The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of th...The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision.展开更多
The Kukaazi Pb-Zn-Cu-W polymetallic deposit, located in the Western Kunlun orogenic belt, is a newly discovered skarn-type deposit. Ore bodies mainly occur in the forms of lenses and veins along beddings of the Mesopr...The Kukaazi Pb-Zn-Cu-W polymetallic deposit, located in the Western Kunlun orogenic belt, is a newly discovered skarn-type deposit. Ore bodies mainly occur in the forms of lenses and veins along beddings of the Mesoproterozoic metamorphic rocks. Three ore blocks, KⅠ,KⅡ, and KⅢ, have been outlined in different parts of the Kukaazi deposit in terms of mineral assemblages. The KⅠ ore block is mainly composed of chalcopyrite, scheelite,pyrrhotite, sphalerite, galena and minor pyrite, arsenopyrite,and molybdenite, whereas the other two ore blocks are made up of galena, sphalerite, magnetite and minor arsenopyrite and pyrite. In this study, we obtained a molybdenite isochron Re–Os age of 450.5 ± 6.4 Ma(2σ,MSWD = 0.057) and a scheelite Sm–Nd isochron age of 426 ± 59 Ma(2σ, MSWD = 0.49) for the KⅠ ore block.They are broadly comparable to the ages of granitoid in the region. Scheelite grains from the KⅠ ore block contain high abundances of rare earth elements(REE, 42.0–95.7 ppm)and are enriched in light REE compared to heavy REE, with negative Eu anomalies(δEu = 0.13–0.55). They display similar REE patterns and Sm/Nd ratios to those of the coeval granitoids in the region. Moreover, they also have similar Sr and Nd isotopes [ ^(87)Sr/ ^(86)Sr = 0.7107–0.7118;ε_(Nd)(t) =-4.1 to-4.0] to those of such granitoids, implying that the tungsten-bearing fluids in the Kukaazi deposit probably originate from the granitic magmas. Our results first defined that the Early Paleozoic granitoids could lead to economic Mo–W–(Cu) mineralization at some favorable districts in the Western Kunlun orogenic belt and could be prospecting exploration targets.展开更多
In this study, plagiogranites in the Diyanmiao ophiolite of the southeastern Central Asian Orogenic Belt(Altaids) were investigated for the first time. The plagiogranites are composed predominantly of albite and quart...In this study, plagiogranites in the Diyanmiao ophiolite of the southeastern Central Asian Orogenic Belt(Altaids) were investigated for the first time. The plagiogranites are composed predominantly of albite and quartz, and occur as irregular intrusive veins in pillow basalts. The plagiogranites have high SiO_2(74.37–76.68 wt%) and low Al_2O_3(11.99–13.30 wt%), and intensively high Na_2O(4.52–5.49 wt%) and low K_2O(0.03–0.40 wt%) resulting in high Na_2O/K_2O ratios(11.3–183). These rocks are classified as part of the low-K tholeiitic series. The plagiogranites have low total rare earth element contents(∑REE)(23.62–39.77 ppm), small negative Eu anomalies(δEu=0.44–0.62), and flat to slightly LREE-depleted chondrite-normalized REE patterns((La/Yb)N=0.68–0.76), similar to N-MORB. The plagiogranites are also characterized by Th, U, Zr, and Hf enrichment, and Nb, P, and Ti depletion, have overall flat primitivemantle-normalized trace element patterns. Field and petrological observations and geochemical data suggest that the plagiogranites in the Diyanmiao ophiolite are similar to fractionation-type plagiogranites. Furthermore, the REE patterns of the plagiogranites are similar to those of the gabbros and pillow basalts in the ophiolite. In plots of SREE–SiO_2, La–SiO_2, and Yb–SiO_2, the plagiogranites, pillow basalts, and gabbros show trends typical of crystal fractionation. As such, the plagiogranites are oceanic in origin, formed by crystal fractionation from basaltic magmas derived from depleted mantle, and are part of the Diyanmiao ophiolite. LA–ICP–MS U–Pb dating of zircons from the plagiogranites yielded ages of 328.6±2.1 and 327.1±2.1 Ma, indicating an early Carboniferous age for the Diyanmiao ophiolite. These results provide petrological and geochronological evidence for the identification of the Erenhot–Hegenshan oceanic basin and Hegenshan suture of the Paleo-Asian Ocean.展开更多
This paper reports a newly discovered Late Mesoproterozoic–Early Neoproterozoic stromatolite assemblage, named here the “Jiawengmen stromatolite assemblage”, represented by a Conophyton-Baicalia association in the ...This paper reports a newly discovered Late Mesoproterozoic–Early Neoproterozoic stromatolite assemblage, named here the “Jiawengmen stromatolite assemblage”, represented by a Conophyton-Baicalia association in the Jiawenmen area in the southern belt of the Eastern Kunlun. This stromatolite assemblage is dominated by large-scale conical stromatolites and related elements, i.e., Conophyton garganicus var. inkeni, C. cf. ressoti Menchikov, Jacutophyton cf., Conicodomenia f., which commonly co-exist with elements of the group of Baicalia. This assemblage can be correlated with that of the middle Jixian-middle Qingbaikou System in North and Northwest China, but is different from that in South China. Correlation can also be made with that in the upper horizon of the Middle Riphean-lower horizon of the Upper Riphean in the South Ural Mountains and Siberia of Russia, in North Africa, and in the Alaskan Peninsula of North America. These facts suggest that the Jiawengmen stromatolite assemblage probably colonized during 1300–850 Ma ago. Accordingly, the stromatolite-bearing carbonate rocks are then proposed to correspond to the middle Jixian System-middle Qingbaikou System or the upper Middle Riphean-lower Upper Riphean. Our stromatolite data further suggest that a Precambrian microblock, named the Xialawen microblock here, occurred in the southern belt of Eastern Kunlun, the western part of the Maqên microblock. Similar stromatolite assemblages in the Maqên microblock and those blocks that occurred in North China, Siberia and North Africa point to similar paleogeographic and paleoenvironmental conditions. These microblock and blocks were probably located at low latitudes and on the continental margins of the Rodinian supercontinent, where warm epicontinental seas were favorable to widespread colonization of stromatolites during the Late Mesoproterozoic-Early Neoproterozoic. However, these stromatolite assemblages are quite different from those of the South China block, which is suggestive of different paleogeographic contexts, and probably also of a different tectonic affinity.展开更多
1 Geological Background This paper reports geochemistry(major and trace elements),zircon U-Pb and Lu-Hf isotope studies of leucogranite,granodiorite and clinopyroxene-bearing diorite from the Zengga intrusive body,eas...1 Geological Background This paper reports geochemistry(major and trace elements),zircon U-Pb and Lu-Hf isotope studies of leucogranite,granodiorite and clinopyroxene-bearing diorite from the Zengga intrusive body,eastern Gangdese batholith,Tibet.Massive granodiorite is mainly composed of fine-and medium-grained plagioclase(65 modal%),展开更多
Described in paper is the principle of optimal partitioning method for stratigraphic division and correlation.The Nihewan Beds are taken for example to show how to apply this approach in stratigraphic division and cor...Described in paper is the principle of optimal partitioning method for stratigraphic division and correlation.The Nihewan Beds are taken for example to show how to apply this approach in stratigraphic division and correlation.The semiquantitative spectral analysis data on aggregate trace elements in 324 samples taken from the nine sections in the Nihewan Basin are treated with multivariate statistical method for stratigraphic division and correlation.First ,the data from all the sections are respectively calculated by the optimal partitioning method to establish the stratigraphic boundaries.The optimal partitioning method has proved itself to be applicable to stratigraphic division and correlation. In our practice the Nihewan Beds are divided into five zones (I-V).Zone I includes subzones Ia and Ib,Zones Ia,Ib,II and III are considered to be corresponding to the Pliocene(N2),the early Early Pleistocene,the late Early Pleistocene,and the Middle Pleistocene,respectively .Zones IV and V are probably Late Pleistocene in age.This indicated that sediments deposited con-temporaneous in the sections of the same basin are similar in geochemical characteristics,although dif-ferent in geographical location.However,the sediments also show some variations ,with a transitional relationship from one section to another .For example ,in Zone II,the sediments of the Xiaodukou section show not only the characteristics of the Nangou-Hongya and Hutouliang sections,but also those of the Xiashagou,Shixiaxi,Shixiadong and Wulitai sections.It can be seen from the above that the zones can be characteristically correlated with one another.In addition the feasibility of the optimal partitioning method is also described in the present paper.展开更多
Matrix effect primarily impacts the accuracy and precision of zircon LA-ICP-MS U-Pb data.This paper describes three types of matrix effect in zircon LA-ICPMS U-Pb dating,i.e.,the element matrix effect,high Ddpa or ura...Matrix effect primarily impacts the accuracy and precision of zircon LA-ICP-MS U-Pb data.This paper describes three types of matrix effect in zircon LA-ICPMS U-Pb dating,i.e.,the element matrix effect,high Ddpa or uranium matrix effect and alpha dose matrix effect,and illustrates the correction of these three effects.In addition,we point out the limitation and possible problems of the existing correction methods.展开更多
Four distinct lithe-tectonic belts (zones) in the Yinshan area, North China, were identified by pressure-temperature contours and litho-tectonic features, such as the Sanggan granulite belt, Jining metasedimentary bel...Four distinct lithe-tectonic belts (zones) in the Yinshan area, North China, were identified by pressure-temperature contours and litho-tectonic features, such as the Sanggan granulite belt, Jining metasedimentary belt. Wulashan-Daqingshan front tectonic zone and Se’ eratengshan belt. This area witnessed two important thermo-tectonic events. The older one is c. 2.5 Ga while the younger one c. 1.9 Ga. The Se’ ertengshan Neoarchaean terrane features a clockwise PT path with the decompression ranging from 】 1500 MPa to 800-1000 MPa in the Se’ ertengshan belt, which implies an island arc setting. The Sanggan belt is a Mesoarchaean microcontinent reworked by Neoarchaean magma underplating, which shows an counterclockwise PT path. During the Palaeoproterozoic period, two Archaean continent (arc) collided. The Archaean basement of the Sanggan and Wulashan-Daqingshan belts overthrust northwards, the PTt paths of basement show a decompression from 1000-1200 MPa to 500-700 MPa. The PT paths of the Jining and展开更多
The Yarlung Zongbo Suture Zone(YZSZ)is thought to be the most important geological boundary,the collision between the India plate and the Eurasia happened since Cretaceous-Tertiary(Aitchison et al.,2011).The YZSZ,bord...The Yarlung Zongbo Suture Zone(YZSZ)is thought to be the most important geological boundary,the collision between the India plate and the Eurasia happened since Cretaceous-Tertiary(Aitchison et al.,2011).The YZSZ,bordered to the north by the Lhasa Block and to the south by the Tethyan sedimentary sequence and the展开更多
The Gejiu-Bozushan-Laojunshan W-Sn polymetallic metallogenic belt(GBLB)in southeast Yunnan Province is an important part of the southwestern Yangtze Block in South China.Tin polymetallic mineralization in this belt in...The Gejiu-Bozushan-Laojunshan W-Sn polymetallic metallogenic belt(GBLB)in southeast Yunnan Province is an important part of the southwestern Yangtze Block in South China.Tin polymetallic mineralization in this belt includes the Niusipo,Malage,Songshujiao,Laochang and Kafang ore fields in the Gejiu area which are spatially and temporally associated with the Kafang-Laochang and Songshujiao granite plutons.These granites are characterized by variable A/CNK values(mostly>1.1,except for two samples with 1.09),high contents of SiO2(74.38-76.84 wt.%)and Al2 O3(12.46-14.05 wt.%)and variable CaO/Na2 O ratios(0.2-0.65)as well as high zirconδ18O values(7.74‰-9.86‰),indicative of S-type affinities.These rocks are depleted in Rb,Th,U,Ti,LREE[(La/Yb)N=1.4-20.51],Ba,Nb,Sr,and Ti and display strong negative Eu and Ba anomalies.The rocks possess high Rb/Sr and Rb/Ba ratios,relatively low initial 87Sr/86Sr ratios(0.6917-0.7101),and less radiogenicεNd(t)values(-8.0 to-9.1).The zircon grains from these rocks show negativeεHf(t)values in the range of-3.7 to-9.9 with mean TDM2(Nd)and TDM2(Hf)values of 1.57 Ga and 1.55 Ga.They show initial 207Pb/204Pb ranging from15.69 to 15.71 and 206Pb/204Pb from 18.36 to 18.70.Monazite from Songshujiao granites exhibits higher U and lower Th/U ratios,lowerδ18O values and higherεHf(t)values than those of the zircon grains in the KafangLaochang granites.The geochemical and isotopic features indicate that the Laochang-Kafang granites originated by partial melting of Mesoproterozoic crustal components including biotite-rich metapelite and metagraywacke,whereas the Songshujiao granites were derived from Mesoproterozoic muscovite-rich metapelite crustal source.Most zircon grains from the Songshujiao,Laochang and Kafang granites have high-U concentrations and their SIMS U-Pb ages show age scatter from 81.6 Ma to 88.6 Ma,80.7 Ma to 86.1 Ma and 82.3 Ma to 87.0 Ma,suggesting formation earlier than the monazite and cassiterite.Monazite SIMS U-Pb ages and Th-Pb ages of three same granite samples are consistent and show yielded 206 Pb/238U ages of 83.7±0.6 Ma,83.7±0.6 Ma,and 83.4±0.6 Ma,and 208Pb/232Th ages of 83.2±0.5 Ma,83.8±0.4 Ma,and 83.5±0.9 Ma,which are within the range of the SIMS zircon U-Pb ages from these rocks.The data constrain the crystallization of the granites at ca.83 Ma.In situ U-Pb dating of two cassiterite samples from the cassiterite-sulfide ore in the Songshujiao ore field and Kafang ore field,and two from the cassiterite-oxide+cassiterite bearing dolomite in the Laochang ore field yielded weighted mean 206 Pb/238U ages of 83.5±0.4 Ma(MSWD=0.6),83.5±0.4 Ma(MSWD=0.5),83.6±0.4 Ma(MSWD=0.6)and 83.2±0.7 Ma(MSWD=0.6),respectively.Combined with geological characteristics,the new geochronological data indicate that the formation of the granites and Sn polymetallic deposits are coeval.We correlate the magmatic and metallogenic event with lithospheric thinning and asthenosphere upwelling in continental extension setting in relation to the eastward subduction of the Neo-Tethys beneath the Sanjiang tectonic domain during Late Cretaceous.展开更多
Glauconite is widely distributed in space and time.In China glauconite-bearing strata are extensive occurrence ranging from Late Cretaceous to Middle Proterozoic in age.X-ray powder analysis,X-ray diffracition analysi...Glauconite is widely distributed in space and time.In China glauconite-bearing strata are extensive occurrence ranging from Late Cretaceous to Middle Proterozoic in age.X-ray powder analysis,X-ray diffracition analysis and differential thermal analysis revealed that glauconite has a mica-type structure between dioctahedron and trioctahedron.Its chemical composition is:Al2O310.6%,SiO249.23%,MgO3.24%,Fe2O317.40%,FeO1.8%,and K2O7.92%,Its crystal form and thermal properties are very similar to those of mica-like clay minerls.According to isotopic age determinations of glauconite in modern oceans (including the East China Sea,the South China Sea and the Yellow Sea),we consider that in the extreme case glauconite is an authigenic mineral.It is generally formed in sedimentary rocks.Is has further proved that glauconite can be used to determine the ages of sedimentary rocks.展开更多
The metasedimentary-volcanic series of the Wutai and Hutuo groups experienced regional metamorphism and thus turned into moderate-to low-grade metamorphic rocks.REE abundances and REE distribution patterns in the Shiz...The metasedimentary-volcanic series of the Wutai and Hutuo groups experienced regional metamorphism and thus turned into moderate-to low-grade metamorphic rocks.REE abundances and REE distribution patterns in the Shizui and Taihuai Subgroup metasedimentary-volcanic rocks are typical of the Archean,whereas the Gaofan Subgroup and the Hutuo Group show post-Archean REE geochemical char-acteristics.Five types of REE distribution pattern are distinguished:(1)rightward inclined smooth curves with little REE anomaly(Eu/Eu*=0.73-0.95) and heavy REE depletion (e.g.the Late Archean metasedimentary rocks);(2)rightward inclined V-shaped curves with sharp Eu anoma-ly (Eu/Eu*=0.48-0.76) and slightly higher ∑REE (e.g.the post-Archean metasedimentary rocks);(3) rightward inclined steep curves with negative Eu anomaly(Eu/Eu*=0.73-0.76) and the lowest ∑REE (e.g.the post-Archean dolomites);(4)rightward inclined,nearly smooth curves with both positive Eu anomaly and unremarkable positive Eu anomaly(Eu/Eu*=0.95-1.25)(e.g.the meta-basic volcanic rocks);and (5) rightward inclined curves with Eu anomaly(Eu/Eu*=1.09-1.19)and heavy REE depletion(e.g.the meta-acid volcanic rocks).Strata of the two groups are considered to have been formed in an island-arc belt-an instable continental petrogenetic environment.展开更多
1 Introduction Listwanite is a suite of silica-carbonate alteration products formed when CO2-bearing hydrothermal fluids meet and react with serpentinized mafic and ultramafic rocks(Robinson et al.,2005).This alterati...1 Introduction Listwanite is a suite of silica-carbonate alteration products formed when CO2-bearing hydrothermal fluids meet and react with serpentinized mafic and ultramafic rocks(Robinson et al.,2005).This alteration product is of great economic significance.Gold,mercury,magnesite and base metal deposits are often associated展开更多
Structural and petrological data suggest that the Xigaze ophiolite from the Yarlung Zangbo Suture Zone(YZSZ)in south Tibet was a typical slow-spreading ridge.A new field,geochemical,mineral,and U-Pb zircon dataset of ...Structural and petrological data suggest that the Xigaze ophiolite from the Yarlung Zangbo Suture Zone(YZSZ)in south Tibet was a typical slow-spreading ridge.A new field,geochemical,mineral,and U-Pb zircon dataset of plagiogranite intrusions were used to constrain the dynamic processes of oceanic accretion in this slow-spreading ridge.Plagiogranites mainly occur as dykes or intrusions intruded into the whole sequence of the ophiolite and have a similar orientation to the dolerite dykes developed in the late stage of detachment faulting.U-Pb zircon ages of 122–123 Ma were obtained for two types of plagiogranites and associated dolerite dykes.Detailed geochemical and mineralogical examinations suggest that the plagiogranites are the product of low-pressure(2–3 kbar)fractional crystallization of midocean ridge basalt-like magma and unlikely to have been derived from the partial melting of hydrous gabbroic rocks.The complex cross-cut relationship between the plagiogranites and ophiolite sequence reflects that they are controlled by small discontinued melt lenses rather than a big magma chamber under the ridge axis and reveals multiple injections during the oceanic crust accretion.The formation of plagiogranites possibly reflects the complex characteristic of oceanic accretion at slow-spreading ridges,time-dependent on structural(external)and magmatic(internal)processes.展开更多
The Gantaohe Group is an important early Precambrian unit in the Trans-North China Orogen,North China Craton,and is mainly composed of greenschist-facies metabasalt,meta-sandstone and dolomitic marble.We report whole-...The Gantaohe Group is an important early Precambrian unit in the Trans-North China Orogen,North China Craton,and is mainly composed of greenschist-facies metabasalt,meta-sandstone and dolomitic marble.We report whole-rock geochemical compositions and SHRIMP zircon ages as well as LA-ICP-MS Hf-in-zircon isotopeic analyses for metabasalts from the Gantaohe Group.SHRIMP dating yielded a weighted mean 207Pb/206Pb age of 2087±16 Ma(MSWD=1.3) for magmatic zircons,but there are also abundant ca.2.5 Ga inherited zircon xenocrysts.The magmatic zircons shows a large Hf(t) variation in Hf(t) from 7.17 to +0.45,suggesting an isotopically highly heterogeneous source for the metabasalt.Chemically all samples show no distinct Zr or Hf anomalies,and some samples show no Nd or Ta anomalies in a primitive mantle-normalized trace element variation diagram,and their whole-rock Nd(t) values range from 4.0 to 0.8.We suggest that the basalt is formed by partial melting of a depleted mantle source,followed by significant crustal contamination.Field observations,the presence of abundant inherited zircon,as well as isotope and trace elements geochemistry support formation of the Gantaohe Group on top of a continental basement.These data and the regional geology lead us to conclude that the Trans-North China Orogen constituted an intracontinental rift during the Paleoproterozoic that was connected to the Eastern Block since the end of the Archean.展开更多
The South China Block(SCB)is among the large-scale W-Sn mineralized regions of the globe.The Laojunshan W-Sn-dominant ore area(LOA)in the western part of the SCB preserves the records of the tectonic history of the Te...The South China Block(SCB)is among the large-scale W-Sn mineralized regions of the globe.The Laojunshan W-Sn-dominant ore area(LOA)in the western part of the SCB preserves the records of the tectonic history of the Tethys realm extending through North Vietnam,and Yangtze to Cathaysia blocks,with coeval formation of giant metallic deposits.The prolonged tectonic activities and their control on the genesis and spatio-temporal distribution of giant metallic deposits in the LOA provide a window for a holistic understanding of the tectono-metallogenesis of the SCB.In this study,we present results from a multi-chronologic study to determine the timing of formation of the cassiterite-wolframite-schee lite mineralization.The results suggest three distinct tectono-metallogenic periods in the LOA during the geodynamic evolution of the surrounding tectonic units.The opening of the Proto-Tethys Ocean between the Yangtze-Indochina blocks and the westward Paleo-Pacific subduction beneath the Cathaysia block(420–380 Ma)jointly contributed to the Silurian to early Devonian intracontinental orogeny in the middle of the SCB that involved top-to-the-north thrusting along NE-striking shear zones.This event generated the Dulong-Song Chay granitoids,together with the formation of Xinzhai Sn deposit related to sheared mylonitic granites(ca.419 Ma)and pegmatites(ca.389 Ma),which include the early-stage Sn-sulfide skarn(ca.418 Ma)and the late-stage Sn-bearing schist(ca.389 Ma).During the Late Permian to Late Triassic(260–220 Ma),with the closure of the Proto-Tethys oceans in the west and ongoing Paleo-Pacific westward subduction in the east,the SCB and Indochina Block(IB)were amalgamated which also marks the time of formation of the Nanwenhe scheelite skarn deposit.The subducted PaleoTethys oceanic crust was likely entrained by the nearby rising Emeishan mantle plume(270–259 Ma),which formed the Maguan diabase(ca.260 Ma)that shows significantly older Re-Os model age of ca.268 Ma,suggesting that the Nanwenhe mineralization is potentially derived from ca.260 Ma source.Furthermore,the intraplate shortening induced thin skinned crustal deformation and low grade metamorphism(ca.230 Ma),with the main stage of scheelite-Sn-Mo mineralization(229.9,229.8 and 219 Ma)and contemporary formation of the pegmatite(230.7 Ma).The Late Cretaceous involved two episodes of alternate extension and shortening,driven by the subduction polarity change from northwestward subduction of the Okhotomorsk block to northward subduction of the NeoTethys seafloor.The evolution of the LOA consists of the NW–SE transpression ending ca.100 Ma,the WNW–ESE extension in the earlier episode lasting from 100 Ma to 86 Ma,the WNW–ESE transpression beginning at ca.85 Ma and the NAS extension in the later episode during the latest Cretaceous,which produced the extension-related three periods of Laojunshan granitic magmatism and coeval Sn-W mineralization,with ages in the range of 90–89 Ma,87–85 Ma and 83–79 Ma.We also evaluate the implications of magmaticmetamorphic-metallogenic degassing on the regional paleoclimatic history.展开更多
The Western Kunlun Range in northern Qinghai-Tibet Plateau is composed of the North Kunlun Terrane,the South Kunlun Terrane and the Karakorum-Tianshuihai Terrane. Here we report zircon SHRIMP and LA-ICP-MS U-Pb ages o...The Western Kunlun Range in northern Qinghai-Tibet Plateau is composed of the North Kunlun Terrane,the South Kunlun Terrane and the Karakorum-Tianshuihai Terrane. Here we report zircon SHRIMP and LA-ICP-MS U-Pb ages of some metamorphic and igneous rocks and field observations in order to pro-vide a better understanding of their Precambrian and Palaeozoic-early Mesozoic tectonic evolution. Based on these data we draw the following conclusions: (1) The paragneisses in the North Kunlun Terrane are likely of late Mesoproterozoic age rather than Palaeoproterozoic age as previously thought,representing tectonothermal episodes at 1.0―0.9 Ga and ～0.8 Ga. (2) The North Kunlun Terrane was an orogenic belt accreted to the southern margin of Tarim during late Mesoproterozoic to early Neopro-terozoic,the two episodes of metamorphisms correspond to the assemblage and breakup of Rodinia respectively. (3) The Bulunkuole Group in western South Kunlun Terrane,which was considered to be the Palaeoproterozoic basement of the South Kunlun Terrane by previous studies,is now subdivided into the late Neoproterzoic to early Palaeozoic paragneisses (khondalite) and the early Mesozoic metamorphic volcano-sedimentary series; the paragneisses were thrust onto the metamorphic vol-cano-sedimentary series from south to north,with two main teconothermal episodes (i.e.,Caledonian,460―400 Ma,and Hercynian-Indosinian,340―200 Ma),and have been documented by zircon U-Pb ages. (4) In the eastern part of the South Kunlun Terrane,a gneissic granodiorite pluton,which intruded the khondalite,was crystallized at ca. 505 Ma and metamorphosed at ca. 240 Ma. In combination with geochronology data of the paragneiss,we suggest that the South Kunlun Terrane was a Caledonian accretionary orogenic belt and overprinted by late Paleozoic to early Mesozoic arc magmatism.展开更多
The Ondor Sum Group in the central Inner Mongolia is mainly composed of meta-basic volcanics intercalated with ferruginous quartzite and quartz schist,and has been interpreted as slices of oceanic crust or an ophiolit...The Ondor Sum Group in the central Inner Mongolia is mainly composed of meta-basic volcanics intercalated with ferruginous quartzite and quartz schist,and has been interpreted as slices of oceanic crust or an ophiolite suite of the Early Paleozoic or much older ages.This paper presents new LA-ICP-MS zircon U-Pb dating and geochemical data for the meta-basic volcanics.The results show that zircons in the meta-basic volcanics were derived from complicated sources,most of which may be captured by basic magma from the country rocks or other sources.They yield a large age range from the Late Archean to Early Mesozoic with the youngest age group between 246 and 261 Ma,constraining the protolith of the meta-basic volcanics formed in the Late Permian to Early Triassic.The meta-basic volcanics have an affinity to E-MORB in geochemistry,and also a similarity toward OIB,representing a tectonic setting of limited intra-continental ocean basin.This limited basin might have been related to the continuous extension of the area since the Early Permian and finally closed in the Early Mesozoic.展开更多
基金supported by the National Key R&D Program of China(2017YFC0601304)the National Basic Research Program of China(also called 973 Program)(No.2013CB429802)the National Natural Science Foundation of China(NSFC)(No.41272094)
文摘The Yangbishan iron–tungsten deposit in the Shuangyashan area of Heilongjiang Province is located in the center of the Jiamusi Massif in northeastern China. The rare earth element and trace element compositions of the scheelite show that it formed in a reducing environment and inherited the rare earth element features of the ore-forming fluid. The geochemical characteristics of the gneissic granite associated with the tungsten mineralization show that the magma formed in this reducing environment and originated from the partial melting of metamorphosed shale that contained organic carbon and was enriched with tungsten. In addition, in situ Hf isotopic analysis of zircons from the gneissic granite indicates that they probably originated from the partial melting of a predominantly Paleo–Mesoproterozoic crustal source. According to LA-ICP-MS zircon dating, the Yangbishan orerelated gneissic granite has an Early Paleozoic crystallization age of 520.6 ± 2.8 Ma. This study, together with previous data, indicates that the massifs of northeastern China, including Erguna, Xing'an, Songliao, Jiamusi, and Khanka massifs, belonged to an orogenic belt that existed along the southern margin of the Siberian Craton during the late Pan-African period. The significant continental movements of this orogeny resulted in widespread magmatic activity in northeastern China from 530 Ma to 470 Ma under a tectonic setting that transitioned from compressional syn-collision to extensional postcollision.
基金funded by a "Chinese NSF" Project (41272114) to Xingchun Zhanga "CAS Western Light Talent Culture" Project to Chengbiao Lenga "CAS Hundred Talents" Project to Jianfeng Gao
文摘The Kukaazi Pb-Zn-Cu-W polymetallic deposit, located in the Western Kunlun orogenic belt, is a newly discovered skarn-type deposit. Ore bodies mainly occur in the forms of lenses and veins along beddings of the Mesoproterozoic metamorphic rocks. Three ore blocks, KⅠ,KⅡ, and KⅢ, have been outlined in different parts of the Kukaazi deposit in terms of mineral assemblages. The KⅠ ore block is mainly composed of chalcopyrite, scheelite,pyrrhotite, sphalerite, galena and minor pyrite, arsenopyrite,and molybdenite, whereas the other two ore blocks are made up of galena, sphalerite, magnetite and minor arsenopyrite and pyrite. In this study, we obtained a molybdenite isochron Re–Os age of 450.5 ± 6.4 Ma(2σ,MSWD = 0.057) and a scheelite Sm–Nd isochron age of 426 ± 59 Ma(2σ, MSWD = 0.49) for the KⅠ ore block.They are broadly comparable to the ages of granitoid in the region. Scheelite grains from the KⅠ ore block contain high abundances of rare earth elements(REE, 42.0–95.7 ppm)and are enriched in light REE compared to heavy REE, with negative Eu anomalies(δEu = 0.13–0.55). They display similar REE patterns and Sm/Nd ratios to those of the coeval granitoids in the region. Moreover, they also have similar Sr and Nd isotopes [ ^(87)Sr/ ^(86)Sr = 0.7107–0.7118;ε_(Nd)(t) =-4.1 to-4.0] to those of such granitoids, implying that the tungsten-bearing fluids in the Kukaazi deposit probably originate from the granitic magmas. Our results first defined that the Early Paleozoic granitoids could lead to economic Mo–W–(Cu) mineralization at some favorable districts in the Western Kunlun orogenic belt and could be prospecting exploration targets.
基金financially supported by the National Natural Science Foundation of China(41502211)the China Geological Survey(1212011120701,1212011120711,12120114064201,DD20160041)the Research Fund for the Doctoral Program of Hebei GEO University(BQ2017052)
文摘In this study, plagiogranites in the Diyanmiao ophiolite of the southeastern Central Asian Orogenic Belt(Altaids) were investigated for the first time. The plagiogranites are composed predominantly of albite and quartz, and occur as irregular intrusive veins in pillow basalts. The plagiogranites have high SiO_2(74.37–76.68 wt%) and low Al_2O_3(11.99–13.30 wt%), and intensively high Na_2O(4.52–5.49 wt%) and low K_2O(0.03–0.40 wt%) resulting in high Na_2O/K_2O ratios(11.3–183). These rocks are classified as part of the low-K tholeiitic series. The plagiogranites have low total rare earth element contents(∑REE)(23.62–39.77 ppm), small negative Eu anomalies(δEu=0.44–0.62), and flat to slightly LREE-depleted chondrite-normalized REE patterns((La/Yb)N=0.68–0.76), similar to N-MORB. The plagiogranites are also characterized by Th, U, Zr, and Hf enrichment, and Nb, P, and Ti depletion, have overall flat primitivemantle-normalized trace element patterns. Field and petrological observations and geochemical data suggest that the plagiogranites in the Diyanmiao ophiolite are similar to fractionation-type plagiogranites. Furthermore, the REE patterns of the plagiogranites are similar to those of the gabbros and pillow basalts in the ophiolite. In plots of SREE–SiO_2, La–SiO_2, and Yb–SiO_2, the plagiogranites, pillow basalts, and gabbros show trends typical of crystal fractionation. As such, the plagiogranites are oceanic in origin, formed by crystal fractionation from basaltic magmas derived from depleted mantle, and are part of the Diyanmiao ophiolite. LA–ICP–MS U–Pb dating of zircons from the plagiogranites yielded ages of 328.6±2.1 and 327.1±2.1 Ma, indicating an early Carboniferous age for the Diyanmiao ophiolite. These results provide petrological and geochronological evidence for the identification of the Erenhot–Hegenshan oceanic basin and Hegenshan suture of the Paleo-Asian Ocean.
基金This work was supported by the KIP Key Project of the Chinese Academy of Sciences(KZCX3-SW-143)the KIP Key Project of the Chinese Academy of Sciences(KZCX2-SW-119)+3 种基金the Key Project of the National Natural Science Foundation of China(Grant No.40334044)the Chinese National Key Basic Research Project(2002CB4 12600)the National Natural Science Foundation of China(Grant No.49872077)the Lu Jiaxi Foundation of the Chinese Academy of Sciences.
文摘This paper reports a newly discovered Late Mesoproterozoic–Early Neoproterozoic stromatolite assemblage, named here the “Jiawengmen stromatolite assemblage”, represented by a Conophyton-Baicalia association in the Jiawenmen area in the southern belt of the Eastern Kunlun. This stromatolite assemblage is dominated by large-scale conical stromatolites and related elements, i.e., Conophyton garganicus var. inkeni, C. cf. ressoti Menchikov, Jacutophyton cf., Conicodomenia f., which commonly co-exist with elements of the group of Baicalia. This assemblage can be correlated with that of the middle Jixian-middle Qingbaikou System in North and Northwest China, but is different from that in South China. Correlation can also be made with that in the upper horizon of the Middle Riphean-lower horizon of the Upper Riphean in the South Ural Mountains and Siberia of Russia, in North Africa, and in the Alaskan Peninsula of North America. These facts suggest that the Jiawengmen stromatolite assemblage probably colonized during 1300–850 Ma ago. Accordingly, the stromatolite-bearing carbonate rocks are then proposed to correspond to the middle Jixian System-middle Qingbaikou System or the upper Middle Riphean-lower Upper Riphean. Our stromatolite data further suggest that a Precambrian microblock, named the Xialawen microblock here, occurred in the southern belt of Eastern Kunlun, the western part of the Maqên microblock. Similar stromatolite assemblages in the Maqên microblock and those blocks that occurred in North China, Siberia and North Africa point to similar paleogeographic and paleoenvironmental conditions. These microblock and blocks were probably located at low latitudes and on the continental margins of the Rodinian supercontinent, where warm epicontinental seas were favorable to widespread colonization of stromatolites during the Late Mesoproterozoic-Early Neoproterozoic. However, these stromatolite assemblages are quite different from those of the South China block, which is suggestive of different paleogeographic contexts, and probably also of a different tectonic affinity.
基金funded by the Key project of national natural science funds (40930313)Chinese Geological Survey Project Funds (12120114061801, 12120114057701 and 12120114061501)
文摘1 Geological Background This paper reports geochemistry(major and trace elements),zircon U-Pb and Lu-Hf isotope studies of leucogranite,granodiorite and clinopyroxene-bearing diorite from the Zengga intrusive body,eastern Gangdese batholith,Tibet.Massive granodiorite is mainly composed of fine-and medium-grained plagioclase(65 modal%),
文摘Described in paper is the principle of optimal partitioning method for stratigraphic division and correlation.The Nihewan Beds are taken for example to show how to apply this approach in stratigraphic division and correlation.The semiquantitative spectral analysis data on aggregate trace elements in 324 samples taken from the nine sections in the Nihewan Basin are treated with multivariate statistical method for stratigraphic division and correlation.First ,the data from all the sections are respectively calculated by the optimal partitioning method to establish the stratigraphic boundaries.The optimal partitioning method has proved itself to be applicable to stratigraphic division and correlation. In our practice the Nihewan Beds are divided into five zones (I-V).Zone I includes subzones Ia and Ib,Zones Ia,Ib,II and III are considered to be corresponding to the Pliocene(N2),the early Early Pleistocene,the late Early Pleistocene,and the Middle Pleistocene,respectively .Zones IV and V are probably Late Pleistocene in age.This indicated that sediments deposited con-temporaneous in the sections of the same basin are similar in geochemical characteristics,although dif-ferent in geographical location.However,the sediments also show some variations ,with a transitional relationship from one section to another .For example ,in Zone II,the sediments of the Xiaodukou section show not only the characteristics of the Nangou-Hongya and Hutouliang sections,but also those of the Xiashagou,Shixiaxi,Shixiadong and Wulitai sections.It can be seen from the above that the zones can be characteristically correlated with one another.In addition the feasibility of the optimal partitioning method is also described in the present paper.
文摘Matrix effect primarily impacts the accuracy and precision of zircon LA-ICP-MS U-Pb data.This paper describes three types of matrix effect in zircon LA-ICPMS U-Pb dating,i.e.,the element matrix effect,high Ddpa or uranium matrix effect and alpha dose matrix effect,and illustrates the correction of these three effects.In addition,we point out the limitation and possible problems of the existing correction methods.
文摘Four distinct lithe-tectonic belts (zones) in the Yinshan area, North China, were identified by pressure-temperature contours and litho-tectonic features, such as the Sanggan granulite belt, Jining metasedimentary belt. Wulashan-Daqingshan front tectonic zone and Se’ eratengshan belt. This area witnessed two important thermo-tectonic events. The older one is c. 2.5 Ga while the younger one c. 1.9 Ga. The Se’ ertengshan Neoarchaean terrane features a clockwise PT path with the decompression ranging from 】 1500 MPa to 800-1000 MPa in the Se’ ertengshan belt, which implies an island arc setting. The Sanggan belt is a Mesoarchaean microcontinent reworked by Neoarchaean magma underplating, which shows an counterclockwise PT path. During the Palaeoproterozoic period, two Archaean continent (arc) collided. The Archaean basement of the Sanggan and Wulashan-Daqingshan belts overthrust northwards, the PTt paths of basement show a decompression from 1000-1200 MPa to 500-700 MPa. The PT paths of the Jining and
文摘The Yarlung Zongbo Suture Zone(YZSZ)is thought to be the most important geological boundary,the collision between the India plate and the Eurasia happened since Cretaceous-Tertiary(Aitchison et al.,2011).The YZSZ,bordered to the north by the Lhasa Block and to the south by the Tethyan sedimentary sequence and the
基金financially supported by the China Geological Survey Program(Grant Nos.1212011121260,1212011220928)the National Natural Science Foundation of China(Project No.491755206)。
文摘The Gejiu-Bozushan-Laojunshan W-Sn polymetallic metallogenic belt(GBLB)in southeast Yunnan Province is an important part of the southwestern Yangtze Block in South China.Tin polymetallic mineralization in this belt includes the Niusipo,Malage,Songshujiao,Laochang and Kafang ore fields in the Gejiu area which are spatially and temporally associated with the Kafang-Laochang and Songshujiao granite plutons.These granites are characterized by variable A/CNK values(mostly>1.1,except for two samples with 1.09),high contents of SiO2(74.38-76.84 wt.%)and Al2 O3(12.46-14.05 wt.%)and variable CaO/Na2 O ratios(0.2-0.65)as well as high zirconδ18O values(7.74‰-9.86‰),indicative of S-type affinities.These rocks are depleted in Rb,Th,U,Ti,LREE[(La/Yb)N=1.4-20.51],Ba,Nb,Sr,and Ti and display strong negative Eu and Ba anomalies.The rocks possess high Rb/Sr and Rb/Ba ratios,relatively low initial 87Sr/86Sr ratios(0.6917-0.7101),and less radiogenicεNd(t)values(-8.0 to-9.1).The zircon grains from these rocks show negativeεHf(t)values in the range of-3.7 to-9.9 with mean TDM2(Nd)and TDM2(Hf)values of 1.57 Ga and 1.55 Ga.They show initial 207Pb/204Pb ranging from15.69 to 15.71 and 206Pb/204Pb from 18.36 to 18.70.Monazite from Songshujiao granites exhibits higher U and lower Th/U ratios,lowerδ18O values and higherεHf(t)values than those of the zircon grains in the KafangLaochang granites.The geochemical and isotopic features indicate that the Laochang-Kafang granites originated by partial melting of Mesoproterozoic crustal components including biotite-rich metapelite and metagraywacke,whereas the Songshujiao granites were derived from Mesoproterozoic muscovite-rich metapelite crustal source.Most zircon grains from the Songshujiao,Laochang and Kafang granites have high-U concentrations and their SIMS U-Pb ages show age scatter from 81.6 Ma to 88.6 Ma,80.7 Ma to 86.1 Ma and 82.3 Ma to 87.0 Ma,suggesting formation earlier than the monazite and cassiterite.Monazite SIMS U-Pb ages and Th-Pb ages of three same granite samples are consistent and show yielded 206 Pb/238U ages of 83.7±0.6 Ma,83.7±0.6 Ma,and 83.4±0.6 Ma,and 208Pb/232Th ages of 83.2±0.5 Ma,83.8±0.4 Ma,and 83.5±0.9 Ma,which are within the range of the SIMS zircon U-Pb ages from these rocks.The data constrain the crystallization of the granites at ca.83 Ma.In situ U-Pb dating of two cassiterite samples from the cassiterite-sulfide ore in the Songshujiao ore field and Kafang ore field,and two from the cassiterite-oxide+cassiterite bearing dolomite in the Laochang ore field yielded weighted mean 206 Pb/238U ages of 83.5±0.4 Ma(MSWD=0.6),83.5±0.4 Ma(MSWD=0.5),83.6±0.4 Ma(MSWD=0.6)and 83.2±0.7 Ma(MSWD=0.6),respectively.Combined with geological characteristics,the new geochronological data indicate that the formation of the granites and Sn polymetallic deposits are coeval.We correlate the magmatic and metallogenic event with lithospheric thinning and asthenosphere upwelling in continental extension setting in relation to the eastward subduction of the Neo-Tethys beneath the Sanjiang tectonic domain during Late Cretaceous.
文摘Glauconite is widely distributed in space and time.In China glauconite-bearing strata are extensive occurrence ranging from Late Cretaceous to Middle Proterozoic in age.X-ray powder analysis,X-ray diffracition analysis and differential thermal analysis revealed that glauconite has a mica-type structure between dioctahedron and trioctahedron.Its chemical composition is:Al2O310.6%,SiO249.23%,MgO3.24%,Fe2O317.40%,FeO1.8%,and K2O7.92%,Its crystal form and thermal properties are very similar to those of mica-like clay minerls.According to isotopic age determinations of glauconite in modern oceans (including the East China Sea,the South China Sea and the Yellow Sea),we consider that in the extreme case glauconite is an authigenic mineral.It is generally formed in sedimentary rocks.Is has further proved that glauconite can be used to determine the ages of sedimentary rocks.
文摘The metasedimentary-volcanic series of the Wutai and Hutuo groups experienced regional metamorphism and thus turned into moderate-to low-grade metamorphic rocks.REE abundances and REE distribution patterns in the Shizui and Taihuai Subgroup metasedimentary-volcanic rocks are typical of the Archean,whereas the Gaofan Subgroup and the Hutuo Group show post-Archean REE geochemical char-acteristics.Five types of REE distribution pattern are distinguished:(1)rightward inclined smooth curves with little REE anomaly(Eu/Eu*=0.73-0.95) and heavy REE depletion (e.g.the Late Archean metasedimentary rocks);(2)rightward inclined V-shaped curves with sharp Eu anoma-ly (Eu/Eu*=0.48-0.76) and slightly higher ∑REE (e.g.the post-Archean metasedimentary rocks);(3) rightward inclined steep curves with negative Eu anomaly(Eu/Eu*=0.73-0.76) and the lowest ∑REE (e.g.the post-Archean dolomites);(4)rightward inclined,nearly smooth curves with both positive Eu anomaly and unremarkable positive Eu anomaly(Eu/Eu*=0.95-1.25)(e.g.the meta-basic volcanic rocks);and (5) rightward inclined curves with Eu anomaly(Eu/Eu*=1.09-1.19)and heavy REE depletion(e.g.the meta-acid volcanic rocks).Strata of the two groups are considered to have been formed in an island-arc belt-an instable continental petrogenetic environment.
基金funded by the Key project of national natural science funds (40930313)Chinese Geological Survey Project Funds (12120114061801, 12120114057701 and 12120114061501)
文摘1 Introduction Listwanite is a suite of silica-carbonate alteration products formed when CO2-bearing hydrothermal fluids meet and react with serpentinized mafic and ultramafic rocks(Robinson et al.,2005).This alteration product is of great economic significance.Gold,mercury,magnesite and base metal deposits are often associated
基金supported by grants from the National Natural Science Foundation of China(Grant Nos.41720104009 and 41772231)the China Geological Survey Project(Grant No.DD20190060).
文摘Structural and petrological data suggest that the Xigaze ophiolite from the Yarlung Zangbo Suture Zone(YZSZ)in south Tibet was a typical slow-spreading ridge.A new field,geochemical,mineral,and U-Pb zircon dataset of plagiogranite intrusions were used to constrain the dynamic processes of oceanic accretion in this slow-spreading ridge.Plagiogranites mainly occur as dykes or intrusions intruded into the whole sequence of the ophiolite and have a similar orientation to the dolerite dykes developed in the late stage of detachment faulting.U-Pb zircon ages of 122–123 Ma were obtained for two types of plagiogranites and associated dolerite dykes.Detailed geochemical and mineralogical examinations suggest that the plagiogranites are the product of low-pressure(2–3 kbar)fractional crystallization of midocean ridge basalt-like magma and unlikely to have been derived from the partial melting of hydrous gabbroic rocks.The complex cross-cut relationship between the plagiogranites and ophiolite sequence reflects that they are controlled by small discontinued melt lenses rather than a big magma chamber under the ridge axis and reveals multiple injections during the oceanic crust accretion.The formation of plagiogranites possibly reflects the complex characteristic of oceanic accretion at slow-spreading ridges,time-dependent on structural(external)and magmatic(internal)processes.
基金supported by the China Geological Survey(1212010811033)the National Basic Research Program of China(2012CB416601)
文摘The Gantaohe Group is an important early Precambrian unit in the Trans-North China Orogen,North China Craton,and is mainly composed of greenschist-facies metabasalt,meta-sandstone and dolomitic marble.We report whole-rock geochemical compositions and SHRIMP zircon ages as well as LA-ICP-MS Hf-in-zircon isotopeic analyses for metabasalts from the Gantaohe Group.SHRIMP dating yielded a weighted mean 207Pb/206Pb age of 2087±16 Ma(MSWD=1.3) for magmatic zircons,but there are also abundant ca.2.5 Ga inherited zircon xenocrysts.The magmatic zircons shows a large Hf(t) variation in Hf(t) from 7.17 to +0.45,suggesting an isotopically highly heterogeneous source for the metabasalt.Chemically all samples show no distinct Zr or Hf anomalies,and some samples show no Nd or Ta anomalies in a primitive mantle-normalized trace element variation diagram,and their whole-rock Nd(t) values range from 4.0 to 0.8.We suggest that the basalt is formed by partial melting of a depleted mantle source,followed by significant crustal contamination.Field observations,the presence of abundant inherited zircon,as well as isotope and trace elements geochemistry support formation of the Gantaohe Group on top of a continental basement.These data and the regional geology lead us to conclude that the Trans-North China Orogen constituted an intracontinental rift during the Paleoproterozoic that was connected to the Eastern Block since the end of the Archean.
基金supported by the China Geological Survey Program(Grant Nos.1212011121260,1212011220928)the National Natural Science Foundation of China(Gant No.91755206)。
文摘The South China Block(SCB)is among the large-scale W-Sn mineralized regions of the globe.The Laojunshan W-Sn-dominant ore area(LOA)in the western part of the SCB preserves the records of the tectonic history of the Tethys realm extending through North Vietnam,and Yangtze to Cathaysia blocks,with coeval formation of giant metallic deposits.The prolonged tectonic activities and their control on the genesis and spatio-temporal distribution of giant metallic deposits in the LOA provide a window for a holistic understanding of the tectono-metallogenesis of the SCB.In this study,we present results from a multi-chronologic study to determine the timing of formation of the cassiterite-wolframite-schee lite mineralization.The results suggest three distinct tectono-metallogenic periods in the LOA during the geodynamic evolution of the surrounding tectonic units.The opening of the Proto-Tethys Ocean between the Yangtze-Indochina blocks and the westward Paleo-Pacific subduction beneath the Cathaysia block(420–380 Ma)jointly contributed to the Silurian to early Devonian intracontinental orogeny in the middle of the SCB that involved top-to-the-north thrusting along NE-striking shear zones.This event generated the Dulong-Song Chay granitoids,together with the formation of Xinzhai Sn deposit related to sheared mylonitic granites(ca.419 Ma)and pegmatites(ca.389 Ma),which include the early-stage Sn-sulfide skarn(ca.418 Ma)and the late-stage Sn-bearing schist(ca.389 Ma).During the Late Permian to Late Triassic(260–220 Ma),with the closure of the Proto-Tethys oceans in the west and ongoing Paleo-Pacific westward subduction in the east,the SCB and Indochina Block(IB)were amalgamated which also marks the time of formation of the Nanwenhe scheelite skarn deposit.The subducted PaleoTethys oceanic crust was likely entrained by the nearby rising Emeishan mantle plume(270–259 Ma),which formed the Maguan diabase(ca.260 Ma)that shows significantly older Re-Os model age of ca.268 Ma,suggesting that the Nanwenhe mineralization is potentially derived from ca.260 Ma source.Furthermore,the intraplate shortening induced thin skinned crustal deformation and low grade metamorphism(ca.230 Ma),with the main stage of scheelite-Sn-Mo mineralization(229.9,229.8 and 219 Ma)and contemporary formation of the pegmatite(230.7 Ma).The Late Cretaceous involved two episodes of alternate extension and shortening,driven by the subduction polarity change from northwestward subduction of the Okhotomorsk block to northward subduction of the NeoTethys seafloor.The evolution of the LOA consists of the NW–SE transpression ending ca.100 Ma,the WNW–ESE extension in the earlier episode lasting from 100 Ma to 86 Ma,the WNW–ESE transpression beginning at ca.85 Ma and the NAS extension in the later episode during the latest Cretaceous,which produced the extension-related three periods of Laojunshan granitic magmatism and coeval Sn-W mineralization,with ages in the range of 90–89 Ma,87–85 Ma and 83–79 Ma.We also evaluate the implications of magmaticmetamorphic-metallogenic degassing on the regional paleoclimatic history.
基金the National Natural Science Foundation of China (Grant Nos40303007 and 40421303)Chinese Geology Survey (Grant No. 200113900070)
文摘The Western Kunlun Range in northern Qinghai-Tibet Plateau is composed of the North Kunlun Terrane,the South Kunlun Terrane and the Karakorum-Tianshuihai Terrane. Here we report zircon SHRIMP and LA-ICP-MS U-Pb ages of some metamorphic and igneous rocks and field observations in order to pro-vide a better understanding of their Precambrian and Palaeozoic-early Mesozoic tectonic evolution. Based on these data we draw the following conclusions: (1) The paragneisses in the North Kunlun Terrane are likely of late Mesoproterozoic age rather than Palaeoproterozoic age as previously thought,representing tectonothermal episodes at 1.0―0.9 Ga and ～0.8 Ga. (2) The North Kunlun Terrane was an orogenic belt accreted to the southern margin of Tarim during late Mesoproterozoic to early Neopro-terozoic,the two episodes of metamorphisms correspond to the assemblage and breakup of Rodinia respectively. (3) The Bulunkuole Group in western South Kunlun Terrane,which was considered to be the Palaeoproterozoic basement of the South Kunlun Terrane by previous studies,is now subdivided into the late Neoproterzoic to early Palaeozoic paragneisses (khondalite) and the early Mesozoic metamorphic volcano-sedimentary series; the paragneisses were thrust onto the metamorphic vol-cano-sedimentary series from south to north,with two main teconothermal episodes (i.e.,Caledonian,460―400 Ma,and Hercynian-Indosinian,340―200 Ma),and have been documented by zircon U-Pb ages. (4) In the eastern part of the South Kunlun Terrane,a gneissic granodiorite pluton,which intruded the khondalite,was crystallized at ca. 505 Ma and metamorphosed at ca. 240 Ma. In combination with geochronology data of the paragneiss,we suggest that the South Kunlun Terrane was a Caledonian accretionary orogenic belt and overprinted by late Paleozoic to early Mesozoic arc magmatism.
基金supported by the National Natural Science Foundation of China(40902021)the National Basic Research Program of China(2013CB429801)the China Survey of Geology(1212010911005)
文摘The Ondor Sum Group in the central Inner Mongolia is mainly composed of meta-basic volcanics intercalated with ferruginous quartzite and quartz schist,and has been interpreted as slices of oceanic crust or an ophiolite suite of the Early Paleozoic or much older ages.This paper presents new LA-ICP-MS zircon U-Pb dating and geochemical data for the meta-basic volcanics.The results show that zircons in the meta-basic volcanics were derived from complicated sources,most of which may be captured by basic magma from the country rocks or other sources.They yield a large age range from the Late Archean to Early Mesozoic with the youngest age group between 246 and 261 Ma,constraining the protolith of the meta-basic volcanics formed in the Late Permian to Early Triassic.The meta-basic volcanics have an affinity to E-MORB in geochemistry,and also a similarity toward OIB,representing a tectonic setting of limited intra-continental ocean basin.This limited basin might have been related to the continuous extension of the area since the Early Permian and finally closed in the Early Mesozoic.
基金supported by the Ministry of Land and Re-sources of the Peoples’ Republic of China (Grant Nos. 1212010811033, 1212010711815) and the Beijing SHRIMP Center
