFE0115900)Innovative Science and Technology Platform Project of Cooperation between Yangzhou City and Yangzhou University(No.YZ2020266)Lvyang Jinfeng Plan for Excellent Doctor of Yangzhou City,Special Funds for Self-Made Experimental Equipment of Yangzhou Universitythe Doctor of Suzhou University Scientific Research Foundation Project(No.2022BSK003).
文摘2D MXenes are highly attractive for fabricating high-precision gas sensors operated at room temperature(RT)due to their high surface-to-volume ratio.However,the limited selectivity and low sensitivity are still long-standing challenges for their further applications.Herein,the self-assembly of 0D-2D heterostructure for highly sensitive NO_(2) detection was achieved by integrating ZnO nanoparticles on Ti_(3)C_(2)Tx MXene-derived TiO_(2) nanosheets(designated as ZnO@MTiO_(2)).ZnO nanoparticles can not only act as spacers to prevent the restacking of MTiO_(2) nanosheets and ensure effective transfer for gas molecules,but also enhance the sensitivity of the sensor the through trapping effect on electrons.Meanwhile,MTiO_(2) nanosheets facilitate gas diffusion for rapid sensor response.Benefiting from the synergistic effect of individual components,the ZnO@MTiO_(2)0D-2D heterostructure-based sensors revealed remarkable sensitivity and excellent selectivity to low concentration NO_(2) at RT.This work may facilitate the sensing application of MXene derivative and provide a new avenue for the development of high-performance gas sensors in safety assurance and environmental monitoring.
基金Funded by the Youth Science Plan for Light of the Morning Sun of Wuhan City(No.200750731270).
文摘W-15Cu composite powders prepared by mechanical alloying(MA)of raw powders were consolidated by spark plasma sintering(SPS)process at temperature ranged 1 230-1 300℃for 10 min and under a pressure of 30 MPa.By using high energy milling,particles containing very fine tungsten grains embedded in copper,called composite particles,could be produced.The W grains were homogeneously dispersed in copper phase,which was very important to obtain W-Cu alloy with high mechanical properties, fine and homogeneous microstructure.The microstructure and properties of W-15Cu alloys prepared by SPS processes at different temperature were researched.The results show that W-15Cu alloys consolidated by SPS can reach 99.6%relative density,and transverse rupture strength(TRS)is 1 400.9 MPa,Rockwell C hardness (HRC)is 45.2,the thermal conductivity is 196 W/m·K at room temperature,the average grain size is less than 2 μm,and W-15Cu alloy with excellent properties,homogeneous and fine microstructure is obtained.
基金Project(50765005) supported by the National Natural Science Foundation of ChinaProject(01306016) supported by the Science Research Foundation of East China Jiaotong University, China
文摘A new type of hybrid SiC foam-SiC particles-Al composites used as an electronic packaging substrate material were fabricated by squeeze casting technique. The mechanical properties and the fracture mechanism of the hybrid composites were investigated. The influence of SiC particles and foam hybrid reinforcement on the behavior of the composites was studied. The results show that the interface bonding in the hybrid composites is good for the composites with the unique double interpenetrating structure. The compressive strength of the hybrid composite reinforced by the SiC with the volume fraction of 59.9% is 680 MPa,which is higher than that of any other composites with the same volume fraction of SiC particles reinforcement.
基金supported by the National Key R&D ProgramStrategic Scientific and Technological Innovation Cooperation(2022YFB3803500)the National Key Research and Development Program of China(2019YFA0705700)+1 种基金the National Natural Science Foundation of China(52076121,51904016,and 52004138)the Fundamental Research Funds for the Central Universities。
文摘As the energy density of battery increases rapidly,lithium-ion batteries(LIBs)are facing serious safety issue with thermal runaway,which largely limits the large-scale applications of high-energy-density LIBs.It is generally agreed that the chemical crosstalk between the cathode and anode leads to thermal runaway of LIBs.Herein,a multifunctional high safety electrolyte is designed with synergistic construction of cathode electrolyte interphase and capture of reactive free radicals to limit the intrinsic pathway of thermal runaway.The cathode electrolyte interphase not only resists the gas attack from the anode but suppresses the parasitic side reactions induced by electrolyte.And the function of free radical capture has the ability of reducing heat release from thermal runaway of battery.The dual strategy improves the intrinsic safety of battery prominently that the triggering temperature of thermal runaway is increased by 24.4℃and the maximum temperature is reduced by 177.7℃.Simultaneously,the thermal runaway propagation in module can be self-quenched.Moreover,the electrolyte design balances the trade-off of electrochemical and safety performance of high-energy batteries.The capacity retention of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)|graphite pouch cell has been significantly increased from 53.85%to 97.05%with higher coulombic efficiency of 99.94%at operating voltage extended up to 4.5 V for 200 cycles.Therefore,this work suggests a feasible strategy to mitigate the safety risk of high-energy-density LIBs without sacrificing electrochemical performances.
基金supported by the National Natural Sci ence Foundation of China(No.50105011)the Foundation for the author by the National Excellent Doctoral Disserta tion of China(200231)+2 种基金the Natural Science Foundation of Shandong Province(Y2004F14)the SRF for ROCS([2002]247),MOE,Chinathe SRF for ROCS(2002[247]),SEM.
文摘Si3N4/TiC nanocomposite ceramics have been fabricated by hot pressing technique with AI2O3 and Y2O3 as additives.The results showed that well dispersed composite powder wascarried out by adding dispersant and adjusting pH valuesof suspensions. Remarkable increase in flexural strength at room temperatures was obtained by adding nanoparticlesin Si3N4 matrix with 10% (wt pct) of nano-Si3N4 and 15% of nano-TiC. The flexural strength, fracture toughnessand hardness were 1025 MPa, 7.5 MPa·m1/2 and 15.6 GPa, respectively. The microstructures of materials wereanalyzed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM), which indicated thatTiC nanoparticles distribute in the matrix and at the grain boundaries. According to the fracture form, low contentsof nano particles could refine matrix grains and lead to the track deflection as well as crack pinning. The multiplexmicrostructure was formed by mixing nano-Si3N4 particles. The crack trajectories exhibited crack deflection, rod-likegrain bridging and pull-out.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11974336 and 12304401)the National Key R&D Program of China(Grant No.2017YFA0304100)+1 种基金the Key Project of Natural Science Research in Universities of Anhui Province(Grant No.KJ2021A1107)the Scientific Research Foundation of Suzhou University(Grant Nos.2020BS006 and 2021XJPT18).
文摘Spin qubits and superconducting qubits are promising candidates for realizing solid-state quantum information processors.Designing a hybrid architecture that combines the advantages of different qubits on the same chip is a highly desirable but challenging goal.Here we propose a hybrid architecture that utilizes a high-impedance SQUID array resonator as a quantum bus,thereby coherently coupling different solid-state qubits.We employ a resonant exchange spin qubit hosted in a triple quantum dot and a superconducting transmon qubit.Since this hybrid system is highly tunable,it can operate in a dispersive regime,where the interaction between the different qubits is mediated by virtual photons.By utilizing such interactions,entangling gate operations between different qubits can be realized in a short time of 30 ns with a fidelity of up to 96.5%under realistic parameter conditions.Further utilizing this interaction,remote entangled state between different qubits can be prepared and is robust to perturbations of various parameters.These results pave the way for exploring efficient fault-tolerant quantum computation on hybrid quantum architecture platforms.
基金supported by the National High Technology Research and Development Program of China (Grant No. 2008AA06Z209)CNPC Innovation Fund (Grant No. 2006-A)+1 种基金Special Items Fund of Beijing Municipal Commiss ion of EducationProgram for New Century Excellent Talents,Ministry of Education (Grant No. NCET-05-0110)
文摘An incipient mechanical fault detection method, combining multifractal theory and Mahalanobis-Taguchi system (MTS), which is based on statistical technology, is proposed in this paper. Multifractal features of vibration signals obtained from machine state monitoring are extracted by multifractal spectrum analysis and generalized fractal dimensions. Considering the situation of mass samples of normal mechanical running state and few fault states, the feature parameters corresponding to different mechanical running states are further optimized by a statistical method, based on which incipient faults are subsequently identifi ed and diagnosed accurately. Experimental results proved that the method combining multifractal theory and MTS can be used for incipient fault state recognition effectively during the mechanical running process, and the accuracy of fault state identifi cation is improved.
基金Project(50474007) supported by the National Natural Science Foundation of ChinaProject(0450050) supported by the Natural Science Foundation of Jiangxi Province, China Projects(GanJiaoZi[2005]2, 24) supported by the Science and Technology Program of Education Department of Jiangxi Province, China
文摘The semi-solid slurry of wrought aluminum alloy 2024 was prepared by a well developed rheocasting process, low superheat pouring with shearing field(LSPSF). The appreciate combination of pouring temperature and rotation speed of barrel, can give rise to a transition of the growth morphology of primary α(Al) from coarse-dendritic to coarse-particle-like and further to fine-globular. The combined effects of both localized rapid cooling and vigorous mixing during the initial stage of solidification can enhance wall nucleation and nuclei survival, which leads to the formation of fine-globular primary α(Al). By using semi-solid slurry prepared by LSPSF, direct squeeze cast cup-shaped component with improved mechanical properties such as yield strength of 198 MPa, ultimate tensile strength of 306 MPa and elongation of 10.4%, can be obtained.
基金financially supported by the National Natural Science Foundation of China (No. 19934003)the Key Program of Natural Science Foundation of Anhui Province (Nos. KJ2011A259 and KJ2013A245)+1 种基金the Program of Professors and Doctors' Research Startup Foundation of Suzhou College (Nos. 2011jb01 and 2011jb02)the Program of Cultivating Base of Anhui Key Laboratory of Spintronics and Nano-materials Research (No. 2012YKF09)
文摘The perovskite samples La1-x (Sr1-yKy )xMnO3 (y = 0.0, 0.2, 04, 0.6, 0.8) were prepared by the solid-state reaction method with comparatively low sintering temperature and with comparatively short sintering time, and the electric transport property and temperature stability of MR of this system were studied. The q-T curves show the abnormal phenomenon that with the increase of K doping amount, resistivity increases, and the insulator-metal transition temperature decreases, which is because the influence of the occupation disorder degree of A-site ions σ2 on the electric transport property of perovskite manganites is larger than that of the radius of A-site ions<rA>. In the temperature range below 225 K, MR increases continuously with the decrease of temperature, which is the characteristic of low-field magnetoresistance; in the comparatively wide temperature range near 250 K, the MR-T curves of all the samples are comparatively flat, and the value of MR almost does not change with temperature, which shows the temperature stability of magnetoresistance, and can be explained by the competition between the low-field magnetoresistance induced by spin-dependent tunneling of surface phase and the intrinsic magnetoresistance of grain phase. The magnetoresistance value of the sample with y = 0.8 keeps at (7.92 ± 0.36) % in the very wide temperature range of 225-275 K, and this is a good reference for the preparation of this kind of sample with practical application value in the future.
基金Project(200802015) supported by Post-doctoral Foundation of Shandong Province,ChinaProject(50625101) supported by the National Natural Science Foundation for Distinguished Young Scholars of China
文摘The structural and electronic properties of bulk and (001) plane of TiC were investigated by the first-principles total-energy pseudopotential method based on density functional theory.The calculated bulk properties indicate that bonding nature in TiC is a combination of ionicity,covalency and metallicity,in which the Ti-C covalent bonding is the predominate one.The calculated results of structural relaxation and surface energy for TiC(001) slab indicate that slab with 7 layers shows bulk-like characteristic interiors,and the changes of slab occur on the outmost three layers,which shows that the relaxation only influences the top three layers.Meanwhile,the strong Ti-C covalent bonding can be found in the distribution of charge density on the (110) and (001) planes.Ti-C covalent bonding is enhanced by the charge depletion and accumulation in the vacuum and the interlayer region between top two atomic layers.
基金Supported by National Natural Science Foundation of China(Grant No.51475343)International Science and Technology Cooperation Program of China(Grant No.2015DFA70340)
文摘Thermal error monitoring technology is the key technological support to solve the thermal error problem of heavy-duty CNC(computer numerical control) machine tools. Currently, there are many review literatures introducing the thermal error research of CNC machine tools,but those mainly focus on the thermal issues in small and medium-sized CNC machine tools and seldom introduce thermal error monitoring technologies. This paper gives an overview of the research on the thermal error of CNC machine tools and emphasizes the study of thermal error of the heavy-duty CNC machine tool in three areas. These areas are the causes of thermal error of heavy-duty CNC machine tool and the issues with the temperature monitoring technology and thermal deformation monitoring technology. A new optical measurement technology called the ‘‘fiber Bragg grating(FBG) distributed sensing technology'' for heavy-duty CNC machine tools is introduced in detail. This technology forms an intelligent sensing and monitoring system for heavy-duty CNC machine tools.This paper fills in the blank of this kind of review articlesto guide the development of this industry field and opens up new areas of research on the heavy-duty CNC machine tool thermal error.
基金supported by the National Natural Foundation of China (No. 19934003)the Natural Science Research Key Program of Anhui Educational Committee (No. KJ2011A259)+2 种基金the Cultivating Base of Anhui Key Laboratory of Spintronics and Nano-materials Research Program(No. 2010YKF01No. 2010YKF04)the Professors’ and Doctors’ Research Startup Foundation of Suzhou University (Nos. 2011jb01 and 2011jb02)
文摘A series of the samples La_(1-x)(Sr_(1-y)Na_y)_xMnO_3(y=0.0,0.2,0.4,0.6,0.8,1.0) were prepared by the solid-state reaction method.Magnetoresistance enhancement and temperature stability of magnetoresistance in the system La_(1-x)(Sr_(1-y)Na_y)_xMnO_3 with unchanged Mn^(3+)/Mn^(4+) ratio through the doping of both monovalent and divalent elements at A site were studied through the measurements of X-ray diffraction(XRD) patterns,resistivity-temperature(ρ-T) curves and magnetoresistance-temperature(MR-T) curves.The results indicate that with the increase of Na doping amount,the peak value of MR increases,and it increases from 12.4% for y=0.2 to 50.6% for y=1.0 in the magnetic field B=0.8 T;ρ-T curves exhibit the double-peak phenomenon,which comes from the competition between the resistivity of surface phase and that of body phase;for the sample of y=0.8,MR increases slowly from 8.3% to 9.4% in the temperature range from 259 to 179 K,and MR is so stable in such a wide temperature range,which provides reference for the research on the temperature stability of MR.
基金the National Natural Science Foundation of China (No. 50372043).
文摘This paper deals with the effects of codoped VC/Cr3C2 and sintering temperature on the magnetic and mechanical properties of ultra-fine grained WC-12%Co alloys. Results show that the synergistic action of doped VC/Cr3C2 in optimal proportion enhances both the hardness and transverse rupture strength (TRS) of the alloys, with more homogeneous microstructure. When the alloy is sintered at 1430°C and with 0.5% Cr3C2/0.2% VC, the TRS reaches 3786 MPa, the hardness is 91.7 HRA and the grain size smaller than 0.6 μm. The numerical analyses on grain growth during the sintering process show that both VC precipitating on the WC grain boundary and Cr3C2 dissolving in the Co phase decrease the solid/liquid interfacial energy γ, the process of dissolution and reprecipitation is greatly retarded and the coarsening of WC grains is inhibited.
