Corrosiveness or scaling is an inherent threat to oil operations. The primary cause for this threat is the presence of water having complex geochemical matrix. Unanticipated water production, particularly if it contai...Corrosiveness or scaling is an inherent threat to oil operations. The primary cause for this threat is the presence of water having complex geochemical matrix. Unanticipated water production, particularly if it contains unwanted impurities, can significantly impact hydrocarbon production. The current paper discusses the degree of threat posed to oil operation facilities based on the water characteristics. Methodology involved the collection and analysis of water samples from major sources in oil industry such as groundwater, wellheads and seawater. The parameters tested include geochemical, microbiological and pollutants. The lab data was used to develop scaling and corrosion prediction indices such as Langelier Saturation Index (LSI), Ryznar Stability Index (RSI) and Puckorius Scaling Index (PSI). The study indicated varying water chemistry for different sources. Mixing of those waters may lead to ionic saturation and scaling in different facilities. Presence of the SRB and GAB in some water sources also posed threat to water system by forming fouling and corrosion. Seawater used for offshore oilfields water injection to maintain reservoir pressure and improve oil recovery showed scaling tendency, whereas under different reservoir pressure, it can cause corrosion. Some of the samples also had corrosion residuals such as iron, which indicated active corrosion. Current study showed higher alkalinity with high sulfate for one groundwater sample with presence of active corrosion residuals such as dissolved iron and manganese. The study showed positive value for LSI which indicated supersaturation of the water samples with respect to calcium carbonate (CaCO<sub>3</sub>) and scale forming. Similarly, for RSI and PSI, the value was below six which confirmed the scaling potential for all the samples. Even though the index value was pointing towards scaling potential, the geochemistry, microbiology and presence of other impurities indicated corrosion threat to the oil and gas industrial facilities. The study concluded the importance of different scale inhibition mechanism and corrosion control in Oil and Gas industry.展开更多
Oil and gas industries generate a significant amount of water during the production. The composition of this water varies with the geologic age, depth, and geochemistry of the region along with the chemicals added dur...Oil and gas industries generate a significant amount of water during the production. The composition of this water varies with the geologic age, depth, and geochemistry of the region along with the chemicals added during the process. Geochemistry of formation water is used for aquifer identification, pollution problems, water compatibility studies, corrosion monitoring, water-quality control, water flooding, exploration, and to diagnose wellbore integrity issues. The current study investigates the spatial and temporal variation of produced water geochemistry from one of the largest conventional oil field, Ghawar field, Saudi Arabia. Produced water from different wellheads were collected and analyzed for different geochemical characteristics. Sixteen wells from ABQQ, nineteen wells from ANDR and twenty wells from SDGM area were selected for the current study. Sampling and analysis were performed as per the standard procedures. Results indicated that the pH of the sample varied from 6.0 to 7.4, and Electrical conductivity from 94200 to 102690 μS/cm. The spatial variation of major cations and anions were also recorded and represented by graphical plots. Metal analysis indicated the highest concentration for boron, which is 20.5 mg/L at ABQQ area, whereas all other metals are very low in concentration. Temporal variation of a single well at SDGM area indicated drastic change in the ionic concentration, whereas the geochemistry remains same as indicated by Tickler plot. The water type of the respective area was studied by tickler plots, which indicated same source of formation water in different wells at ABQQ, ANDR and SDGM areas. The ionic concentration is also used to predict corrosion and scaling issues. By Langelier Saturation Index (LSI) and Ryznar Stability Index (RSI), the sample from all the wells showed higher scaling potential. The study concludes that the water type in different areas under Ghawar field remains same regardless of drastic changes in the ionic concentration, which can be used to diagnose wellbore integrity issues.展开更多
Saudi Arabia has </span><span style="font-family:Verdana;">some of </span><span style="font-family:Verdana;">the biggest oil and gas reserves in the world, </span><...Saudi Arabia has </span><span style="font-family:Verdana;">some of </span><span style="font-family:Verdana;">the biggest oil and gas reserves in the world, </span><span style="font-family:Verdana;">and has</span><span style="font-family:Verdana;"> expanded its drilling operations gradually to meet the global demand.</span><span style="font-family:""> </span><span style="font-family:Verdana;">Improper handling of contaminated drilling wastes may cause serious negative environmental impacts. The current study investigates the toxicological effects of heavy metals in drilling waste by </span><span style="font-family:""><span style="font-family:Verdana;">quantification and developing different contamination indices</span><span style="font-family:Verdana;">. Solid and liquid samples from different drilling waste pits were collected and analyzed for heavy metals. The average concentration varies significantly and decrease</span></span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;"> in the order of Fe > Al > Sr > Mn > Cu > Cr > Zn > Ni > Pb > Cd > Ag > Co. The spatial variation showed </span><span style="font-family:Verdana;">the </span><span style="font-family:Verdana;">highest concentration at SDGM Site 1, West. Comparison of current data </span><span style="font-family:Verdana;">showed</span><span style="font-family:Verdana;"> continental crust average values within the specifications for most of the sites. For metals like Cd, Cr and Cu, the concentration is higher than the continental crust value. Indices such as pollution load index, modified degree of contamination etc. were calculated from the available data. </span><span style="font-family:Verdana;">The </span><span style="font-family:Verdana;">contamination level for different site calculat</span><span style="font-family:Verdana;">ions</span><span style="font-family:Verdana;"> showed nil to a very low degree of contamination. Spatial variation of the contamination level indicated comparatively higher values for sites UTMN-4 and SDGM-1 North, which indicates the necessity of precautionary methods. The metal concentration in the pit water samples exceeded generally accepted standards, if this water w</span><span style="font-family:Verdana;">as</span><span style="font-family:Verdana;"> to be discharged/leaked from the pit. </span><span style="font-family:Verdana;">The </span><span style="font-family:Verdana;">current study concluded presence of different heavy metals in samples from the drilling waste pits, whereas the degree of contamination is minute.展开更多
It is known that one of the causes of pitting corrosion of copper tubes is residual carbon on the inner surface. It was confirmed that type I” pitting corrosion of the copper tube is suppressed by keeping the residua...It is known that one of the causes of pitting corrosion of copper tubes is residual carbon on the inner surface. It was confirmed that type I” pitting corrosion of the copper tube is suppressed by keeping the residual carbon amount at 2 mg/m<sup>2</sup> or less, which is lower than that of the type I’ pitting corrosion, or by removing the fine particles that are the corrosion product of galvanized steel pipes. The developed water treatment chemical was evaluated using three types of copper tubes with residual carbon amounts of 0 mg/m<sup>2</sup>, 0.5 mg/m<sup>2</sup>, and 6.1 mg/m<sup>2</sup>. The evaluation was conducted for three months in an open-circulation cooling water system and compared with the current water treatment chemical. Under the current water treatment chemical conditions, only the copper tube with a residual carbon amount of 6.1 mg/m<sup>2</sup> showed a significant increase in the natural corrosion potential after two weeks, and pitting corrosion occurred. No pitting corrosion and no increase in the natural corrosion potential were observed in any of the copper tubes that were treated with the developed water treatment chemical. In addition, the polarization curve was measured using the cooling water from this field test, and the anodic polarization of two cooling waters was compared. For copper tubes with a large amount of residual carbon, the current density near 0 mV vs. Ag/AgCl electrode (SSE) increased when the developed water treatment chemical was added.展开更多
The modern TSs （total stations） have reached a very high level in the provided reading and reliability （accuracy and precision） of their measurements. The evolution of the digital technology has helped in this dir...The modern TSs （total stations） have reached a very high level in the provided reading and reliability （accuracy and precision） of their measurements. The evolution of the digital technology has helped in this direction. Thus, the TSs can support all requirements for the stake out and monitoring of modern survey engineering and constructions projects. Their complicated manufacturing process and the sensitivity of their components require gauging, adjusting and calibration at certain time intervals. This appears to be the only way in order to assure the precision of measurements provided by the manufacturer and the reliability of the works they are used for. The goal of this paper is to propose a method for the estimation of the gauging time interval for modern YSs. which could be used by any user. More specifically, the indispensable need for the TSs gauging is elevated and documented. All the parameters that influence their operation are registered. A model expressed by a scale of grades is defined, leading thus to an equation for the calculation of the time interval for the next needed gauging and calibration.展开更多
Background: Gastrointestinal symptoms are not rare among coronavirus disease 2019(COVID-19) patients, but there have been no reports regarding convalescent plasma therapy for the recovery of gastrointestinal problems ...Background: Gastrointestinal symptoms are not rare among coronavirus disease 2019(COVID-19) patients, but there have been no reports regarding convalescent plasma therapy for the recovery of gastrointestinal problems in COVID-19 patients.Case presentation: We present two cases of patients with COVID-19-associated recurrent diarrhea and positive fecal occult blood who successfully recovered after a one-time convalescent plasma administration.Conclusion: When COVID-19 patients develop recurrent or refractory gastrointestinal symptoms and fail to respond to the available treatment, alternative therapy with convalescent plasma administration may be considered.展开更多
It has been reported that pitting corrosion in copper tubes occurs due to the effect of a carbon film produced by the influence of undergoing an oil and heat treatment. As a quantitative method for determining the res...It has been reported that pitting corrosion in copper tubes occurs due to the effect of a carbon film produced by the influence of undergoing an oil and heat treatment. As a quantitative method for determining the residual carbon amount, it has been reported that the inner surface of a copper tube can be dissolved with a mixed acid to collect and analyze the adhering carbon;however, this method is dangerous and difficult. Therefore, two methods were examined as a simple quantitative method for obtaining the residual carbon amount using copper tubes with known residual carbon amounts. One method utilizes X-ray photoelectron spectroscopy (XPS), and the other method utilizes the potential difference between the carbon film-adhered surface and carbon film-removed surface. In regard to XPS measurement, a linear correlation was found between the spectral intensity of C and the residual carbon amount;therefore, XPS measurements were considered to be effective as a simple measurement method for the carbon film on the inner surface of a copper tube. In the evaluation method by measuring the corrosion potential, a correlation was observed between the potential difference ΔE and the residual carbon amount of the inner surface of the tube and the outer surface of the polished tube. It is considered possible to estimate the residual carbon amount from the prepared calibration curve. Through these studies, it is suggested that the carbon film was non-uniformly present on the surface of the copper tube. Therefore, the galvanic current was measured, and the effect of a non-uniform carbon film on corrosion behavior was investigated. As a result, in the measurement of galvanic current, the current flowed from the copper tube with a large amount of residual carbon (cathode) to the copper tube with a small amount of residual carbon (anode). In addition, the higher the area ratio of the carbon film was, the larger the galvanic current tended to be.展开更多
One Field has been eternally acknowledged as a sweet arena without the presence of any souring phenomena.On the other hand,the Sulfate Reducing Bacteria(SRB)growth which has been lately observed in the field Water Inj...One Field has been eternally acknowledged as a sweet arena without the presence of any souring phenomena.On the other hand,the Sulfate Reducing Bacteria(SRB)growth which has been lately observed in the field Water Injection System played a major role in increasing the H2S concentrations in particular A fields.The objective of this study is to mitigate the SRB growth in the A Water Injection System and manage the risk of the Hydrogen Sulfide(H2S).In order to reduce the H2S concentrations and the return the Fields back to their original states.Thereafter,Biocide Treatment usage;based on the thorough evaluation performed in both the Lab and Fields by collecting more than 100 samples from designated wellheads and identified sampling points in the field Water Injection System network.Biocide field trial for one year was conducted with a persistent monitoring program.It appealed that the Biocide Treatment is influential,efficient and functional,carving deeper in the SRB mitigation and H2S risk management,the averaged H2S concentrations and trends in the Fields are being controlled and minimized in both the oil and gas phases.展开更多
文摘Corrosiveness or scaling is an inherent threat to oil operations. The primary cause for this threat is the presence of water having complex geochemical matrix. Unanticipated water production, particularly if it contains unwanted impurities, can significantly impact hydrocarbon production. The current paper discusses the degree of threat posed to oil operation facilities based on the water characteristics. Methodology involved the collection and analysis of water samples from major sources in oil industry such as groundwater, wellheads and seawater. The parameters tested include geochemical, microbiological and pollutants. The lab data was used to develop scaling and corrosion prediction indices such as Langelier Saturation Index (LSI), Ryznar Stability Index (RSI) and Puckorius Scaling Index (PSI). The study indicated varying water chemistry for different sources. Mixing of those waters may lead to ionic saturation and scaling in different facilities. Presence of the SRB and GAB in some water sources also posed threat to water system by forming fouling and corrosion. Seawater used for offshore oilfields water injection to maintain reservoir pressure and improve oil recovery showed scaling tendency, whereas under different reservoir pressure, it can cause corrosion. Some of the samples also had corrosion residuals such as iron, which indicated active corrosion. Current study showed higher alkalinity with high sulfate for one groundwater sample with presence of active corrosion residuals such as dissolved iron and manganese. The study showed positive value for LSI which indicated supersaturation of the water samples with respect to calcium carbonate (CaCO<sub>3</sub>) and scale forming. Similarly, for RSI and PSI, the value was below six which confirmed the scaling potential for all the samples. Even though the index value was pointing towards scaling potential, the geochemistry, microbiology and presence of other impurities indicated corrosion threat to the oil and gas industrial facilities. The study concluded the importance of different scale inhibition mechanism and corrosion control in Oil and Gas industry.
文摘Oil and gas industries generate a significant amount of water during the production. The composition of this water varies with the geologic age, depth, and geochemistry of the region along with the chemicals added during the process. Geochemistry of formation water is used for aquifer identification, pollution problems, water compatibility studies, corrosion monitoring, water-quality control, water flooding, exploration, and to diagnose wellbore integrity issues. The current study investigates the spatial and temporal variation of produced water geochemistry from one of the largest conventional oil field, Ghawar field, Saudi Arabia. Produced water from different wellheads were collected and analyzed for different geochemical characteristics. Sixteen wells from ABQQ, nineteen wells from ANDR and twenty wells from SDGM area were selected for the current study. Sampling and analysis were performed as per the standard procedures. Results indicated that the pH of the sample varied from 6.0 to 7.4, and Electrical conductivity from 94200 to 102690 μS/cm. The spatial variation of major cations and anions were also recorded and represented by graphical plots. Metal analysis indicated the highest concentration for boron, which is 20.5 mg/L at ABQQ area, whereas all other metals are very low in concentration. Temporal variation of a single well at SDGM area indicated drastic change in the ionic concentration, whereas the geochemistry remains same as indicated by Tickler plot. The water type of the respective area was studied by tickler plots, which indicated same source of formation water in different wells at ABQQ, ANDR and SDGM areas. The ionic concentration is also used to predict corrosion and scaling issues. By Langelier Saturation Index (LSI) and Ryznar Stability Index (RSI), the sample from all the wells showed higher scaling potential. The study concludes that the water type in different areas under Ghawar field remains same regardless of drastic changes in the ionic concentration, which can be used to diagnose wellbore integrity issues.
文摘Saudi Arabia has </span><span style="font-family:Verdana;">some of </span><span style="font-family:Verdana;">the biggest oil and gas reserves in the world, </span><span style="font-family:Verdana;">and has</span><span style="font-family:Verdana;"> expanded its drilling operations gradually to meet the global demand.</span><span style="font-family:""> </span><span style="font-family:Verdana;">Improper handling of contaminated drilling wastes may cause serious negative environmental impacts. The current study investigates the toxicological effects of heavy metals in drilling waste by </span><span style="font-family:""><span style="font-family:Verdana;">quantification and developing different contamination indices</span><span style="font-family:Verdana;">. Solid and liquid samples from different drilling waste pits were collected and analyzed for heavy metals. The average concentration varies significantly and decrease</span></span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;"> in the order of Fe > Al > Sr > Mn > Cu > Cr > Zn > Ni > Pb > Cd > Ag > Co. The spatial variation showed </span><span style="font-family:Verdana;">the </span><span style="font-family:Verdana;">highest concentration at SDGM Site 1, West. Comparison of current data </span><span style="font-family:Verdana;">showed</span><span style="font-family:Verdana;"> continental crust average values within the specifications for most of the sites. For metals like Cd, Cr and Cu, the concentration is higher than the continental crust value. Indices such as pollution load index, modified degree of contamination etc. were calculated from the available data. </span><span style="font-family:Verdana;">The </span><span style="font-family:Verdana;">contamination level for different site calculat</span><span style="font-family:Verdana;">ions</span><span style="font-family:Verdana;"> showed nil to a very low degree of contamination. Spatial variation of the contamination level indicated comparatively higher values for sites UTMN-4 and SDGM-1 North, which indicates the necessity of precautionary methods. The metal concentration in the pit water samples exceeded generally accepted standards, if this water w</span><span style="font-family:Verdana;">as</span><span style="font-family:Verdana;"> to be discharged/leaked from the pit. </span><span style="font-family:Verdana;">The </span><span style="font-family:Verdana;">current study concluded presence of different heavy metals in samples from the drilling waste pits, whereas the degree of contamination is minute.
文摘It is known that one of the causes of pitting corrosion of copper tubes is residual carbon on the inner surface. It was confirmed that type I” pitting corrosion of the copper tube is suppressed by keeping the residual carbon amount at 2 mg/m<sup>2</sup> or less, which is lower than that of the type I’ pitting corrosion, or by removing the fine particles that are the corrosion product of galvanized steel pipes. The developed water treatment chemical was evaluated using three types of copper tubes with residual carbon amounts of 0 mg/m<sup>2</sup>, 0.5 mg/m<sup>2</sup>, and 6.1 mg/m<sup>2</sup>. The evaluation was conducted for three months in an open-circulation cooling water system and compared with the current water treatment chemical. Under the current water treatment chemical conditions, only the copper tube with a residual carbon amount of 6.1 mg/m<sup>2</sup> showed a significant increase in the natural corrosion potential after two weeks, and pitting corrosion occurred. No pitting corrosion and no increase in the natural corrosion potential were observed in any of the copper tubes that were treated with the developed water treatment chemical. In addition, the polarization curve was measured using the cooling water from this field test, and the anodic polarization of two cooling waters was compared. For copper tubes with a large amount of residual carbon, the current density near 0 mV vs. Ag/AgCl electrode (SSE) increased when the developed water treatment chemical was added.
文摘The modern TSs （total stations） have reached a very high level in the provided reading and reliability （accuracy and precision） of their measurements. The evolution of the digital technology has helped in this direction. Thus, the TSs can support all requirements for the stake out and monitoring of modern survey engineering and constructions projects. Their complicated manufacturing process and the sensitivity of their components require gauging, adjusting and calibration at certain time intervals. This appears to be the only way in order to assure the precision of measurements provided by the manufacturer and the reliability of the works they are used for. The goal of this paper is to propose a method for the estimation of the gauging time interval for modern YSs. which could be used by any user. More specifically, the indispensable need for the TSs gauging is elevated and documented. All the parameters that influence their operation are registered. A model expressed by a scale of grades is defined, leading thus to an equation for the calculation of the time interval for the next needed gauging and calibration.
基金supported by the Key Foundation of Wuhan Huoshenshan Hospital (2020 [18])Key Research&Development Program of Jiangsu Province (BE2018713)+3 种基金Medical Innovation Project of Logistics Service (18JS005)the Foundation of Jiangsu Population Association (JSPA2019017)Medical Science and Technology Development FoundationNanjing Department of Health (YKK18179)。
文摘Background: Gastrointestinal symptoms are not rare among coronavirus disease 2019(COVID-19) patients, but there have been no reports regarding convalescent plasma therapy for the recovery of gastrointestinal problems in COVID-19 patients.Case presentation: We present two cases of patients with COVID-19-associated recurrent diarrhea and positive fecal occult blood who successfully recovered after a one-time convalescent plasma administration.Conclusion: When COVID-19 patients develop recurrent or refractory gastrointestinal symptoms and fail to respond to the available treatment, alternative therapy with convalescent plasma administration may be considered.
文摘It has been reported that pitting corrosion in copper tubes occurs due to the effect of a carbon film produced by the influence of undergoing an oil and heat treatment. As a quantitative method for determining the residual carbon amount, it has been reported that the inner surface of a copper tube can be dissolved with a mixed acid to collect and analyze the adhering carbon;however, this method is dangerous and difficult. Therefore, two methods were examined as a simple quantitative method for obtaining the residual carbon amount using copper tubes with known residual carbon amounts. One method utilizes X-ray photoelectron spectroscopy (XPS), and the other method utilizes the potential difference between the carbon film-adhered surface and carbon film-removed surface. In regard to XPS measurement, a linear correlation was found between the spectral intensity of C and the residual carbon amount;therefore, XPS measurements were considered to be effective as a simple measurement method for the carbon film on the inner surface of a copper tube. In the evaluation method by measuring the corrosion potential, a correlation was observed between the potential difference ΔE and the residual carbon amount of the inner surface of the tube and the outer surface of the polished tube. It is considered possible to estimate the residual carbon amount from the prepared calibration curve. Through these studies, it is suggested that the carbon film was non-uniformly present on the surface of the copper tube. Therefore, the galvanic current was measured, and the effect of a non-uniform carbon film on corrosion behavior was investigated. As a result, in the measurement of galvanic current, the current flowed from the copper tube with a large amount of residual carbon (cathode) to the copper tube with a small amount of residual carbon (anode). In addition, the higher the area ratio of the carbon film was, the larger the galvanic current tended to be.
文摘One Field has been eternally acknowledged as a sweet arena without the presence of any souring phenomena.On the other hand,the Sulfate Reducing Bacteria(SRB)growth which has been lately observed in the field Water Injection System played a major role in increasing the H2S concentrations in particular A fields.The objective of this study is to mitigate the SRB growth in the A Water Injection System and manage the risk of the Hydrogen Sulfide(H2S).In order to reduce the H2S concentrations and the return the Fields back to their original states.Thereafter,Biocide Treatment usage;based on the thorough evaluation performed in both the Lab and Fields by collecting more than 100 samples from designated wellheads and identified sampling points in the field Water Injection System network.Biocide field trial for one year was conducted with a persistent monitoring program.It appealed that the Biocide Treatment is influential,efficient and functional,carving deeper in the SRB mitigation and H2S risk management,the averaged H2S concentrations and trends in the Fields are being controlled and minimized in both the oil and gas phases.
