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Structure and Electrorheological Performance of Nanosized Y_2O_3-Doped TiO_2 Particle Materials 被引量:1
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作者 马淑珍 李淑新 +5 位作者 廖复辉 许明远 李俊然 陈淑梅 魏宸官 高松 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第2期242-244,共3页
The nanosized particle materials of doped-TiO_2 with Y_2O_3 were prepared by means of sol-gel technique for use in electrorheological (ER) fluids, and their crystal structures were measured by X-ray diffraction (XRD) ... The nanosized particle materials of doped-TiO_2 with Y_2O_3 were prepared by means of sol-gel technique for use in electrorheological (ER) fluids, and their crystal structures were measured by X-ray diffraction (XRD) analysis. To compare with the pure TiO_2, a distinct enhancement in the shear stress under dc electric field was found by using such materials. This can be explained by the increase of the dielectric loss and dielectric constant at low frequency. The effects of the crystal structure of the particles on the dielectric property and ER performance of materials were investigated. 展开更多
关键词 inorganic nonmetallic materials crystal structure ER performance doped-TiO_2 rare earths
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Preparation and Electrorheological Property of NaNO_3-Doped Y_2O_3 Material 被引量:1
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作者 霍莉 马淑珍 +4 位作者 商艳丽 贾云玲 许明远 李俊然 张少华 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第1期39-43,共5页
A new class of electrorheological (ER) material using rare earth (RE = Y) oxide as the substrate, NaNO3- doped Y2O3 materials, were synthesized using Na2CO3 and Y(NO3)3 as starting materials. Their ER performanc... A new class of electrorheological (ER) material using rare earth (RE = Y) oxide as the substrate, NaNO3- doped Y2O3 materials, were synthesized using Na2CO3 and Y(NO3)3 as starting materials. Their ER performance, dielectric property, and crystal structure were studied. The results show that doping NaNO3 can markedly enhance the ER activity of the Y2O3 material. For the suspensions of these materials in dimethyl silicone oil, a clear dependence of the shear stress on the doping degree of NANO3 was observed, and the optimal value of Na/Y molar ratio of 0.6 in doping degree was discovered, the relative viscosity ηr( ηE/η0, E = 4.2 kV·mm^-1) of the suspensions is nine times higher than that of pure Y2O3 material. The new results of the relationship between ER effect and the microstructure were obtained, which are helpful for further understanding the mechanism of ER effect and synthesizing a good ER material. 展开更多
关键词 electrorheological property yttrium oxide NaNO3 doping microstructure rare earths
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Effect of Y_2(CO_3)_3 and Surfactants on Electrorheological Performance of SiO_2 Particle Materials
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作者 许明远 马淑珍 +4 位作者 李淑新 李俊然 张少华 魏宸官 高松 《Journal of Rare Earths》 SCIE EI CAS CSCD 2004年第5期586-590,共5页
The SiO_2 particle material has weak electrorheological (ER) activity. The ER performance of the SiO_2 particles can be ameliorated after adsorbing Y_2(CO_3)_3. In this paper, the effect of Y_2(CO_3)_3 and different s... The SiO_2 particle material has weak electrorheological (ER) activity. The ER performance of the SiO_2 particles can be ameliorated after adsorbing Y_2(CO_3)_3. In this paper, the effect of Y_2(CO_3)_3 and different surfactants on the ER performance of the SiO_2 particle materials is investigated. The results show that anionic or cationic surfactants maybe enhance the ER activity of SiO_2 material, and nonionic surfactants cannot when surfactants are added during the process of the SiO_2 particle preparation, only the anionic surfactant, AES, can enhance markedly the ER performance of the material. The surface area, pore volume and pore diameter of the particles were measured. The effect of Y_2(CO_3)_3 and the surfactants on the microstructure of SiO_2 materials and the relationship between ER effect and the microstructure are described. 展开更多
关键词 SURFACTANT adsorption SiO_2 particle material ER performance rare earths
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Preparation and Electrorheological Performance of SiO_2 Particle Materials Adsorbed with YF_3, Y_2(CO_3)_3, Y_2(C_2O_4)_3 or YPO_4
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作者 许明远 马淑珍 +3 位作者 李淑新 李俊然 张邵华 高松 《Journal of Rare Earths》 SCIE EI CAS CSCD 2002年第6期666-669,共4页
The SiO 2 adsorbing YF 3, Y 2(CO 3) 3, Y 2(C 2O 4) 3 and YPO 4, respectively, formed four systems of particle materials: SiO 2·YF 3, SiO 2·Y 2(CO 3) 3 , SiO 2·Y 2(C 2O 4) 3 and SiO ... The SiO 2 adsorbing YF 3, Y 2(CO 3) 3, Y 2(C 2O 4) 3 and YPO 4, respectively, formed four systems of particle materials: SiO 2·YF 3, SiO 2·Y 2(CO 3) 3 , SiO 2·Y 2(C 2O 4) 3 and SiO 2·YPO 4. The electrorheological(ER) behavior of the electrorheological fluids (ERF) prepared by dispersing them in silicone oil was tested at 20 ℃ under d.c. field. The results show that the system of SiO 2·YF 3 does not display ER activity, and the ER performance of the particle materials of SiO 2·Y 2(CO 3) 3 is the best among them. The shearing stress of ERF with SiO 2·Y 2(CO 3) 3 particles is 1.644 KPa and the relative viscosity η r(=η E/η 0) is 20.3 (under field strength E=4200 V·mm -1) while the adsorbed content of Y 2(CO 3) 3 in the SiO 2 particle materials is 12.4%(mass fraction). 展开更多
关键词 rare earths adsorb particle material ER performance
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Effect of Microstructure on Electrorheological Property for Pure TiO_(2) Particle Material
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作者 Yanli SHANG Shuzhen MA +3 位作者 Junran LI Mingxiu LI Juan WANG Shaohua ZHANG 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2006年第4期572-576,共5页
Pure titanium dioxide (TiO2) particle materials were prepared by hydrolyzing titanium tetrachloride (TiCl4). The microstructures of these materials were determined by X-ray diffraction (XRD), accelerated surface... Pure titanium dioxide (TiO2) particle materials were prepared by hydrolyzing titanium tetrachloride (TiCl4). The microstructures of these materials were determined by X-ray diffraction (XRD), accelerated surface area and porosimetry apparatus (BET), and transmission electron microscopy (TEM). The TiO2 materials obtained by calcinations under different temperatures distinctly revealed different microstructures in crystal structure type, surface area, pore size, pore volume and grain size. The relationship between the microstructure of the TiO2 materials and their electrorheological (ER) activity was investigated. Anatase titania particles have better ER performance than rutile titania particles. Amorphous TiO2 materials display higher ER activity than the crystalline titania materials. A large pore volume can be more advantageous in improving the ER effect of a particle material. 展开更多
关键词 Titanium dioxide TEMPERATURE MICROSTRUCTURE Electrorheolagical property
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