A slow-wave structure （SWS） with two opposite gratings inside a rectangular waveguide is presented and analysed. As an all-metal slow-wave circuit, this structure is especially suited for use in millimetre-wave trav...A slow-wave structure （SWS） with two opposite gratings inside a rectangular waveguide is presented and analysed. As an all-metal slow-wave circuit, this structure is especially suited for use in millimetre-wave travelling wave tubes （TWTs） due to its advantages of large size, high manufacturing precision and good heat dissipation. The first part of this paper concerns the wave properties of this structure in vacuum. The influence of the geometrical dimensions on dispersion characteristics and coupling impedance is investigated. The theoretical results show that this structure has a very strong dispersion and the coupling impedance for the fundamental wave is several tens of ohms, but the coupling impedance for -1 space harmonic wave is much lower than that for the fundamental wave, so the risk of backward wave oscillation is reduced. Besides these, the CST microwave studio is also used to simulate the dispersion property of the SWS. The simulation results from CST and the theoretical results agree well with each other, which supports the theory. In the second part, a small-signal analysis of a double rectangular waveguide grating TWT is presented. The typical small-signal gain per period is about 0.45 dB, and the 3-dB small-signal gain bandwidth is only 4%.展开更多
The ground-state phase transition and the phonon dispersion relation of the quantum double-well model are studied by means of the time-dependent variational approach combined with a Hartree-type many-body trial wavefu...The ground-state phase transition and the phonon dispersion relation of the quantum double-well model are studied by means of the time-dependent variational approach combined with a Hartree-type many-body trial wavefunction. The single-particle state is taken to be a frozen Jackiw-Kerman wavefunction. Under the condition of minimum uncertainty relation, we obtain an effective classical Hamiltonian for the system and equations of motion for the particle＇s expectation values. It is shown that the effective substrate potential transits from a symmetric double-well potential to a symmetric single-well potential, and the ground state exhibits a transition from a broken symmetry phase to a restored symmetry phase as increasing the strength of quantum fluctuations. We also obtain the phonon dispersion relations and the phonon gaps at the two phases.展开更多
Vortex solitons with a ring vortex core residing in a single lattice site in the semi-infinite gap of square optical lattices are reported. These solitons are no longer bound states of the Bloch-wave unit （Bloch-wave...Vortex solitons with a ring vortex core residing in a single lattice site in the semi-infinite gap of square optical lattices are reported. These solitons are no longer bound states of the Bloch-wave unit （Bloch-wave distribution in one lattice site） at the band edge of the periodic lattice, and consequently they do not bifurcate from the corresponding band edge. For saturable nonlinearity, one family of such solitons is found, and its existing curve forms a closed loop, which is very surprising. For Kerr nonlinearity, two families of such vortex solitons are found.展开更多
Much experimental evidence of superluminal phenomena has been available by electromagnetic wave propagation experiments, with the results showing that the phase time describes the barrier traversal time. Based on the ...Much experimental evidence of superluminal phenomena has been available by electromagnetic wave propagation experiments, with the results showing that the phase time describes the barrier traversal time. Based on the extrapolated phase time approach and numerical methods, we show that, in contrast to the ordinary Bessel waves of real argument, the group velocities of modified Bessel waves are superluminal. We obtain the following results. The group velocities increase with the increase of propagation distance, which is similar to the evanescent plane- wave cases. For large wave numbers, the group velocities fall off as the wave numbers increase, which is similar to the evanescent plane-wave cases. For small wave numbers, the group velocities increase with the increase of wave numbers, this is different from the evanescent plane-wave cases.展开更多
A novel slow-wave structure （SWS）, the folded double-ridged waveguide structure, is presented and its linear gain properties are investigated. The perturbed dispersion equation is derived and the small signal growth...A novel slow-wave structure （SWS）, the folded double-ridged waveguide structure, is presented and its linear gain properties are investigated. The perturbed dispersion equation is derived and the small signal growth rate is caleulated for dimensions of the ridge-loaded region and the parameters of the electron beam. The novel structure has potential applications in the production of high power and broad band radiation. For a cold beam, the linear theory predicts a gain of 1.1-1.27dB/period and a 3-dB small-signal gain bandwidth of 30% in W-band. A comparison between the folded double-ridged waveguide SWS and folded waveguide SWS （FWSWS） shows that with the same physical parameters, the novel SWS has an advantage over the FWSWS on the bandwidth and electron efficiency.展开更多
In this paper, the enhanced terahertz radiation transformed from surface plasmon polaritons, excited by a uniformly moving electron bunch, in a structure consisting of a monolayer graphene supported on a dielectric gr...In this paper, the enhanced terahertz radiation transformed from surface plasmon polaritons, excited by a uniformly moving electron bunch, in a structure consisting of a monolayer graphene supported on a dielectric grating with arbitrary profile is investigated. The results show that the grating profile has significant influence on the dispersion curves and radiation characteristics including radiation frequency and intensity. The dependence of dispersion and radiation characteristics on the grating shape for both the symmetric and asymmetric gratings is studied in detail. Moreover, we find that, for an asymmetric grating with certain profile, there exist two different diffraction types, and one of the two types can provide higher radiation intensity comparing to the other one. These results will definitely facilitate the practical application in developing a room-temperature, tunable, coherent and miniature terahertz radiation source.展开更多
Parameters of hydrogen plasma in a miniature Penning discharge ion source, including the electron temperature and the electron density, were measured by using double probes. The results indicate that the electron dens...Parameters of hydrogen plasma in a miniature Penning discharge ion source, including the electron temperature and the electron density, were measured by using double probes. The results indicate that the electron density increases and the electron temperature decreases with the increase in gas pressure and the discharge current. The electron temperature is about 5 - 9 eV and the electron density is 6.0× 10^13 ～ 1.2 × 10^14 m^-3 while the discharge current is in a range of 50 - 120 μA.展开更多
Rhythm of brain activities represents oscillations of postsynaptic potentials in neocortex, therefore it can serve as an indicator of the brain activity state. In order to check the connectivity of brain rhythm, this ...Rhythm of brain activities represents oscillations of postsynaptic potentials in neocortex, therefore it can serve as an indicator of the brain activity state. In order to check the connectivity of brain rhythm, this paper develops a new method of constructing functional network based on phase synchronization. Electroencephalogram （EEG） data were collected while subjects looking at a green cross in two states, performing an attention task and relaxing with eyes-open. The EEG from these two states was filtered by three band-pass filters to obtain signals of theta （4-7 Hz）, alpha （8-13 Hz） and beta （14-30 Hz） bands. Mean resultant length was used to estimate strength of phase synchronization in three bands to construct networks of both states, and mean degree K and cluster coefficient C of networks were calculated as a function of threshold. The result shows higher cluster coetticient in the attention state than in the eyes-open state in all three bands, suggesting that cluster coefficient reflects brain state. In addition, an obvious fronto-parietal network is found in the attention state, which is a well-known attention network. These results indicate that attention modulates the fronto-parietal connectivity in different modes as compared with the eyes-open state. Taken together this method is an objective and important tool to study the properties of neural networks of brain rhythm,展开更多
The highly selective catalytic transfer hydrogenation(CTH)of furfural(FF)to furfuryl alcohol(FOL)is a significant route of biomass valorization.Herein,a series microporous Zr-metal organic framework(ZrMOF)functionaliz...The highly selective catalytic transfer hydrogenation(CTH)of furfural(FF)to furfuryl alcohol(FOL)is a significant route of biomass valorization.Herein,a series microporous Zr-metal organic framework(ZrMOF)functionalized by sulfonic groups are prepared.Based on the comprehensive structural characterizations by means of X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),N2 physisorption,Thermogravimetric(TG)and Fourier transformed infrared spectroscopy(FTIR),we find that sulfonic acid(–SO_(3)H)functional groups are tethered on the UIO-66 without affecting the structure of the framework.Systematic characterizations(NH_(3)-TPD,CO_(2)-TPD,and in-situ FTIR)demonstrate that modifying of sulfonic groups on UIO-66 results in the formation of stronger Lewis acidic-basic and Brnsted acidis sites.The cooperative role of the versatile Lewis acidic-basic and Brnsted acidic sites in 60%mol fraction of sulfonic acid-containing UIO-66(UIO-S_(0.6))retain high surface area and exhibit excellent catalytic performance of 94.7%FOL yield and 16.9 h^(-1).turnover number(TOF)under mild conditions.Kinetic experiments reveal that the activation energy of the CTH of furfural(FF)over UIO-S_(0.6) catalyst is as low as 50.8 k J mol^(-1).Besides,the hydrogen transfer mechanism is investigated through isotope labeling experiments,exhibiting that theβ-H in isopropanol is transferred to the a-C of FF by forming six-membered intermediates on the Lewis acidic-basic and Brnsted acidic sites of the UIO-S_(0.6),which is the rate-determining step in the formation of FOL.展开更多
Photonic crystals （PCs） are increasingly attracting attention due to their ability to control light propagation.In this paper,the dispersion properties of a two-dimensional （2D） square lattice PCs with plane- wave...Photonic crystals （PCs） are increasingly attracting attention due to their ability to control light propagation.In this paper,the dispersion properties of a two-dimensional （2D） square lattice PCs with plane- wave expansion （PWE） method are presented,the equi-frequency contours and the band structure are analyzed,and the alignment transmission characteristics are simulated by using the finite difference time domain （FDTD） method.In addition,for the wavelength of 1.55 m,a kind of application structure with the lattice constant a=405 nm and the radius of air holes R=135 nm which can restrict the transmission of beams in photonic crystal without defect is proposed and simulated.The structure which can collimate the output beam and compress its divergence angle is easy to design.It has wide application prospects in optical communication and three-dimensional （3D） imaging lidar systems.展开更多
The residual symmetries of the Ablowitz-Kaup-Newell-Segur （AKNS） equations are obtained by the truncated Painleve analysis. The residual symmetries for the AKNS equations are proved to be nonlocal and the nonlocal r...The residual symmetries of the Ablowitz-Kaup-Newell-Segur （AKNS） equations are obtained by the truncated Painleve analysis. The residual symmetries for the AKNS equations are proved to be nonlocal and the nonlocal residual symmetries are extended to the local Lie point symmetries of a prolonged AKNS system. The local Lie point symme- tries of the prolonged AKNS equations are composed of the residual symmetries and the standard Lie point symmetries, which suggests that the residual symmetry method is a useful complement to the classical Lie group theory. The calcula- tion on the symmetries shows that the enlarged equations are invariant under the scaling transformations, the space-time translations, and the shift translations. Three types of similarity solutions and the reduction equations are demonstrated. Furthermore, several types of exact solutions for the AKNS equations are obtained with the help of the symmetry method and the Backlund transformations between the AKNS equations and the Schwarzian AKNS equation.展开更多
The folded double-ridged waveguide structure is presented and its properties used for wide-band traveling-wave tube are investigated. Expressions of dispersion characteristics, normalized phase velocity and interactio...The folded double-ridged waveguide structure is presented and its properties used for wide-band traveling-wave tube are investigated. Expressions of dispersion characteristics, normalized phase velocity and interaction impedance of this structure are derived and numerically calculated. The calculated results using our theory agree well with those obtained by using the 3D electromagnetic simulation software HFSS. Influences of the ridge-loaded area and broad-wall dimensions on the high frequency characteristics of the novel slow-wave structure are discussed. It is shown that the folded double-ridged waveguide structure has a much wider relative passband than the folded waveguide slow-wave structure and a relative passband of 67% could be obtained, indicating that this structure can operate in broad-band frequency ranges of beam-wave interaction. The small signal gain property is investigated for ensuring the improvement of bandwidth. Meanwhile, with comparable dispersion characteristics, the transverse section dimension of this novel structure is much smaller than that of conventional one, which indicates an available way to reduce the weight of traveling-wave tube.展开更多
The periodic nonuniform folded waveguides are special structures, the physical dimension of which is between the periodic folded waveguide and the tapering period folded waveguide. Therefore, the synchronization betwe...The periodic nonuniform folded waveguides are special structures, the physical dimension of which is between the periodic folded waveguide and the tapering period folded waveguide. Therefore, the synchronization between the microwave and the electron beam can be maintained in the whole interaction process and the periods are not tapered. In comparison with the tapering period folded waveguide, the theoretical analysis and the technological requirements for this structure are more convenient. In order to study this structure, the space harmonics are analysed, the conditions to make the rn-th space harmonic synchronizing with the electron beam in the whole interaction process are present, and the dispersion curve and the coupling impedance curve are obtained by the simulation software HFSS.展开更多
We assess the feasibility of our developed quantitative thermoacoustic tomography(qTAT)system for breast tumor characterization using mastectomy specimens before the clinical investigation.A circular scanning TAT syst...We assess the feasibility of our developed quantitative thermoacoustic tomography(qTAT)system for breast tumor characterization using mastectomy specimens before the clinical investigation.A circular scanning TAT system coupled with a finite-element based reconstruction algorithm is used to recover the dielectric property distribution of normal and tumor tissues from three female subjects who underwent mastectomy.Statistical method is used to analyze the tissue dielectric properties obtained.The recovered qTAT images reveal large contrast in conductivity between tumor and normal breast tissues.In addition,significant difference in conductivity exists among all the specimens examined.Finally,the recovered tumor size for these specimens agrees well with their exact size.This preclinical evaluation suggests that it is feasible to detect and characterize a breast tumor quantitatively with our qTAT method.展开更多
This paper studies the dispersion characteristics of a modified photonic band-gap slow-wave structure with an open boundary by simulation and experiment. A mode launcher with a wheel radiator and a coupling probe is p...This paper studies the dispersion characteristics of a modified photonic band-gap slow-wave structure with an open boundary by simulation and experiment. A mode launcher with a wheel radiator and a coupling probe is presented to excite a pure TM01-like mode. The cold test and simulation results show that the TM01-like mode is effectively excited and no parasitic modes appear. The dispersion characteristics obtained from the cold test are in good agreement with the calculated results.展开更多
An experimental study of leakage current is presented in a semi-insulating（SI） Ga As photoconductive semiconductor switch（PCSS） with voltages up to 5.8 kV（average field is 19.3 kV/cm）. The leakage current increa...An experimental study of leakage current is presented in a semi-insulating（SI） Ga As photoconductive semiconductor switch（PCSS） with voltages up to 5.8 kV（average field is 19.3 kV/cm）. The leakage current increases nonlinearly with the bias voltage increasing from 1.2×10^-9 A to 3.6×10^-5A. Furthermore, the dark resistance, which is characterized as a function of electric field, does not monotonically decrease with the field but displays several distinct regimes. By eliminating the field-dependent drift velocity, the free-electron density n is extracted from the current, and then the critical field for each region of n（E） characteristic of PCSS is obtained. It must be the electric field that provides the free electron with sufficient energy to activate the carrier in the trapped state via multiple physical mechanisms, such as impurity ionization, fielddependent EL2 capture, and impact ionization of donor centers EL10 and EL2. The critical fields calculated from the activation energy of these physical processes accord well with the experimental results. Moreover, agreement between the fitting curve and experimental data of J（E）, further confirms that the dark-state characteristics are related to these field-dependent processes. The effects of voltage on SI-Ga As PCSS may give us an insight into its physical mechanism.展开更多
Modulation caused by surface/subsurface contaminants is one of the important factors for laser-induced damage of fused silica. In this work, a three-dimensional finite-difference time-domain （3D-FDTD） method is empl...Modulation caused by surface/subsurface contaminants is one of the important factors for laser-induced damage of fused silica. In this work, a three-dimensional finite-difference time-domain （3D-FDTD） method is employed to simulate the electric field intensity distribution in the vicinity of particulate contaminants on fused silica surface. The simulated results reveal that the contaminant on both the input and output surfaces plays an important role in the electric field mod- ulation of the incident laser. The influences of the shape, size, embedded depth, dielectric constant （er）, and the number of contaminant particles on the electric field distribution are discussed in detail. Meanwhile, the corresponding physical mechanism is analyzed theoretically.展开更多
The mobility edge （ME） model with single Gaussian density of states （DOS） is simplified based on the recent exper- imental results about the Einstein relationship. The free holes are treated as being non-degenerat...The mobility edge （ME） model with single Gaussian density of states （DOS） is simplified based on the recent exper- imental results about the Einstein relationship. The free holes are treated as being non-degenerate, and the trapped holes are dealt with as being degenerate. This enables the integral for the trapped holes to be easily realized in a program. The J-V curves are obtained through solving drift-diffusion equations. When this model is applied to four organic diodes, an obvious deviation between theoretical curves and experimental data is observed. In order to solve this problem, a new DOS with exponential tall is proposed. The results show that the consistence between J-V curves and experimental data based on a new DOS is far better than that based on the Gaussian DOS. The variation of extracted mobility with temperature can be well described by the Arrhenius relationship.展开更多
The ablation debris and raised rim, as well as residual stress and deep crater will be formed during the mitigation of damage site with a CO2 laser irradiation on fused silica surface, which greatly affects the laser ...The ablation debris and raised rim, as well as residual stress and deep crater will be formed during the mitigation of damage site with a CO2 laser irradiation on fused silica surface, which greatly affects the laser damage resistance of optics. In this study, the experimental study combined with numerical simulation is utilized to investigate the effect of the secondary treatment on a mitigated site by CO2laser irradiation. The results indicate that the ablation debris and the raised rim can be completely eliminated and the depth of crater can be reduced. Notable results show that the residual stress of the mitigation site after treatment will reduce two-thirds of the original stress. Finally, the elimination and the controlling mechanism of secondary treatment on the debris and raised rim, as well as the reasons for changing the profile and stress are analyzed. The results can provide a reference for the optimization treatment of mitigation sites by CO2laser secondary treatment.展开更多
文摘A slow-wave structure （SWS） with two opposite gratings inside a rectangular waveguide is presented and analysed. As an all-metal slow-wave circuit, this structure is especially suited for use in millimetre-wave travelling wave tubes （TWTs） due to its advantages of large size, high manufacturing precision and good heat dissipation. The first part of this paper concerns the wave properties of this structure in vacuum. The influence of the geometrical dimensions on dispersion characteristics and coupling impedance is investigated. The theoretical results show that this structure has a very strong dispersion and the coupling impedance for the fundamental wave is several tens of ohms, but the coupling impedance for -1 space harmonic wave is much lower than that for the fundamental wave, so the risk of backward wave oscillation is reduced. Besides these, the CST microwave studio is also used to simulate the dispersion property of the SWS. The simulation results from CST and the theoretical results agree well with each other, which supports the theory. In the second part, a small-signal analysis of a double rectangular waveguide grating TWT is presented. The typical small-signal gain per period is about 0.45 dB, and the 3-dB small-signal gain bandwidth is only 4%.
文摘The ground-state phase transition and the phonon dispersion relation of the quantum double-well model are studied by means of the time-dependent variational approach combined with a Hartree-type many-body trial wavefunction. The single-particle state is taken to be a frozen Jackiw-Kerman wavefunction. Under the condition of minimum uncertainty relation, we obtain an effective classical Hamiltonian for the system and equations of motion for the particle＇s expectation values. It is shown that the effective substrate potential transits from a symmetric double-well potential to a symmetric single-well potential, and the ground state exhibits a transition from a broken symmetry phase to a restored symmetry phase as increasing the strength of quantum fluctuations. We also obtain the phonon dispersion relations and the phonon gaps at the two phases.
基金Project supported by the National Natural Science Foundation of China (Grant No. 10904009)the Fundamental Research Funds for the Central Universities(Grant Nos. ZYGX2011J039 and ZYGX2011J047)
文摘Vortex solitons with a ring vortex core residing in a single lattice site in the semi-infinite gap of square optical lattices are reported. These solitons are no longer bound states of the Bloch-wave unit （Bloch-wave distribution in one lattice site） at the band edge of the periodic lattice, and consequently they do not bifurcate from the corresponding band edge. For saturable nonlinearity, one family of such solitons is found, and its existing curve forms a closed loop, which is very surprising. For Kerr nonlinearity, two families of such vortex solitons are found.
文摘Much experimental evidence of superluminal phenomena has been available by electromagnetic wave propagation experiments, with the results showing that the phase time describes the barrier traversal time. Based on the extrapolated phase time approach and numerical methods, we show that, in contrast to the ordinary Bessel waves of real argument, the group velocities of modified Bessel waves are superluminal. We obtain the following results. The group velocities increase with the increase of propagation distance, which is similar to the evanescent plane- wave cases. For large wave numbers, the group velocities fall off as the wave numbers increase, which is similar to the evanescent plane-wave cases. For small wave numbers, the group velocities increase with the increase of wave numbers, this is different from the evanescent plane-wave cases.
基金Supported by the National Natural Science Foundation of China under Grant Nos 60532010 and 60401005.
文摘A novel slow-wave structure （SWS）, the folded double-ridged waveguide structure, is presented and its linear gain properties are investigated. The perturbed dispersion equation is derived and the small signal growth rate is caleulated for dimensions of the ridge-loaded region and the parameters of the electron beam. The novel structure has potential applications in the production of high power and broad band radiation. For a cold beam, the linear theory predicts a gain of 1.1-1.27dB/period and a 3-dB small-signal gain bandwidth of 30% in W-band. A comparison between the folded double-ridged waveguide SWS and folded waveguide SWS （FWSWS） shows that with the same physical parameters, the novel SWS has an advantage over the FWSWS on the bandwidth and electron efficiency.
基金Project supported by the National Basic Research Program of China(Grant No.2014CB339801)the National Natural Science Foundation of China(Grant Nos.61231005,11305030,and 612111076)+1 种基金the Fundamental Research Funds for the Central Universities of China(Grant No.ZYGX2013J058)the National High-tech Research and Development Project of China(Grant No.2011AA010204)
文摘In this paper, the enhanced terahertz radiation transformed from surface plasmon polaritons, excited by a uniformly moving electron bunch, in a structure consisting of a monolayer graphene supported on a dielectric grating with arbitrary profile is investigated. The results show that the grating profile has significant influence on the dispersion curves and radiation characteristics including radiation frequency and intensity. The dependence of dispersion and radiation characteristics on the grating shape for both the symmetric and asymmetric gratings is studied in detail. Moreover, we find that, for an asymmetric grating with certain profile, there exist two different diffraction types, and one of the two types can provide higher radiation intensity comparing to the other one. These results will definitely facilitate the practical application in developing a room-temperature, tunable, coherent and miniature terahertz radiation source.
文摘Parameters of hydrogen plasma in a miniature Penning discharge ion source, including the electron temperature and the electron density, were measured by using double probes. The results indicate that the electron density increases and the electron temperature decreases with the increase in gas pressure and the discharge current. The electron temperature is about 5 - 9 eV and the electron density is 6.0× 10^13 ～ 1.2 × 10^14 m^-3 while the discharge current is in a range of 50 - 120 μA.
基金supported by the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 30800242)
文摘Rhythm of brain activities represents oscillations of postsynaptic potentials in neocortex, therefore it can serve as an indicator of the brain activity state. In order to check the connectivity of brain rhythm, this paper develops a new method of constructing functional network based on phase synchronization. Electroencephalogram （EEG） data were collected while subjects looking at a green cross in two states, performing an attention task and relaxing with eyes-open. The EEG from these two states was filtered by three band-pass filters to obtain signals of theta （4-7 Hz）, alpha （8-13 Hz） and beta （14-30 Hz） bands. Mean resultant length was used to estimate strength of phase synchronization in three bands to construct networks of both states, and mean degree K and cluster coefficient C of networks were calculated as a function of threshold. The result shows higher cluster coetticient in the attention state than in the eyes-open state in all three bands, suggesting that cluster coefficient reflects brain state. In addition, an obvious fronto-parietal network is found in the attention state, which is a well-known attention network. These results indicate that attention modulates the fronto-parietal connectivity in different modes as compared with the eyes-open state. Taken together this method is an objective and important tool to study the properties of neural networks of brain rhythm,
基金supported by the National Key R&D Program of China(2020YFA0710000)the National Natural Science Foundation of China(22122901,21902047)+1 种基金the Provincial Natural Science Foundation of Hunan(2020JJ5045,2021JJ20024,2021RC3054)the Shenzhen Science and Technology Program(JCYJ20210324140610028)。
文摘The highly selective catalytic transfer hydrogenation(CTH)of furfural(FF)to furfuryl alcohol(FOL)is a significant route of biomass valorization.Herein,a series microporous Zr-metal organic framework(ZrMOF)functionalized by sulfonic groups are prepared.Based on the comprehensive structural characterizations by means of X-ray diffraction(XRD),scanning electron microscopy(SEM),transmission electron microscopy(TEM),N2 physisorption,Thermogravimetric(TG)and Fourier transformed infrared spectroscopy(FTIR),we find that sulfonic acid(–SO_(3)H)functional groups are tethered on the UIO-66 without affecting the structure of the framework.Systematic characterizations(NH_(3)-TPD,CO_(2)-TPD,and in-situ FTIR)demonstrate that modifying of sulfonic groups on UIO-66 results in the formation of stronger Lewis acidic-basic and Brnsted acidis sites.The cooperative role of the versatile Lewis acidic-basic and Brnsted acidic sites in 60%mol fraction of sulfonic acid-containing UIO-66(UIO-S_(0.6))retain high surface area and exhibit excellent catalytic performance of 94.7%FOL yield and 16.9 h^(-1).turnover number(TOF)under mild conditions.Kinetic experiments reveal that the activation energy of the CTH of furfural(FF)over UIO-S_(0.6) catalyst is as low as 50.8 k J mol^(-1).Besides,the hydrogen transfer mechanism is investigated through isotope labeling experiments,exhibiting that theβ-H in isopropanol is transferred to the a-C of FF by forming six-membered intermediates on the Lewis acidic-basic and Brnsted acidic sites of the UIO-S_(0.6),which is the rate-determining step in the formation of FOL.
基金supported by the Pre-research Foundation under Grant No. G020104PJ09DZ0246
文摘Photonic crystals （PCs） are increasingly attracting attention due to their ability to control light propagation.In this paper,the dispersion properties of a two-dimensional （2D） square lattice PCs with plane- wave expansion （PWE） method are presented,the equi-frequency contours and the band structure are analyzed,and the alignment transmission characteristics are simulated by using the finite difference time domain （FDTD） method.In addition,for the wavelength of 1.55 m,a kind of application structure with the lattice constant a=405 nm and the radius of air holes R=135 nm which can restrict the transmission of beams in photonic crystal without defect is proposed and simulated.The structure which can collimate the output beam and compress its divergence angle is easy to design.It has wide application prospects in optical communication and three-dimensional （3D） imaging lidar systems.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11305031,11365017,and 11305106)the Natural Science Foundation of Guangdong Province,China(Grant No.S2013010011546)+2 种基金the Natural Science Foundation of Zhejiang Province,China(Grant No.LQ13A050001)the Science and Technology Project Foundation of Zhongshan,China(Grant Nos.2013A3FC0264 and 2013A3FC0334)the Training Programme Foundation for Outstanding Young Teachers in Higher Education Institutions of Guangdong Province,China(Grant No.Yq2013205)
文摘The residual symmetries of the Ablowitz-Kaup-Newell-Segur （AKNS） equations are obtained by the truncated Painleve analysis. The residual symmetries for the AKNS equations are proved to be nonlocal and the nonlocal residual symmetries are extended to the local Lie point symmetries of a prolonged AKNS system. The local Lie point symme- tries of the prolonged AKNS equations are composed of the residual symmetries and the standard Lie point symmetries, which suggests that the residual symmetry method is a useful complement to the classical Lie group theory. The calcula- tion on the symmetries shows that the enlarged equations are invariant under the scaling transformations, the space-time translations, and the shift translations. Three types of similarity solutions and the reduction equations are demonstrated. Furthermore, several types of exact solutions for the AKNS equations are obtained with the help of the symmetry method and the Backlund transformations between the AKNS equations and the Schwarzian AKNS equation.
基金Project supported in part by the National Natural Science Foundation of China (Grant No. 60971038)in part by the Fundamental Research Funds for Central Universities,China (Grant No. ZYGX2009Z003)
文摘The folded double-ridged waveguide structure is presented and its properties used for wide-band traveling-wave tube are investigated. Expressions of dispersion characteristics, normalized phase velocity and interaction impedance of this structure are derived and numerically calculated. The calculated results using our theory agree well with those obtained by using the 3D electromagnetic simulation software HFSS. Influences of the ridge-loaded area and broad-wall dimensions on the high frequency characteristics of the novel slow-wave structure are discussed. It is shown that the folded double-ridged waveguide structure has a much wider relative passband than the folded waveguide slow-wave structure and a relative passband of 67% could be obtained, indicating that this structure can operate in broad-band frequency ranges of beam-wave interaction. The small signal gain property is investigated for ensuring the improvement of bandwidth. Meanwhile, with comparable dispersion characteristics, the transverse section dimension of this novel structure is much smaller than that of conventional one, which indicates an available way to reduce the weight of traveling-wave tube.
基金supported by the National Natural Science Foundation of China (Grant Nos 60532010 and 60401005)
文摘The periodic nonuniform folded waveguides are special structures, the physical dimension of which is between the periodic folded waveguide and the tapering period folded waveguide. Therefore, the synchronization between the microwave and the electron beam can be maintained in the whole interaction process and the periods are not tapered. In comparison with the tapering period folded waveguide, the theoretical analysis and the technological requirements for this structure are more convenient. In order to study this structure, the space harmonics are analysed, the conditions to make the rn-th space harmonic synchronizing with the electron beam in the whole interaction process are present, and the dispersion curve and the coupling impedance curve are obtained by the simulation software HFSS.
基金Supported in part by the University of Electronic Science and Technology of China,and the J.Crayton Pruitt Family Endow-ment.
文摘We assess the feasibility of our developed quantitative thermoacoustic tomography(qTAT)system for breast tumor characterization using mastectomy specimens before the clinical investigation.A circular scanning TAT system coupled with a finite-element based reconstruction algorithm is used to recover the dielectric property distribution of normal and tumor tissues from three female subjects who underwent mastectomy.Statistical method is used to analyze the tissue dielectric properties obtained.The recovered qTAT images reveal large contrast in conductivity between tumor and normal breast tissues.In addition,significant difference in conductivity exists among all the specimens examined.Finally,the recovered tumor size for these specimens agrees well with their exact size.This preclinical evaluation suggests that it is feasible to detect and characterize a breast tumor quantitatively with our qTAT method.
基金supported by the National Natural Science Foundation of China (Grant Nos. 10975036 and 61071018)the Guangxi Natural Science Foundation,China (Grant No. 2010GXNSFB013049)
文摘This paper studies the dispersion characteristics of a modified photonic band-gap slow-wave structure with an open boundary by simulation and experiment. A mode launcher with a wheel radiator and a coupling probe is presented to excite a pure TM01-like mode. The cold test and simulation results show that the TM01-like mode is effectively excited and no parasitic modes appear. The dispersion characteristics obtained from the cold test are in good agreement with the calculated results.
基金supported by the National Natural Science Foundation of China(Grant No.31470822)the Advanced Research Foundation of China(Grant Nos.9140A05030114DZ02068,9140A07030514DZ02101,and 9140A07010715DZ02001)
文摘An experimental study of leakage current is presented in a semi-insulating（SI） Ga As photoconductive semiconductor switch（PCSS） with voltages up to 5.8 kV（average field is 19.3 kV/cm）. The leakage current increases nonlinearly with the bias voltage increasing from 1.2×10^-9 A to 3.6×10^-5A. Furthermore, the dark resistance, which is characterized as a function of electric field, does not monotonically decrease with the field but displays several distinct regimes. By eliminating the field-dependent drift velocity, the free-electron density n is extracted from the current, and then the critical field for each region of n（E） characteristic of PCSS is obtained. It must be the electric field that provides the free electron with sufficient energy to activate the carrier in the trapped state via multiple physical mechanisms, such as impurity ionization, fielddependent EL2 capture, and impact ionization of donor centers EL10 and EL2. The critical fields calculated from the activation energy of these physical processes accord well with the experimental results. Moreover, agreement between the fitting curve and experimental data of J（E）, further confirms that the dark-state characteristics are related to these field-dependent processes. The effects of voltage on SI-Ga As PCSS may give us an insight into its physical mechanism.
基金supported by the National Natural Science Foundation of China(Grant No.61178018)the Ph.D.Funding Support Program of Education Ministry of China(Grant No.20110185110007)
文摘Modulation caused by surface/subsurface contaminants is one of the important factors for laser-induced damage of fused silica. In this work, a three-dimensional finite-difference time-domain （3D-FDTD） method is employed to simulate the electric field intensity distribution in the vicinity of particulate contaminants on fused silica surface. The simulated results reveal that the contaminant on both the input and output surfaces plays an important role in the electric field mod- ulation of the incident laser. The influences of the shape, size, embedded depth, dielectric constant （er）, and the number of contaminant particles on the electric field distribution are discussed in detail. Meanwhile, the corresponding physical mechanism is analyzed theoretically.
基金Project supported by the National Natural Science Foundation of China(Grant No.31470822)
文摘The mobility edge （ME） model with single Gaussian density of states （DOS） is simplified based on the recent exper- imental results about the Einstein relationship. The free holes are treated as being non-degenerate, and the trapped holes are dealt with as being degenerate. This enables the integral for the trapped holes to be easily realized in a program. The J-V curves are obtained through solving drift-diffusion equations. When this model is applied to four organic diodes, an obvious deviation between theoretical curves and experimental data is observed. In order to solve this problem, a new DOS with exponential tall is proposed. The results show that the consistence between J-V curves and experimental data based on a new DOS is far better than that based on the Gaussian DOS. The variation of extracted mobility with temperature can be well described by the Arrhenius relationship.
基金supported by the National Natural Science Foundation of China(Grant Nos.61505170,61505171,and 51535003)the Joint Fund of the National Natural Science Foundation of China+1 种基金the Chinese Academy of Engineering Physics(Grant No.U1530109)the China Postdoctoral Science Foundation(Grant No.2016M592709)
文摘The ablation debris and raised rim, as well as residual stress and deep crater will be formed during the mitigation of damage site with a CO2 laser irradiation on fused silica surface, which greatly affects the laser damage resistance of optics. In this study, the experimental study combined with numerical simulation is utilized to investigate the effect of the secondary treatment on a mitigated site by CO2laser irradiation. The results indicate that the ablation debris and the raised rim can be completely eliminated and the depth of crater can be reduced. Notable results show that the residual stress of the mitigation site after treatment will reduce two-thirds of the original stress. Finally, the elimination and the controlling mechanism of secondary treatment on the debris and raised rim, as well as the reasons for changing the profile and stress are analyzed. The results can provide a reference for the optimization treatment of mitigation sites by CO2laser secondary treatment.
