Estimation of natural recharge and potential for seawater intrusion are critical considerations for management of coastal freshwater aquifers. We show hydrochemical signatures of groundwater to identify the influence ...Estimation of natural recharge and potential for seawater intrusion are critical considerations for management of coastal freshwater aquifers. We show hydrochemical signatures of groundwater to identify the influence of geological control on chemical processes in a coastal groundwater system. We used dominant hydrochemical facies, salinity and magnesium ions to determine two main groundwater flow paths with different origins and ages. Mixing of groundwater with different origins and ages results in unreliable recharge estimates using chlorofluorocarbon (CFC) and chloride mass balance (CMB) methods, thus limiting available methods for recharge assessment. Interpretation of hydrochemical data suggests that calcium carbonate dissolution, ion exchange processes and mixing with sea aerosol in coastal zones are the main influencing factors on groundwater chemistry. Restricted groundwater flows due to occurrence of a basement high at the southern side of the basin boundary influence the distance to the toe of the saline wedge. Thus, knowledge of geological control over groundwater systems forms an important part of characterising basins and contributes toward effective management of groundwater resources.展开更多
Blue Lake, a volcanic crater provides municipal water supply to the city of Mount Gambier, population of 26,000. Current average annual pumping from the lake is 3.6 × 106 m3. The lake is fed by karstic unconfined...Blue Lake, a volcanic crater provides municipal water supply to the city of Mount Gambier, population of 26,000. Current average annual pumping from the lake is 3.6 × 106 m3. The lake is fed by karstic unconfined Gambier Limestone aquifer. Storm water of the city discharges to the aquifer via about 400 drainage wells and three large sinkholes. Average annual storm water discharge is estimated at approximately 6.6 × 106 m3 through drainage wells and sinkholes within 16.8 km2 of the central part of the city. Chemical mass balance for calcium was used to estimate groundwater inflow to the lake at 6.3 × 106 m3, almost equal to the volume of storm water discharge and slightly higher than the previous estimates using environmental isotopes (4.8 - 6.0 × 106 m3). Considering the lake outflow volume of 2.7 × 106 m3, the net inflow to the lake equates to the current annual pumping and therefore it is considered that the current pumping rate is at the upper limit. For meeting the short-term future demand, confined aquifer water may be used and in the longerterm, an additional well field is required outside the Blue Lake capture zone, preferably to the north-east of the city. For water supply security, inflow to the lake along with water quality has to be maintained within the city. Current annual private abstraction within the capture zone is about 4.4 × 106 m3 and in order to maintain aquifer water levels, no additional allocation should be allowed.展开更多
The vertical leakage to confined aquifers is rarely quantified in complex settings, where the recharge zone is characterized by both diffuse and preferential flows. In such setting, conventional hydraulic or tracer ba...The vertical leakage to confined aquifers is rarely quantified in complex settings, where the recharge zone is characterized by both diffuse and preferential flows. In such setting, conventional hydraulic or tracer based estimation of recharge or vertical leakage is problematic, unless the effects of duality of flow regimes are considered. A water balance approach by the use of calibrated groundwater models can be used, as the mass balance is independent of the particular mode of recharge and vertical leakage processes. Here, we adopt a water balance approach to provide a first order assessment of recharge to the unconfined Tertiary limestone aquifer (TLA) and vertical leakage to the Tertiary confined sand aquifer (TCSA) within the Glencoe-Nangwarry-Nagwarry (GNN) recharge zone of the Gambier Basin in South Australia. Despite many studies expressing concern about the impact of land use on recharge to the TLA and vertical leakage to the TCSA, no estimates have been made to quantify the vertical leakage within the GNN recharge zone. In the GNN recharge zone, relatively high recharge to the unconfined aquifer and vertical leakage to the confined aquifer occurs as a result of both diffuse and preferential flow processes. This is due to presence of structural faults and thin or absent aquitard. Within the Hundred of Nangwarry, where 83% of the area is covered with plantation forest, the model calculated recharge to the TLA of 80 mm·year<sup>-1</sup>, about 44% reduction compared to adjacent non-forested area (144 mm·year<sup>-1</sup>). Vertical leakage to the TCSA within the Hundred of Nangwarry area is higher (84.5 mm·year<sup>-1</sup>) than recharge to the TLA. Higher vertical leakage combined with the reduced recharge to TLA resulted in depletion of the TLA storage, as evidenced by drying of the TLA at one locality. In contrast, in plantation forest areas where diffuse recharge is the dominant process (Hundred of Penola), recharge to the TLA is about 19 mm·year<sup>-1</sup>, a 78% reduction compared to the non-forested areas, a mix of irrigation and dryland pasture. In these areas, vertical leakage to the TCSA is much smaller: 8 mm·year<sup>-1</sup> through a thick aquitard. Simulation of a management scenario in which plantation forest is replaced by dryland pasture in the Hundred of Nangwarry results in 135 mm·year<sup>-1</sup> recharge to TLA and a 98 mm·year<sup>-1</sup> vertical leakage to the TCSA.展开更多
High performance size exclusion chromatography （HPSEC） is used in water quality research primarily to determine the molecular weight distribution of the dissolved organic matter （DOM）, but by applying peak fitting...High performance size exclusion chromatography （HPSEC） is used in water quality research primarily to determine the molecular weight distribution of the dissolved organic matter （DOM）, but by applying peak fitting to the chromatogram, this technique can also be used as a tool to model and predict DOM removal. Six low specific UV absorbance （SUVA） source waters were treated using coagulation with alum and both the source and treated water samples were analysed using HPSEC. By comparing the molecular weight profiles of the source and treated waters, it was established that several DOM components were not effectively removed by alum coagulation even after high dosage alum treatment. A peak-fitting technique was applied based on the concept of linking the character （molecular weight profile） of the recalcitrant organics in the treated water with those of the source water. This was then applied to predict DOM treatability by determining the areas of the peaks which were assigned to removable organics from the source water molecular weight profile after peak fitting, and this technique quantified the removable and non-removable organics. The prediction was compared with the actual dissolved organic carbon （DOC） removal determined from jar testing and showed good agreement, with variance between 2% and 10%. This confirmed that this prediction approach, which was originally developed for high SUVA waters, can also be applied successfully to predict DOC removal in low SUVA waters.展开更多
The treatment of organics present in the lower reaches of a major river system（the Murray–Darling Basin, Australia） before（March–July 2010）, during（December 2010–May 2011） and after（April–December 2012） a ...The treatment of organics present in the lower reaches of a major river system（the Murray–Darling Basin, Australia） before（March–July 2010）, during（December 2010–May 2011） and after（April–December 2012） a major flood period was investigated. The flood period（over 6 months）occurred during an intense La Nia cycle, leading to rapid and high increases in river flows and organic loads in the river water. Dissolved organic carbon（DOC） increased（2–3 times） to high concentrations（up to 16 mg/L） and was found to correlate with river flow rates. The treatability of organics was studied using conventional jar tests with alum and an enhanced coagulation model（mEnCo）. Predicted mean alum dose rates（per mg DOC） were higher before（9.1 mg alum/mg DOC） and after（8.5 mg alum/mg DOC） than during the flood event（8.0 mg alum/mg DOC）,indicating differences in the character of the organics in raw waters. To assess the character of natural organic matter present in raw and treated waters, high performance size exclusion chromatography with UV and fluorescence detectors were used. During the flood period, high molecular weight UV absorbing compounds（〉2 kDa） were mostly detected in waters collected,but were not evident in waters collected before and afterwards. The relative abundances of humic-like and protein-like compounds during and following the flood period were also investigated and found to be of a higher molecular weight during the flood period. The treatability of the organics was found to vary over the three climate conditions investigated.展开更多
Calcium aluminate cement(CAC)—based strain hardening cementitious composites(SHCC)has been developed and used for the rehabilitation of sewerage pipelines.In addition to well-known microbiologically induced corrosion...Calcium aluminate cement(CAC)—based strain hardening cementitious composites(SHCC)has been developed and used for the rehabilitation of sewerage pipelines.In addition to well-known microbiologically induced corrosion,CO_(2)concentration in the sewerage environment is high,which may cause significant carbonation of pipelines.Thus,this paper aims to investigate the effects of carbonation on the mechanical performance of CAC-based SHCC.Two types of CAC-based SHCC with different strength grades and a referenced OPC-based SHCC were prepared.The accelerated carbonation test was conducted in a carbonation chamber with a 5%CO_(2)concentration.The compressive and tensile behaviour of SHCC was tested first,and microstructure analysis,e.g.,X-ray diffraction and scanning electron microscopy,was then performed.The results showed that CAC-based SHCC specimens exhibited robust strain-hardening performance as well as large deformation capacity in tension due to the fiber-bridging effect.Also,the compressive and tensile strength was significantly improved as well as achieving a higher tensile strain capacity after carbonation when compared with OPC-based SHCC.Microstructure analysis revealed that the metastable phases in carbonated CAC-based SHCC were converted into stable phases and calcium carbonate polymorphs,densifying the binder matrix.The obtained results of this paper may provide new insight into utilizing carbonation to avoid the unstable conversion of hydrates in calcium aluminate cement.展开更多
Maintaining soil fertility, while controlling pollution from excessive chemical fertilizer application is important for keeping soil productivity of sustainable agriculture. Variety of straws have been used and proven...Maintaining soil fertility, while controlling pollution from excessive chemical fertilizer application is important for keeping soil productivity of sustainable agriculture. Variety of straws have been used and proven to be good soil amendments for increasing soil organic matter （OM） and a range of additional soil nutrients. However, little is known about the utilization of cotton straw for soil amendment. To better understand the mechanism behind cotton straw soil amendments, investigations were performed upon cucumber seedlings, where changes to soil nutrients and microbial communities were investigated. The results revealed that the cotton straw application promoted the cucumber seedling growth by significantly increasing the soil OM, available nitrogen, available phosphorus, and available potassium. The concentration of cotton straw was positively correlated to both the number of the culturable microorganisms and also the total microbial biomass within soil. Furthermore, assessment of cotton straw application using Biolog metabolic profiling and phospholipid fatty acid analysis revealed that such application increased the microbial community metabolic activity, and markedly changed the structure of microbial community. 16S rRNA gene clone library construction and phylogenetic analysis of soil bacteria revealed 7- Proteobacteria sequences dominated the cotton straw amendment soil, comprising 27.8% of the total number of analyzed sequences, while they were less represented in control soil （13.4%）. On the contrary, the Sphingobacteria （7.8%） and Verrucomicrobia （2.4%） in the cotton straw amendment soil decreased after application when compared to the control soil 15.2% and 15.2%.展开更多
Minimizing particles in water is a key goal for improving drinking water quality and safety.The media filtration process,as the last step of the solid–liquid separation process,is largely influenced by the characteri...Minimizing particles in water is a key goal for improving drinking water quality and safety.The media filtration process,as the last step of the solid–liquid separation process,is largely influenced by the characteristics of flocs,which are formed and controlled within the coagulation process.In a laboratory-based study,the impacts of the physical characteristics of flocs formed using aluminum sulfate on the filtration treatment of two comparative water samples were investigated using a photometric dispersion analyzer and a filterability apparatus.In general,the optimum dosage for maximizing filterability was higher than that for minimizing turbidity under neutral p H conditions.For a monomeric aluminum-based coagulant,the charge neutralization mechanism produced better floc characteristics,including floc growth speed and size,than the sweep flocculation mechanism.In addition,the charge neutralization mechanism showed better performance compared to sweep flocculation in terms of DOC removal and floc filterability improvement for both waters,and showed superiority in turbidity removal only when the raw water had high turbidity.For the different mechanisms,the ways that floc characteristics impacted on floc filterability also differed.The low variation in floc size distribution obtained under the charge neutralization mechanism resulted in the flocs being amenable to removal by filtration processes.For the sweep flocculation mechanism,increasing the floc size improved the settling ability of flocs,resulting in higher filter efficiency.展开更多
文摘Estimation of natural recharge and potential for seawater intrusion are critical considerations for management of coastal freshwater aquifers. We show hydrochemical signatures of groundwater to identify the influence of geological control on chemical processes in a coastal groundwater system. We used dominant hydrochemical facies, salinity and magnesium ions to determine two main groundwater flow paths with different origins and ages. Mixing of groundwater with different origins and ages results in unreliable recharge estimates using chlorofluorocarbon (CFC) and chloride mass balance (CMB) methods, thus limiting available methods for recharge assessment. Interpretation of hydrochemical data suggests that calcium carbonate dissolution, ion exchange processes and mixing with sea aerosol in coastal zones are the main influencing factors on groundwater chemistry. Restricted groundwater flows due to occurrence of a basement high at the southern side of the basin boundary influence the distance to the toe of the saline wedge. Thus, knowledge of geological control over groundwater systems forms an important part of characterising basins and contributes toward effective management of groundwater resources.
文摘Blue Lake, a volcanic crater provides municipal water supply to the city of Mount Gambier, population of 26,000. Current average annual pumping from the lake is 3.6 × 106 m3. The lake is fed by karstic unconfined Gambier Limestone aquifer. Storm water of the city discharges to the aquifer via about 400 drainage wells and three large sinkholes. Average annual storm water discharge is estimated at approximately 6.6 × 106 m3 through drainage wells and sinkholes within 16.8 km2 of the central part of the city. Chemical mass balance for calcium was used to estimate groundwater inflow to the lake at 6.3 × 106 m3, almost equal to the volume of storm water discharge and slightly higher than the previous estimates using environmental isotopes (4.8 - 6.0 × 106 m3). Considering the lake outflow volume of 2.7 × 106 m3, the net inflow to the lake equates to the current annual pumping and therefore it is considered that the current pumping rate is at the upper limit. For meeting the short-term future demand, confined aquifer water may be used and in the longerterm, an additional well field is required outside the Blue Lake capture zone, preferably to the north-east of the city. For water supply security, inflow to the lake along with water quality has to be maintained within the city. Current annual private abstraction within the capture zone is about 4.4 × 106 m3 and in order to maintain aquifer water levels, no additional allocation should be allowed.
文摘The vertical leakage to confined aquifers is rarely quantified in complex settings, where the recharge zone is characterized by both diffuse and preferential flows. In such setting, conventional hydraulic or tracer based estimation of recharge or vertical leakage is problematic, unless the effects of duality of flow regimes are considered. A water balance approach by the use of calibrated groundwater models can be used, as the mass balance is independent of the particular mode of recharge and vertical leakage processes. Here, we adopt a water balance approach to provide a first order assessment of recharge to the unconfined Tertiary limestone aquifer (TLA) and vertical leakage to the Tertiary confined sand aquifer (TCSA) within the Glencoe-Nangwarry-Nagwarry (GNN) recharge zone of the Gambier Basin in South Australia. Despite many studies expressing concern about the impact of land use on recharge to the TLA and vertical leakage to the TCSA, no estimates have been made to quantify the vertical leakage within the GNN recharge zone. In the GNN recharge zone, relatively high recharge to the unconfined aquifer and vertical leakage to the confined aquifer occurs as a result of both diffuse and preferential flow processes. This is due to presence of structural faults and thin or absent aquitard. Within the Hundred of Nangwarry, where 83% of the area is covered with plantation forest, the model calculated recharge to the TLA of 80 mm·year<sup>-1</sup>, about 44% reduction compared to adjacent non-forested area (144 mm·year<sup>-1</sup>). Vertical leakage to the TCSA within the Hundred of Nangwarry area is higher (84.5 mm·year<sup>-1</sup>) than recharge to the TLA. Higher vertical leakage combined with the reduced recharge to TLA resulted in depletion of the TLA storage, as evidenced by drying of the TLA at one locality. In contrast, in plantation forest areas where diffuse recharge is the dominant process (Hundred of Penola), recharge to the TLA is about 19 mm·year<sup>-1</sup>, a 78% reduction compared to the non-forested areas, a mix of irrigation and dryland pasture. In these areas, vertical leakage to the TCSA is much smaller: 8 mm·year<sup>-1</sup> through a thick aquitard. Simulation of a management scenario in which plantation forest is replaced by dryland pasture in the Hundred of Nangwarry results in 135 mm·year<sup>-1</sup> recharge to TLA and a 98 mm·year<sup>-1</sup> vertical leakage to the TCSA.
基金supported by the National Natural Science Foundation of China (No. 51025830)the National Basic Research Program of (973) China (No.2011CB933700)+1 种基金the South Australian Premier’s Science and Research Fund Project "Development of materials engineering solutions for treatment of Murray-Darling Basin sourced water supplies"supported by the special fund from the State Key Laboratory of Environmental Aquatic Chemistry, Project 08K08ESPCR
文摘High performance size exclusion chromatography （HPSEC） is used in water quality research primarily to determine the molecular weight distribution of the dissolved organic matter （DOM）, but by applying peak fitting to the chromatogram, this technique can also be used as a tool to model and predict DOM removal. Six low specific UV absorbance （SUVA） source waters were treated using coagulation with alum and both the source and treated water samples were analysed using HPSEC. By comparing the molecular weight profiles of the source and treated waters, it was established that several DOM components were not effectively removed by alum coagulation even after high dosage alum treatment. A peak-fitting technique was applied based on the concept of linking the character （molecular weight profile） of the recalcitrant organics in the treated water with those of the source water. This was then applied to predict DOM treatability by determining the areas of the peaks which were assigned to removable organics from the source water molecular weight profile after peak fitting, and this technique quantified the removable and non-removable organics. The prediction was compared with the actual dissolved organic carbon （DOC） removal determined from jar testing and showed good agreement, with variance between 2% and 10%. This confirmed that this prediction approach, which was originally developed for high SUVA waters, can also be applied successfully to predict DOC removal in low SUVA waters.
基金supported by a South Australian Premier's Science and Research Fund project‘Development of Materials Engineering Solutions for Treatment of Murray-Darling Basin Sourced Water Supplies’and the Australian Research Council through the ARC Linkage Project‘Materials Engineering Solutions for Tomorrow's Water Resources’,LP100100616
文摘The treatment of organics present in the lower reaches of a major river system（the Murray–Darling Basin, Australia） before（March–July 2010）, during（December 2010–May 2011） and after（April–December 2012） a major flood period was investigated. The flood period（over 6 months）occurred during an intense La Nia cycle, leading to rapid and high increases in river flows and organic loads in the river water. Dissolved organic carbon（DOC） increased（2–3 times） to high concentrations（up to 16 mg/L） and was found to correlate with river flow rates. The treatability of organics was studied using conventional jar tests with alum and an enhanced coagulation model（mEnCo）. Predicted mean alum dose rates（per mg DOC） were higher before（9.1 mg alum/mg DOC） and after（8.5 mg alum/mg DOC） than during the flood event（8.0 mg alum/mg DOC）,indicating differences in the character of the organics in raw waters. To assess the character of natural organic matter present in raw and treated waters, high performance size exclusion chromatography with UV and fluorescence detectors were used. During the flood period, high molecular weight UV absorbing compounds（〉2 kDa） were mostly detected in waters collected,but were not evident in waters collected before and afterwards. The relative abundances of humic-like and protein-like compounds during and following the flood period were also investigated and found to be of a higher molecular weight during the flood period. The treatability of the organics was found to vary over the three climate conditions investigated.
基金The first author would like to acknowledge the University of South Australia Postgraduate Research Award and Research Training Program scholarships for his Ph.D study.
文摘Calcium aluminate cement(CAC)—based strain hardening cementitious composites(SHCC)has been developed and used for the rehabilitation of sewerage pipelines.In addition to well-known microbiologically induced corrosion,CO_(2)concentration in the sewerage environment is high,which may cause significant carbonation of pipelines.Thus,this paper aims to investigate the effects of carbonation on the mechanical performance of CAC-based SHCC.Two types of CAC-based SHCC with different strength grades and a referenced OPC-based SHCC were prepared.The accelerated carbonation test was conducted in a carbonation chamber with a 5%CO_(2)concentration.The compressive and tensile behaviour of SHCC was tested first,and microstructure analysis,e.g.,X-ray diffraction and scanning electron microscopy,was then performed.The results showed that CAC-based SHCC specimens exhibited robust strain-hardening performance as well as large deformation capacity in tension due to the fiber-bridging effect.Also,the compressive and tensile strength was significantly improved as well as achieving a higher tensile strain capacity after carbonation when compared with OPC-based SHCC.Microstructure analysis revealed that the metastable phases in carbonated CAC-based SHCC were converted into stable phases and calcium carbonate polymorphs,densifying the binder matrix.The obtained results of this paper may provide new insight into utilizing carbonation to avoid the unstable conversion of hydrates in calcium aluminate cement.
文摘Maintaining soil fertility, while controlling pollution from excessive chemical fertilizer application is important for keeping soil productivity of sustainable agriculture. Variety of straws have been used and proven to be good soil amendments for increasing soil organic matter （OM） and a range of additional soil nutrients. However, little is known about the utilization of cotton straw for soil amendment. To better understand the mechanism behind cotton straw soil amendments, investigations were performed upon cucumber seedlings, where changes to soil nutrients and microbial communities were investigated. The results revealed that the cotton straw application promoted the cucumber seedling growth by significantly increasing the soil OM, available nitrogen, available phosphorus, and available potassium. The concentration of cotton straw was positively correlated to both the number of the culturable microorganisms and also the total microbial biomass within soil. Furthermore, assessment of cotton straw application using Biolog metabolic profiling and phospholipid fatty acid analysis revealed that such application increased the microbial community metabolic activity, and markedly changed the structure of microbial community. 16S rRNA gene clone library construction and phylogenetic analysis of soil bacteria revealed 7- Proteobacteria sequences dominated the cotton straw amendment soil, comprising 27.8% of the total number of analyzed sequences, while they were less represented in control soil （13.4%）. On the contrary, the Sphingobacteria （7.8%） and Verrucomicrobia （2.4%） in the cotton straw amendment soil decreased after application when compared to the control soil 15.2% and 15.2%.
基金supported by the National Natural Science Foundation of China(Nos.51308008,51179099)SA Water Visiting International Academics,Graduates,Researchers and Affiliates(VIAGRA) FundUni SA Visiting Researcher Fund
文摘Minimizing particles in water is a key goal for improving drinking water quality and safety.The media filtration process,as the last step of the solid–liquid separation process,is largely influenced by the characteristics of flocs,which are formed and controlled within the coagulation process.In a laboratory-based study,the impacts of the physical characteristics of flocs formed using aluminum sulfate on the filtration treatment of two comparative water samples were investigated using a photometric dispersion analyzer and a filterability apparatus.In general,the optimum dosage for maximizing filterability was higher than that for minimizing turbidity under neutral p H conditions.For a monomeric aluminum-based coagulant,the charge neutralization mechanism produced better floc characteristics,including floc growth speed and size,than the sweep flocculation mechanism.In addition,the charge neutralization mechanism showed better performance compared to sweep flocculation in terms of DOC removal and floc filterability improvement for both waters,and showed superiority in turbidity removal only when the raw water had high turbidity.For the different mechanisms,the ways that floc characteristics impacted on floc filterability also differed.The low variation in floc size distribution obtained under the charge neutralization mechanism resulted in the flocs being amenable to removal by filtration processes.For the sweep flocculation mechanism,increasing the floc size improved the settling ability of flocs,resulting in higher filter efficiency.
