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Controllable Crystallization Optimizes Thermal Stability of A Novel Red-emitting Phosphor in Self-reduction System
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作者 LU Shiwei DONG Rui +5 位作者 BAI Yuxing DU Haihong ZHENG Lirong WU Li KONG Yongfa XU Jingjun 《发光学报》 北大核心 2025年第2期285-295,共11页
Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significan... Thermal quenching(TQ)at elevated temperature is a major factor affecting the luminescent intensity and efficiency of phosphors.Improving the thermal stability of phosphors and weakening the TQ effect are of significance for the high-quality illumination of phosphor-converted WLEDs.Here,a novel red-emitting phosphor K_(2)Zn(PO_(3))_(4)∶Mn^(2+)is synthesized by standard high temperature solid state reaction in ambient atmosphere,which is a new member of self-reduction system.An effective synthesis strategy is proposed to optimize its photoluminescent performances.Combined with X-ray photoelectron spectroscopy and X-ray absorption fine structure spectroscopy,oxygen vacancy defects introduced by Mn doping are proved to play an important role in the transition of Mn^(4+)→Mn^(2+).Thermoluminescence analysis reveals that the distribution of trap levels,especially the deep ones,is effectively regulated by the controllable crystallization and significantly affect the thermal stability of phosphors.Then a defect-assisted model is proposed to address the inner mechanism of the phenomenon.The carriers trapped by deep trap levels can be released under the high-temperature stimulus,which return back to the luminescent centers and participate in the radiative recombination to improve thermal stability.This study provides a new crystallographic idea and theoretical support for obtaining luminescent materials with high thermal stability. 展开更多
关键词 photoluminescence lattice defects self-reduction thermal stability
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Self-assembly of block copolymers grafted onto a flat substrate:Recent progress in theory and simulations
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作者 王铮 李宝会 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第1期270-281,共12页
Block copolymers are a class of soft matter that self-assemble to form ordered morphologies on the scale of nanome- ters, making them ideal materials for various applications. These applications directly depend on the... Block copolymers are a class of soft matter that self-assemble to form ordered morphologies on the scale of nanome- ters, making them ideal materials for various applications. These applications directly depend on the shape and size of the self-assembled morphologies, and hence, a high degree of control over the self-assembly is desired. Grafting block copolymer chains onto a substrate to form copolymer brushes is a versatile method to fabricate functional surfaces. Such surfaces demonstrate a response to their environment, i.e., they change their surface topography in response to different external conditions. Furthermore, such surfaces may possess nanoscale patterns, which are important for some applica- tions; however, such patterns may not form with spun-cast films under the same condition. In this review, we summarize the recent progress of the self-assembly of block copolymers grafted onto a flat substrate. We mainly concentrate on the self-assembled morphologies of end-grafted AB dibloek eopolymers, junction p0int-grafted AB diblock copolymers (i.e., Y-shaped brushes), and end-grafted ABA triblock copolymers. Special emphasis is placed on theoretical and simulation progress. 展开更多
关键词 grafted AB diblock copolymers grafted ABA triblock copolymers SELF-ASSEMBLY block copoly-mer brushes
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Role of Heavy Metal Ions in the Formation of Oxyfluoride Glasses and Glass Ceramics 被引量:3
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作者 Min Liu Lijuan Zhao +4 位作者 Yan Liu Zijian Lan Lifen Chang Yiming Li Hua Yu 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2014年第12期1213-1216,共4页
In order to investigate the influence of different heavy metal ions on the formation of the oxyfluoride glasses and glass ceramics, samples with different Pb F2/Cd F2 ratios have been prepared by the melting quenching... In order to investigate the influence of different heavy metal ions on the formation of the oxyfluoride glasses and glass ceramics, samples with different Pb F2/Cd F2 ratios have been prepared by the melting quenching and thermal treatment method. The different effects of Pb2 tand Cd2ton the glass network structure are investigated by FTIR and Raman spectra. During the formation of glass network structure, Pb2 tprefers to break the Sie Oe Si bond and subsequently bond to F for charge compensation, and Cd2 tprefers to break the SieO eA l bond and is surrounded by O2. Pb2 tand F gather together and form the fluoride nanocrystals,while Cd2 tremains in oxide matrix after thermal treatment. Introduction of proper Cd F2 is important to adjust and control the glass network structure and crystallization process in the fabrication of the transparent glass ceramics. 展开更多
关键词 Pb Cd Glass network Oxyfluoride glass ceramics
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Light transmission in porous silicon dioxide filled with liquids of different refractive indices
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作者 李俊 张心正 +4 位作者 石凡 徐燕 王丕东 禹宣伊 许京军 《Chinese Optics Letters》 SCIE EI CAS CSCD 2011年第6期94-96,共3页
Optical transmission at 532 nm from nonabsorbing disordered porous silicon dioxide has been studied experimentally. The transmission behaviors can be adjusted by filling the pores with liquids of different refractive ... Optical transmission at 532 nm from nonabsorbing disordered porous silicon dioxide has been studied experimentally. The transmission behaviors can be adjusted by filling the pores with liquids of different refractive indics, which are analyzed based on the theory of diffusion in a weak scattering regime. In our experiment, the transmission coefficient changes from a value less than 1% to one that is greater than 75%, that is, the opaque sample becomes transparent, which means that the transport mean free path of light within the material has been effectively adjusted. In addition, this method is a useful nondestructive method to derive the refractive index of an unknown bulk porous material. 展开更多
关键词 Light refraction Porous materials Porous silicon Refractive index REFRACTOMETERS SILICA
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Effect of thermal annealing on sub-band-gap absorptance of microstructured silicon in air
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作者 曹丽萍 陈战东 +1 位作者 张春玲 姚江宏 《Frontiers of physics》 SCIE CSCD 2015年第4期103-109,共7页
The optical absorption properties of femtosecond-laser-made "black silicon" as a function of the annealing conditions were investigated. We found that the annealing process changes the surface morphology and absorpt... The optical absorption properties of femtosecond-laser-made "black silicon" as a function of the annealing conditions were investigated. We found that the annealing process changes the surface morphology and absorption spectroscopy of the "black silicon" samples, and obtained a maximum sub-band-gap absorptance value of approximately 30% by annealing at 1000 ~C for 30 min. The thermal relaxation and atomic structural transformation mechanisms are used to describe the lat- tice recovery and the increase and decrease of the substitutional dopant atom concentration in the microstructured surface during the annealing. Our results confirm that: i) owing to the ther- mal relaxation, the lattice defects decrease with the increase of the annealing temperature; ii) the quasi-substitutional and interstitial configurations of the doped atoms transform into substitutional arrangements when the annealing temperature increases; iii) the quasi-substitutional and intersti- tial configurations with higher energies of the doped atoms transform into interstitial configurations with the lowest energy after high-temperature annealing for a long period of time, causing the de- activation or reactivation of the sub-band-gap absorptance by diffusion. The results demonstrate that the annealing can improve the properties of "black silicon", including defects repairing, carrier lifetime lengthening, and retention of a high absorptive performance. 展开更多
关键词 sub-band-gap absorptance black silicon ANNEALING DIFFUSION
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Beam control in tri-core photonic lattices
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作者 叶卓艺 夏世强 +2 位作者 宋道红 唐莉勤 楼慈波 《Chinese Physics B》 SCIE EI CAS CSCD 2014年第2期312-315,共4页
We report on theoretical investigations of beam control in one-dimensional tri-core photonic lattices (PLs). Linear splitting is illustrated in tri-core PLs; the effect of defect strength on the splitting is discuss... We report on theoretical investigations of beam control in one-dimensional tri-core photonic lattices (PLs). Linear splitting is illustrated in tri-core PLs; the effect of defect strength on the splitting is discussed in depth for single-wavelength light. We reveal that splitting disappears when the defect strength trends to zero, while reoccurring under nonlinearity. Multi-color splitting and active control are also proposed in such photonic structures. 展开更多
关键词 tri-core photonic lattices SPLITTING
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Realization of photonic p-orbital higher-order topological insulators 被引量:8
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作者 Yahui Zhang Domenico Bongiovanni +9 位作者 Ziteng Wang Xiangdong Wang Shiqi Xia Zhichan Hu Daohong Song Dario Jukic Jingjun Xu Roberto Morandotti Hrvoje Buljan Zhigang Chen 《eLight》 2023年第1期230-238,共9页
The orbital degrees of freedom play a pivotal role in understanding fundamental phenomena in solid-state materials as well as exotic quantum states of matter including orbital superfluidity and topological semimetals.... The orbital degrees of freedom play a pivotal role in understanding fundamental phenomena in solid-state materials as well as exotic quantum states of matter including orbital superfluidity and topological semimetals.Despite tremendous efforts in engineering synthetic cold-atom,as well as electronic and photonic lattices to explore orbital physics,thus far high orbitals in an important class of materials,namely,higher-order topological insulators(HOTIs),have not been realized.Here,we demonstrate p-orbital corner states in a photonic HOTI,unveiling their underlying topological invariant,symmetry protection,and nonlinearity-induced dynamical rotation.In a Kagome-type HOTI,we find that the topological protection of p-orbital corner states demands an orbital-hopping symmetry in addition to generalized chiral symmetry.Due to orbital hybridization,nontrivial topology of the p-orbital HOTI is“hidden”if bulk polarization is used as the topological invariant,but well manifested by the generalized winding number.Our work opens a pathway for the exploration of intriguing orbital phenomena mediated by higher-band topology applicable to a broad spectrum of systems. 展开更多
关键词 Higher-band topology Orbital degrees of freedom Generalized chiral symmetry Bulk polarization Winding number Breathing Kagome lattice
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Real-time transition dynamics and stability of chipscale dispersion-managed frequency microcombs 被引量:5
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作者 Yongnan Li Shu-Wei Huang +9 位作者 Bowen Li Hao Liu Jinghui Yang Abhinav Kumar Vinod Ke Wang Mingbin Yu Dim-Lee Kwong Hui-Tian Wang Kenneth Kin-Yip Wong Chee Wei Wong 《Light(Science & Applications)》 SCIE EI CAS CSCD 2020年第1期1520-1529,共10页
Femtosecond mode-locked laser frequency combs have served as the cornerstone in precision spectroscopy,alloptical atomic clocks,and measurements of ultrafast dynamics.Recently frequency microcombs based on nonlinear m... Femtosecond mode-locked laser frequency combs have served as the cornerstone in precision spectroscopy,alloptical atomic clocks,and measurements of ultrafast dynamics.Recently frequency microcombs based on nonlinear microresonators have been examined,exhibiting remarkable precision approaching that of laser frequency combs,on a solid-state chip-scale platform and from a fundamentally different physical origin.Despite recent successes,to date,the real-time dynamical origins and high-power stabilities of such frequency microcombs have not been fully addressed.Here,we unravel the transitional dynamics of frequency microcombs from chaotic background routes to femtosecond mode-locking in real time,enabled by our ultrafast temporal magnifier metrology and improved stability of dispersion-managed dissipative solitons.Through our dispersion-managed oscillator,we further report a stability zone that is more than an order-of-magnitude larger than its prior static homogeneous counterparts,providing a novel platform for understanding ultrafast dissipative dynamics and offering a new path towards high-power frequency microcombs. 展开更多
关键词 DISPERSION STABILITY dynamics
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Self-trapping and oscillation of quadruple beams in high band gap of 2D photonic lattices 被引量:2
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作者 夏世强 宋道红 +2 位作者 唐莉勤 楼慈波 李乙刚 《Chinese Optics Letters》 SCIE EI CAS CSCD 2013年第9期21-24,共4页
through single-site excitation. By changing the initial to the lattices, periodic oscillations of the localized quadruple state becomes a rotating doubly charged undergo charge-flipping when the rotating direction is ... through single-site excitation. By changing the initial to the lattices, periodic oscillations of the localized quadruple state becomes a rotating doubly charged undergo charge-flipping when the rotating direction is orientation of the incident quadruple beam related quadruple mode may be obtained. The localized optical vortex (DCV) during rotation and should reversed. 展开更多
关键词 Self-trapping and oscillation of quadruple beams in high band gap of 2D photonic lattices HIGH
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Information‑entropy enabled identifying topological photonic phase in real space
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作者 Rui Ma Qiuchen Yan +5 位作者 Yihao Luo Yandong Li Xingyuan Wang Cuicui Lu Xiaoyong Hu Qihuang Gong 《Frontiers of Optoelectronics》 EI CSCD 2024年第2期1-9,共9页
The topological photonics plays an important role in the fields of fundamental physics and photonic devices.The traditional method of designing topological system is based on the momentum space,which is not a direct a... The topological photonics plays an important role in the fields of fundamental physics and photonic devices.The traditional method of designing topological system is based on the momentum space,which is not a direct and convenient way to grasp the topological properties,especially for the perturbative structures or coupled systems.Here,we propose an interdisciplinary approach to study the topological systems in real space through combining the information entropy and topological photonics.As a proof of concept,the Kagome model has been analyzed with information entropy.We reveal that the bandgap closing does not correspond to the topological edge state disappearing.This method can be used to identify the topological phase conveniently and directly,even the systems with perturbations or couplings.As a promotional validation,Su-Schrieffer-Heeger model and the valley-Hall photonic crystal have also been studied based on the information entropy method.This work provides a method to study topological photonic phase based on information theory,and brings inspiration to analyze the physical properties by taking advantage of interdisciplinarity. 展开更多
关键词 Information entropy Kagome model Topological photonic phase
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Advances in on-chip photonic devices based on lithium niobate on insulator 被引量:45
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作者 JINTIAN LIN FANG BO +1 位作者 YA CHENG JINGJUN XU 《Photonics Research》 SCIE EI CAS CSCD 2020年第12期1910-1936,共27页
Crystalline lithium niobate(LN)is an important optical material because of its broad transmission window that spans from ultraviolet to mid-infrared and its large nonlinear and electro-optic coefficients.Furthermore,t... Crystalline lithium niobate(LN)is an important optical material because of its broad transmission window that spans from ultraviolet to mid-infrared and its large nonlinear and electro-optic coefficients.Furthermore,the recent development and commercialization of LN-on-insulator(LNOI)technology has opened an avenue for the realization of integrated on-chip photonic devices with unprecedented performances in terms of propagation loss,optical nonlinearity,and electro-optic tunability.This review begins with a brief introduction of the history and current status of LNOI photonics.We then discuss the fabrication techniques of LNOI-based photonic structures and devices.The recent revolution in the LN photonic industry has been sparked and is still being powered by innovations of the nanofabrication technology of LNOI,which enables the production of building block structures,such as optical microresonators and waveguides of unprecedented optical qualities.The following sections present various on-chip LNOI devices categorized into nonlinear photonic and electro-optic tunable devices and photonic-integrated circuits.Some conclusions and future perspectives are provided. 展开更多
关键词 LITHIUM INSULATOR REALIZATION
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Controllable optical activity with non-chiral plasmonic metasurfaces 被引量:9
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作者 Ping Yu Jianxiong Li +8 位作者 Chengchun Tang Hua Cheng Zhaocheng Liu Zhancheng Li Zhe Liu Changzhi Gu Junjie Li Shuqi Chen Jianguo Tian 《Light(Science & Applications)》 SCIE EI CAS CSCD 2016年第1期646-652,共7页
Optical activity is the rotation of the plane of linearly polarized light along the propagation direction as the light travels through optically active materials.In existing methods,the strength of the optical activit... Optical activity is the rotation of the plane of linearly polarized light along the propagation direction as the light travels through optically active materials.In existing methods,the strength of the optical activity is determined by the chirality of the materials,which is difficult to control quantitatively.Here we numerically and experimentally investigated an alternative approach to realize and control the optical activity with non-chiral plasmonic metasurfaces.Through judicious design of the structural units of the metasurfaces,the right and left circular polarization components of the linearly polarized light have different phase retardations after transmitting through the metasurfaces,leading to large optical activity.Moreover,the strength of the optical activity can be easily and accurately tuned by directly adjusting the phase difference.The proposed approach based on non-chiral plasmonic metasurfaces exhibits large optical activity with a high controllable degree of freedom,which may provide more possibilities for applications in photonics. 展开更多
关键词 metasurfaces optical activity surface plasmon polaritons
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Boosting third-harmonic generation by a mirror-enhanced anapole resonator 被引量:8
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作者 Lei Xu Mohsen Rahmani +10 位作者 Khosro Zangeneh Kamali Aristeidis Lamprianidis Lavinia Ghirardini Jürgen Sautter Rocio Camacho-Morales Haitao Chen Matthew Parry Isabelle Staude Guoquan Zhang Dragomir Neshev Andrey E.Miroshnichenko 《Light(Science & Applications)》 SCIE EI CAS CSCD 2018年第1期661-668,共8页
We demonstrate that a dielectric anapole resonator on a metallic mirror can enhance the third harmonic emission by two orders of magnitude compared to a typical anapole resonator on an insulator substrate.By employing... We demonstrate that a dielectric anapole resonator on a metallic mirror can enhance the third harmonic emission by two orders of magnitude compared to a typical anapole resonator on an insulator substrate.By employing a gold mirror under a silicon nanodisk,we introduce a novel characteristic of the anapole mode through the spatial overlap of resonantly excited Cartesian electric and toroidal dipole modes.This is a remarkable improvement on the early demonstrations of the anapole mode in which the electric and toroidal modes interfere off-resonantly.Therefore,our system produces a significant near-field enhancement,facilitating the nonlinear process.Moreover,the mirror surface boosts the nonlinear emission via the free-charge oscillations within the interface,equivalent to producing a mirror image of the nonlinear source and the pump beneath the interface.We found that these improvements result in an extremely high experimentally obtained efficiency of 0.01%. 展开更多
关键词 RESONATOR PUMP MIRROR
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Sum-frequency generation in on-chip lithium niobate microdisk resonators 被引量:6
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作者 ZHENZHONG HAO JIE WANG +5 位作者 SHUQIONG MA WENBO MAO FANG BO FENG GAO GUOQUAN ZHANG JINGJUN XU 《Photonics Research》 SCIE EI 2017年第6期142-147,共6页
We report the first observation, to the best of our knowledge, of sum-frequency generation in on-chip lithium niobate microdisk resonators. The sum-frequency signal in the 780 nm band, distinct in wavelength from seco... We report the first observation, to the best of our knowledge, of sum-frequency generation in on-chip lithium niobate microdisk resonators. The sum-frequency signal in the 780 nm band, distinct in wavelength from secondharmonic signals, was obtained in lithium niobate microresonators under the pump of two individual 1550 nm band lasers. The sum-frequency conversion efficiency was measured to be 1.4 × 10^(-7) mW^(-1). The dependence of the intensities of the nonlinear signals on the total pump power and the wavelength of one pump laser was investigated while fixing the wavelength of the other. This work paves the way for applications of on-chip lithium niobate microdisk resonators ranging from infrared single-photon detection to infrared spectroscopy. 展开更多
关键词 SFG Sum-frequency generation in on-chip lithium niobate microdisk resonators SHG
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Diabolical points in coupled active cavities with quantum emitters 被引量:2
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作者 Jingnan Yang Chenjiang Qian +17 位作者 Xin Xie Kai Peng Shiyao Wu Feilong Song Sibai Sun Jianchen Dang Yang Yu Shushu Shi Jiongji He Matthew JSteer Iain GThayne Bei-Bei Li Fang Bo Yun-Feng Xiao Zhanchun Zuo Kuijuan Jin Changzhi Gu Xiulai Xu 《Light(Science & Applications)》 SCIE EI CAS CSCD 2020年第1期1943-1950,共8页
In single microdisks,embedded active emitters intrinsically affect the cavity modes of the microdisks,resulting in trivial symmetric backscattering and low controllability.Here we demonstrate macroscopic control of th... In single microdisks,embedded active emitters intrinsically affect the cavity modes of the microdisks,resulting in trivial symmetric backscattering and low controllability.Here we demonstrate macroscopic control of the backscattering direction by optimizing the cavity size.The signature of the positive and negative backscattering directions in each single microdisk is confirmed with two strongly coupled microdisks.Furthermore,diabolical points are achieved at the resonance of the two microdisks,which agrees well with theoretical calculations considering the backscattering directions.Diabolical points in active optical structures pave the way for an implementation of quantum information processing with geometric phase in quantum photonic networks. 展开更多
关键词 QUANTUM BACKSCATTERING DIRECTIONS
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Self-accelerating and self-breathing Bessel-like beams along arbitrary trajectories
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作者 赵娟莹 张鹏 +4 位作者 邓冬梅 楼慈波 宋道红 刘京郊 陈志刚 《Chinese Optics Letters》 SCIE EI CAS CSCD 2013年第11期42-45,共4页
We theoretically and experimentally study self-accelerating and self-breathing Bessel-like beams that fol- low arbitrary trajectories, including hyperbolic, hyperbolic secant, and three-dimensional (3D) spiraling tr... We theoretically and experimentally study self-accelerating and self-breathing Bessel-like beams that fol- low arbitrary trajectories, including hyperbolic, hyperbolic secant, and three-dimensional (3D) spiraling trajectories. The beams have an overall Bessel-like profile in transverse dimensions; however, the intensity of their central main lobe breathes while traveling along a curved trajectory. Such beams can be readily generated experimentally through appropriate phase modulation of the optical wavefront. The beams con- tribute to the design of new families of self-accelerating beams. 展开更多
关键词 Bessel functions Laser beams Phase modulation Three dimensional
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