When the contacts of a medium-voltage DC air circuit breaker(DCCB) are separated, the energy distribution of the arc is determined by the formation process of the near-electrode sheath. Therefore, the voltage drop thr...When the contacts of a medium-voltage DC air circuit breaker(DCCB) are separated, the energy distribution of the arc is determined by the formation process of the near-electrode sheath. Therefore, the voltage drop through the near-electrode sheath is an important means to build up the arc voltage, which directly determines the current-limiting performance of the DCCB. A numerical model to describe the near-electrode sheath formation process can provide insight into the physical mechanism of the arc formation, and thus provide a method for arc energy regulation. In this work, we establish a two-dimensional axisymmetric time-varying model of a medium-voltage DCCB arc when interrupted by high current based on a fluid-chemical model involving 16 kinds of species and 46 collision reactions. The transient distributions of electron number density, positive and negative ion number density, net space charge density, axial electric field, axial potential between electrodes, and near-cathode sheath are obtained from the numerical model. The computational results show that the electron density in the arc column increases, then decreases, and then stabilizes during the near-cathode sheath formation process, and the arc column's diameter gradually becomes wider. The 11.14 V–12.33 V drops along the17 μm space charge layer away from the cathode(65.5 k V/m–72.5 k V/m) when the current varies from 20 k A–80 k A.The homogeneous external magnetic field has little effect on the distribution of particles in the near-cathode sheath core,but the electron number density at the near-cathode sheath periphery can increase as the magnetic field increases and the homogeneous external magnetic field will lead to arc diffusion. The validity of the numerical model can be proven by comparison with the experiment.展开更多
The Young's modulus, shear modulus and Poisson's ratio of monolayer arsenene with different sizes were calculated by finite element method, so as to explore the influence of dimension and orientation on the me...The Young's modulus, shear modulus and Poisson's ratio of monolayer arsenene with different sizes were calculated by finite element method, so as to explore the influence of dimension and orientation on the mechanical properties of monolayer arsenene. The calculation results show that the small size has a significant effect on the mechanical properties of the monolayer arsenene. The smaller the size, the larger the Young's modulus and Poisson's ratio of the monolayer arsenene. The size change has a great influence on the Young's modulus of the arsenene handrail direction, and the Young's modulus of the zigzag direction is not sensitive to the size change. Similarly, the size change has a significant effect on the shear modulus of arsenene in the handrail direction, while the shear modulus in the zigzag direction has no significant effect on its size change. For the Poisson's ratio, the situation is just the opposite, and the effect of the size change on the Poisson's ratio of the arsenene zigzag direction is greater than that of the handrail direction.展开更多
High-precision and real-time diagnosis of sucker rod pumping system(SRPS)is important for quickly mastering oil well operations.Deep learning-based method for classifying the dynamometer card(DC)of oil wells is an eff...High-precision and real-time diagnosis of sucker rod pumping system(SRPS)is important for quickly mastering oil well operations.Deep learning-based method for classifying the dynamometer card(DC)of oil wells is an efficient diagnosis method.However,the input of the DC as a two-dimensional image into the deep learning framework suffers from low feature utilization and high computational effort.Additionally,different SRPSs in an oil field have various system parameters,and the same SRPS generates different DCs at different moments.Thus,there is heterogeneity in field data,which can dramatically impair the diagnostic accuracy.To solve the above problems,a working condition recognition method based on 4-segment time-frequency signature matrix(4S-TFSM)and deep learning is presented in this paper.First,the 4-segment time-frequency signature(4S-TFS)method that can reduce the computing power requirements is proposed for feature extraction of DC data.Subsequently,the 4S-TFSM is constructed by relative normalization and matrix calculation to synthesize the features of multiple data and solve the problem of data heterogeneity.Finally,a convolutional neural network(CNN),one of the deep learning frameworks,is used to determine the functioning conditions based on the 4S-TFSM.Experiments on field data verify that the proposed diagnostic method based on 4S-TFSM and CNN(4S-TFSM-CNN)can significantly improve the accuracy of working condition recognition with lower computational cost.To the best of our knowledge,this is the first work to discuss the effect of data heterogeneity on the working condition recognition performance of SRPS.展开更多
The H+NaF reaction is investigated at the quantum state-resolved level using the time-dependent wavepacket method based on a set of accurate diabatic potential energy surfaces.Oscillatory structures in the total react...The H+NaF reaction is investigated at the quantum state-resolved level using the time-dependent wavepacket method based on a set of accurate diabatic potential energy surfaces.Oscillatory structures in the total reaction probability indicate the presence of the short-lived intermediate complex.展开更多
Rapid online analysis of liquid slag is essential for optimizing the quality and energy efficiency of steel production. To investigate the key factors that affect the online measurement of refined slag using laser-ind...Rapid online analysis of liquid slag is essential for optimizing the quality and energy efficiency of steel production. To investigate the key factors that affect the online measurement of refined slag using laser-induced breakdown spectroscopy(LIBS), this study examined the effects of slag composition and temperature on the intensity and stability of the LIBS spectra. The experimental temperature was controlled at three levels: 1350℃, 1400℃, and 1450℃. The results showed that slag composition and temperature significantly affected the intensity and stability of the LIBS spectra. Increasing the Fe content and temperature in the slag reduces its viscosity, resulting in an enhanced intensity and stability of the LIBS spectra. Additionally, 42 refined slag samples were quantitatively analyzed for Fe, Si, Ca, Mg, Al, and Mn at 1350℃, 1400℃, and 1450℃.The normalized full spectrum combined with partial least squares(PLS) quantification modeling was used, using the Ca Ⅱ 317.91 nm spectral line as an internal standard. The results show that using the internal standard normalization method can significantly reduce the influence of spectral fluctuations. Meanwhile, a temperature of 1450℃ has been found to yield superior results compared to both 1350℃ and 1400℃, and it is advantageous to conduct a quantitative analysis of the slag when it is in a “water-like” state with low viscosity.展开更多
Anode materials are an essential part of lithium-ion batteries(LIBs),which determine the performance and safety of LIBs.Currently,graphite,as the anode material of commercial LIBs,is limited by its low theoretical cap...Anode materials are an essential part of lithium-ion batteries(LIBs),which determine the performance and safety of LIBs.Currently,graphite,as the anode material of commercial LIBs,is limited by its low theoretical capacity of 372 mA·h·g^(−1),thus hindering further development toward high-capacity and large-scale applications.Alkaline earth metal iron-based oxides are considered a promising candidate to replace graphite because of their low preparation cost,good thermal stability,superior stability,and high electrochemical performance.Nonetheless,many issues and challenges remain to be addressed.Herein,we systematically summarize the research progress of alkaline earth metal iron-based oxides as LIB anodes.Meanwhile,the material and structural properties,synthesis methods,electrochemical reaction mechanisms,and improvement strategies are introduced.Finally,existing challenges and future research directions are discussed to accelerate their practical application in commercial LIBs.展开更多
Compared with the conventional casting process, digital pattern-less casting technology has many advantages such as good machining accuracy, a short processing cycle, and low production cost. It is a new rapid manufac...Compared with the conventional casting process, digital pattern-less casting technology has many advantages such as good machining accuracy, a short processing cycle, and low production cost. It is a new rapid manufacturing technology for castings, integrated with CAD/CAM, casting, CNC machining and many other advanced technologies. With this digital casting technology, no pattern is needed for making molds; it is precise, f lexible, and green. Usually, art castings have complex structures and are made in small batches or even made in a single-piece, especially for large-sized art castings. So it has the shortcomings of high cost, low eff iciency and long time for making a pattern to produce art castings with the conventional casting processes. However, the digital pattern-less casting technology can be applied to fabricate art castings, since it can greatly shorten the manufacturing cycle and lower the production cost, thus having a very good prospect. In this study, based on the digital pattern-less casting technology, a plaque casting with artistic Chinese characters(a Chinese poem) was designed and manufactured, and the production process was demonstrated in detail.展开更多
The squeeze cast technology is only applicable, at present, to the castings with a ratio of height to thickness less than 3.5. Researching the squeeze cast technology for castings with a large ratio of height to thick...The squeeze cast technology is only applicable, at present, to the castings with a ratio of height to thickness less than 3.5. Researching the squeeze cast technology for castings with a large ratio of height to thickness will broaden the applicable range of the advanced casting technology. This paper describes a study of the temperature distribution during solidification for castings with a ratio of height to thickness of 7 by the methods of experiment and computer simulation. The shrinkage porosity distribution in the castings and the mechanical properties of the castings were also researched. The experimental and simulated results show that increasing squeeze force, or enhancing mold temperature, cannot reduce the shrinkage porosities in the castings. When castings solidify in a sequential manner and the squeeze force effectively acts on the surface of the liquid metal, the shrinkage porosities in the castings are eliminated and mechanical properties are clearly improved.展开更多
To enhance the performance of in-situ synthesized 6vol.%(Ti C+Ti B)/TC4 titanium matrix composites fabricated by casting,a variety of heat treatment processes were carried out.Upon conducting microstructure observatio...To enhance the performance of in-situ synthesized 6vol.%(Ti C+Ti B)/TC4 titanium matrix composites fabricated by casting,a variety of heat treatment processes were carried out.Upon conducting microstructure observations following various heat treatments,it was found that the composites exhibit a basketweave microstructure,consisting of an α phase and a transformed β phase.The sizes of(α+β) phases were found to be refined to varying degrees after the heat treatment processes,while the morphology of Ti B remains largely unchanged and Ti C becomes granulated.Compressive testing revealed that all composites subjected to different heat treatments demonstrate a notable increase in ultimate compressive strength as well as a slight improvement in plasticity compared to the as-cast state.The results of the tribological performance test indicated that the heat-treated composites exhibit lower average friction coefficient,specific wear rate,and worn surface roughness compared to the as-cast composite.Among the heat treatment processes studied,the composite solution heated at 1,150 °C/1 h followed by air cooling,then 950 °C/1 h followed by air cooling,and finally 500 °C/4 h followed by air cooling,demonstrates the highest levels of hardness,compressive strength,and wear resistance.These improvements are attributed to the combined effects of solid solution strengthening,grain refinement,and the pinning of dislocation slip.展开更多
Fault activation has been the focus of research community for years.However,the studies of fault activation remain immature,such as the fault activation mode and its major factors under constant normal stiffness(CNS)c...Fault activation has been the focus of research community for years.However,the studies of fault activation remain immature,such as the fault activation mode and its major factors under constant normal stiffness(CNS)conditions associated with large thickness of fault surrounding rock mass.In this study,the rock friction experiments were conducted to understand the fault activation modes under the CNS conditions.Two major parameters,i.e.the initial normal stress and loading rate,were considered and calibrated in the tests.To reveal the response mechanism of fault activation,the local strains near the fault plane were recorded,and the macroscopic stresses and displacements were analyzed.The testing results show that the effect of displacement-controlled loading rate is more pronounced under the CNS conditions than that under constant normal load(CNL)conditions.Both the normal and shear stresses drop suddenly when the stick-slip occurs.The decrease and increase of the normal stress are synchronous with the shear stress in the regular stick-slip scenario,but mismatch with the shear stress during the chaotic stick-slip process.The results are helpful for understanding the fault sliding mode and the prediction and prevention of fault slip.展开更多
A method to eliminate spiral waves and spatiotemporal chaos by using the synchronization transmission technology of network signals is proposed in this paper.The character of the spiral waves and the spatiotemporal ch...A method to eliminate spiral waves and spatiotemporal chaos by using the synchronization transmission technology of network signals is proposed in this paper.The character of the spiral waves and the spatiotemporal chaos in the Fitzhugh-Nagumo model is presented.The network error evolution equation with spatiotemporal variables and the corresponding eigenvalue equation are determined based on the stability theory,and the global synchronization condition is obtained.Simulations are made in a complex network with Fitzhugh-Nagumo models as the nodes to verify the effectiveness of the synchronization transmission principle of the network signal.展开更多
University student education is the main part of higher education in China. Therefore, the comprehensive quality of university students shows the level of higher education. Ecological literacy is the basic literacy of...University student education is the main part of higher education in China. Therefore, the comprehensive quality of university students shows the level of higher education. Ecological literacy is the basic literacy of college students under the background of green development to build socialism with Chinese characteristics. The green development education is based on the research idea of the relationship between the individual and the surrounding environment in ecology, which requires respecting the subjectivity of the active object, paying attention to the integrity and connection of the object. Compared with the traditional education, green development education pays more attention to the cultivation of moral quality and sound personality of the educated, and it can make the students understand the ecological environment. Under the premise of ecological system and the mechanism of biological growth and development, respect and love of life are formed naturally, and then the universal concern for environment and others is formed. College students, as advanced groups of young people, are leading the social fashion and influencing the social ethical environment. Ecological literacy is the new requirement of the times for college students. We should integrate the education of green development into the ideological education,make great efforts to shape the ecological ethical system of college students, and cultivate their ecological consciousness, ecological thinking and behavior habits. It is an important issue for ideological education to improve the quality of green development in an all-round way.展开更多
Metal-organic frameworks(MOFs)have attracted considerable research attention as a new type of porous material for catalytic applications.Herein,2,5-dihydroxyterephthalic acid was proposed to replace conventional terep...Metal-organic frameworks(MOFs)have attracted considerable research attention as a new type of porous material for catalytic applications.Herein,2,5-dihydroxyterephthalic acid was proposed to replace conventional terephthalic acid and reacted with chromic nitrate nonahydrate to synthesize a functional metal–organic framework(FMIL-101).This was then used to immobilize various compound ionic liquids to prepare three ionic liquids immobilized on FMIL-101 catalysts,namely,FMIL-101-[HeMIM]Cl/(ZnBr_(2))_(2),FMIL-101-[CeMIM]Cl/(ZnBr_(2))_(2),and FMIL-101-[AeMIM]Br/(ZnBr_(2))_(2).After characterization by Fourier-transform infrared spectroscopy,X-ray diffraction,ultraviolet spectroscopy,thermogravimetry,specific surface area analysis,and scanning electron microscopy,the catalysts were used to mediate cycloaddition reactions between carbon dioxide(CO_(2))and propylene oxide.The effects of reaction temperature,reaction pressure,reaction time,and catalyst dosage on the catalytic performance were investigated.The results revealed that the FMIL-101-supported CIL catalysts afforded the target product propylene carbonate with good catalytic performance and thermal stability.The optimal catalyst,FMIL-101-[CeMIM]Cl/(ZnBr_(2))_(2),displayed a propylene oxide conversion of 98.64%and a propylene carbonate selectivity of 96.63%at a reaction temperature of 110℃,a reaction pressure of 2.0 MPa,a catalyst dosage of 2.0%relative to propylene oxide,and a reaction time of 2.5 h.In addition,the conversion and selectivity of the catalyst decreased slightly after four cycles.Additionally,the catalyst decreased slightly in catalytic performance after being recycled four times.展开更多
Vanadium oxides have attracted one’s wide attention due to their diverse valences and spatial structure as cathode for aqueous zinc ion batteries.However,a strong electrostatic interaction exists between Zn ions and ...Vanadium oxides have attracted one’s wide attention due to their diverse valences and spatial structure as cathode for aqueous zinc ion batteries.However,a strong electrostatic interaction exists between Zn ions and host materials,which leads to their sluggish reaction kinetics and inferior structural stability.Herein,we design a kind of vanadium-based electrode materials with abundant phase boundaries and oxygen defects.The assembled Zn//V_(6)O_(13)/VO_(2) batteries deliver a specific capacity of 498.3 mA h g^(-1)at 0.2 A g^(-1) and retain a capacity of 485.8 mA h g^(-1)after 100 cycles.Moreover,they achieve a retention rate of 96.8% after 5000 cycles at 10 A g^(-1).The soft pack cells also show excellent mechanical stability at different folding conditions.展开更多
Temperature has an important impact on the corrosion resistance of mold with cooling channels prepared by casting method.The effect of preheating temperature of the mold and the carbon fiber core on the roughness and ...Temperature has an important impact on the corrosion resistance of mold with cooling channels prepared by casting method.The effect of preheating temperature of the mold and the carbon fiber core on the roughness and corrosion resistance of U-shaped cooling channels made of Al-12Si alloy was examined in depth.The experimental results suggest that as the preheating temperature increased from 273 K to 573 K,the roughness of the inner wall of the cooling channel reduced from 96.6μm to 77.0μm.When the preheating temperature continued to increase to 723 K,the roughness increased to 85.3μm.The wetting between the Al melt and the carbon fiber will reduce micro bubbles and waves on the channel wall as the preheating temperature rises,thereby reducing the roughness.However,with the further increase of preheating temperature,it will increase the solidification time of the Al melt.At this time,the carbon fiber and Al melt will take more time to react,which increases the roughness of the channel wall to a certain extent.The results of exfoliation corrosion show that the larger roughness will aggravate exfoliation corrosion.The prolongation of high temperature reaction time between the carbon fiber and the Al melt will lead to the segregation of Si,which is easy to cause intergranular corrosion.Therefore,reasonable preheating temperature has an important impact on the roughness and corrosion resistance of U-shaped cooling channels.展开更多
A type of heat-curing phosphate binder was proposed,and orthogonal experiments based on the tensile strength of sand samples determined that the optimal composition of the binder was phosphoric acid:water:aluminum hyd...A type of heat-curing phosphate binder was proposed,and orthogonal experiments based on the tensile strength of sand samples determined that the optimal composition of the binder was phosphoric acid:water:aluminum hydroxide:magnesium oxide:boric acid=300:70:60:9:8.Adding 10%polyvinyl alcohol(PVA)solution during the sand mixture process can significantly improve the 24 h tensile strength of sand samples.When adding 30 g phosphate binder and 8 g 10%PVA solution,the initial tensile strength of the sample is 0.76 MPa,the room temperature tensile strength is 2.29 MPa,and the 24 h tensile strength is 1.73 MPa.The heat-curing modified phosphate sand mold has high tensile strength and low gas generation,which can meet general casting production requirements.展开更多
To obtain better comprehensive properties of cast Al-Cu-Mg alloys,the secondary aging(T6I6)process(including initial aging,interrupted aging and re-aging stages)was optimized by an orthogonal method.The microstructure...To obtain better comprehensive properties of cast Al-Cu-Mg alloys,the secondary aging(T6I6)process(including initial aging,interrupted aging and re-aging stages)was optimized by an orthogonal method.The microstructures of the optimized Al-Cu-Mg alloy were observed by means of scanning electron microscopy and transmission electron microscopy,and the properties were investigated by hardness measurements,tensile tests,exfoliation corrosion tests,and intergranular corrosion tests.Results show that the S phase andθ’phase simultaneously exist in the T6I6 treated alloy.Appropriately increasing the temperature of the interrupted aging in the T6I6 process can improve the mechanical properties and corrosion resistance of Al-Cu-Mg alloy.The optimal comprehensive properties(tensile strength of 443.6 MPa,hardness of 161.6 HV)of the alloy are obtained by initial aging at 180℃for 2 h,interrupted aging at 90℃for 30 min,and re-aging at 170℃for 4 h.展开更多
Given the challenges of manufacturing resource sharing and competition in the modern manufacturing industry,the coordinated scheduling problem of parallel machine production and transportation is investigated.The prob...Given the challenges of manufacturing resource sharing and competition in the modern manufacturing industry,the coordinated scheduling problem of parallel machine production and transportation is investigated.The problem takes into account the coordination of production and transportation before production as well as the disparities in machine spatial position and performance.A non-cooperative game model is established,considering the competition and self-interest behavior of jobs from different customers for machine resources.The job from different customers is mapped to the players in the game model,the corresponding optional processing machine and location are mapped to the strategy set,and the makespan of the job is mapped to the payoff.Then the solution of the scheduling model is transformed into the Nash equilibrium of the non-cooperative game model.A Nash equilibrium solution algorithm based on the genetic algorithm(NEGA)is designed,and the effective solution of approximate Nash equilibrium for the game model is realized.The fitness function,single-point crossover operator,and mutation operator are derived from the non-cooperative game model’s characteristics and the definition of Nash equilibrium.Rules are also designed to avoid the generation of invalid offspring chromosomes.The effectiveness of the proposed algorithm is demonstrated through numerical experiments of various sizes.Compared with other algorithms such as heuristic algorithms(FCFS,SPT,and LPT),the simulated annealing algorithm(SA),and the particle swarm optimization algorithm(PSO),experimental results show that the proposed NE-GA algorithm has obvious performance advantages.展开更多
The effects of addition of minor amount of(0.5 wt.%) antimony(Sb) or gadolinium(Gd) and combined addition of Sb and Gd(0.5 wt.%,respectively) on the hot tearing susceptibility(HTS) of Mg-5Al-3Ca alloy were investigate...The effects of addition of minor amount of(0.5 wt.%) antimony(Sb) or gadolinium(Gd) and combined addition of Sb and Gd(0.5 wt.%,respectively) on the hot tearing susceptibility(HTS) of Mg-5Al-3Ca alloy were investigated experimentally using a “T-shaped” hot tearing measuring system. Various solidification parameters of the alloys were measured and calculated through thermal analysis experiments. The microstructure, grain size, and morphology of the crack zone were characterized by scanning electron microscopy and electron backscatter diffraction, and the crystal phases of the alloys were analyzed by X-ray diffraction and energy-dispersive X-ray spectroscopy. The results showed that the addition of 0.5 wt.% Gd resulted in the increase in the vulnerable temperature range(Tv) and reduced the eutectic structure content that could participate in feeding, thereby improving the HTS of the alloy. However, addition of 0.5 wt.% Sb or combined addition of Gd and Sb(0.5 wt.%, respectively) to the Mg-5Al-3Ca alloy shortened the Tvand improved the skeleton strength of the alloy, thereby reducing HTS. Moreover, significantly refined structure of Mg-5Al-3Ca-0.5Gd-0.5Sb alloy improved the feeding ability of the eutectic structure, thus the alloy exhibited the lowest HTS.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No.51977132)Key Special Science and Technology Project of Liaoning Province (Grant No.2020JH1/10100012)General Program of the Education Department of Liaoning Province (Grant No.LJKZ0126)。
文摘When the contacts of a medium-voltage DC air circuit breaker(DCCB) are separated, the energy distribution of the arc is determined by the formation process of the near-electrode sheath. Therefore, the voltage drop through the near-electrode sheath is an important means to build up the arc voltage, which directly determines the current-limiting performance of the DCCB. A numerical model to describe the near-electrode sheath formation process can provide insight into the physical mechanism of the arc formation, and thus provide a method for arc energy regulation. In this work, we establish a two-dimensional axisymmetric time-varying model of a medium-voltage DCCB arc when interrupted by high current based on a fluid-chemical model involving 16 kinds of species and 46 collision reactions. The transient distributions of electron number density, positive and negative ion number density, net space charge density, axial electric field, axial potential between electrodes, and near-cathode sheath are obtained from the numerical model. The computational results show that the electron density in the arc column increases, then decreases, and then stabilizes during the near-cathode sheath formation process, and the arc column's diameter gradually becomes wider. The 11.14 V–12.33 V drops along the17 μm space charge layer away from the cathode(65.5 k V/m–72.5 k V/m) when the current varies from 20 k A–80 k A.The homogeneous external magnetic field has little effect on the distribution of particles in the near-cathode sheath core,but the electron number density at the near-cathode sheath periphery can increase as the magnetic field increases and the homogeneous external magnetic field will lead to arc diffusion. The validity of the numerical model can be proven by comparison with the experiment.
基金Funded by Project of Liaoning Provincial Department of Education (No.LZGD2019003)。
文摘The Young's modulus, shear modulus and Poisson's ratio of monolayer arsenene with different sizes were calculated by finite element method, so as to explore the influence of dimension and orientation on the mechanical properties of monolayer arsenene. The calculation results show that the small size has a significant effect on the mechanical properties of the monolayer arsenene. The smaller the size, the larger the Young's modulus and Poisson's ratio of the monolayer arsenene. The size change has a great influence on the Young's modulus of the arsenene handrail direction, and the Young's modulus of the zigzag direction is not sensitive to the size change. Similarly, the size change has a significant effect on the shear modulus of arsenene in the handrail direction, while the shear modulus in the zigzag direction has no significant effect on its size change. For the Poisson's ratio, the situation is just the opposite, and the effect of the size change on the Poisson's ratio of the arsenene zigzag direction is greater than that of the handrail direction.
基金We would like to thank the associate editor and the reviewers for their constructive comments.This work was supported in part by the National Natural Science Foundation of China under Grant 62203234in part by the State Key Laboratory of Robotics of China under Grant 2023-Z03+1 种基金in part by the Natural Science Foundation of Liaoning Province under Grant 2023-BS-025in part by the Research Program of Liaoning Liaohe Laboratory under Grant LLL23ZZ-02-02.
文摘High-precision and real-time diagnosis of sucker rod pumping system(SRPS)is important for quickly mastering oil well operations.Deep learning-based method for classifying the dynamometer card(DC)of oil wells is an efficient diagnosis method.However,the input of the DC as a two-dimensional image into the deep learning framework suffers from low feature utilization and high computational effort.Additionally,different SRPSs in an oil field have various system parameters,and the same SRPS generates different DCs at different moments.Thus,there is heterogeneity in field data,which can dramatically impair the diagnostic accuracy.To solve the above problems,a working condition recognition method based on 4-segment time-frequency signature matrix(4S-TFSM)and deep learning is presented in this paper.First,the 4-segment time-frequency signature(4S-TFS)method that can reduce the computing power requirements is proposed for feature extraction of DC data.Subsequently,the 4S-TFSM is constructed by relative normalization and matrix calculation to synthesize the features of multiple data and solve the problem of data heterogeneity.Finally,a convolutional neural network(CNN),one of the deep learning frameworks,is used to determine the functioning conditions based on the 4S-TFSM.Experiments on field data verify that the proposed diagnostic method based on 4S-TFSM and CNN(4S-TFSM-CNN)can significantly improve the accuracy of working condition recognition with lower computational cost.To the best of our knowledge,this is the first work to discuss the effect of data heterogeneity on the working condition recognition performance of SRPS.
基金supported by the National Natural Science Foundation of China(Grant Nos.12374226 and 12304273)。
文摘The H+NaF reaction is investigated at the quantum state-resolved level using the time-dependent wavepacket method based on a set of accurate diabatic potential energy surfaces.Oscillatory structures in the total reaction probability indicate the presence of the short-lived intermediate complex.
基金financially supported by the National Key R&D Program Projects of China (No.2021YFB3202402)National Natural Science Foundation of China (No.62173321)。
文摘Rapid online analysis of liquid slag is essential for optimizing the quality and energy efficiency of steel production. To investigate the key factors that affect the online measurement of refined slag using laser-induced breakdown spectroscopy(LIBS), this study examined the effects of slag composition and temperature on the intensity and stability of the LIBS spectra. The experimental temperature was controlled at three levels: 1350℃, 1400℃, and 1450℃. The results showed that slag composition and temperature significantly affected the intensity and stability of the LIBS spectra. Increasing the Fe content and temperature in the slag reduces its viscosity, resulting in an enhanced intensity and stability of the LIBS spectra. Additionally, 42 refined slag samples were quantitatively analyzed for Fe, Si, Ca, Mg, Al, and Mn at 1350℃, 1400℃, and 1450℃.The normalized full spectrum combined with partial least squares(PLS) quantification modeling was used, using the Ca Ⅱ 317.91 nm spectral line as an internal standard. The results show that using the internal standard normalization method can significantly reduce the influence of spectral fluctuations. Meanwhile, a temperature of 1450℃ has been found to yield superior results compared to both 1350℃ and 1400℃, and it is advantageous to conduct a quantitative analysis of the slag when it is in a “water-like” state with low viscosity.
基金The authors acknowledge the support of the Shenyang University of Technology(QNPY202209-4)the National Natural Science Foundation of China(21571132)+1 种基金Jiangsu University Advanced Talent Fund(5501710002)the Education Department of Liaoning Province(JYTQN2023285).
文摘Anode materials are an essential part of lithium-ion batteries(LIBs),which determine the performance and safety of LIBs.Currently,graphite,as the anode material of commercial LIBs,is limited by its low theoretical capacity of 372 mA·h·g^(−1),thus hindering further development toward high-capacity and large-scale applications.Alkaline earth metal iron-based oxides are considered a promising candidate to replace graphite because of their low preparation cost,good thermal stability,superior stability,and high electrochemical performance.Nonetheless,many issues and challenges remain to be addressed.Herein,we systematically summarize the research progress of alkaline earth metal iron-based oxides as LIB anodes.Meanwhile,the material and structural properties,synthesis methods,electrochemical reaction mechanisms,and improvement strategies are introduced.Finally,existing challenges and future research directions are discussed to accelerate their practical application in commercial LIBs.
基金financially supported by the National Natural Science Foundation of China(No.51105257)
文摘Compared with the conventional casting process, digital pattern-less casting technology has many advantages such as good machining accuracy, a short processing cycle, and low production cost. It is a new rapid manufacturing technology for castings, integrated with CAD/CAM, casting, CNC machining and many other advanced technologies. With this digital casting technology, no pattern is needed for making molds; it is precise, f lexible, and green. Usually, art castings have complex structures and are made in small batches or even made in a single-piece, especially for large-sized art castings. So it has the shortcomings of high cost, low eff iciency and long time for making a pattern to produce art castings with the conventional casting processes. However, the digital pattern-less casting technology can be applied to fabricate art castings, since it can greatly shorten the manufacturing cycle and lower the production cost, thus having a very good prospect. In this study, based on the digital pattern-less casting technology, a plaque casting with artistic Chinese characters(a Chinese poem) was designed and manufactured, and the production process was demonstrated in detail.
基金This project is supported by National Natural Science Foundation of China (No.50275017)Provincial Natural Science Foundation of Liaoning, China (No.20051019).
基金The research is supported by Nature Science Foundation ofChina, No.: 50275098
文摘The squeeze cast technology is only applicable, at present, to the castings with a ratio of height to thickness less than 3.5. Researching the squeeze cast technology for castings with a large ratio of height to thickness will broaden the applicable range of the advanced casting technology. This paper describes a study of the temperature distribution during solidification for castings with a ratio of height to thickness of 7 by the methods of experiment and computer simulation. The shrinkage porosity distribution in the castings and the mechanical properties of the castings were also researched. The experimental and simulated results show that increasing squeeze force, or enhancing mold temperature, cannot reduce the shrinkage porosities in the castings. When castings solidify in a sequential manner and the squeeze force effectively acts on the surface of the liquid metal, the shrinkage porosities in the castings are eliminated and mechanical properties are clearly improved.
基金financially supported by the Scientific Research Fund of Liaoning Provincial Education Department, China (No.LJKZ0122)。
文摘To enhance the performance of in-situ synthesized 6vol.%(Ti C+Ti B)/TC4 titanium matrix composites fabricated by casting,a variety of heat treatment processes were carried out.Upon conducting microstructure observations following various heat treatments,it was found that the composites exhibit a basketweave microstructure,consisting of an α phase and a transformed β phase.The sizes of(α+β) phases were found to be refined to varying degrees after the heat treatment processes,while the morphology of Ti B remains largely unchanged and Ti C becomes granulated.Compressive testing revealed that all composites subjected to different heat treatments demonstrate a notable increase in ultimate compressive strength as well as a slight improvement in plasticity compared to the as-cast state.The results of the tribological performance test indicated that the heat-treated composites exhibit lower average friction coefficient,specific wear rate,and worn surface roughness compared to the as-cast composite.Among the heat treatment processes studied,the composite solution heated at 1,150 °C/1 h followed by air cooling,then 950 °C/1 h followed by air cooling,and finally 500 °C/4 h followed by air cooling,demonstrates the highest levels of hardness,compressive strength,and wear resistance.These improvements are attributed to the combined effects of solid solution strengthening,grain refinement,and the pinning of dislocation slip.
基金supported by the Key Projects of the Yalong River Joint Fund of the National Natural Science Foundation of China(Grant No.U1865203)the National Natural Science Foundation of China(Grant Nos.52109142 and 41941018).
文摘Fault activation has been the focus of research community for years.However,the studies of fault activation remain immature,such as the fault activation mode and its major factors under constant normal stiffness(CNS)conditions associated with large thickness of fault surrounding rock mass.In this study,the rock friction experiments were conducted to understand the fault activation modes under the CNS conditions.Two major parameters,i.e.the initial normal stress and loading rate,were considered and calibrated in the tests.To reveal the response mechanism of fault activation,the local strains near the fault plane were recorded,and the macroscopic stresses and displacements were analyzed.The testing results show that the effect of displacement-controlled loading rate is more pronounced under the CNS conditions than that under constant normal load(CNL)conditions.Both the normal and shear stresses drop suddenly when the stick-slip occurs.The decrease and increase of the normal stress are synchronous with the shear stress in the regular stick-slip scenario,but mismatch with the shear stress during the chaotic stick-slip process.The results are helpful for understanding the fault sliding mode and the prediction and prevention of fault slip.
基金Project Supported by the National Natural Science Foundation of China (Grant No.60974004)
文摘A method to eliminate spiral waves and spatiotemporal chaos by using the synchronization transmission technology of network signals is proposed in this paper.The character of the spiral waves and the spatiotemporal chaos in the Fitzhugh-Nagumo model is presented.The network error evolution equation with spatiotemporal variables and the corresponding eigenvalue equation are determined based on the stability theory,and the global synchronization condition is obtained.Simulations are made in a complex network with Fitzhugh-Nagumo models as the nodes to verify the effectiveness of the synchronization transmission principle of the network signal.
文摘University student education is the main part of higher education in China. Therefore, the comprehensive quality of university students shows the level of higher education. Ecological literacy is the basic literacy of college students under the background of green development to build socialism with Chinese characteristics. The green development education is based on the research idea of the relationship between the individual and the surrounding environment in ecology, which requires respecting the subjectivity of the active object, paying attention to the integrity and connection of the object. Compared with the traditional education, green development education pays more attention to the cultivation of moral quality and sound personality of the educated, and it can make the students understand the ecological environment. Under the premise of ecological system and the mechanism of biological growth and development, respect and love of life are formed naturally, and then the universal concern for environment and others is formed. College students, as advanced groups of young people, are leading the social fashion and influencing the social ethical environment. Ecological literacy is the new requirement of the times for college students. We should integrate the education of green development into the ideological education,make great efforts to shape the ecological ethical system of college students, and cultivate their ecological consciousness, ecological thinking and behavior habits. It is an important issue for ideological education to improve the quality of green development in an all-round way.
基金supported by the National Natural Science Foundation of China (Grant No.22278271)the Key Project of Education Department of Liaoning Province(Grant No.LZGD2020005)
文摘Metal-organic frameworks(MOFs)have attracted considerable research attention as a new type of porous material for catalytic applications.Herein,2,5-dihydroxyterephthalic acid was proposed to replace conventional terephthalic acid and reacted with chromic nitrate nonahydrate to synthesize a functional metal–organic framework(FMIL-101).This was then used to immobilize various compound ionic liquids to prepare three ionic liquids immobilized on FMIL-101 catalysts,namely,FMIL-101-[HeMIM]Cl/(ZnBr_(2))_(2),FMIL-101-[CeMIM]Cl/(ZnBr_(2))_(2),and FMIL-101-[AeMIM]Br/(ZnBr_(2))_(2).After characterization by Fourier-transform infrared spectroscopy,X-ray diffraction,ultraviolet spectroscopy,thermogravimetry,specific surface area analysis,and scanning electron microscopy,the catalysts were used to mediate cycloaddition reactions between carbon dioxide(CO_(2))and propylene oxide.The effects of reaction temperature,reaction pressure,reaction time,and catalyst dosage on the catalytic performance were investigated.The results revealed that the FMIL-101-supported CIL catalysts afforded the target product propylene carbonate with good catalytic performance and thermal stability.The optimal catalyst,FMIL-101-[CeMIM]Cl/(ZnBr_(2))_(2),displayed a propylene oxide conversion of 98.64%and a propylene carbonate selectivity of 96.63%at a reaction temperature of 110℃,a reaction pressure of 2.0 MPa,a catalyst dosage of 2.0%relative to propylene oxide,and a reaction time of 2.5 h.In addition,the conversion and selectivity of the catalyst decreased slightly after four cycles.Additionally,the catalyst decreased slightly in catalytic performance after being recycled four times.
基金supported by the National Natural Science Foundation of China (No. 52172218)。
文摘Vanadium oxides have attracted one’s wide attention due to their diverse valences and spatial structure as cathode for aqueous zinc ion batteries.However,a strong electrostatic interaction exists between Zn ions and host materials,which leads to their sluggish reaction kinetics and inferior structural stability.Herein,we design a kind of vanadium-based electrode materials with abundant phase boundaries and oxygen defects.The assembled Zn//V_(6)O_(13)/VO_(2) batteries deliver a specific capacity of 498.3 mA h g^(-1)at 0.2 A g^(-1) and retain a capacity of 485.8 mA h g^(-1)after 100 cycles.Moreover,they achieve a retention rate of 96.8% after 5000 cycles at 10 A g^(-1).The soft pack cells also show excellent mechanical stability at different folding conditions.
基金financially supported by the National Natural Science Foundation of China(No.51775353)the National Key Research and Development Program of China(No.2019YFB2006501)+2 种基金the Program for Natural Science Foundation of Liaoning Province(No.2021-BS-150)Science and Technology Program of Liaoning Provincial Department of Education(LJKZ0116)Hebei Key Laboratory of Dielectric and Electrolyte Functional Material,Northeastern University at Qinhuangdao(HKDEFM2021204)。
文摘Temperature has an important impact on the corrosion resistance of mold with cooling channels prepared by casting method.The effect of preheating temperature of the mold and the carbon fiber core on the roughness and corrosion resistance of U-shaped cooling channels made of Al-12Si alloy was examined in depth.The experimental results suggest that as the preheating temperature increased from 273 K to 573 K,the roughness of the inner wall of the cooling channel reduced from 96.6μm to 77.0μm.When the preheating temperature continued to increase to 723 K,the roughness increased to 85.3μm.The wetting between the Al melt and the carbon fiber will reduce micro bubbles and waves on the channel wall as the preheating temperature rises,thereby reducing the roughness.However,with the further increase of preheating temperature,it will increase the solidification time of the Al melt.At this time,the carbon fiber and Al melt will take more time to react,which increases the roughness of the channel wall to a certain extent.The results of exfoliation corrosion show that the larger roughness will aggravate exfoliation corrosion.The prolongation of high temperature reaction time between the carbon fiber and the Al melt will lead to the segregation of Si,which is easy to cause intergranular corrosion.Therefore,reasonable preheating temperature has an important impact on the roughness and corrosion resistance of U-shaped cooling channels.
文摘A type of heat-curing phosphate binder was proposed,and orthogonal experiments based on the tensile strength of sand samples determined that the optimal composition of the binder was phosphoric acid:water:aluminum hydroxide:magnesium oxide:boric acid=300:70:60:9:8.Adding 10%polyvinyl alcohol(PVA)solution during the sand mixture process can significantly improve the 24 h tensile strength of sand samples.When adding 30 g phosphate binder and 8 g 10%PVA solution,the initial tensile strength of the sample is 0.76 MPa,the room temperature tensile strength is 2.29 MPa,and the 24 h tensile strength is 1.73 MPa.The heat-curing modified phosphate sand mold has high tensile strength and low gas generation,which can meet general casting production requirements.
基金financially supported by the Program for National Key Research and Development Plan(No.2017YFB1104000)the National Natural Science Foundation of China(No.51574167)+1 种基金the Liaoning Natural Science Foundation(No.2021-MS-235)the Science and Technology Program of Liaoning Provincial Department of Education(No.LJGD2020010)。
文摘To obtain better comprehensive properties of cast Al-Cu-Mg alloys,the secondary aging(T6I6)process(including initial aging,interrupted aging and re-aging stages)was optimized by an orthogonal method.The microstructures of the optimized Al-Cu-Mg alloy were observed by means of scanning electron microscopy and transmission electron microscopy,and the properties were investigated by hardness measurements,tensile tests,exfoliation corrosion tests,and intergranular corrosion tests.Results show that the S phase andθ’phase simultaneously exist in the T6I6 treated alloy.Appropriately increasing the temperature of the interrupted aging in the T6I6 process can improve the mechanical properties and corrosion resistance of Al-Cu-Mg alloy.The optimal comprehensive properties(tensile strength of 443.6 MPa,hardness of 161.6 HV)of the alloy are obtained by initial aging at 180℃for 2 h,interrupted aging at 90℃for 30 min,and re-aging at 170℃for 4 h.
基金supported in part by the Project of Liaoning BaiQianWan Talents ProgramunderGrand No.2021921089the Science Research Foundation of EducationalDepartment of Liaoning Province under Grand No.LJKQZ2021057 and WJGD2020001the Key Program of Social Science Planning Foundation of Liaoning Province under Grant L21AGL017.
文摘Given the challenges of manufacturing resource sharing and competition in the modern manufacturing industry,the coordinated scheduling problem of parallel machine production and transportation is investigated.The problem takes into account the coordination of production and transportation before production as well as the disparities in machine spatial position and performance.A non-cooperative game model is established,considering the competition and self-interest behavior of jobs from different customers for machine resources.The job from different customers is mapped to the players in the game model,the corresponding optional processing machine and location are mapped to the strategy set,and the makespan of the job is mapped to the payoff.Then the solution of the scheduling model is transformed into the Nash equilibrium of the non-cooperative game model.A Nash equilibrium solution algorithm based on the genetic algorithm(NEGA)is designed,and the effective solution of approximate Nash equilibrium for the game model is realized.The fitness function,single-point crossover operator,and mutation operator are derived from the non-cooperative game model’s characteristics and the definition of Nash equilibrium.Rules are also designed to avoid the generation of invalid offspring chromosomes.The effectiveness of the proposed algorithm is demonstrated through numerical experiments of various sizes.Compared with other algorithms such as heuristic algorithms(FCFS,SPT,and LPT),the simulated annealing algorithm(SA),and the particle swarm optimization algorithm(PSO),experimental results show that the proposed NE-GA algorithm has obvious performance advantages.
基金financial support from Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science (2019JH3/30100014)Liaoning Bai Qian Wan Talents Program. Liaoning Revitalization Talents Program (Nos. XLYC1807021 and 1907007)+2 种基金High Level Innovation Team of Liaoning Province(XLYC1908006)Project of Liaoning Education Department(Nos. LQGD2019002, and LJGD2020008)Liaoning Nature Fund Guidance Plan (No. 2019-ZD-0210)。
文摘The effects of addition of minor amount of(0.5 wt.%) antimony(Sb) or gadolinium(Gd) and combined addition of Sb and Gd(0.5 wt.%,respectively) on the hot tearing susceptibility(HTS) of Mg-5Al-3Ca alloy were investigated experimentally using a “T-shaped” hot tearing measuring system. Various solidification parameters of the alloys were measured and calculated through thermal analysis experiments. The microstructure, grain size, and morphology of the crack zone were characterized by scanning electron microscopy and electron backscatter diffraction, and the crystal phases of the alloys were analyzed by X-ray diffraction and energy-dispersive X-ray spectroscopy. The results showed that the addition of 0.5 wt.% Gd resulted in the increase in the vulnerable temperature range(Tv) and reduced the eutectic structure content that could participate in feeding, thereby improving the HTS of the alloy. However, addition of 0.5 wt.% Sb or combined addition of Gd and Sb(0.5 wt.%, respectively) to the Mg-5Al-3Ca alloy shortened the Tvand improved the skeleton strength of the alloy, thereby reducing HTS. Moreover, significantly refined structure of Mg-5Al-3Ca-0.5Gd-0.5Sb alloy improved the feeding ability of the eutectic structure, thus the alloy exhibited the lowest HTS.
