Microwave heating contributes to coal fracturing and gas desorption. However, problems of low penetration depth, local overheating and fracture closure exist. Coal demineralisation by acids has advantages in coal unbl...Microwave heating contributes to coal fracturing and gas desorption. However, problems of low penetration depth, local overheating and fracture closure exist. Coal demineralisation by acids has advantages in coal unblocking and permeability improvement, while it is difficult for acid to enter microcracks.Microwave-asisted acidification may offer an alternative. In this work, XRD,^(1)H-NMR, and SEM were used to evaluate the effect of microwave-assisted acidification on the microstructure of coal. Results show that kaolinite, calcite, and dolomite can be dissolved by acid. After microwave irradiation, the graphitization of microcrystalline structure of carbon improves. Microwave-assisted acidification erodes minerals in coal and enhances the graphitization degree of microcrystalline structure. Compared to individual microwave irradiation or acidification, the pore volume and pore connectivity can be greatly enhanced by microwave-assisted acidification. The NMR permeability of coal increased by 28.05%. This study demonstrates the potential of microwave-assisted acidification for coalbed methane recovery.展开更多
Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechani...Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined.To solve the above problems,in this study,identical homogeneous sandstone samples were selected to simulate lowpermeability sandstone;a permeability evolution model considering the combined action of vibration stress,pore water pressure,water flow impact force,and chemical erosion was established;and vibration leaching experiments were performed to test the model accuracy.Both the permeability and chemical reactions were found to simultaneously restrict U6þleaching,and the vibration treatment increased the permeability,causing the U6þleaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate.Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion,to prove the correctness of the mechanism according to the experimental results,and to develop a new method for determining the optimum permeability in uranium leaching.The uranium leaching was found to primarily follow a process consisting of(1)a permeability control stage,(2)achieving the optimum permeability,(3)a chemical reactive rate control stage,and(4)a channel flow stage.The resolution of these problems is of great significance for facilitating the application and promotion of lowfrequency vibration in the CO_(2)+O_(2) leaching process.展开更多
In the process of in situ leaching of uranium,the microstructure controls and influences the flow distribution,percolation characteristics,and reaction mechanism of lixivium in the pores of reservoir rocks and directl...In the process of in situ leaching of uranium,the microstructure controls and influences the flow distribution,percolation characteristics,and reaction mechanism of lixivium in the pores of reservoir rocks and directly affects the leaching of useful components.In this study,the pore throat,pore size distribution,and mineral composition of low-permeability uranium-bearing sandstone were quantitatively analyzed by high pressure mercury injection,nuclear magnetic resonance,X-ray diffraction,and wavelength-dispersive X-ray fluorescence.The distribution characteristics of pores and minerals in the samples were qualitatively analyzed using energy-dispersive scanning electron microscopy and multi-resolution CT images.Image registration with the landmarks algorithm provided by FEI Avizo was used to accurately match the CT images with different resolutions.The multi-scale and multi-mineral digital core model of low-permeability uranium-bearing sandstone is reconstructed through pore segmentation and mineral segmentation of fusion core scanning images.The results show that the pore structure of low-permeability uranium-bearing sandstone is complex and has multi-scale and multi-crossing characteristics.The intergranular pores determine the main seepage channel in the pore space,and the secondary pores have poor connectivity with other pores.Pyrite and coffinite are isolated from the connected pores and surrounded by a large number of clay minerals and ankerite cements,which increases the difficulty of uranium leaching.Clays and a large amount of ankerite cement are filled in the primary and secondary pores and pore throats of the low-permeability uraniumbearing sandstone,which significantly reduces the porosity of the movable fluid and results in low overall permeability of the cores.The multi-scale and multi-mineral digital core proposed in this study provides a basis for characterizing macroscopic and microscopic pore-throat structures and mineral distributions of low-permeability uranium-bearing sandstone and can better understand the seepage characteristics.展开更多
Debris-covered glaciers,characterized by the presence of supraglacial debris mantles in their ablation zones,are widespread in the China-Pakistan Economic Corridor(CPEC)and surroundings.For these glaciers,thin debris ...Debris-covered glaciers,characterized by the presence of supraglacial debris mantles in their ablation zones,are widespread in the China-Pakistan Economic Corridor(CPEC)and surroundings.For these glaciers,thin debris layers accelerate the melting of underlying ice compared to that of bare ice,while thick debris layers retard ice melting,called debriscover effect.Knowledge about the thickness and thermal properties of debris cover on CPEC glaciers is still unclear,making it difficult to assess the regional debris-cover effect.In this study,thermal resistance of the debris layer estimated from remotely sensed data reveals that about 54.0%of CPEC glaciers are debris-covered glaciers,on which the total debris-covered area is about 5,072 km2,accounting for 14.0%of the total glacier area of the study region.We find that marked difference in the extent and thickness of debris cover is apparent from region to region,as well as the debris-cover effect.53.3%of the total debris-covered area of the study region is concentrated in Karakoram,followed by Pamir with 30.2%of the total debris-covered area.As revealed by the thermal resistance,the debris thickness is thick in Hindu Kush on average,with the mean thermal resistance of 7.0×10^-2((m^2∙K)/W),followed by Karakoram,while the thickness in western Himalaya is thin with the mean value of 2.0×10^-2((m^2∙K)/W).Our findings provide a basis for better assessments of changes in debriscovered glaciers and their associated hydrological impacts in the CPEC and surroundings.展开更多
Pressure nozzle is commonly used in the dust-reduction techniques by spraying of underground coal mines.Based on the internal structure,the pressure nozzle can be divided into the following types:spiral channel nozzle...Pressure nozzle is commonly used in the dust-reduction techniques by spraying of underground coal mines.Based on the internal structure,the pressure nozzle can be divided into the following types:spiral channel nozzle,tangential flow-guided nozzle and X-swirl nozzle.In order to provide better guidance on the selection of nozzles for the coal mine dust-reduction systems by spraying,we designed comparing experiments to study the atomization characteristics and dust-reduction performance of four commonly used nozzles in the coal mine underground with different internal structures.From the experimental results on the atomization characteristics,both the tangential flow-guided nozzle and the X-swirl nozzle have high flow coefficients.The atomization angle is the largest in the spiral non-porous nozzle,and smallest in both the X-swirl nozzle and the spiral porous nozzle.The spraying range and the droplet velocity are inversely proportional to the atomization angle.When the water pressure is low,the atomization performance of the spiral non-porous nozzle is the best among the four types of nozzles.The atomization performance of the X-swirl nozzle is superior to other types when the water pressure is high.Under the high water pressure,the particle size of the atomized droplets is smallest in the X-swirl nozzle.Through the experiments on the dust-reduction performance of the four types of nozzles and the comprehensive analysis,the X-swirl nozzle is recommended for the coal mine application site with low water pressure in the dust-reduction system,while at the sites with high water pressure,the spiral non-porous nozzle is recommended,which has the lowest water consumption and obvious economic advantages.展开更多
Coking coal dust is extremely hydrophobic;therefore,combination with droplets in the air is difficult and dust suppression is challenging.Here,a dust suppressant spray for coking coal dust was studied in order to impr...Coking coal dust is extremely hydrophobic;therefore,combination with droplets in the air is difficult and dust suppression is challenging.Here,a dust suppressant spray for coking coal dust was studied in order to improve of the combination of droplets and coking coal dust.Based on monomer optimization and compounding analysis,two surfactant monomers,fatty alcohol ether sodium sulfate(AES)and sodium dodecyl benzene sulfonate(SDBS)were selected as the surfactant components of the dust suppressant.The surfactant monomers were combined with four inorganic salts and the reverse osmosis moisture absorption of each solution was determined.By combining the reverse osmosis moisture absorption values with the water retention experimental results,CaCl_(2)was identified as the optimal inorganic salt additive for the dust suppressant.Finally,the optimal concentration of each component was obtained using orthogonal experimental design i.e.,AES(0.03%),SDBS(0.05%),and CaCl_(2)(0.4%).The dust suppressant solution formulated using this method had a high moisture absorption capacity and excellent performance.展开更多
A severe accident in a marine nuclear reactor leads to radionuclide leakage,which causes hidden dangers to workers and has adverse effects of environmental pollution.It is necessary to propose a novel approach to radi...A severe accident in a marine nuclear reactor leads to radionuclide leakage,which causes hidden dangers to workers and has adverse effects of environmental pollution.It is necessary to propose a novel approach to radionuclide diffusion in a confined environment after a severe accident in a marine nuclear reactor.Therefore,this study proposes a new method for the severe accident analysis program MELCOR coupled with computational fluid dynamics scSTREAM to study radioactive diffusion in severe accidents.The radionuclide release fraction and temperature calculated by MELCOR were combined with the scSTREAM calculations to study the radionuclide diffusion behavior and the phenomenon of radionuclide diffusion in different space environments of the reactor under the conditions of varying wind velocities of the ventilation system and diffusion speed.The results show that the wind velocity of the ventilation system is very small or zero,and the turbulent diffusion of radionuclides is not obvious and diffuses slowly in the form of condensation sedimentation and gravity settlement.When the wind speed of the ventilation system increases,the flow of radionuclides meets the wall and forms eddy currents,affecting the time variation of radionuclides diffusing into chamber 2.The wind velocity of the ventilation system and the diffusion speed has opposite effects on the time variation trend of radionuclide diffusion into the four chambers.展开更多
A total of 71,177 glaciers exist on the Qinghai-Tibet Plateau,according to the Randolph Glacier Inventory(RGI 6.0).Despite their large number,glacier ice thickness data are relatively scarce.This study utilizes digita...A total of 71,177 glaciers exist on the Qinghai-Tibet Plateau,according to the Randolph Glacier Inventory(RGI 6.0).Despite their large number,glacier ice thickness data are relatively scarce.This study utilizes digital elevation model data and ground-penetrating radar thickness measurements to estimate the distribution and variation of ice thickness of the Longbasaba Glacier using Glacier bed Topography(GlabTop),a full-width expansion model,and the Huss and Farinotti(HF)model.Results show that the average absolute deviations of GlabTop,the full-width expansion model,and the HF model are 9.8,15.5,and 10.9 m,respectively,indicating that GlabTop performs the best in simulating glacier thickness distribution.During 1980−2015,the Longbasaba Glacier thinned by an average of 7.9±1.3 m or 0.23±0.04 m/a,and its ice volume shrunk by 0.28±0.04 km3 with an average reduction rate of 0.0081±0.0001 km^3/a.In the investigation period,the area and volume of Longbasaba Lake expanded at rates of 0.12±0.01 km^2/a and 0.0132±0.0018 km3/a,respectively.This proglacial lake could potentially extend up to 5,000 m from the lake dam.展开更多
Mountain glacier-related hazards occur worldwide in response to increasing glacier instability and human activity intensity in modern glacierized regions.These hazards are characterized by their spatial aggregation an...Mountain glacier-related hazards occur worldwide in response to increasing glacier instability and human activity intensity in modern glacierized regions.These hazards are characterized by their spatial aggregation and temporal repeatability.Comprehensive knowledge about mountain glacier-related hazards is critical for hazard assessment,mitigation,and prevention in the mountain cryosphere and downstream regions.This article systematically schematizes various mountain glacier-related hazards and analyzes their inherent associations with glacier changes.Besides,the processes,manifestations,and mechanisms of each of the glacier-related hazards are summarized.In the future,more extensive and detailed systematic surveys,for example,considering integrated ground−air−space patterns,should be undertaken for typical glacierized regions to enhance existing knowledge of such hazards.The use of coupled numerical models based on multisource data is challenging but will be essential to improve our understanding of the complex chain of processes involved in thermal−hydrogeomorphic glacier-related hazards in the mountain cryosphere.展开更多
The Co-free Li Ni_(0.5)Mn_(1.5)O_(4)(LNMO)is a promising cathode for lithium-ion batteries owing to its high operating voltage and low costs.However,the synthesis of LNMO is generally time and energy consuming,and its...The Co-free Li Ni_(0.5)Mn_(1.5)O_(4)(LNMO)is a promising cathode for lithium-ion batteries owing to its high operating voltage and low costs.However,the synthesis of LNMO is generally time and energy consuming,and its practical application is hindered by the lack of a compatible electrolyte.Herein,a spray pyrolysis-based energy-saving synthesis method as well as a diluted low concentration electrolyte(0.5 M LiPF_(6) in a mixture of fluoroethylene carbonate/dimethyl carbonate/1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether(FEC:DMC:TTE,1:4:5 by volume))are proposed to address these challenges.Owing to the unique features of the precursor prepared by spray pyrolysis,well-crystallized LNMO single-crystal can be obtained within 1 h calcination at 900℃.Besides,the fluorinated interphases derived from the diluted low concentration electrolyte not only mitigate the Mn dissolution and Al corrosion at the cathode side,but also suppresses dendritic Li deposition at the anode side,thus enabling stable cycling of both LNMO and Li metal anode.Thus,30μm Li|LNMO(1.75 m A h cm^(-2))cells achieve a high capacity retention(90.9%)after 168 cycles in the diluted low concentration electrolyte.展开更多
The study of pressure stimulated current(PSC)changes of rocks is significant to monitor dynamic disasters in mines and rock masses.The existing studies focus on change laws and mechanism of currents generated under th...The study of pressure stimulated current(PSC)changes of rocks is significant to monitor dynamic disasters in mines and rock masses.The existing studies focus on change laws and mechanism of currents generated under the loading of rocks.An electrical and mechanics test system was established in this paper to explore the impacts of loading rates on PSCs.The results indicated that PSC curves of different rocks had different change laws under low/high loading rates.When the loading rate was relatively low,PSC curves firstly changed gently and then increased exponentially.Under high loading rates,PSC curves experienced the rapid increase stage,gentle increase stage and sudden change stage.The compressive strength could greatly affect the peak PSC in case of rock failure.The loading rate was a key factor in average PSC.Under low loading rates,the variations of PSCs conformed to the damage charge model of fracture mechanics,while they did not at the fracture moment.Under high loading rates,the PSCs at low stress didn’t fit the model due to the stress impact effects.The experimental results could provide theoretical basis for the influence of loading rates on PSCs.展开更多
Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading dr...Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.展开更多
The stability of coal pillar dams is crucial for the long-term service of underground reservoirs storing water or heat.Chemi-cal damage of coal dams induced by ions-atttacking in coal is one of the main reasons for th...The stability of coal pillar dams is crucial for the long-term service of underground reservoirs storing water or heat.Chemi-cal damage of coal dams induced by ions-atttacking in coal is one of the main reasons for the premature failure of coal dams.However,the diffusion process of harmful ions in coal is far from clear,limiting the reliability and durability of coal dam designs.This paper investigates sulfate diffusion in coal pillar through experimental and analytical methods.Coal specimens are prepared and exposed to sulfate solutions with different concentrations.The sulfate concentrations at different locations and time are measured.Based on experimental data and Fick's law,the time-dependent surface concentration of sulfate and diffusion coefficient are determined and formulated.Further,an analytical model for predicting sulfate diffusion in coal pillar is developed by considering dual time-dependent characteristics and Laplace transformations.Through comparisons with experimental data,the accuracy of the analytical model for predicting sulfate diffusion is verified.Further,sulfate diffusions in coal dams for different concentrations of sulfate in mine water are investigated.It has been found that the sulfate concen-tration of exposure surface and diffusion coefficient in coal are both time-dependent and increase with time.Conventional Fick's law is not able to predict the sulfate diffusion in coal pillar due to the dual time-dependent characteristics.The sulfate attacking makes the coal dam a typical heterogeneous gradient structure.For sulfate concentrations 0.01-0.20 mol/L in mine water,it takes almost 1.5 and 4 years for sulfate ions to diffuse 9.46 and 18.92 m,respectively.The experimental data and developed model provide a practical method for predicting sulfate diffusion in coal pillar,which helps the service life design of coal dams.展开更多
Extraction of uranium from low-permeability sandstone is a long-standing challenge in mining.The improvement of sandstone permeability has therefore become a key research focus to improve the uranium leaching effect.T...Extraction of uranium from low-permeability sandstone is a long-standing challenge in mining.The improvement of sandstone permeability has therefore become a key research focus to improve the uranium leaching effect.To address the low-permeability problem and corresponding leaching limits,leaching experiments are performed using newly developed equipment that could apply low-frequency vibration to the sandstone samples.The test results indicate that low-frequency vibration significantly improves the uranium leaching performance and permeability of the sandstone samples.The leaching effect of low-frequency vibration treatment is approximately nine times more effective than ultrasonic vibration treatment,whereas the concentration of uranium ions generated without vibration treatment is not detectable.Mathematical model that considers the combined action of physico-mechanical vibration and chemical erosion is established to describe the effect of low-frequency vibration on the permeability.The calculated results are in good agreement with the tested permeability values.This study thus offers a new method to effectively leach more uranium from low-permeability sandstone using CO_(2)+O_(2)and provides an insight into the impact of low-frequency vibration on the uranium leaching process.展开更多
As one of the five components of Earth's climatic system,the cryosphere has been undergoing rapid shrinking due to global warming.Studies on the formation,evolution,distribution and dynamics of cryospheric compone...As one of the five components of Earth's climatic system,the cryosphere has been undergoing rapid shrinking due to global warming.Studies on the formation,evolution,distribution and dynamics of cryospheric components and their interactions with the human system are of increasing importance to society.In recent decades,the mass loss of glaciers,including the Greenland and Antarctic ice sheets,has accelerated.The extent of sea ice and snow cover has been shrinking,and permafrost has been degrading.The main sustainable development goals in cryospheric regions have been impacted.The shrinking of the cryosphere results in sea-level rise,which is currently affecting,or is soon expected to affect,17 coastal megacities and some small island countries.In East Asia,South Asia and North America,climate anomalies are closely related to the extent of Arctic sea ice and snow cover in the Northern Hemisphere.Increasing freshwater melting from the ice sheets and sea ice may be one reason for the slowdown in Atlantic meridional overturning circulation in the Arctic and Southern Oceans.The foundations of ports and infrastructure in the circum-Arctic permafrost regions suffer from the consequences of permafrost degradation.In high plateaus and mountainous regions,the cryosphere's shrinking has led to fluctuations in river runoff,caused water shortages and increased flooding risks in certain areas.These changes in cryospheric components have shown significant heterogeneity at different temporal and spatial scales.Our results suggest that the quantitative evaluation of future changes in the cryosphere still needs to be improved by enhancing existing observations and model simulations.Theoretical and methodological innovations are required to strengthen social economies'resilience to the impact of cryospheric change.展开更多
Automatic and accurate classification is a fundamental problem to the analysis and modeling of LiDAR(Light Detection and Ranging)data.Recently,convolutional neural network(ConvNet or CNN)has achieved remarkable perfor...Automatic and accurate classification is a fundamental problem to the analysis and modeling of LiDAR(Light Detection and Ranging)data.Recently,convolutional neural network(ConvNet or CNN)has achieved remarkable performance in image recognition and computer vision.While significant efforts have also been made to develop various deep networks for satellite image scene classification,it still needs to further investigate suitable deep learning network frameworks for 3D dense mobile laser scanning(MLS)data.In this paper,we present a simple deep CNN for multiple object classification based on multi-scale context representation.For the pointwise classification,we first extracted the neighboring points within spatial context and transformed them into a three-channel image for each point.Then,the classification task can be treated as the image recognition using CNN.The proposed CNN architecture adopted common convolution,maximum pooling and rectified linear unit(ReLU)layers,which combined multiple deeper network layers.After being trained and tested on approximately seven million labeled MLS points,the deep CNN model can classify accurately into nine classes.Comparing with the widely used ResNet algorithm,this model performs better precision and recall rates,and less processing time,which indicated the significant potential of deep-learning-based methods in MLS data classification.展开更多
Solid oxide fuel cells(SOFCs)and electrolysis cells(SOECs)are promising energy conversion devices,on whose basis green hydrogen energy technologies can be developed to support the transition to a carbon-free future.As...Solid oxide fuel cells(SOFCs)and electrolysis cells(SOECs)are promising energy conversion devices,on whose basis green hydrogen energy technologies can be developed to support the transition to a carbon-free future.As compared with oxygen-conducting cells,the operational temperatures of protonic ceramic fuel cells(PCFCs)and electrolysis cells(PCECs)can be reduced by several hundreds of degrees(down to low-and intermediatetemperature ranges of 400–700C)while maintaining high performance and efficiency.This is due to the distinctive characteristics of charge carriers for proton-conducting electrolytes.However,despite achieving outstanding lab-scale performance,the prospects for industrial scaling of PCFCs and PCECs remain hazy,at least in the near future,in contrast to commercially available SOFCs and SOECs.In this review,we reveal the reasons for the delayed technological development,which need to be addressed in order to transfer fundamental findings into industrial processes.Possible solutions to the identified problems are also highlighted.展开更多
In boreal forest ecosystems, permafrost and forest types are mutually interdependent;permafrost degradation impacts forest ecosystem structure and functions. The Xing’an permafrost in Northeast China is on the southe...In boreal forest ecosystems, permafrost and forest types are mutually interdependent;permafrost degradation impacts forest ecosystem structure and functions. The Xing’an permafrost in Northeast China is on the southern margin of the Eastern Asia latitudinal permafrost body. Under a warming climate, permafrost undergoes rapid and extensive degradation. In this study, the frost-number (Fn) model based on air temperatures and ground surface temperatures was used to predict the distribution of the Xing’an permafrost, and, temporal and spatial changes in air and ground-surface temperatures from 1961 to 2019 are analyzed. The results show that Northeast China has experienced a rapid and substantial climate warming over the past 60 years. The rises in mean annual air and mean annual ground-surface temperatures were higher in permafrost zones than those in the seasonal frost zone. The frost numbers of air and ground-surface temperatures were calculated for determining the southern limit of latitudinal permafrost and for permafrost zonation. The southern limits of discontinuous permafrost, sporadic permafrost, and latitudinal permafrost moved northward significantly. According to the air-temperature frost-number criteria for permafrost zoning, compared with that in the 1960s, the extent of Xing’an permafrost in Northeast China had decreased by 40.6% by the 2010s. With an average rate of increase in mean annual air temperatures at 0.03 ℃ a^(−1), the extent of permafrost in Northeast China will decrease to 26.42 × 10^(4) by 2020, 14.69 × 10^(4) by 2040 and to 11.24 × 10^(4) km^(2) by 2050. According to the ground-surface temperature frost-number criteria, the southern limit of latitudinal permafrost was at the 0.463. From the 1960s to the 2010s, the extent of latitudinal permafrost declined significantly. Due to the nature of the ecosystem-protected Xing’an-Baikal permafrost, management and protection (e.g., more prudent and effective forest fire management and proper logging of forests) of the Xing’an permafrost eco-environment should be strengthened.展开更多
Prof.Xie Zichu passed away on January 25,2020 in Changsha,Hunan Province,China at the age of 83 years old.Being one of the internationally renowned and highly respected glaciologists of China,this issue is dedicated w...Prof.Xie Zichu passed away on January 25,2020 in Changsha,Hunan Province,China at the age of 83 years old.Being one of the internationally renowned and highly respected glaciologists of China,this issue is dedicated with all respect in memory of him for his life-long effort and contribution to advance studies on glaciology in China.He has undertaken field investigations on glacier mass balance.展开更多
A new medium entropy material LiCo_(0.25)Fe_(0.25)Mn_(0.2)5Ni_(0.2)5O_(2)(LCFMN)is proposed as a cathode for proton-conducting solid oxide fuel cells(H-SOFCs).Unlike traditional LiXO_(2)(X=Co,Fe,Mn,Ni)lithiated oxides...A new medium entropy material LiCo_(0.25)Fe_(0.25)Mn_(0.2)5Ni_(0.2)5O_(2)(LCFMN)is proposed as a cathode for proton-conducting solid oxide fuel cells(H-SOFCs).Unlike traditional LiXO_(2)(X=Co,Fe,Mn,Ni)lithiated oxides,which have issues like phase impurity,poor chemical compatibility,or poor fuel cell performance,the new LCFMN material mitigates these problems,allowing for the successful preparation of pure phase LCFMN with good chemical and thermal compatibility to the electrolyte.Furthermore,the entropy engineering strategy is found to weaken the covalence bond between the metal and oxygen in the LCFMN lattice,favoring the creation of oxygen vacancies and increasing cathode activity.As a result,the H-SOFC with the LCFMN cathode achieves an unprecedented fuel cell output of 1803 mW·cm^(−2)at 700℃,the highest ever reported for H-SOFCs with lithiated oxide cathodes.In addition to high fuel cell performance,the LCFMN cathode permits stable fuel cell operation for more than 450 h without visible degradation,demonstrating that LCFMN is a suitable cathode choice for H-SOFCs that combining high performance and good stability.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 52274195, 52274196, 51904103, and 52174180)the Science and Technology Innovation Program of Hunan Province (No. 2022RC1178)+1 种基金Hunan Provincial Natural Science Foundation of China (Nos. 2022JJ20024, and 2021JJ30254)Scientific Research Foundation of Hunan Provincial Education Department (No. 21B0465)。
文摘Microwave heating contributes to coal fracturing and gas desorption. However, problems of low penetration depth, local overheating and fracture closure exist. Coal demineralisation by acids has advantages in coal unblocking and permeability improvement, while it is difficult for acid to enter microcracks.Microwave-asisted acidification may offer an alternative. In this work, XRD,^(1)H-NMR, and SEM were used to evaluate the effect of microwave-assisted acidification on the microstructure of coal. Results show that kaolinite, calcite, and dolomite can be dissolved by acid. After microwave irradiation, the graphitization of microcrystalline structure of carbon improves. Microwave-assisted acidification erodes minerals in coal and enhances the graphitization degree of microcrystalline structure. Compared to individual microwave irradiation or acidification, the pore volume and pore connectivity can be greatly enhanced by microwave-assisted acidification. The NMR permeability of coal increased by 28.05%. This study demonstrates the potential of microwave-assisted acidification for coalbed methane recovery.
基金supported by the National Natural Science Foundation of China(Grant No.11705086)the National Science Foundation of Hunan Province,China(Grant No.2018JJ3424)the Foundation of Hunan Educational Committee(Grant No.16C1387).
文摘Low-frequency vibrations can effectively improve natural sandstone permeability,and higher vibration frequency is associated with larger permeability.However,the optimum permeability and permeability evolution mechanism for uranium leaching and the relationship between permeability and the change of chemical reactive rate affecting uranium leaching have not been determined.To solve the above problems,in this study,identical homogeneous sandstone samples were selected to simulate lowpermeability sandstone;a permeability evolution model considering the combined action of vibration stress,pore water pressure,water flow impact force,and chemical erosion was established;and vibration leaching experiments were performed to test the model accuracy.Both the permeability and chemical reactions were found to simultaneously restrict U6þleaching,and the vibration treatment increased the permeability,causing the U6þleaching reaction to no longer be diffusion-constrained but to be primarily controlled by the reaction rate.Changes of the model calculation parameters were further analyzed to determine the permeability evolution mechanism under the influence of vibration and chemical erosion,to prove the correctness of the mechanism according to the experimental results,and to develop a new method for determining the optimum permeability in uranium leaching.The uranium leaching was found to primarily follow a process consisting of(1)a permeability control stage,(2)achieving the optimum permeability,(3)a chemical reactive rate control stage,and(4)a channel flow stage.The resolution of these problems is of great significance for facilitating the application and promotion of lowfrequency vibration in the CO_(2)+O_(2) leaching process.
基金This work was supported by the National Natural Science Foundation of China(No.11775107)the Key Projects of Education Department of Hunan Province of China(No.16A184).
文摘In the process of in situ leaching of uranium,the microstructure controls and influences the flow distribution,percolation characteristics,and reaction mechanism of lixivium in the pores of reservoir rocks and directly affects the leaching of useful components.In this study,the pore throat,pore size distribution,and mineral composition of low-permeability uranium-bearing sandstone were quantitatively analyzed by high pressure mercury injection,nuclear magnetic resonance,X-ray diffraction,and wavelength-dispersive X-ray fluorescence.The distribution characteristics of pores and minerals in the samples were qualitatively analyzed using energy-dispersive scanning electron microscopy and multi-resolution CT images.Image registration with the landmarks algorithm provided by FEI Avizo was used to accurately match the CT images with different resolutions.The multi-scale and multi-mineral digital core model of low-permeability uranium-bearing sandstone is reconstructed through pore segmentation and mineral segmentation of fusion core scanning images.The results show that the pore structure of low-permeability uranium-bearing sandstone is complex and has multi-scale and multi-crossing characteristics.The intergranular pores determine the main seepage channel in the pore space,and the secondary pores have poor connectivity with other pores.Pyrite and coffinite are isolated from the connected pores and surrounded by a large number of clay minerals and ankerite cements,which increases the difficulty of uranium leaching.Clays and a large amount of ankerite cement are filled in the primary and secondary pores and pore throats of the low-permeability uraniumbearing sandstone,which significantly reduces the porosity of the movable fluid and results in low overall permeability of the cores.The multi-scale and multi-mineral digital core proposed in this study provides a basis for characterizing macroscopic and microscopic pore-throat structures and mineral distributions of low-permeability uranium-bearing sandstone and can better understand the seepage characteristics.
基金This study was supported by the National Natural Science Foundation of China(Grant Nos.41761144075,41671057,and 41771075)the Research Funds for New Talents of Yunnan University(YJRC3201702).
文摘Debris-covered glaciers,characterized by the presence of supraglacial debris mantles in their ablation zones,are widespread in the China-Pakistan Economic Corridor(CPEC)and surroundings.For these glaciers,thin debris layers accelerate the melting of underlying ice compared to that of bare ice,while thick debris layers retard ice melting,called debriscover effect.Knowledge about the thickness and thermal properties of debris cover on CPEC glaciers is still unclear,making it difficult to assess the regional debris-cover effect.In this study,thermal resistance of the debris layer estimated from remotely sensed data reveals that about 54.0%of CPEC glaciers are debris-covered glaciers,on which the total debris-covered area is about 5,072 km2,accounting for 14.0%of the total glacier area of the study region.We find that marked difference in the extent and thickness of debris cover is apparent from region to region,as well as the debris-cover effect.53.3%of the total debris-covered area of the study region is concentrated in Karakoram,followed by Pamir with 30.2%of the total debris-covered area.As revealed by the thermal resistance,the debris thickness is thick in Hindu Kush on average,with the mean thermal resistance of 7.0×10^-2((m^2∙K)/W),followed by Karakoram,while the thickness in western Himalaya is thin with the mean value of 2.0×10^-2((m^2∙K)/W).Our findings provide a basis for better assessments of changes in debriscovered glaciers and their associated hydrological impacts in the CPEC and surroundings.
基金Financial support for this work,provided by the National Natural Science Foundation of China(No.51574123)the Hunan Provincial Natural Science Foundation of China(No.2017JJ3076)Hunan Graduate Research and Innovation Project(No.CX2018B661),are gratefully acknowledged.
文摘Pressure nozzle is commonly used in the dust-reduction techniques by spraying of underground coal mines.Based on the internal structure,the pressure nozzle can be divided into the following types:spiral channel nozzle,tangential flow-guided nozzle and X-swirl nozzle.In order to provide better guidance on the selection of nozzles for the coal mine dust-reduction systems by spraying,we designed comparing experiments to study the atomization characteristics and dust-reduction performance of four commonly used nozzles in the coal mine underground with different internal structures.From the experimental results on the atomization characteristics,both the tangential flow-guided nozzle and the X-swirl nozzle have high flow coefficients.The atomization angle is the largest in the spiral non-porous nozzle,and smallest in both the X-swirl nozzle and the spiral porous nozzle.The spraying range and the droplet velocity are inversely proportional to the atomization angle.When the water pressure is low,the atomization performance of the spiral non-porous nozzle is the best among the four types of nozzles.The atomization performance of the X-swirl nozzle is superior to other types when the water pressure is high.Under the high water pressure,the particle size of the atomized droplets is smallest in the X-swirl nozzle.Through the experiments on the dust-reduction performance of the four types of nozzles and the comprehensive analysis,the X-swirl nozzle is recommended for the coal mine application site with low water pressure in the dust-reduction system,while at the sites with high water pressure,the spiral non-porous nozzle is recommended,which has the lowest water consumption and obvious economic advantages.
基金The project was supported by the National Natural Science Foundation of China(No.51574123)the Scientific Research Project of Hunan Province Office of Education(No.18A185),which is gratefully acknowledged.
文摘Coking coal dust is extremely hydrophobic;therefore,combination with droplets in the air is difficult and dust suppression is challenging.Here,a dust suppressant spray for coking coal dust was studied in order to improve of the combination of droplets and coking coal dust.Based on monomer optimization and compounding analysis,two surfactant monomers,fatty alcohol ether sodium sulfate(AES)and sodium dodecyl benzene sulfonate(SDBS)were selected as the surfactant components of the dust suppressant.The surfactant monomers were combined with four inorganic salts and the reverse osmosis moisture absorption of each solution was determined.By combining the reverse osmosis moisture absorption values with the water retention experimental results,CaCl_(2)was identified as the optimal inorganic salt additive for the dust suppressant.Finally,the optimal concentration of each component was obtained using orthogonal experimental design i.e.,AES(0.03%),SDBS(0.05%),and CaCl_(2)(0.4%).The dust suppressant solution formulated using this method had a high moisture absorption capacity and excellent performance.
基金supported by the Postgraduate Scientific Research Innovation Project of Hunan Province (No. CX20210922)
文摘A severe accident in a marine nuclear reactor leads to radionuclide leakage,which causes hidden dangers to workers and has adverse effects of environmental pollution.It is necessary to propose a novel approach to radionuclide diffusion in a confined environment after a severe accident in a marine nuclear reactor.Therefore,this study proposes a new method for the severe accident analysis program MELCOR coupled with computational fluid dynamics scSTREAM to study radioactive diffusion in severe accidents.The radionuclide release fraction and temperature calculated by MELCOR were combined with the scSTREAM calculations to study the radionuclide diffusion behavior and the phenomenon of radionuclide diffusion in different space environments of the reactor under the conditions of varying wind velocities of the ventilation system and diffusion speed.The results show that the wind velocity of the ventilation system is very small or zero,and the turbulent diffusion of radionuclides is not obvious and diffuses slowly in the form of condensation sedimentation and gravity settlement.When the wind speed of the ventilation system increases,the flow of radionuclides meets the wall and forms eddy currents,affecting the time variation of radionuclides diffusing into chamber 2.The wind velocity of the ventilation system and the diffusion speed has opposite effects on the time variation trend of radionuclide diffusion into the four chambers.
基金The work was funded by the National Natural Science Foundation of China(No.41701061,No.41761144075,No.41771075,and No.41271091).
文摘A total of 71,177 glaciers exist on the Qinghai-Tibet Plateau,according to the Randolph Glacier Inventory(RGI 6.0).Despite their large number,glacier ice thickness data are relatively scarce.This study utilizes digital elevation model data and ground-penetrating radar thickness measurements to estimate the distribution and variation of ice thickness of the Longbasaba Glacier using Glacier bed Topography(GlabTop),a full-width expansion model,and the Huss and Farinotti(HF)model.Results show that the average absolute deviations of GlabTop,the full-width expansion model,and the HF model are 9.8,15.5,and 10.9 m,respectively,indicating that GlabTop performs the best in simulating glacier thickness distribution.During 1980−2015,the Longbasaba Glacier thinned by an average of 7.9±1.3 m or 0.23±0.04 m/a,and its ice volume shrunk by 0.28±0.04 km3 with an average reduction rate of 0.0081±0.0001 km^3/a.In the investigation period,the area and volume of Longbasaba Lake expanded at rates of 0.12±0.01 km^2/a and 0.0132±0.0018 km3/a,respectively.This proglacial lake could potentially extend up to 5,000 m from the lake dam.
基金The study was funded by the Ministry of Science and Technology(2018YFE010010002)the National Natural Science Foundation of China(No.41771075 and No.41701061).
文摘Mountain glacier-related hazards occur worldwide in response to increasing glacier instability and human activity intensity in modern glacierized regions.These hazards are characterized by their spatial aggregation and temporal repeatability.Comprehensive knowledge about mountain glacier-related hazards is critical for hazard assessment,mitigation,and prevention in the mountain cryosphere and downstream regions.This article systematically schematizes various mountain glacier-related hazards and analyzes their inherent associations with glacier changes.Besides,the processes,manifestations,and mechanisms of each of the glacier-related hazards are summarized.In the future,more extensive and detailed systematic surveys,for example,considering integrated ground−air−space patterns,should be undertaken for typical glacierized regions to enhance existing knowledge of such hazards.The use of coupled numerical models based on multisource data is challenging but will be essential to improve our understanding of the complex chain of processes involved in thermal−hydrogeomorphic glacier-related hazards in the mountain cryosphere.
基金supported by the Fund of University of South China (No.201RGC013 and N0.200XQD052)。
文摘The Co-free Li Ni_(0.5)Mn_(1.5)O_(4)(LNMO)is a promising cathode for lithium-ion batteries owing to its high operating voltage and low costs.However,the synthesis of LNMO is generally time and energy consuming,and its practical application is hindered by the lack of a compatible electrolyte.Herein,a spray pyrolysis-based energy-saving synthesis method as well as a diluted low concentration electrolyte(0.5 M LiPF_(6) in a mixture of fluoroethylene carbonate/dimethyl carbonate/1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether(FEC:DMC:TTE,1:4:5 by volume))are proposed to address these challenges.Owing to the unique features of the precursor prepared by spray pyrolysis,well-crystallized LNMO single-crystal can be obtained within 1 h calcination at 900℃.Besides,the fluorinated interphases derived from the diluted low concentration electrolyte not only mitigate the Mn dissolution and Al corrosion at the cathode side,but also suppresses dendritic Li deposition at the anode side,thus enabling stable cycling of both LNMO and Li metal anode.Thus,30μm Li|LNMO(1.75 m A h cm^(-2))cells achieve a high capacity retention(90.9%)after 168 cycles in the diluted low concentration electrolyte.
基金the State Key Laboratory of Coal Resources and Safe Mining,China University of Mining and Technology(No.SKLCRSM22KF011)the National Natural Science Foundation of China(Nos.52130411,52104191,51974120,and 51904103)+1 种基金the Natural Science Foundation of Hunan Province(No.2021JJ40204)the Science and Technology Innovation Program of Hunan Province(No.2020RC3047).
文摘The study of pressure stimulated current(PSC)changes of rocks is significant to monitor dynamic disasters in mines and rock masses.The existing studies focus on change laws and mechanism of currents generated under the loading of rocks.An electrical and mechanics test system was established in this paper to explore the impacts of loading rates on PSCs.The results indicated that PSC curves of different rocks had different change laws under low/high loading rates.When the loading rate was relatively low,PSC curves firstly changed gently and then increased exponentially.Under high loading rates,PSC curves experienced the rapid increase stage,gentle increase stage and sudden change stage.The compressive strength could greatly affect the peak PSC in case of rock failure.The loading rate was a key factor in average PSC.Under low loading rates,the variations of PSCs conformed to the damage charge model of fracture mechanics,while they did not at the fracture moment.Under high loading rates,the PSCs at low stress didn’t fit the model due to the stress impact effects.The experimental results could provide theoretical basis for the influence of loading rates on PSCs.
基金We thank Esther Posner,PhD,from Edanz Group China(www.liwenbianji.cn/ac)for English language editing on an earlier draft of this manuscript.This work was supported by the 2017 Hunan Provincial Graduate Research Innovation Project of China(No.CX2017B649)the National Natural Science Foundation of China(No.51774134)+2 种基金the Excellent Youth Project of Hunan Provincial Department of Education(No.19B223)the Hunan Provincial Natural Science Foundation of China(No.2019JJ60044)the Hunan Provincial Natural Science Foundation of China(No.2018JJ64028).
文摘Based onmultiphase flowtheory and capillary mechanics,the dimensionless bond number expression of the influence of string grille wire spacing on droplet spreading is derived.Taking a liquid film formed by spreading droplets based on Kelvin correlation,the Young-Laplace equation,and the Hagen-Poiseuille law,an equation for calculating the thickness and height of the liquid film is established with temperature,relative humidity and molar volume of liquid phase as independent variables.According to the theory of string grille filtration and dust removal,a dust removal efficiency calculation model covering the wet string grille wire group is constructed based on the liquid film thickness,height,wire diameter,water film area,and vortex shedding frequency.Finally,a theoretical analysis of the influence of water film area on the efficiency of wet string grille dust removal is carried out based on the spray pressure and the ratio of string grille wire distance to wire diameter.It is found that the effect of spray pressure on water film area and dust removal efficiency is more significant than the string grille wire distance diameter ratio.Moreover,the optimized combination of wet string grille wire distance diameter ratio 0.84,wind speed 3m/s and spray pressure 0.8 MPa is found,which could provide an important reference for engineering applications.
基金supported by Hunan Provincial Education Department Funded Research Projects (Grant No.22C0221)Open Fund of State Key Laboratory of Water Resource Protection and Utilization in Coal Mining (Grant No.GJNY-18-73.11).
文摘The stability of coal pillar dams is crucial for the long-term service of underground reservoirs storing water or heat.Chemi-cal damage of coal dams induced by ions-atttacking in coal is one of the main reasons for the premature failure of coal dams.However,the diffusion process of harmful ions in coal is far from clear,limiting the reliability and durability of coal dam designs.This paper investigates sulfate diffusion in coal pillar through experimental and analytical methods.Coal specimens are prepared and exposed to sulfate solutions with different concentrations.The sulfate concentrations at different locations and time are measured.Based on experimental data and Fick's law,the time-dependent surface concentration of sulfate and diffusion coefficient are determined and formulated.Further,an analytical model for predicting sulfate diffusion in coal pillar is developed by considering dual time-dependent characteristics and Laplace transformations.Through comparisons with experimental data,the accuracy of the analytical model for predicting sulfate diffusion is verified.Further,sulfate diffusions in coal dams for different concentrations of sulfate in mine water are investigated.It has been found that the sulfate concen-tration of exposure surface and diffusion coefficient in coal are both time-dependent and increase with time.Conventional Fick's law is not able to predict the sulfate diffusion in coal pillar due to the dual time-dependent characteristics.The sulfate attacking makes the coal dam a typical heterogeneous gradient structure.For sulfate concentrations 0.01-0.20 mol/L in mine water,it takes almost 1.5 and 4 years for sulfate ions to diffuse 9.46 and 18.92 m,respectively.The experimental data and developed model provide a practical method for predicting sulfate diffusion in coal pillar,which helps the service life design of coal dams.
基金sponsored by the National Natural Science Foundation of China (Grant No. 11705086)Natural Science Foundation of Hunan Province (Grant No. 2018JJ3424)Fund of Hunan Provincial Department of Education (Grant No. 16C1387)
文摘Extraction of uranium from low-permeability sandstone is a long-standing challenge in mining.The improvement of sandstone permeability has therefore become a key research focus to improve the uranium leaching effect.To address the low-permeability problem and corresponding leaching limits,leaching experiments are performed using newly developed equipment that could apply low-frequency vibration to the sandstone samples.The test results indicate that low-frequency vibration significantly improves the uranium leaching performance and permeability of the sandstone samples.The leaching effect of low-frequency vibration treatment is approximately nine times more effective than ultrasonic vibration treatment,whereas the concentration of uranium ions generated without vibration treatment is not detectable.Mathematical model that considers the combined action of physico-mechanical vibration and chemical erosion is established to describe the effect of low-frequency vibration on the permeability.The calculated results are in good agreement with the tested permeability values.This study thus offers a new method to effectively leach more uranium from low-permeability sandstone using CO_(2)+O_(2)and provides an insight into the impact of low-frequency vibration on the uranium leaching process.
基金This research was supported by Yunnan University(YJRC3201702)the National Natural Science Foundation of China(Grant Nos.41761144075,41690142,41941015,41771075,41871096,41671057,41801052,41561016,41701061,41861013)the Ministry of Science and Technology(2013FY111400).
文摘As one of the five components of Earth's climatic system,the cryosphere has been undergoing rapid shrinking due to global warming.Studies on the formation,evolution,distribution and dynamics of cryospheric components and their interactions with the human system are of increasing importance to society.In recent decades,the mass loss of glaciers,including the Greenland and Antarctic ice sheets,has accelerated.The extent of sea ice and snow cover has been shrinking,and permafrost has been degrading.The main sustainable development goals in cryospheric regions have been impacted.The shrinking of the cryosphere results in sea-level rise,which is currently affecting,or is soon expected to affect,17 coastal megacities and some small island countries.In East Asia,South Asia and North America,climate anomalies are closely related to the extent of Arctic sea ice and snow cover in the Northern Hemisphere.Increasing freshwater melting from the ice sheets and sea ice may be one reason for the slowdown in Atlantic meridional overturning circulation in the Arctic and Southern Oceans.The foundations of ports and infrastructure in the circum-Arctic permafrost regions suffer from the consequences of permafrost degradation.In high plateaus and mountainous regions,the cryosphere's shrinking has led to fluctuations in river runoff,caused water shortages and increased flooding risks in certain areas.These changes in cryospheric components have shown significant heterogeneity at different temporal and spatial scales.Our results suggest that the quantitative evaluation of future changes in the cryosphere still needs to be improved by enhancing existing observations and model simulations.Theoretical and methodological innovations are required to strengthen social economies'resilience to the impact of cryospheric change.
基金National Natural Science Foundation of China(Nos.41971423,31972951,41771462)Hunan Provincial Natural Science Foundation of China(No.2020JJ3020)+1 种基金Science and Technology Planning Project of Hunan Province(No.2019RS2043,2019GK2132)Outstanding Youth Project of Education Department of Hunan Province(No.18B224)。
文摘Automatic and accurate classification is a fundamental problem to the analysis and modeling of LiDAR(Light Detection and Ranging)data.Recently,convolutional neural network(ConvNet or CNN)has achieved remarkable performance in image recognition and computer vision.While significant efforts have also been made to develop various deep networks for satellite image scene classification,it still needs to further investigate suitable deep learning network frameworks for 3D dense mobile laser scanning(MLS)data.In this paper,we present a simple deep CNN for multiple object classification based on multi-scale context representation.For the pointwise classification,we first extracted the neighboring points within spatial context and transformed them into a three-channel image for each point.Then,the classification task can be treated as the image recognition using CNN.The proposed CNN architecture adopted common convolution,maximum pooling and rectified linear unit(ReLU)layers,which combined multiple deeper network layers.After being trained and tested on approximately seven million labeled MLS points,the deep CNN model can classify accurately into nine classes.Comparing with the widely used ResNet algorithm,this model performs better precision and recall rates,and less processing time,which indicated the significant potential of deep-learning-based methods in MLS data classification.
文摘Solid oxide fuel cells(SOFCs)and electrolysis cells(SOECs)are promising energy conversion devices,on whose basis green hydrogen energy technologies can be developed to support the transition to a carbon-free future.As compared with oxygen-conducting cells,the operational temperatures of protonic ceramic fuel cells(PCFCs)and electrolysis cells(PCECs)can be reduced by several hundreds of degrees(down to low-and intermediatetemperature ranges of 400–700C)while maintaining high performance and efficiency.This is due to the distinctive characteristics of charge carriers for proton-conducting electrolytes.However,despite achieving outstanding lab-scale performance,the prospects for industrial scaling of PCFCs and PCECs remain hazy,at least in the near future,in contrast to commercially available SOFCs and SOECs.In this review,we reveal the reasons for the delayed technological development,which need to be addressed in order to transfer fundamental findings into industrial processes.Possible solutions to the identified problems are also highlighted.
基金The project is fully funded by the Natural Science Foundation of China Program(Grant Nos.42001052 and 41871052)Startup Research Funding of Northeast Forestry University for Chengdong Outstanding Youth Scholarship(YQ2020-10)+1 种基金Chengdong Leadership(LJ2020-01)the State Key Laboratory of Frozen Soils Engineering Open Fund Project(Grant No.SKLFSE202008).
文摘In boreal forest ecosystems, permafrost and forest types are mutually interdependent;permafrost degradation impacts forest ecosystem structure and functions. The Xing’an permafrost in Northeast China is on the southern margin of the Eastern Asia latitudinal permafrost body. Under a warming climate, permafrost undergoes rapid and extensive degradation. In this study, the frost-number (Fn) model based on air temperatures and ground surface temperatures was used to predict the distribution of the Xing’an permafrost, and, temporal and spatial changes in air and ground-surface temperatures from 1961 to 2019 are analyzed. The results show that Northeast China has experienced a rapid and substantial climate warming over the past 60 years. The rises in mean annual air and mean annual ground-surface temperatures were higher in permafrost zones than those in the seasonal frost zone. The frost numbers of air and ground-surface temperatures were calculated for determining the southern limit of latitudinal permafrost and for permafrost zonation. The southern limits of discontinuous permafrost, sporadic permafrost, and latitudinal permafrost moved northward significantly. According to the air-temperature frost-number criteria for permafrost zoning, compared with that in the 1960s, the extent of Xing’an permafrost in Northeast China had decreased by 40.6% by the 2010s. With an average rate of increase in mean annual air temperatures at 0.03 ℃ a^(−1), the extent of permafrost in Northeast China will decrease to 26.42 × 10^(4) by 2020, 14.69 × 10^(4) by 2040 and to 11.24 × 10^(4) km^(2) by 2050. According to the ground-surface temperature frost-number criteria, the southern limit of latitudinal permafrost was at the 0.463. From the 1960s to the 2010s, the extent of latitudinal permafrost declined significantly. Due to the nature of the ecosystem-protected Xing’an-Baikal permafrost, management and protection (e.g., more prudent and effective forest fire management and proper logging of forests) of the Xing’an permafrost eco-environment should be strengthened.
文摘Prof.Xie Zichu passed away on January 25,2020 in Changsha,Hunan Province,China at the age of 83 years old.Being one of the internationally renowned and highly respected glaciologists of China,this issue is dedicated with all respect in memory of him for his life-long effort and contribution to advance studies on glaciology in China.He has undertaken field investigations on glacier mass balance.
基金supported by the National Natural Science Foundation of China(Grant Nos.52272216 and 51972183)the Hundred Youth Talents Program of Hunan,and the Startup Funding for Talents at University of South China.
文摘A new medium entropy material LiCo_(0.25)Fe_(0.25)Mn_(0.2)5Ni_(0.2)5O_(2)(LCFMN)is proposed as a cathode for proton-conducting solid oxide fuel cells(H-SOFCs).Unlike traditional LiXO_(2)(X=Co,Fe,Mn,Ni)lithiated oxides,which have issues like phase impurity,poor chemical compatibility,or poor fuel cell performance,the new LCFMN material mitigates these problems,allowing for the successful preparation of pure phase LCFMN with good chemical and thermal compatibility to the electrolyte.Furthermore,the entropy engineering strategy is found to weaken the covalence bond between the metal and oxygen in the LCFMN lattice,favoring the creation of oxygen vacancies and increasing cathode activity.As a result,the H-SOFC with the LCFMN cathode achieves an unprecedented fuel cell output of 1803 mW·cm^(−2)at 700℃,the highest ever reported for H-SOFCs with lithiated oxide cathodes.In addition to high fuel cell performance,the LCFMN cathode permits stable fuel cell operation for more than 450 h without visible degradation,demonstrating that LCFMN is a suitable cathode choice for H-SOFCs that combining high performance and good stability.
