To evaluate the effect of restorative materials on stress distribution of endodontically treated teeth, the 3D models of an endodontically treated mandibular fi rst molar, restoration, and cement layer were created. T...To evaluate the effect of restorative materials on stress distribution of endodontically treated teeth, the 3D models of an endodontically treated mandibular fi rst molar, restoration, and cement layer were created. Three different materials(composite resin, ceramage and ceramic) were studied and two loading conditions(vertical and oblique load) were simulated. Mohr-Coulomb failure criterion of enamel, dentine, endocrown and cement were evaluated separately. It is indicated that under both loading conditions, the highest values of Mohr-Coulomb failure criterion were observed in Ceramage-restored group for remaining tooth structure while in ceramic-restored group for the restoration. Compared to composite resin and Ceramage, ceramic endocrown transferred less stress, namely was more protective to the tooth structure.展开更多
Electrocatalyst designs based on oxophilic foreign atoms are considered a promising approach for developing efficient pH-universal hydrogen evolution reaction(HER)electrocatalysts by overcoming the sluggish alkaline H...Electrocatalyst designs based on oxophilic foreign atoms are considered a promising approach for developing efficient pH-universal hydrogen evolution reaction(HER)electrocatalysts by overcoming the sluggish alkaline HER kinetics.Here,we design ternary transition metals-based nickel telluride(Mo WNi Te)catalysts consisting of high valence non-3d Mo and W metals and oxophilic Te as a first demonstration of non-precious heterogeneous electrocatalysts following the bifunctional mechanism.The Mo WNi Te showed excellent HER catalytic performance with overpotentials of 72,125,and 182 mV to reach the current densities of 10,100,and 1000 mA cm^(-2),respectively,and the corresponding Tafel slope of 47,52,and 58 mV dec-1in alkaline media,which is much superior to commercial Pt/C.Additionally,the HER performance of Mo WNi Te is well maintained up to 3000 h at the current density of 100 mA cm^(-2).It is further demonstrated that the Mo WNi Te exhibits remarkable HER activities with an overpotential of 45 mV(31 mV)and Tafel slope of 60 mV dec-1(34 mV dec-1)at 10 mA cm^(-2)in neutral(acid)media.The superior HER performance of Mo WNi Te is attributed to the electronic structure modulation,inducing highly active low valence states by the incorporation of high valence non-3d transition metals.It is also attributed to the oxophilic effect of Te,accelerating water dissociation kinetics through a bifunctional catalytic mechanism in alkaline media.Density functional theory calculations further reveal that such synergistic effects lead to reduced free energy for an efficient water dissociation process,resulting in remarkable HER catalytic performances within universal pH environments.展开更多
Diamond is a wide-bandgap semiconductor with a variety of crystal configurations,and has the potential applications in the field of high-frequency,radiation-hardened,and high-power devices.There are several important ...Diamond is a wide-bandgap semiconductor with a variety of crystal configurations,and has the potential applications in the field of high-frequency,radiation-hardened,and high-power devices.There are several important polytypes of diamonds,such as cubic diamond,lonsdaleite,and nanotwinned diamond(NTD).The thermal conductivities of semiconductors in high-power devices at different temperatures should be calculated.However,there has been no reports about thermal conductivities of cubic diamond and its polytypes both efficiently and accurately based on molecular dynamics(MD).Here,using interatomic potential of neural networks can provide obvious advantages.For example,comparing with the use of density functional theory(DFT),the calculation time is reduced,while maintaining high accuracy in predicting the thermal conductivities of the above-mentioned three diamond polytypes.Based on the neuroevolution potential(NEP),the thermal conductivities of cubic diamond,lonsdaleite,and NTD at 300 K are respectively 2507.3 W·m^(-1)·K^(-1),1557.2 W·m^(-1)·K^(-1),and 985.6 W·m^(-1)·K^(-1),which are higher than the calculation results based on Tersoff-1989 potential(1508 W·m^(-1)·K^(-1),1178 W·m^(-1)·K^(-1),and 794 W·m^(-1)·K^(-1),respectively).The thermal conductivities of cubic diamond and lonsdaleite,obtained by using the NEP,are closer to the experimental data or DFT data than those from Tersoff-potential.The molecular dynamics simulations are performed by using NEP to calculate the phonon dispersions,in order to explain the possible reasons for discrepancies among the cubic diamond,lonsdaleite,and NTD.In this work,we propose a scheme to predict the thermal conductivity of cubic diamond,lonsdaleite,and NTD precisely and efficiently,and explain the differences in thermal conductivity among cubic diamond,lonsdaleite,and NTD.展开更多
CrTiAlN/TiAlN composite coatings were deposited on cemented carbide by using a home-made industrial scale multi-arc ion plating system. The samples were studied by X-ray diffraction, scanning electron microscopy(SEM),...CrTiAlN/TiAlN composite coatings were deposited on cemented carbide by using a home-made industrial scale multi-arc ion plating system. The samples were studied by X-ray diffraction, scanning electron microscopy(SEM), microhardness and ball-on-disk testing. The properties of the CrTiAlN/TiAlN coatings were significantly influenced by the microstructure and the deposition time ratio of TiAlN over CrTiAlN layers. With the increase of deposition time ratio, the microhardness of CrTiAlN/TiAlN increased from 28.6 GPa to 37.5 GPa, much higher than that of CrTiAlN coatings. The friction coefficients of the CrTiAlN/TiAlN coatings were higher than those of CrTiAlN coatings against a cemented carbide ball. The microhardness of the CrTiAlN/TiAlN coatings was changed after annealing at 800 oC, and the friction coefficients of the annealed coatings were increased against the cemented carbide ball.展开更多
Chemical inclusions significantly alter shock responses of crystalline explosives in macroscale gap experiments but their microscale dynamics origin remains unclear.Herein shock-induced energy localization,overall phy...Chemical inclusions significantly alter shock responses of crystalline explosives in macroscale gap experiments but their microscale dynamics origin remains unclear.Herein shock-induced energy localization,overall physical responses,and reactions in a-1,3,5-trinitro-1,3,5-triazinane(a-RDX)crystal entrained various chemical inclusions were investigated by the multi-scale shock technique implemented in the reactive molecular dynamics method.Results indicated that energy localization and shock reaction were affected by the intrinsic factors within chemical inclusions,i.e.,phase states,chemical compositions,and concentrations.The atomic origin of chemical-inclusions effects on energy localization is dependent on the dynamics mechanism of interfacial molecules with free space volume,which includes homogeneous intermolecular compression,interfacial impact and shear,and void collapse and jet.As introducing various chemical inclusions,the initiation of those dynamics mechanisms triggers diverse decay rates of bulk RDX molecules and hereby impacts on growth speeds of final reactions.Adding chemical inclusions can reduce the effectiveness of the void during the shock impacting.Under the shockwave velocity of 9 km/s,the parent RDX decay rate in RDX entrained amorphous carbon decreases the most and is about one fourth of that in RDX with a vacuum void,and solid HMX and TATB inclusions are more reactive than amorphous carbon but less reactive than dry air or acetone inclusions.The lessdense shocking system denotes the greater increases in local temperature and stress,the faster energy liberation,and the earlier final reaction into equilibrium,revealing more pronounced responses to the present intense shockwave.The quantitative models associated with the relative system density(RD_(sys))were proposed for indicating energy-localization mechanisms and evaluating initiation safety in the shocked crystalline explosive.RD_(sys)is defined by the density ratio of defective RDX to perfect crystal after dynamics relaxation and reveals the global density characteristic in shocked systems filled with chemical inclusions.When RD_(sys)is below 0.9,local hydrodynamic jet initiated by void collapse dominates upon energy localization instead of interfacial impact.This study sheds light on novel insights for understanding the shock chemistry and physical-based atomic origin in crystalline explosives considering chemical-inclusions effects.展开更多
Based on the momentum theorem,the fluid governing equation in a lifting pipe is proposed by use of the method combining theoretical analysis with empirical correlations related to the previous research,and the perform...Based on the momentum theorem,the fluid governing equation in a lifting pipe is proposed by use of the method combining theoretical analysis with empirical correlations related to the previous research,and the performance of an airlift pump can be clearly characterized by the triangular relationship among the volumetric flux of air,water and solid particles,which are obtained respectively by using numerical calculation.The meso-scale river sand is used as tested particles to examine the theoretical model.Results of the model are compared with the data in three-phase flow obtained prior to the development of the present model,by an independent experimental team that used the physical conditions of the present approach.The analytical error can be controlled within 12% for predicting the volumetric flux of water and is smaller than that(±16%) of transporting solid particles in three-phase flow.The experimental results and computations are in good agreement for air?water two-phase flow within a margin of ±8%.Reasonable agreement justifies the use of the present model for engineering design purposes.展开更多
The performance of an annular jet pump( AJP) is determined by its area ratio A( ratio of cross sectional area of throat and annular nozzle) and flow rate ratio q( ratio of primary and secondary flow rate,Qs/Qj),while ...The performance of an annular jet pump( AJP) is determined by its area ratio A( ratio of cross sectional area of throat and annular nozzle) and flow rate ratio q( ratio of primary and secondary flow rate,Qs/Qj),while the nozzle lip thickness is neglected in the present studies. This paper presents a study on the effect of the thickness on the flow field and performance of an AJP with A = 1. 75. With the increasing flow rate ratio and nozzle lip thickness,a small vortex forms at the nozzle lip and keeps on growing. However,as the flow rate ratio or nozzle lip thickness is extremely low,the vortex at the lip vanishes thoroughly. Moreover,the recirculation width varies conversely with the nozzle lip thickness when the flow rate ratio q ≤ 0. 13. While the deviation of the recirculation width with different nozzle lip thickness is negligible with q ≥ 0. 13. Additionally the existence of nozzle lip hinders the momentum exchange between the primary and secondary flow and leads to a mutation of velocity gradient near the nozzle exit,which shift the recirculation downstream. Finally,based on the numerical results of the streamwise and spanwise vortex distributions in the suction chamber, the characteristics of the mixing process and the main factors accounting for the AJP performance are clarified.展开更多
In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (...In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thoroughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materials, and hold potential for enhancing their mechanical, chemical, optical and electronic properties.展开更多
Morphology of hydraulic fracture surface has significant effects on oil and gas flow,proppant migration and fracture closure,which plays an important role in oil and gas fracturing stimulation.In this paper,we analyze...Morphology of hydraulic fracture surface has significant effects on oil and gas flow,proppant migration and fracture closure,which plays an important role in oil and gas fracturing stimulation.In this paper,we analyzed the fracture surface characteristics induced by supercritical carbon dioxide(SC-CO_(2))and water in open-hole and perforation completion conditions under triaxial stresses.A simple calculation method was proposed to quantitatively analyze the fracture surface area and roughness in macro-level based on three-dimensional(3D)scanning data.In micro-level,scanning electron micrograph(SEM)was used to analyze the features of fracture surface.The results showed that the surface area of the induced fracture increases with perforation angle for both SC-CO_(2)and water fracturing,and the surface area of SC-CO_(2)-induced fracture is 6.49%e58.57%larger than that of water-induced fracture.The fractal dimension and surface roughness of water-induced fractures increase with the increase in perforation angle,while those of SC-CO_(2)-induced fractures decrease with the increasing perforation angle.A considerable number of microcracks and particle peeling pits can be observed on SC-CO_(2)-induced fracture surface while there are more flat particle surfaces in water-induced fracture surface through SEM images,indicating that fractures tend to propagate along the boundary of the particle for SC-CO_(2)fracturing while water-induced fractures prefer to cut through particles.These findings are of great significance for analyzing fracture mechanism and evaluating fracturing stimulation performance.展开更多
The pinion bracket-assembly(PBA) is a major part of three gorges project(TGP) ship lift drive system. The static strength,fatigue strength and stress distribution of hinge pin of PBA were analyzed by ANSYS, and the st...The pinion bracket-assembly(PBA) is a major part of three gorges project(TGP) ship lift drive system. The static strength,fatigue strength and stress distribution of hinge pin of PBA were analyzed by ANSYS, and the structure of PBA was optimized. The results show that after the optimization, the maximum comprehensive stress is 259.59 MPa, the maximum fatigue cumulative damage of weld joints is 0.94 and the maximum vertical deformation of hinge pin is 0.14 mm. The elastic deformation, hydropneumatic spring cylinder(HSC) load response and the vibration characteristics of PBA were studied by the bearing test when PBA bore the load caused by different water level errors. The results indicate that when the water level of ship chamber ranges from 3.4 m to 3.6 m,the vertical elastic deformation of the pinion shaft is between-8.58 and 10.50 mm. When upward outage-load(1580 k N) is imposed by the test-rack, the vertical elastic deformation of the pinion shaft is 13.42 and 14.07 mm and HSC load response is 795.80-800.80 k N. In the process of imposing load on the pinion by the test-rack, the maximum vibration amplitude and acceleration of PBA internal components are 0.37° and 2.67 rad/s2, respectively; the maximum impact on the pin caused by vibration is 19.89 k N; the pinion shaft vertical displacement and HSC load response do not fluctuate. There is a great difference between the frequency of meshing force of the pinion and the rack(1.06 Hz) and first-order natural frequency of PBA(8.41 Hz), thus PBA will not resonate.From all above, PBA meets the static strength and fatigue strength requirements. The vibration of PBA internal components has no effect on the vertical displacement of the pinion shaft, HSC load response and smooth operation of PBA. There is a liner relationship in the ratio of 2:1 between the thrust imposed by the test-rack and HSC load, thus HSC can limit the load imposed on the pinion.展开更多
The subgrid-scale(SGS)stress and SGS heat flux are modeled by using an artificial neural network(ANN)for large eddy simulation(LES)of compressible turbulence.The input features of ANN model are based on the first-orde...The subgrid-scale(SGS)stress and SGS heat flux are modeled by using an artificial neural network(ANN)for large eddy simulation(LES)of compressible turbulence.The input features of ANN model are based on the first-order and second-order derivatives of filtered velocity and temperature at different spatial locations.The proposed spatial artificial neural network(SANN)model gives much larger correlation coefficients and much smaller relative errors than the gradient model in an a priori analysis.In an a posteriori analysis,the SANN model performs better than the dynamic mixed model(DMM)in the prediction of spectra and statistical properties of velocity and temperature,and the instantaneous flow structures.展开更多
The mechanical properties, creep rupture strength, creep damage and failure characteristics of dissimilar metal welded joint (DMWJ) between martensitic (SA213T91) and bainitic heat-resistant steel (12Cr2MoWVTiB(G102))...The mechanical properties, creep rupture strength, creep damage and failure characteristics of dissimilar metal welded joint (DMWJ) between martensitic (SA213T91) and bainitic heat-resistant steel (12Cr2MoWVTiB(G102)) have been investigated by means of pulsed argon arc welding, high temperature accelerated simulation, mechanical and creep rupture test, and scanning electronic microscope (SEM). The results show that there is a marked drop of mechanical properties of undermatching joint, and low ductility cracking along weld/G102 interface is induced due to creep damage. Creep rupture strength of overmatching joint is the least. The mechanical properties of medium matching joint are superior to those of overmatching and undermatching joint, and creep damage and failure tendency along the interface of weld /G102 are lower than those of overmatching and undermatching joint after accelerated simulation for 500 h, 1 000 h, 1 500 h, and the creep rupture strength of medium matching joint is the same as that of undermatching joint. Therefore, it is reasonable that the medium matching material is used for dissimilar welded joint between martensitic and bainitic steel.展开更多
Currently,wire bonding is the most popular first-level interconnection technology used between the die and package terminals,but even with its long-term and excessive usage,the mechanism of wire bonding has not been c...Currently,wire bonding is the most popular first-level interconnection technology used between the die and package terminals,but even with its long-term and excessive usage,the mechanism of wire bonding has not been completely evaluated.Therefore,fundamental research is still needed.In this study,the mechanism of microweld formation and breakage during Cu-Cu wire bonding was investigated by using molecular dynamics simulation.The contact model for the nanoindentation process between the wire and substrate was developed to simulate the contact process of the Cu wire and Cu substrate.Elastic contact and plastic instability were investigated through the loading and unloading processes.Moreover,the evolution of the indentation morphology and distributions of the atomic stress were also investigated.It was shown that the loading and unloading curves do not coincide,and the unloading curve exhibited hysteresis.For the substrate,in the loading process,the main force changed from attractive to repulsive.The maximum von Mises stress increased and shifted from the center toward the edge of the contact area.During the unloading process,the main force changed from repulsive to attractive.The Mises stress reduced first and then increased.Stress concentration occurs around dislocations in the middle area of the Cu wire.展开更多
High entropy alloys(HEAs)with multi-component solid solution microstructures have the potential for large-scale industrial applications due to their excellent mechanical and functional properties.However,the mechanica...High entropy alloys(HEAs)with multi-component solid solution microstructures have the potential for large-scale industrial applications due to their excellent mechanical and functional properties.However,the mechanical properties of HEAs limit the selection of processing technologies.Additive manufacturing technology possesses strong processing adaptability,making itthe best candidate method to overcome this issue.This comprehensive review examines the current state of selective laser melting(SLM)of HEAs.Introducing SLM to HEAs processing is motivated by its high quality for dimensional accuracy,geometric complexity,surface roughness,and microstructure.This review focuses on analyzing the current developments and challenges in SLM of HEAs,including defects,microstructures,and properties,as well as strengthing prediction models of fabricated HEAs.This review also offers directions for future studies to address existing challenges and promote technological advancement.展开更多
In order to solve the problems including pipe corrosion, scaling and microbial growth, which severely threat safe op-eration of circulating cooling water system, this paper proposes ion exchange softening and alkaliza...In order to solve the problems including pipe corrosion, scaling and microbial growth, which severely threat safe op-eration of circulating cooling water system, this paper proposes ion exchange softening and alkalization process to solve these problems and carries out a series of studies to study the feasibility of ion exchange softening and alkaliza-tion process in the simulation process of circulating cooling water system. The studies include product water quality of ion exchange softening and alkalization process, effect on the performance of carbon steel and brass, and the inhibition that suppresses microbial growth. The results indicate that ion exchange softening and alkalization process is feasible to prevent the circulating cooling water system from scaling, pipe corrosion, and microbial growth without any other chemicals. Thus circulating cooling water system can achieve zerodischarge of wastewater.展开更多
TiBCN films were deposited on Si(100) and cemented carbide substrates by using multi-cathodic arc ion plating in C_2H_2 and N_2atmosp^here. Their structure and mechanical properties were studied systematically under d...TiBCN films were deposited on Si(100) and cemented carbide substrates by using multi-cathodic arc ion plating in C_2H_2 and N_2atmosp^here. Their structure and mechanical properties were studied systematically under different N_2 flow rates. The results showed that the Ti BCN films were adhered well to the substrates. Rutherford backscattering sp^ectroscopy was employed to determine the relative concentration of Ti, B, C and N in the films.The chemical bonding states of the films were explored by X-ray photoelectron sp^ectroscopy, revealing the presence of bonds of Ti N, Ti(C,N), BN, pure B, sp^2C–C and sp^3C–C, which changed with the N_2 flow rate. Ti BCN films contain nanocrystals of Ti N/Ti CN and Ti B_2/Ti(B,C)embedded in an amorphous matrix consisting of amorphous BN and carbon at N_2 flow rate of up to 250 sccm.展开更多
Nanocomposite Cr C/hydrogenated amorphous carbon(nc-CrC/a-C:H) coatings were deposited by a hybrid beams system comprised of a hollow cathode ion source and a cathodic arc ion-plating unit with varying H_2 flow rates....Nanocomposite Cr C/hydrogenated amorphous carbon(nc-CrC/a-C:H) coatings were deposited by a hybrid beams system comprised of a hollow cathode ion source and a cathodic arc ion-plating unit with varying H_2 flow rates. The influences of H_2 flow rates on the morphologies, microstructures, and properties of the coatings were systematically studied. The morphologies and microstructures of the coatings were characterized by SEM, AFM, XPS, Raman spectroscopy, GIXRD, and HRTEM. The mechanical and tribological properties were measured by a nano-indenter, scratch tester, and ball-ondisk tribometer. The wear tracks were evaluated using 3D profilometer, optical microscope, and EDS analysis. It has been found that a moderate H_2 flow rate can effectively smooth the surface, enlarge the fraction of a sp^3 bond, and improve the properties. The coating exhibits the highest hardness and elastic modulus at the H_2 flow rate of 40 sccm. A superior combination of adhesion strength,friction coefficient, and wear resistance can be achieved at the H_2 flow rate of 80 sccm.展开更多
The carbon fiber reinforced composite is a new type of composite material with an excellent property in strength and elastic modulus,and has found extensive applications in aerospace,energy,automotive industry and so ...The carbon fiber reinforced composite is a new type of composite material with an excellent property in strength and elastic modulus,and has found extensive applications in aerospace,energy,automotive industry and so on.However,this composite has a strict requirement on processing techniques,for example,brittle damage or delamination often exists in conventional processing techniques.Abrasive water jet machining technology is a new type of green machining technique with distinct advantages such as high-energy and thermal distortion free.The use of abrasive water jet technique to process carbon fiber composite materials has become a popular trend since it can significantly improve the processing accuracy and surface quality of carbon fiber composite materials.However,there are too many parameters that affect the quality of an abrasive water jet machining.At present,few studies are carried out on the parameter optimization of such a machining process,which leads to the unstable quality of surface processing.In this paper,orthogonal design of experiment and regression analysis were employed to establish the empirical model between cutting surface roughness and machining process parameters.Then a verified model was used to optimize the machining process parameters for abrasive water jet cutting carbon fiber reinforced composites.展开更多
Making use of microsoft visual studio. net platform, the assistant decision-making system of tunnel boring machine in tunnelling has been built to predict the time and cost. Computation methods of the performance para...Making use of microsoft visual studio. net platform, the assistant decision-making system of tunnel boring machine in tunnelling has been built to predict the time and cost. Computation methods of the performance parameters have been discussed. New time and cost prediction models have been depicted. The multivariate linear regression has been used to make the parameters more precise, which are the key factor to affect the prediction near to the reality.展开更多
To improve the rock breaking ability, cavitating waterjet and abrasive waterjet are combined by using a coaxial low-speed waterjet generated around the periphery of a high-speed abrasive waterjet, and a new type of wa...To improve the rock breaking ability, cavitating waterjet and abrasive waterjet are combined by using a coaxial low-speed waterjet generated around the periphery of a high-speed abrasive waterjet, and a new type of waterjet called unsubmerged cavitating abrasive waterjet(UCAWJ) is thus produced. The rock breaking performance of UCAWJ was compared with submerged cavitating abrasive waterjet(SCAWJ)and unsubmerged abrasive waterjet(UAWJ) by impinging sandstone specimens. Moreover, the effects of jet pressure, standoff distance, abrasive flow rate and concentration were studied by evaluating the specific energy consumption, and the area, depth, and mass loss of the eroded specimen. The results show that the artificially generated submerged environment in UCAWJ is able to enhance the rock breaking performance under the same operating parameters. Furthermore, the rock breaking performance of UCAWJ is much better at higher jet pressures and smaller standoff distances when compared with UAWJ. The greatest rock breaking ability of UCAWJ appears at jet pressure of 50 MPa and standoff distance of 32 mm, with the mass loss of sandstone increased by 370.6% and the energy dissipation decreased by 75.8%. In addition, under the experimental conditions the optimal abrasive flow rate and concentration are 76.5 m L/min and 3%, respectively.展开更多
基金Founded by National Natural Science Foundation of China(No.51305306)Hubei Province Science and Technology Support Program(No.2013BCB025)Fundamental Research Funds for the Central University(No.2042014kf0274)
文摘To evaluate the effect of restorative materials on stress distribution of endodontically treated teeth, the 3D models of an endodontically treated mandibular fi rst molar, restoration, and cement layer were created. Three different materials(composite resin, ceramage and ceramic) were studied and two loading conditions(vertical and oblique load) were simulated. Mohr-Coulomb failure criterion of enamel, dentine, endocrown and cement were evaluated separately. It is indicated that under both loading conditions, the highest values of Mohr-Coulomb failure criterion were observed in Ceramage-restored group for remaining tooth structure while in ceramic-restored group for the restoration. Compared to composite resin and Ceramage, ceramic endocrown transferred less stress, namely was more protective to the tooth structure.
基金supported through the National Research Foundation of Korea(NRF)funded by the Ministry of Science and ICT(2022M3H4A1A04096478)the support from the Supercomputing Center of Wuhan University。
文摘Electrocatalyst designs based on oxophilic foreign atoms are considered a promising approach for developing efficient pH-universal hydrogen evolution reaction(HER)electrocatalysts by overcoming the sluggish alkaline HER kinetics.Here,we design ternary transition metals-based nickel telluride(Mo WNi Te)catalysts consisting of high valence non-3d Mo and W metals and oxophilic Te as a first demonstration of non-precious heterogeneous electrocatalysts following the bifunctional mechanism.The Mo WNi Te showed excellent HER catalytic performance with overpotentials of 72,125,and 182 mV to reach the current densities of 10,100,and 1000 mA cm^(-2),respectively,and the corresponding Tafel slope of 47,52,and 58 mV dec-1in alkaline media,which is much superior to commercial Pt/C.Additionally,the HER performance of Mo WNi Te is well maintained up to 3000 h at the current density of 100 mA cm^(-2).It is further demonstrated that the Mo WNi Te exhibits remarkable HER activities with an overpotential of 45 mV(31 mV)and Tafel slope of 60 mV dec-1(34 mV dec-1)at 10 mA cm^(-2)in neutral(acid)media.The superior HER performance of Mo WNi Te is attributed to the electronic structure modulation,inducing highly active low valence states by the incorporation of high valence non-3d transition metals.It is also attributed to the oxophilic effect of Te,accelerating water dissociation kinetics through a bifunctional catalytic mechanism in alkaline media.Density functional theory calculations further reveal that such synergistic effects lead to reduced free energy for an efficient water dissociation process,resulting in remarkable HER catalytic performances within universal pH environments.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.62004141 and 52202045)the Fundamental Research Funds for the Central Universities,China (Grant Nos.2042022kf1028 and 2042023kf0112)+2 种基金the Knowledge Innovation Program of Wuhan-Shuguang,China (Grant Nos.2023010201020243 and 2023010201020255)the Natural Science Foundation of Hubei Province,China (Grant No.2022CFB606)the Guangdong Basic and Applied Basic Research Fund:Guangdong–Shenzhen Joint Fund,China (Grant No.2020B1515120005)。
文摘Diamond is a wide-bandgap semiconductor with a variety of crystal configurations,and has the potential applications in the field of high-frequency,radiation-hardened,and high-power devices.There are several important polytypes of diamonds,such as cubic diamond,lonsdaleite,and nanotwinned diamond(NTD).The thermal conductivities of semiconductors in high-power devices at different temperatures should be calculated.However,there has been no reports about thermal conductivities of cubic diamond and its polytypes both efficiently and accurately based on molecular dynamics(MD).Here,using interatomic potential of neural networks can provide obvious advantages.For example,comparing with the use of density functional theory(DFT),the calculation time is reduced,while maintaining high accuracy in predicting the thermal conductivities of the above-mentioned three diamond polytypes.Based on the neuroevolution potential(NEP),the thermal conductivities of cubic diamond,lonsdaleite,and NTD at 300 K are respectively 2507.3 W·m^(-1)·K^(-1),1557.2 W·m^(-1)·K^(-1),and 985.6 W·m^(-1)·K^(-1),which are higher than the calculation results based on Tersoff-1989 potential(1508 W·m^(-1)·K^(-1),1178 W·m^(-1)·K^(-1),and 794 W·m^(-1)·K^(-1),respectively).The thermal conductivities of cubic diamond and lonsdaleite,obtained by using the NEP,are closer to the experimental data or DFT data than those from Tersoff-potential.The molecular dynamics simulations are performed by using NEP to calculate the phonon dispersions,in order to explain the possible reasons for discrepancies among the cubic diamond,lonsdaleite,and NTD.In this work,we propose a scheme to predict the thermal conductivity of cubic diamond,lonsdaleite,and NTD precisely and efficiently,and explain the differences in thermal conductivity among cubic diamond,lonsdaleite,and NTD.
基金supported by the International Cooperation Program of the Ministry of Science and Technology of China(No.2011DFR50580)Basic Research Funds of the Central Universities of China(No.2012202020217)
文摘CrTiAlN/TiAlN composite coatings were deposited on cemented carbide by using a home-made industrial scale multi-arc ion plating system. The samples were studied by X-ray diffraction, scanning electron microscopy(SEM), microhardness and ball-on-disk testing. The properties of the CrTiAlN/TiAlN coatings were significantly influenced by the microstructure and the deposition time ratio of TiAlN over CrTiAlN layers. With the increase of deposition time ratio, the microhardness of CrTiAlN/TiAlN increased from 28.6 GPa to 37.5 GPa, much higher than that of CrTiAlN coatings. The friction coefficients of the CrTiAlN/TiAlN coatings were higher than those of CrTiAlN coatings against a cemented carbide ball. The microhardness of the CrTiAlN/TiAlN coatings was changed after annealing at 800 oC, and the friction coefficients of the annealed coatings were increased against the cemented carbide ball.
基金the financial support from National Natural Science Foundation of China(Grant Nos.11872119,12172051,and 11972329)Natural Science Foundation of Hubei Province(Grant No.2021CFB120)。
文摘Chemical inclusions significantly alter shock responses of crystalline explosives in macroscale gap experiments but their microscale dynamics origin remains unclear.Herein shock-induced energy localization,overall physical responses,and reactions in a-1,3,5-trinitro-1,3,5-triazinane(a-RDX)crystal entrained various chemical inclusions were investigated by the multi-scale shock technique implemented in the reactive molecular dynamics method.Results indicated that energy localization and shock reaction were affected by the intrinsic factors within chemical inclusions,i.e.,phase states,chemical compositions,and concentrations.The atomic origin of chemical-inclusions effects on energy localization is dependent on the dynamics mechanism of interfacial molecules with free space volume,which includes homogeneous intermolecular compression,interfacial impact and shear,and void collapse and jet.As introducing various chemical inclusions,the initiation of those dynamics mechanisms triggers diverse decay rates of bulk RDX molecules and hereby impacts on growth speeds of final reactions.Adding chemical inclusions can reduce the effectiveness of the void during the shock impacting.Under the shockwave velocity of 9 km/s,the parent RDX decay rate in RDX entrained amorphous carbon decreases the most and is about one fourth of that in RDX with a vacuum void,and solid HMX and TATB inclusions are more reactive than amorphous carbon but less reactive than dry air or acetone inclusions.The lessdense shocking system denotes the greater increases in local temperature and stress,the faster energy liberation,and the earlier final reaction into equilibrium,revealing more pronounced responses to the present intense shockwave.The quantitative models associated with the relative system density(RD_(sys))were proposed for indicating energy-localization mechanisms and evaluating initiation safety in the shocked crystalline explosive.RD_(sys)is defined by the density ratio of defective RDX to perfect crystal after dynamics relaxation and reveals the global density characteristic in shocked systems filled with chemical inclusions.When RD_(sys)is below 0.9,local hydrodynamic jet initiated by void collapse dominates upon energy localization instead of interfacial impact.This study sheds light on novel insights for understanding the shock chemistry and physical-based atomic origin in crystalline explosives considering chemical-inclusions effects.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.51374101 and 51474158)the National Basic Research Program of China(973 Program,Grant No.2014CB239203)the Scientific Research Project of Education Department of Hunan Province(Grant No.14B047)
文摘Based on the momentum theorem,the fluid governing equation in a lifting pipe is proposed by use of the method combining theoretical analysis with empirical correlations related to the previous research,and the performance of an airlift pump can be clearly characterized by the triangular relationship among the volumetric flux of air,water and solid particles,which are obtained respectively by using numerical calculation.The meso-scale river sand is used as tested particles to examine the theoretical model.Results of the model are compared with the data in three-phase flow obtained prior to the development of the present model,by an independent experimental team that used the physical conditions of the present approach.The analytical error can be controlled within 12% for predicting the volumetric flux of water and is smaller than that(±16%) of transporting solid particles in three-phase flow.The experimental results and computations are in good agreement for air?water two-phase flow within a margin of ±8%.Reasonable agreement justifies the use of the present model for engineering design purposes.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51179134)the National Key Basic Research Program of China(Grant No.2014CB239203)Program for New Century Excellent Talents in University(Grant No.NCET-12-0424)
文摘The performance of an annular jet pump( AJP) is determined by its area ratio A( ratio of cross sectional area of throat and annular nozzle) and flow rate ratio q( ratio of primary and secondary flow rate,Qs/Qj),while the nozzle lip thickness is neglected in the present studies. This paper presents a study on the effect of the thickness on the flow field and performance of an AJP with A = 1. 75. With the increasing flow rate ratio and nozzle lip thickness,a small vortex forms at the nozzle lip and keeps on growing. However,as the flow rate ratio or nozzle lip thickness is extremely low,the vortex at the lip vanishes thoroughly. Moreover,the recirculation width varies conversely with the nozzle lip thickness when the flow rate ratio q ≤ 0. 13. While the deviation of the recirculation width with different nozzle lip thickness is negligible with q ≥ 0. 13. Additionally the existence of nozzle lip hinders the momentum exchange between the primary and secondary flow and leads to a mutation of velocity gradient near the nozzle exit,which shift the recirculation downstream. Finally,based on the numerical results of the streamwise and spanwise vortex distributions in the suction chamber, the characteristics of the mixing process and the main factors accounting for the AJP performance are clarified.
基金supported by the National Natural Science Foundation of China (11272357 and 11102140)Doctoral Fund of Ministry of Education of China (200804251520 and 20110141120024)Natural Science Foundation of Shandong Province (ZR2009AQ006)
文摘In this study, we developed a general method to analytically tackle a kind of movable boundary problem from the viewpoint of energy variation. Having grouped the adhesion of a micro-beam, droplet and carbon nanotube (CNT) ring on a substrate into one framework, we used the developed line of reasoning to investigate the adhesion behaviors of these systems. Based upon the derived governing equations and transversality conditions, explicit solutions involving the critical parameters and morphologies for the three systems are successfully obtained, and then the parameter analogies and common characteristics of them are thoroughly investigated. The presented method has been verified via the concept of energy release rate in fracture mechanics. Our analyses provide a new approach for exploring the mechanism of different systems with similarities as well as for understanding the unity of nature. The analysis results may be beneficial for the design of nano-structured materials, and hold potential for enhancing their mechanical, chemical, optical and electronic properties.
基金National Natural Science Foundation of China(Grant No.51804318)the China Postdoctoral Science Foundation Founded Project(Grant No.2019M650963)National Key Basic Research and Development Program of China(Grant No.2014CB239203).
文摘Morphology of hydraulic fracture surface has significant effects on oil and gas flow,proppant migration and fracture closure,which plays an important role in oil and gas fracturing stimulation.In this paper,we analyzed the fracture surface characteristics induced by supercritical carbon dioxide(SC-CO_(2))and water in open-hole and perforation completion conditions under triaxial stresses.A simple calculation method was proposed to quantitatively analyze the fracture surface area and roughness in macro-level based on three-dimensional(3D)scanning data.In micro-level,scanning electron micrograph(SEM)was used to analyze the features of fracture surface.The results showed that the surface area of the induced fracture increases with perforation angle for both SC-CO_(2)and water fracturing,and the surface area of SC-CO_(2)-induced fracture is 6.49%e58.57%larger than that of water-induced fracture.The fractal dimension and surface roughness of water-induced fractures increase with the increase in perforation angle,while those of SC-CO_(2)-induced fractures decrease with the increasing perforation angle.A considerable number of microcracks and particle peeling pits can be observed on SC-CO_(2)-induced fracture surface while there are more flat particle surfaces in water-induced fracture surface through SEM images,indicating that fractures tend to propagate along the boundary of the particle for SC-CO_(2)fracturing while water-induced fractures prefer to cut through particles.These findings are of great significance for analyzing fracture mechanism and evaluating fracturing stimulation performance.
基金Project(SPKJ016-06)supported by the Key Research Project of State Power Corporation,ChinaProject(2004AC1O1D31)supported by the Key Scientific Research Project of Hubei Province,ChinaProject(0722018)supported by the China Three Gorges Corporation
文摘The pinion bracket-assembly(PBA) is a major part of three gorges project(TGP) ship lift drive system. The static strength,fatigue strength and stress distribution of hinge pin of PBA were analyzed by ANSYS, and the structure of PBA was optimized. The results show that after the optimization, the maximum comprehensive stress is 259.59 MPa, the maximum fatigue cumulative damage of weld joints is 0.94 and the maximum vertical deformation of hinge pin is 0.14 mm. The elastic deformation, hydropneumatic spring cylinder(HSC) load response and the vibration characteristics of PBA were studied by the bearing test when PBA bore the load caused by different water level errors. The results indicate that when the water level of ship chamber ranges from 3.4 m to 3.6 m,the vertical elastic deformation of the pinion shaft is between-8.58 and 10.50 mm. When upward outage-load(1580 k N) is imposed by the test-rack, the vertical elastic deformation of the pinion shaft is 13.42 and 14.07 mm and HSC load response is 795.80-800.80 k N. In the process of imposing load on the pinion by the test-rack, the maximum vibration amplitude and acceleration of PBA internal components are 0.37° and 2.67 rad/s2, respectively; the maximum impact on the pin caused by vibration is 19.89 k N; the pinion shaft vertical displacement and HSC load response do not fluctuate. There is a great difference between the frequency of meshing force of the pinion and the rack(1.06 Hz) and first-order natural frequency of PBA(8.41 Hz), thus PBA will not resonate.From all above, PBA meets the static strength and fatigue strength requirements. The vibration of PBA internal components has no effect on the vertical displacement of the pinion shaft, HSC load response and smooth operation of PBA. There is a liner relationship in the ratio of 2:1 between the thrust imposed by the test-rack and HSC load, thus HSC can limit the load imposed on the pinion.
基金This work was supported by the National Natural Science Foundation of China(Grants 91952104,11702127,and 91752201)the Technology and Innovation Commission of Shenzhen Municipality(Grants KQTD20180411143441009,JCYJ20170412151759222,and ZDSYS201802081843517).This work was also supported by Center for Computational Science and Engineering of Southern University of Science and Technology.J.Wang acknowledges the support from Young Elite Scientist Sponsorship Program by CAST(Grant 2016QNRC001).
文摘The subgrid-scale(SGS)stress and SGS heat flux are modeled by using an artificial neural network(ANN)for large eddy simulation(LES)of compressible turbulence.The input features of ANN model are based on the first-order and second-order derivatives of filtered velocity and temperature at different spatial locations.The proposed spatial artificial neural network(SANN)model gives much larger correlation coefficients and much smaller relative errors than the gradient model in an a priori analysis.In an a posteriori analysis,the SANN model performs better than the dynamic mixed model(DMM)in the prediction of spectra and statistical properties of velocity and temperature,and the instantaneous flow structures.
基金Funded by State Key Lab of Advanced Welding and Joint,Harbin Institute of Technology(No.09014)the Natural Science Foundation of Hubei Province in China(No.2007ABA040)
文摘The mechanical properties, creep rupture strength, creep damage and failure characteristics of dissimilar metal welded joint (DMWJ) between martensitic (SA213T91) and bainitic heat-resistant steel (12Cr2MoWVTiB(G102)) have been investigated by means of pulsed argon arc welding, high temperature accelerated simulation, mechanical and creep rupture test, and scanning electronic microscope (SEM). The results show that there is a marked drop of mechanical properties of undermatching joint, and low ductility cracking along weld/G102 interface is induced due to creep damage. Creep rupture strength of overmatching joint is the least. The mechanical properties of medium matching joint are superior to those of overmatching and undermatching joint, and creep damage and failure tendency along the interface of weld /G102 are lower than those of overmatching and undermatching joint after accelerated simulation for 500 h, 1 000 h, 1 500 h, and the creep rupture strength of medium matching joint is the same as that of undermatching joint. Therefore, it is reasonable that the medium matching material is used for dissimilar welded joint between martensitic and bainitic steel.
基金the National Key R&D Program of China(Grant No.2019YFB1704600)the Hubei Provincial Natural Science Foundation of China(Grant No.2020CFA032).
文摘Currently,wire bonding is the most popular first-level interconnection technology used between the die and package terminals,but even with its long-term and excessive usage,the mechanism of wire bonding has not been completely evaluated.Therefore,fundamental research is still needed.In this study,the mechanism of microweld formation and breakage during Cu-Cu wire bonding was investigated by using molecular dynamics simulation.The contact model for the nanoindentation process between the wire and substrate was developed to simulate the contact process of the Cu wire and Cu substrate.Elastic contact and plastic instability were investigated through the loading and unloading processes.Moreover,the evolution of the indentation morphology and distributions of the atomic stress were also investigated.It was shown that the loading and unloading curves do not coincide,and the unloading curve exhibited hysteresis.For the substrate,in the loading process,the main force changed from attractive to repulsive.The maximum von Mises stress increased and shifted from the center toward the edge of the contact area.During the unloading process,the main force changed from repulsive to attractive.The Mises stress reduced first and then increased.Stress concentration occurs around dislocations in the middle area of the Cu wire.
基金This research is financially supported by the National Key Research and Development Program of China(Grant Nos.2017YFB1103900 and 2018YFB1107701)the Fundamental Research Funds for the Central Universities(Grant No.2042019kf0015)+1 种基金the Key R&D projects of Sichuan Province(Grant No.2020YFSY0054)the National Natural Science Foundation of China(Grant No.51605343).
文摘High entropy alloys(HEAs)with multi-component solid solution microstructures have the potential for large-scale industrial applications due to their excellent mechanical and functional properties.However,the mechanical properties of HEAs limit the selection of processing technologies.Additive manufacturing technology possesses strong processing adaptability,making itthe best candidate method to overcome this issue.This comprehensive review examines the current state of selective laser melting(SLM)of HEAs.Introducing SLM to HEAs processing is motivated by its high quality for dimensional accuracy,geometric complexity,surface roughness,and microstructure.This review focuses on analyzing the current developments and challenges in SLM of HEAs,including defects,microstructures,and properties,as well as strengthing prediction models of fabricated HEAs.This review also offers directions for future studies to address existing challenges and promote technological advancement.
文摘In order to solve the problems including pipe corrosion, scaling and microbial growth, which severely threat safe op-eration of circulating cooling water system, this paper proposes ion exchange softening and alkalization process to solve these problems and carries out a series of studies to study the feasibility of ion exchange softening and alkaliza-tion process in the simulation process of circulating cooling water system. The studies include product water quality of ion exchange softening and alkalization process, effect on the performance of carbon steel and brass, and the inhibition that suppresses microbial growth. The results indicate that ion exchange softening and alkalization process is feasible to prevent the circulating cooling water system from scaling, pipe corrosion, and microbial growth without any other chemicals. Thus circulating cooling water system can achieve zerodischarge of wastewater.
基金supported by the National Natural Science Foundation of China(Nos.11375135 and 11275141)International Cooperation Program of the Ministry of Science and Technology of China(No.2015DFR00720)Fundamental Research Funds for the Central Universities
文摘TiBCN films were deposited on Si(100) and cemented carbide substrates by using multi-cathodic arc ion plating in C_2H_2 and N_2atmosp^here. Their structure and mechanical properties were studied systematically under different N_2 flow rates. The results showed that the Ti BCN films were adhered well to the substrates. Rutherford backscattering sp^ectroscopy was employed to determine the relative concentration of Ti, B, C and N in the films.The chemical bonding states of the films were explored by X-ray photoelectron sp^ectroscopy, revealing the presence of bonds of Ti N, Ti(C,N), BN, pure B, sp^2C–C and sp^3C–C, which changed with the N_2 flow rate. Ti BCN films contain nanocrystals of Ti N/Ti CN and Ti B_2/Ti(B,C)embedded in an amorphous matrix consisting of amorphous BN and carbon at N_2 flow rate of up to 250 sccm.
基金supported by the National Natural Science Foundation of China(Nos.11275141 and 11175133)the International Cooperation Program of the Ministry of Science and Technology of China(No.2015DFR00720)+2 种基金the Center for Electron Microscopy of Wuhan Universitythe Center of Nanosci. and Nanotech,Research of Wuhan Universitythe Analysis and Test Center of Wuhan University
文摘Nanocomposite Cr C/hydrogenated amorphous carbon(nc-CrC/a-C:H) coatings were deposited by a hybrid beams system comprised of a hollow cathode ion source and a cathodic arc ion-plating unit with varying H_2 flow rates. The influences of H_2 flow rates on the morphologies, microstructures, and properties of the coatings were systematically studied. The morphologies and microstructures of the coatings were characterized by SEM, AFM, XPS, Raman spectroscopy, GIXRD, and HRTEM. The mechanical and tribological properties were measured by a nano-indenter, scratch tester, and ball-ondisk tribometer. The wear tracks were evaluated using 3D profilometer, optical microscope, and EDS analysis. It has been found that a moderate H_2 flow rate can effectively smooth the surface, enlarge the fraction of a sp^3 bond, and improve the properties. The coating exhibits the highest hardness and elastic modulus at the H_2 flow rate of 40 sccm. A superior combination of adhesion strength,friction coefficient, and wear resistance can be achieved at the H_2 flow rate of 80 sccm.
基金National High-Tech R&D Program of China(863 Program)(2015AA043401)。
文摘The carbon fiber reinforced composite is a new type of composite material with an excellent property in strength and elastic modulus,and has found extensive applications in aerospace,energy,automotive industry and so on.However,this composite has a strict requirement on processing techniques,for example,brittle damage or delamination often exists in conventional processing techniques.Abrasive water jet machining technology is a new type of green machining technique with distinct advantages such as high-energy and thermal distortion free.The use of abrasive water jet technique to process carbon fiber composite materials has become a popular trend since it can significantly improve the processing accuracy and surface quality of carbon fiber composite materials.However,there are too many parameters that affect the quality of an abrasive water jet machining.At present,few studies are carried out on the parameter optimization of such a machining process,which leads to the unstable quality of surface processing.In this paper,orthogonal design of experiment and regression analysis were employed to establish the empirical model between cutting surface roughness and machining process parameters.Then a verified model was used to optimize the machining process parameters for abrasive water jet cutting carbon fiber reinforced composites.
文摘Making use of microsoft visual studio. net platform, the assistant decision-making system of tunnel boring machine in tunnelling has been built to predict the time and cost. Computation methods of the performance parameters have been discussed. New time and cost prediction models have been depicted. The multivariate linear regression has been used to make the parameters more precise, which are the key factor to affect the prediction near to the reality.
基金financially supported by the National Natural Science Foundation of China (Nos. 52175245 and 52274093)the Natural Science Foundation of Hubei Province (No. 2021CFB462)。
文摘To improve the rock breaking ability, cavitating waterjet and abrasive waterjet are combined by using a coaxial low-speed waterjet generated around the periphery of a high-speed abrasive waterjet, and a new type of waterjet called unsubmerged cavitating abrasive waterjet(UCAWJ) is thus produced. The rock breaking performance of UCAWJ was compared with submerged cavitating abrasive waterjet(SCAWJ)and unsubmerged abrasive waterjet(UAWJ) by impinging sandstone specimens. Moreover, the effects of jet pressure, standoff distance, abrasive flow rate and concentration were studied by evaluating the specific energy consumption, and the area, depth, and mass loss of the eroded specimen. The results show that the artificially generated submerged environment in UCAWJ is able to enhance the rock breaking performance under the same operating parameters. Furthermore, the rock breaking performance of UCAWJ is much better at higher jet pressures and smaller standoff distances when compared with UAWJ. The greatest rock breaking ability of UCAWJ appears at jet pressure of 50 MPa and standoff distance of 32 mm, with the mass loss of sandstone increased by 370.6% and the energy dissipation decreased by 75.8%. In addition, under the experimental conditions the optimal abrasive flow rate and concentration are 76.5 m L/min and 3%, respectively.
