As an important river in the western part of Jilin Province,the lower reach of the Nenjiang River is an important wetland water source conservation area in Jilin Province.Within the watershed,it governs the Momoge Wet...As an important river in the western part of Jilin Province,the lower reach of the Nenjiang River is an important wetland water source conservation area in Jilin Province.Within the watershed,it governs the Momoge Wetland,the Xianghai Wetland,and the Danjiang Wetland in Jilin Province.The main problem in the lower reaches of the Nenjiang River is the uneven distribution of water resources in time and space,and the intensification of land salinization.Zhenlai County and Da an City in the Nenjiang River Basin have sufficient surface water resources,with surface water as the drinking water source.Baicheng City and Tongyu County have scarce surface water resources,and both use groundwater as their domestic water source.The main polluted section in the basin is the Xianghai Reservoir,and the annual water quality evaluation is Class V.However,the water quality of the Tao er River,the main stream of the Nenjiang River,is significantly better than that of the Xianghai Reservoir.In order to better study the water environmental pollution situation in the Nenjiang River basin,monitoring data from five sections of non seasonal rivers in the basin from 2012 to 2021 were selected for studying water quality.This in-depth exploration of the water pollution status and river water quality change trends in the Nenjiang River basin is of great significance for future rural development,agricultural pattern transformation,and the promotion of water ecological civilization construction.展开更多
As an important river in the central part of Jilin Province, the Yinma River plays a crucial role in the daily lives of the people in Jilin Province. In this paper, 15 cross sections were selected in the Yinma River b...As an important river in the central part of Jilin Province, the Yinma River plays a crucial role in the daily lives of the people in Jilin Province. In this paper, 15 cross sections were selected in the Yinma River basin. Based on the water quality monitoring data from 2012 to 2021, referring to the Environmental Quality Standards for Surface Water (GB 3838-2002) and historical monitoring data of the river, dissolved oxygen (DO), five-day biochemical oxygen demand (BOD 5), permanganate index (COD Mn ), chemical oxygen demand (COD), ammonia nitrogen (NH 4-N), total phosphorus (TP), and total nitrogen (TN) were determined as 7 evaluation indicators, and the water quality of 15 cross sections in the Yinma River basin was comprehensively evaluated. A characteristic analysis was conducted on the water quality of the Yinma River, and its pollution sources were identified. Based on the conclusions, constructive control measures were proposed.展开更多
Niligou Reservoir,a typical reservoir in the eastern region of Jilin Province,is subordinate to Niligou River,which is located in the Changbai Mountains in eastern Jilin,with abundant plant and animal resources and we...Niligou Reservoir,a typical reservoir in the eastern region of Jilin Province,is subordinate to Niligou River,which is located in the Changbai Mountains in eastern Jilin,with abundant plant and animal resources and well protected biodiversity in the basin,but there are also some related problems such as fragile ecosystem of forest wetland.This paper carried out a health assessment of Niligou River,including water quality monitoring,aquatic organism monitoring,and riparian zone investigation.According to the requirements of the Technical Guidelines for River and Lake Health Assessment,13 assessment indexes were selected to build a river and lake health assessment index system.By sorting and analyzing the monitoring and investigation data,we got a clear picture of the ecological environment status and existing problems of Niligou Res-ervoir.Based on the actual situation of Niligou River,we evaluated the hydrologic integrity,chemical integrity,morphological and structural integrity,biological integrity and sustainability of social service function,and put forward corresponding countermeasures according to the re-sults,in order to provide a technical support for the health treatment of rivers and lakes in Jilin Province.展开更多
Floodplains are important and distinctive ecosystems around the world,and the recruitment of ichthyoplankton from river to floodplain lakes is crucial to maintain this unique ecosystem.However,this process has not bee...Floodplains are important and distinctive ecosystems around the world,and the recruitment of ichthyoplankton from river to floodplain lakes is crucial to maintain this unique ecosystem.However,this process has not been well documented.In this study,ichthyoplankton were sampled to investigate the details of ichthyoplankton recruitment from the Changjiang(Yangtze)River to the Dongting Lake via a floodway channel,the Songzi River,from May to July in 2013 and 2014.During the study period,41 species of eggs and larvae were sampled.Among the samples,16 were river-lake migratory species(RL),representing 23.5%of the species in the Dongting Lake.In 2013,an estimated 130 million eggs and 3180 million larvae drifted through the sampling section,and in 2014,an estimated 1 060 million eggs and 1040 million larvae drifted through the sampling section.The amount of eggs and larvae of RL reached 3 210 million in 2013 and 1 850 million in 2014,respectively.These results demonstrated the importance of ichthyoplankton recruitment from the river to the lake,as species diversity will decrease sharply without this recruitment.Canonical correspondence analysis(CCA)showed that water temperature and water flow are the two most important factors influencing the spawning activities of fish.To maintain the high fish diversity in the Changjiang floodplain,we suggest to irrigate the channel to increase water discharge and increase the transport of ichthyoplankton from the Changjiang mainstream into the Dongting Lake.展开更多
Benthos are aquatic organisms living at the bottom of water bodies for all or most of their life history.Apart from the settled and moving living,their forms of habitat are mostly attached to the hard substrate like r...Benthos are aquatic organisms living at the bottom of water bodies for all or most of their life history.Apart from the settled and moving living,their forms of habitat are mostly attached to the hard substrate like rocks or soft bases such as mud and sand.In addition,there are benthic species that attach to the plant surfaces or other benthic animals,and inhabit the intertidal zone.In terms of feeding methods,most benthic animals feed on suspended matter and sediment.Most of them are invertebrates and are a complex ecological group.According to the size,they can be divided into macrobenthos and meio-benthos[1].Benthos are an important part of the water ecosystem.Using a typical river(Gaya River)in eastern Jilin Province,this paper analyzed the water quality,the components of benthic organisms and their biological density through sampling surveys of three typical locations in the upper,middle and lower reaches of the Gaya River.In addition,it made a biological evaluation of the water quality of the Gaya River.展开更多
In order to comprehensively understand the water quality in Yinma River Basin,and to analyze the spatial-temporal variation characteristics of water quality over the years and the causes of water pollution,15 sections...In order to comprehensively understand the water quality in Yinma River Basin,and to analyze the spatial-temporal variation characteristics of water quality over the years and the causes of water pollution,15 sections were selected in the Yinma River Basin.Based on the water quality monitoring data in the past decade,7 evaluation indexes including dissolved oxygen(DO),5-day biochemical oxygen demand(BOD_(5)),permanganate index(COD_(MN)),chemical oxygen demand(COD),ammonia nitrogen(NH_(4)-N),total phosphorus(TP)and total nitrogen(TN)were determined,according to the Environmental Quality Standard for Surface Water(GB3838-2002)and the historical monitoring data of rivers.The water quality of 15 sections in Yinma River Basin was comprehensively evaluated,and the water quality categories and the evolution of river water quality were analyzed.The pollution sources of Yinma River Basin were analyzed,and the constructive countermeasures were put forward according to the conclusions.展开更多
Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,...Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,euhedral gypsums were observed in the boundary clay.The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column.The result indicates that it was probably lower dysoxia condition in the temporal ocean.Moreover,the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition,which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before.In addition,sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition.Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However,the redox condition in temporal ocean was probably not stable,with short-term fluctuations.展开更多
Lake Dianchi has undergone accelerated alternations resulting from human activities during the last 50 years, and provides an exceptional example for the study of regime shift in a shallow lake. Focusing on regime shi...Lake Dianchi has undergone accelerated alternations resulting from human activities during the last 50 years, and provides an exceptional example for the study of regime shift in a shallow lake. Focusing on regime shift, we systematically studied and analysed alternations of key components of its ecosystem, including water parameters, phytoplankton and zooplankton biomass, macrophyte composition and fish populations. We found that the shifting course of Lake Dianchi went through three major phases, corresponding to three distinct states: Phase I clean, stable state during the 1950 s; Phase II transitional state during the 1970 s–1980 s; and phase III stable, turbid state since 1993. We analysed all data and samples, identifying the threshold concentrations at which regime shift occurred: total nitrogen(TN) and phosphorus(TP) reaching 1.2 mg/L and 0.13 mg/L, respectively. Results from this study strongly suggest that the increasing input of external nutrients, reclaiming land from the lake and foreign fish invasion were major inducements to the accelerated shift of Lake Dianchi to its turbid, stable state. These findings provide valuable guidelines for potential efforts to reverse this unnatural process in Lake Dianchi. The restoration may need to:(1) thoroughly and accurately identify pollution sources to control and reduce excessive external nutrients flowing into the lake;(2) return reclaimed land to the lake and recover the littoral zone to its natural state to facilitate increased restoration of macrophytes; and(3) strategically adjust fish populations by reducing benthivorous and filter-feeding fish populations that prey on zooplankton, while enlarging zooplankton populations to control phytoplankton biomass.展开更多
Higher fullerenes(C84,C90,C92,C94 and C96) were successfully isolated from the Soxhlet extract of the synthetical "Graphote Smokes" soot(GS sample) by using a big Cosmosil Buckysep(Phenomenex) column(250 mm ...Higher fullerenes(C84,C90,C92,C94 and C96) were successfully isolated from the Soxhlet extract of the synthetical "Graphote Smokes" soot(GS sample) by using a big Cosmosil Buckysep(Phenomenex) column(250 mm × 10 mm) with a large injection.The fractions isolated have been determined by high performance liquid chro-matography(HPLC) and laser desorption mass spectrometry(LDMS).It is found that there are different fullerenes molecules in different fractions with retention time.The result indicates that fullerenes do exist in GS samples.Also,it excludes the suspicion to some extent that fullerene molecules might be generated by the laser desorption process in the LDMS.In addition,it also provides the experimental basis for the study of natural higher fullerenes and might be helpful to figure out the question if higher fullerenes do exist in the natural samples.展开更多
Changes in wetland ecosystems have a critical impact on the local ecology and species diversity.Different development scenarios and policies are key factors influencing their changes.Therefore,we studied changes of we...Changes in wetland ecosystems have a critical impact on the local ecology and species diversity.Different development scenarios and policies are key factors influencing their changes.Therefore,we studied changes of wetlands in the middle Yangtze River basin(MYRB)in 2001-2020,and a patch-generated land use simulation(PLUS)model and random forest(RF)method were applied to predict and analyze the changes under different scenarios in the MYRB in the future(i.e.2035-2095).The results indicated that:(1)The regions with high wetland proportions were concentrated in the central and eastern MYRB in 2001-2020,with a 1.5%decrease in overall wetland area;(2)The RF could simulate the future ecological quality with training and testing accuracies of 0.98 and 0.92,respectively;(3)Remote Sensing Ecological Index(RSEI)less than 0.5 in the central and eastern regions and 13.3%reduction in the northwest in the SSP245 scenario.In general,the study provides a basis for future regional studies of ecosystem quality and provides data to support wetland conservation and management.展开更多
PAHPN. a naphthalimide-based mitotracker with reasonable two-photon excitation emission activity and polarity-sensitive fluorescence properties has been efficiently synthesized and studied in twophoton, co-localizatio...PAHPN. a naphthalimide-based mitotracker with reasonable two-photon excitation emission activity and polarity-sensitive fluorescence properties has been efficiently synthesized and studied in twophoton, co-localization, and FLIM imaging.展开更多
Tri(2-chloroethyl) phosphate(TCEP) with the initial concentration of 5 mg/L was degraded by UV/H2O2 oxidation process. The removal rate of TCEP in the UV/H2O2 system was 89.1% with the production of Cl-and PO4^3- of 0...Tri(2-chloroethyl) phosphate(TCEP) with the initial concentration of 5 mg/L was degraded by UV/H2O2 oxidation process. The removal rate of TCEP in the UV/H2O2 system was 89.1% with the production of Cl-and PO4^3- of 0.23 and 0.64 mg/L. The removal rate of total organic carbon of the reaction was 48.8% and the pH reached 3.3 after the reaction. The oxidative degradation process of TCEP in the UV/H2O2 system obeyed the first order kinetic reaction with the apparent rate constant of 0.0025 min^-1( R^2 = 0.9788). The intermediate products were isolated and identified by gas chromatography-mass spectrometer. The addition reaction of HO · and H2O and the oxidation reaction with H2O2 were found during the degradation pathway of 5 mg/L TCEP in the UV/H2O2 system. For the first time, environment risk was estimated via the "ecological structure activity relationships" program and acute and chronic toxicity changes of intermediate products were pointed out. The luminescence inhibition rate of photobacterium was used to evaluate the acute toxicity of intermediate products. The results showed that the toxicity of the intermediate products increased with the increase of reaction time, which may be due to the production of chlorine compounds. Some measures should be introduced to the UV/H2O2 system to remove the highly toxic Cl-containing compounds, such as a nanofiltration or reverse osmosis unit.展开更多
文摘As an important river in the western part of Jilin Province,the lower reach of the Nenjiang River is an important wetland water source conservation area in Jilin Province.Within the watershed,it governs the Momoge Wetland,the Xianghai Wetland,and the Danjiang Wetland in Jilin Province.The main problem in the lower reaches of the Nenjiang River is the uneven distribution of water resources in time and space,and the intensification of land salinization.Zhenlai County and Da an City in the Nenjiang River Basin have sufficient surface water resources,with surface water as the drinking water source.Baicheng City and Tongyu County have scarce surface water resources,and both use groundwater as their domestic water source.The main polluted section in the basin is the Xianghai Reservoir,and the annual water quality evaluation is Class V.However,the water quality of the Tao er River,the main stream of the Nenjiang River,is significantly better than that of the Xianghai Reservoir.In order to better study the water environmental pollution situation in the Nenjiang River basin,monitoring data from five sections of non seasonal rivers in the basin from 2012 to 2021 were selected for studying water quality.This in-depth exploration of the water pollution status and river water quality change trends in the Nenjiang River basin is of great significance for future rural development,agricultural pattern transformation,and the promotion of water ecological civilization construction.
文摘As an important river in the central part of Jilin Province, the Yinma River plays a crucial role in the daily lives of the people in Jilin Province. In this paper, 15 cross sections were selected in the Yinma River basin. Based on the water quality monitoring data from 2012 to 2021, referring to the Environmental Quality Standards for Surface Water (GB 3838-2002) and historical monitoring data of the river, dissolved oxygen (DO), five-day biochemical oxygen demand (BOD 5), permanganate index (COD Mn ), chemical oxygen demand (COD), ammonia nitrogen (NH 4-N), total phosphorus (TP), and total nitrogen (TN) were determined as 7 evaluation indicators, and the water quality of 15 cross sections in the Yinma River basin was comprehensively evaluated. A characteristic analysis was conducted on the water quality of the Yinma River, and its pollution sources were identified. Based on the conclusions, constructive control measures were proposed.
文摘Niligou Reservoir,a typical reservoir in the eastern region of Jilin Province,is subordinate to Niligou River,which is located in the Changbai Mountains in eastern Jilin,with abundant plant and animal resources and well protected biodiversity in the basin,but there are also some related problems such as fragile ecosystem of forest wetland.This paper carried out a health assessment of Niligou River,including water quality monitoring,aquatic organism monitoring,and riparian zone investigation.According to the requirements of the Technical Guidelines for River and Lake Health Assessment,13 assessment indexes were selected to build a river and lake health assessment index system.By sorting and analyzing the monitoring and investigation data,we got a clear picture of the ecological environment status and existing problems of Niligou Res-ervoir.Based on the actual situation of Niligou River,we evaluated the hydrologic integrity,chemical integrity,morphological and structural integrity,biological integrity and sustainability of social service function,and put forward corresponding countermeasures according to the re-sults,in order to provide a technical support for the health treatment of rivers and lakes in Jilin Province.
基金Supported by the National Key Research and Development Program of China(No.2016YFC0402005)the Three Gorges Project EcoEnvironmental Monitoring System(No.JJ [2017]-011)+1 种基金the National Natural Science Foundation of China(No.NSFC31400359)the China Three Gorges Corporation(No.0704097)
文摘Floodplains are important and distinctive ecosystems around the world,and the recruitment of ichthyoplankton from river to floodplain lakes is crucial to maintain this unique ecosystem.However,this process has not been well documented.In this study,ichthyoplankton were sampled to investigate the details of ichthyoplankton recruitment from the Changjiang(Yangtze)River to the Dongting Lake via a floodway channel,the Songzi River,from May to July in 2013 and 2014.During the study period,41 species of eggs and larvae were sampled.Among the samples,16 were river-lake migratory species(RL),representing 23.5%of the species in the Dongting Lake.In 2013,an estimated 130 million eggs and 3180 million larvae drifted through the sampling section,and in 2014,an estimated 1 060 million eggs and 1040 million larvae drifted through the sampling section.The amount of eggs and larvae of RL reached 3 210 million in 2013 and 1 850 million in 2014,respectively.These results demonstrated the importance of ichthyoplankton recruitment from the river to the lake,as species diversity will decrease sharply without this recruitment.Canonical correspondence analysis(CCA)showed that water temperature and water flow are the two most important factors influencing the spawning activities of fish.To maintain the high fish diversity in the Changjiang floodplain,we suggest to irrigate the channel to increase water discharge and increase the transport of ichthyoplankton from the Changjiang mainstream into the Dongting Lake.
文摘Benthos are aquatic organisms living at the bottom of water bodies for all or most of their life history.Apart from the settled and moving living,their forms of habitat are mostly attached to the hard substrate like rocks or soft bases such as mud and sand.In addition,there are benthic species that attach to the plant surfaces or other benthic animals,and inhabit the intertidal zone.In terms of feeding methods,most benthic animals feed on suspended matter and sediment.Most of them are invertebrates and are a complex ecological group.According to the size,they can be divided into macrobenthos and meio-benthos[1].Benthos are an important part of the water ecosystem.Using a typical river(Gaya River)in eastern Jilin Province,this paper analyzed the water quality,the components of benthic organisms and their biological density through sampling surveys of three typical locations in the upper,middle and lower reaches of the Gaya River.In addition,it made a biological evaluation of the water quality of the Gaya River.
文摘In order to comprehensively understand the water quality in Yinma River Basin,and to analyze the spatial-temporal variation characteristics of water quality over the years and the causes of water pollution,15 sections were selected in the Yinma River Basin.Based on the water quality monitoring data in the past decade,7 evaluation indexes including dissolved oxygen(DO),5-day biochemical oxygen demand(BOD_(5)),permanganate index(COD_(MN)),chemical oxygen demand(COD),ammonia nitrogen(NH_(4)-N),total phosphorus(TP)and total nitrogen(TN)were determined,according to the Environmental Quality Standard for Surface Water(GB3838-2002)and the historical monitoring data of rivers.The water quality of 15 sections in Yinma River Basin was comprehensively evaluated,and the water quality categories and the evolution of river water quality were analyzed.The pollution sources of Yinma River Basin were analyzed,and the constructive countermeasures were put forward according to the conclusions.
基金supported by China Scholarship Council,National Natural Science Foundation of China(No40572020)Doctoral Program of Higher Education(No20040290005)
文摘Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,euhedral gypsums were observed in the boundary clay.The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column.The result indicates that it was probably lower dysoxia condition in the temporal ocean.Moreover,the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition,which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before.In addition,sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition.Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However,the redox condition in temporal ocean was probably not stable,with short-term fluctuations.
基金Supported by the National Key Technology R&D Program of China(No.2011BAC12B01)
文摘Lake Dianchi has undergone accelerated alternations resulting from human activities during the last 50 years, and provides an exceptional example for the study of regime shift in a shallow lake. Focusing on regime shift, we systematically studied and analysed alternations of key components of its ecosystem, including water parameters, phytoplankton and zooplankton biomass, macrophyte composition and fish populations. We found that the shifting course of Lake Dianchi went through three major phases, corresponding to three distinct states: Phase I clean, stable state during the 1950 s; Phase II transitional state during the 1970 s–1980 s; and phase III stable, turbid state since 1993. We analysed all data and samples, identifying the threshold concentrations at which regime shift occurred: total nitrogen(TN) and phosphorus(TP) reaching 1.2 mg/L and 0.13 mg/L, respectively. Results from this study strongly suggest that the increasing input of external nutrients, reclaiming land from the lake and foreign fish invasion were major inducements to the accelerated shift of Lake Dianchi to its turbid, stable state. These findings provide valuable guidelines for potential efforts to reverse this unnatural process in Lake Dianchi. The restoration may need to:(1) thoroughly and accurately identify pollution sources to control and reduce excessive external nutrients flowing into the lake;(2) return reclaimed land to the lake and recover the littoral zone to its natural state to facilitate increased restoration of macrophytes; and(3) strategically adjust fish populations by reducing benthivorous and filter-feeding fish populations that prey on zooplankton, while enlarging zooplankton populations to control phytoplankton biomass.
基金supported by China Scholarship Council and National Natural Science Foundation ofChina (No. 40572020)
文摘Higher fullerenes(C84,C90,C92,C94 and C96) were successfully isolated from the Soxhlet extract of the synthetical "Graphote Smokes" soot(GS sample) by using a big Cosmosil Buckysep(Phenomenex) column(250 mm × 10 mm) with a large injection.The fractions isolated have been determined by high performance liquid chro-matography(HPLC) and laser desorption mass spectrometry(LDMS).It is found that there are different fullerenes molecules in different fractions with retention time.The result indicates that fullerenes do exist in GS samples.Also,it excludes the suspicion to some extent that fullerene molecules might be generated by the laser desorption process in the LDMS.In addition,it also provides the experimental basis for the study of natural higher fullerenes and might be helpful to figure out the question if higher fullerenes do exist in the natural samples.
基金supported by Open Research Fund of State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin(China Institute of Water Resources and Hydropower Research)[grant number IWHR-SKL-202217]Open Fund of National Engineering Research Center for Geographic Information System,China University of Geosciences[grant number 2021KFJJ01]National Nature Science Foundation of China[grant number 42171047].
文摘Changes in wetland ecosystems have a critical impact on the local ecology and species diversity.Different development scenarios and policies are key factors influencing their changes.Therefore,we studied changes of wetlands in the middle Yangtze River basin(MYRB)in 2001-2020,and a patch-generated land use simulation(PLUS)model and random forest(RF)method were applied to predict and analyze the changes under different scenarios in the MYRB in the future(i.e.2035-2095).The results indicated that:(1)The regions with high wetland proportions were concentrated in the central and eastern MYRB in 2001-2020,with a 1.5%decrease in overall wetland area;(2)The RF could simulate the future ecological quality with training and testing accuracies of 0.98 and 0.92,respectively;(3)Remote Sensing Ecological Index(RSEI)less than 0.5 in the central and eastern regions and 13.3%reduction in the northwest in the SSP245 scenario.In general,the study provides a basis for future regional studies of ecosystem quality and provides data to support wetland conservation and management.
基金National Natural Science Foundation of China(Nos.21174022,21376038)National Basic Research Program of China(No.2013CB733702)+1 种基金Key Project of the Education Department of Sichuan Province(No.12ZA087)Specialized Research Fund for the Doctoral Program of Higher Education(No.20110041110009)
文摘PAHPN. a naphthalimide-based mitotracker with reasonable two-photon excitation emission activity and polarity-sensitive fluorescence properties has been efficiently synthesized and studied in twophoton, co-localization, and FLIM imaging.
基金supported by the National Nature Science Foundation of China (No. 21777067)the Primary Research&Development Plan of Jiangsu Province (No. BE2019679)+1 种基金Open Fund of National Key Laboratory of Collaborative Control and Remediation of Soil and Water Pollution for Environmental Protection (No. GHBK-001)the Open Fund of the State Environmental Protection Key Laboratory of Wetland Ecology and Vegetation Restoration,Northeast Normal University (No. 130028903)。
文摘Tri(2-chloroethyl) phosphate(TCEP) with the initial concentration of 5 mg/L was degraded by UV/H2O2 oxidation process. The removal rate of TCEP in the UV/H2O2 system was 89.1% with the production of Cl-and PO4^3- of 0.23 and 0.64 mg/L. The removal rate of total organic carbon of the reaction was 48.8% and the pH reached 3.3 after the reaction. The oxidative degradation process of TCEP in the UV/H2O2 system obeyed the first order kinetic reaction with the apparent rate constant of 0.0025 min^-1( R^2 = 0.9788). The intermediate products were isolated and identified by gas chromatography-mass spectrometer. The addition reaction of HO · and H2O and the oxidation reaction with H2O2 were found during the degradation pathway of 5 mg/L TCEP in the UV/H2O2 system. For the first time, environment risk was estimated via the "ecological structure activity relationships" program and acute and chronic toxicity changes of intermediate products were pointed out. The luminescence inhibition rate of photobacterium was used to evaluate the acute toxicity of intermediate products. The results showed that the toxicity of the intermediate products increased with the increase of reaction time, which may be due to the production of chlorine compounds. Some measures should be introduced to the UV/H2O2 system to remove the highly toxic Cl-containing compounds, such as a nanofiltration or reverse osmosis unit.
