Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction...Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.展开更多
Biological slices are an effective tool for studying the physiological structure and evolutionmechanism of biological systems.However,due to the complexity of preparation technology and the presence of many uncontroll...Biological slices are an effective tool for studying the physiological structure and evolutionmechanism of biological systems.However,due to the complexity of preparation technology and the presence of many uncontrollable factors during the preparation processing,leads to problems such as difficulty in preparing slice images and breakage of slice images.Therefore,we proposed a biological slice image small-scale corruption inpainting algorithm with interpretability based on multi-layer deep sparse representation,achieving the high-fidelity reconstruction of slice images.We further discussed the relationship between deep convolutional neural networks and sparse representation,ensuring the high-fidelity characteristic of the algorithm first.A novel deep wavelet dictionary is proposed that can better obtain image prior and possess learnable feature.And multi-layer deep sparse representation is used to implement dictionary learning,acquiring better signal expression.Compared with methods such as NLABH,Shearlet,Partial Differential Equation(PDE),K-Singular Value Decomposition(K-SVD),Convolutional Sparse Coding,and Deep Image Prior,the proposed algorithm has better subjective reconstruction and objective evaluation with small-scale image data,which realized high-fidelity inpainting,under the condition of small-scale image data.And theOn2-level time complexitymakes the proposed algorithm practical.The proposed algorithm can be effectively extended to other cross-sectional image inpainting problems,such as magnetic resonance images,and computed tomography images.展开更多
The in-situ growing approach was utilized in this article to construct the magnesium–aluminum layered double hydroxide(MgAl-LDH)film on the surface of a 1060 aluminum anodized film.To improve the corrosion resistance...The in-situ growing approach was utilized in this article to construct the magnesium–aluminum layered double hydroxide(MgAl-LDH)film on the surface of a 1060 aluminum anodized film.To improve the corrosion resistance and friction qualities of aluminum alloy,the MgAl-LDH coating was treated using stearic acid(SA)and thiourea(TU).The aluminum substrate and anodized aluminum film layer corroded to varying degrees after 24 h of immersion in 3.5%(mass)NaCl solution,while the modified hydrotalcite film layer continued to exhibit the same microscopic morphology even after being immersed for 7 d.The results show that the synergistic action of thiourea and stearic acid can effectively improve the corrosion resistance of the MgAl-LDH substrate.The tribological testing reveals that the hydrotalcite film layer and the modified film layer lowered the friction coefficient of the anodized aluminum surface substantially.The results of the simulations and experiments demonstrate that SA forms the dense LDH-TU interlayer film layer by exchanging NO_(3)^(-)ions between TU layers on the one hand and the LDH-SA film layer by adsorption on the surface of LDH on the other.Together,these two processes create LDH-TUSA,which can significantly increase the substrate’s corrosion resistance.This synergistically modified superhydrophobic and retardant hydrotalcite film layer offers a novel approach to the investigation of wear reduction and corrosion protection on the surface of aluminum and its alloys.展开更多
The Reynolds-averaged Navier–Stokes(RANS)equation was solved using computational fluid dynamics to study the effect of the circulating tank wall on the hydrodynamic coefficient of an autonomous underwater vehicle(AUV...The Reynolds-averaged Navier–Stokes(RANS)equation was solved using computational fluid dynamics to study the effect of the circulating tank wall on the hydrodynamic coefficient of an autonomous underwater vehicle(AUV).Numerical results were compared with the experimental results in the circulating water tank of Harbin Engineering University.The numerical results of the model with different scale ratios under the same water in the flume were studied to investigate the effect of blockage on the hydrodynamic performance of AUV in the circulating flume model test.The results show that the hydrodynamic coefficient is stable with the scale reduction of the model.The influence of blocking effect on AUV is given by combining theoretical calculation with experiment.展开更多
Global ecosystems and public health have been greatly impacted by the accumulation of heavy metal(loid)s in water.Source-specific risk apportionment is needed to prevent and manage potential groundwater contamination ...Global ecosystems and public health have been greatly impacted by the accumulation of heavy metal(loid)s in water.Source-specific risk apportionment is needed to prevent and manage potential groundwater contamination with heavy metal(loid)s.The heavy metal(loid)s contamination status,water quality,ecological risk,and health risk apportionment of the Shule River Basin groundwater are poorly understood.Therefore,field sampling was performed to explore the water quality and risk of heavy metal(loid)s in the groundwater of the Shule River Basin in northwestern China.A total of 96 samples were collected from the study area to acquire data for water quality and heavy metal(loid)s risk.There was noticeable accumulation of ferrum in the groundwater of the Shule River Basin.The levels of pollution were considered to be moderately low,as evaluated by the degree of contamination,heavy metal evaluation index,heavy metal pollution index,and Nemerow pollution index.The ecological risks were also low.However,an assessment of the water quality index revealed that only 58.34%of the groundwater samples had good water quality.The absolute principal component scores-multiple linear regression model was more suited for this study area than the positive matrix factorization model.There were no obvious noncarcinogenic or carcinogenic concerns for all types of receptors according to the values of the total hazard index and total carcinogenic risk.The human activities and the initial geological environment factor(65.85%)was the major source of noncarcinogenic risk(residential children:87.56%;residential adults:87.52%;recreational children:86.77%;and recreational adults:85.42%),while the industrial activity factor(16.36%)was the major source of carcinogenic risk(residential receptors:87.96%;and recreational receptors:68.73%).These findings provide fundamental and crucial information for reducing the health issues caused by heavy metal(loid)s contamination of groundwater in arid areas.展开更多
Rare earth luminescence has attracted widespread attention for several decades, among which nearinfrared(NIR) light-related up-conversion luminescence and NIR-Ⅱ luminescence are widely used in the biomedical field. T...Rare earth luminescence has attracted widespread attention for several decades, among which nearinfrared(NIR) light-related up-conversion luminescence and NIR-Ⅱ luminescence are widely used in the biomedical field. The NIR-related luminescence is widely studied due to the excellent performance, such as good biocompatibility, deep tissue penetration depth, low self-fluorescence and minimal light damage to organisms. In this review, we mainly introduce the mechanism for rare earth up-conversion luminescence, NIR-Ⅱ luminescence and conclude their advantages compared with traditional luminescence.These excellent priorities provide the basis for NIR-related luminescence bioimaging in vivo. Additionally,we hilglight the scheme for the sensitive detection of substances in organisms and various methods for biological therapy. In spite of the existing research, it is outlined that NIR-related luminescence has great potential to be applied in different aspects, expanding perspectives and future challenges of research in related fields. Based on the current scientific achievements, this review can provide reference for research in the areas mentioned above, expand the research direction and arouse a broad interest in different disciplines to pay attention to rare earth luminescence.展开更多
We investigated the correlation between leaf/soil minerals and fruit quality in apple trees grown in orchards,with the ultimate goal of improving the latter.Leaf mineral nutrients;soil nutrients in the 0-20,20-40,and ...We investigated the correlation between leaf/soil minerals and fruit quality in apple trees grown in orchards,with the ultimate goal of improving the latter.Leaf mineral nutrients;soil nutrients in the 0-20,20-40,and 40-60 cm layers;and fruit quality traits in 32 apple orchards in China were monitored for 2 years.Significant factors associated with fruit quality were identified via correlation analysis.An analysis of leaf data revealed that leaf nitrogen(N) and leaf magnesium(Mg) levels were extremely high in 75 and 89%of the orchards,respectively.In the Bohai Gulf region,94%of the orchards showed significantly higher values than the standard.The soil pH values of the orchards in eastern China like eastern Shandong or Liaoning were lower than 7.0,while the pH values in the Loess Plateau of northwestern China like Shaanxi were much higher than 7.Soil alkali-hydrolyzable N levels in 47%of the orchards were lower than the optimal level of 70 mg kg^(-1).Generally,the soil alkali-hydrolyzable N levels of orchards in the Bohai Gulf region were significantly higher than those in the Loess Plateau region.The available P levels in the orchards of the Bohai Gulf region were up to three times higher than those of the Loess Plateau region.However,although the available potassium(K) in most orchards was sufficient(51.39-309.94 mg kg^(-1)),leaf K content in 73%of the orchards was low,possibly due to fruit bagging or fruit overload.Approximately 63%of the orchards in Shandong and 29%of the orchards in Shannxi showed leaf Fe deficiencies.In the Loess Plateau,most orchards showed high leaf Ca levels,a strong correlation was observed between leaf and soil phosphorus/potassium(P/K)content and fruit organic acid content.The amounts of fruit soluble sugar or fructose were positively correlated with soil calcium/potassium(Ca/K) levels and leaf calcium/boron(Ca/B) levels in most orchards.The excessive leaf N levels caused by the extensive application of N fertilizers had a negative effect on fruit quality in most apple orchards in China.P,K,Ca,and B were key minerals associated with fruit quality.展开更多
Selected trace metals(Pb, Cd, Cu, Hg) and arsenic in seawater and surface sediments of Laizhou Bay were determined, to evaluate their spatial distribution, pollution risk and potential ecological risk. Concentrations ...Selected trace metals(Pb, Cd, Cu, Hg) and arsenic in seawater and surface sediments of Laizhou Bay were determined, to evaluate their spatial distribution, pollution risk and potential ecological risk. Concentrations of the elements were 0.56–2.07, 0.14–0.38, 12.70–18.40, 0.014–0.094, and 1.13–2.37 μg/L in the seawater and 8.94–32.2, 0.18–0.67, 4.51–30.5, 0.006–0.058, and 5.75–15.3 mg/kg in sediments for Pb, Cd, Cu, Hg and As, respectively. High concentrations of the trace metals and arsenic in seawater and surface sediments were generally observed near the river estuary. The pollution risk result of the elements showed that Cu was the prominent trace metal pollutant in seawater, followed by Hg, Pb, Cd and As. The metal complex pollution index in seawater was at a medium level. The most important trace metal pollutant in sediments was Cd, followed by As, Cu, Pb, and Hg. Our pollution assessment suggests that trace metal pollution in Laizhou Bay sediments was at a low level. The potential ecological risk was also low in surface sediment.展开更多
A combined experimental and numerical investigation is carried out to study the performance of a vertical-axis eccentric-disc variable-pitch turbine(VEVT).A scheme of eccentric disc pitch control mechanism based on do...A combined experimental and numerical investigation is carried out to study the performance of a vertical-axis eccentric-disc variable-pitch turbine(VEVT).A scheme of eccentric disc pitch control mechanism based on doubleblock mechanism is proposed.The eccentric control mechanism and the deflection angle control mechanism in the pitch control structure are designed and optimized according to the functional requirements of the turbine,and the three-dimensional model of the turbine is established.Kinematics analysis of the eccentric disc pitch control mechanism is carried out.Kinematics parameters and kinematics equations which can characterize its motion characteristics are derived.Kinematics analysis and simulation are carried out,and the motion law of the corresponding mechanical system is obtained.By analyzing the force and motion of blade of VEVT,the expressions of the important parameters such as deflection angle,attack angle and energy utilization coefficient are obtained.The lateral induced velocity coefficient is acquired by momentum theorem,the hydrodynamic parameters such as energy utilization coefficient are derived,and the hydrodynamic characteristics of VEVT are also obtained.The experimental results show that the turbine has good energy capture capability at different inflow velocities of different sizes and directions,which verifies that VEVT has good self-startup performance and high energy capture efficiency.展开更多
A review is provided of various approaches that have been adopted recently to assess the fatigue of ships and offshore structures.The relevant fatigue loading is reviewed first,focusing on the successive loading and u...A review is provided of various approaches that have been adopted recently to assess the fatigue of ships and offshore structures.The relevant fatigue loading is reviewed first,focusing on the successive loading and unloading of the cargo and the transient loadings.The factors influencing fatigue strength are discussed,including the geometrical parameters,material,residual stress,and ones related to the environment.Different approaches for fatigue analyses of seam-welded joints are covered,i.e.,the structural stress or strain approach,the notch stress or strain approach,notch intensity approach,and the crack propagation approach.展开更多
The increase of water temperature, due to thermal discharges from two nuclear power stations, was one of the most significant environmental changes since 1982 in the Daya Bay, located in the north of the South China S...The increase of water temperature, due to thermal discharges from two nuclear power stations, was one of the most significant environmental changes since 1982 in the Daya Bay, located in the north of the South China Sea. This study investigates the long-term (1982-2012) environmental changes in Daya Bay in response to the increase of water temperature, via comprehensively interpreting and analyzing both satellite and in situ observations along with previous data. The results show that: 1) salinity, dissolved oxygen (DO), chemical oxygen demand (COD) and nutrients had been enhanced after the thermal discharges started in 1994;2) the concentration of Chl-a increased while the net-phytoplankton abundance decreased;3) diversity of the phytoplankton community had decreased;4) fishery production had declined;and 5) frequency of Harmful Algal Bloom occurrence had increased. Satellite images show clearly that a thermal plume from the power stations extended toward the interior of Daya Bay, and that surface temperature of the seawater increased as one approached the power stations. The analysis suggests that the thermal water discharged from the two power stations was a driver of the ecosystem’s change in Daya Bay. Several factors, including nutrients, salinity, DO, and COD, varied according to the increase of water temperature. These factors affected the water quality, Chl-a, and phytoplankton in the short term and impaired aquatic organisms and the whole ecosystem in the long term.展开更多
In this paper,the mechatronic design and maneuverability analysis of a novel robotic shark are presented.To obtain good maneuverability,a barycenter regulating device is designed to assist the posture adjustment at lo...In this paper,the mechatronic design and maneuverability analysis of a novel robotic shark are presented.To obtain good maneuverability,a barycenter regulating device is designed to assist the posture adjustment at low speeds.Based on the Newton-Euler approach,an analytical dynamic model is established with particular consideration of pectoral fins for threedimensional motions.The hydrodynamic coefficients are computed using computational fluid dynamics(CFD)methods.Oscillation amplitudes and phases are determined by fitting an optimized fish body wave.The performance of the robotic shark is estimated by varying the oscillation frequency and offset angle.The results show that with oscillation frequency increasing,the swimming speed increases linearly.The robotic shark reaches the maximum swimming speed of 1.05 m/s with an oscillation frequency of 1.2 Hz.Furthermore,the turning radius decreases nonlinearly as the offset angle increased.The robotic shark reaches the minimum turning radius of 1.4 times the body length with 0.2 Hz frequency and 12°offset angle.In the vertical plane,as the pectoral fin angle increases,the diving velocity increases nonlinearly with increase rate slowing down.展开更多
Non-isomorphic two dimensional indecomposable modules over infinite dimensional hereditary path algebras are described. We infer that none of them can be determined by their dimension vectors.
Perinereis aibuhitensis(Grube, 1878) lives in marine sediments of estuary or shoal areas, where substrate has some crucial environmental factors affecting its burrowing and distribution. In order to provide basic data...Perinereis aibuhitensis(Grube, 1878) lives in marine sediments of estuary or shoal areas, where substrate has some crucial environmental factors affecting its burrowing and distribution. In order to provide basic data for the habitat selection and suitability evaluations of the artificial aquaculture of P. aibuhitensis, this paper conducted a quantified analysis of its burrowing ability and explored its behavioral preferences in different substrates,including mud(<75 μm), fine sand(125–250 μm), medium sand(250–500 μm), coarse sand(500–2 000 μm), gravel(2 000–4 000 μm) and ceramsite(4 000–8 000 μm). The research results revealed that substrate grain size significantly affected the burrowing time, burrowing rate, burrowing depth and distribution rate(P<0.01).Moreover, P. aibuhitensis demonstrated preferential selections relating to substrate grain sizes, had higher burrowing ability in ceramsite, mud and fine sand compared with other substrates. The strongest burrowing ability and the highest distribution rate were observed in ceramsite. The study indicated that P. aibuhitensis was sensitive to substrate grain size, which also had an impact on its burrowing process and population distribution.In the natural sea, substrates mainly composed of mud and fine sand are fit for aquaculture and stock enhancement. Based on behavioral preferences and ecological rehabilitation function of P. aibuhitensis, this paper proposes a symbiotic system of marine animals and halophytes, and constructs an ecosystem model of"Marine fish-Halophytes-Perinereis aibuhitensis" with P. aibuhitensis as the link.展开更多
Seven ground cucumber varieties were cultivated in open field for the comparative experiment. The results showed that Texuan cucumber and Yantai ground cucumber had good commodity characters,good taste and high yield,...Seven ground cucumber varieties were cultivated in open field for the comparative experiment. The results showed that Texuan cucumber and Yantai ground cucumber had good commodity characters,good taste and high yield,and their output value exceeded 16 000 yuan/666. 7 m2,so they are more suitable for open cultivation in Yantai region. The next ones are Meiyu Diguawang and Aweishi ground cucumber.展开更多
This procedure specifies production area environment, production technology, prevention and control of plant diseases and insect pests, and production files of pollution-free foods by taking tomato as an example. This...This procedure specifies production area environment, production technology, prevention and control of plant diseases and insect pests, and production files of pollution-free foods by taking tomato as an example. This procedure is applicable to greenhouse production of pollution-free food in Shandong Province.展开更多
In order to get the formation about the content of alkali-hydrolyzable nitrogen in soil, available phosphorus and available potassium, and the input of chemical fertilizer in apple orchard, we survey 25 peasant househ...In order to get the formation about the content of alkali-hydrolyzable nitrogen in soil, available phosphorus and available potassium, and the input of chemical fertilizer in apple orchard, we survey 25 peasant households' input of chemical fertilizer in apple orchard, and collect soil samples for measuring and analysis. The results show that the average input of nitrogen, phosphorus and potassium nutrient is 839.6 kg/hm2, 520.4 kg/hm2, and 899.7 kg/hm2, respectively; the input proportion of nitrogen to phosphorus to potassium nutrient is 1∶0.62∶1.07; in 0-60cm soil, the average content of alkali-hydrolyzable nitrogen is 53.49 mg/kg, the average content of available phosphorus in soil is 70.73 kg/mg, and the average content of available potassium in soil is 180.1 mg/kg (the proportion of alkali-hydrolyzable nitrogen to available phosphorus to available potassium in soil is 1:1.32:3.37). It indicates that the overall level of input of chemical fertilizer in apple orchard is relatively high; the content of alkali-hydrolyzable nitrogen in soil is very low on the whole, the content of available phosphorus in soil is very high, and the content of available potassium in soil is high.展开更多
The electric inversion technique reconstructs the subsurface medium distribution from acquired data.On the basis of electric inversion,objects buried under the earth or seabed,such as pipelines and unexploded ordnance...The electric inversion technique reconstructs the subsurface medium distribution from acquired data.On the basis of electric inversion,objects buried under the earth or seabed,such as pipelines and unexploded ordnance,are detected and located in a contactless manner.However,the process of accurately reconstructing the shape of the target object is challenging because electric inversion is a nonlinear and ill-posed problem.In this work,we present an inverse multiquadric(IMQ)regularization method based on the level set function for reconstructing buried pipelines.In the case of locating underwater objects,the unknown inversion area is split into two parts,the background and the pipeline with known conductivity.The geometry of the pipeline is represented based on the level set function for achieving a noiseless inversion image.To obtain a binary image,the IMQ is used as the regularization term,which‘pushes’the level set function away from 0.We also provide an appropriate method to select the bandwidth and regularization parameters for the IMQ regularization term,resulting in reconstructed images with sharp edges.The simulation results and analysis show that the proposed method performs better than classical inversion methods.展开更多
It is very important to adopt standardized production technology in the process of maize cultivation,which is conducive to giving full play to the high-yield,high-quality and multi-resistant characteristics of Jinhai ...It is very important to adopt standardized production technology in the process of maize cultivation,which is conducive to giving full play to the high-yield,high-quality and multi-resistant characteristics of Jinhai 5.This paper standardized the cultivation technology of Jinhai 5 from the aspects of maize seed quality,fertilization before sowing,sowing,seedling management,mid-period management,later management,disease and pest control,and harvesting,so as to provide reference for the standardized production of maize Jinhai 5.展开更多
基金S.G.acknowledges the financial support from the National Natural Science Foundation of China(NSFC 52272144,51972076)the Heilongjiang Provincial Natural Science Foundation of China(JQ2022E001)+4 种基金the Natural Science Foundation of Shandong Province(ZR2020ZD42)the Fundamental Research Funds for the Central Universities.H.D.acknowledges the financial support from the National Natural Science Foundation of China(NSFC 22205048)China Postdoctoral Science Foundation(2022M710931 and 2023T160154)Heilongjiang Postdoctoral Science Foundation(LBH-Z22010)G.Y.acknowledges the financial support from the National Science Foundation of Heilongjiang Education Department(324022075).
文摘Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.
基金supported by the National Natural Science Foundation of China(Grant No.61871380)the Shandong Provincial Natural Science Foundation(Grant No.ZR2020MF019)Beijing Natural Science Foundation(Grant No.4172034).
文摘Biological slices are an effective tool for studying the physiological structure and evolutionmechanism of biological systems.However,due to the complexity of preparation technology and the presence of many uncontrollable factors during the preparation processing,leads to problems such as difficulty in preparing slice images and breakage of slice images.Therefore,we proposed a biological slice image small-scale corruption inpainting algorithm with interpretability based on multi-layer deep sparse representation,achieving the high-fidelity reconstruction of slice images.We further discussed the relationship between deep convolutional neural networks and sparse representation,ensuring the high-fidelity characteristic of the algorithm first.A novel deep wavelet dictionary is proposed that can better obtain image prior and possess learnable feature.And multi-layer deep sparse representation is used to implement dictionary learning,acquiring better signal expression.Compared with methods such as NLABH,Shearlet,Partial Differential Equation(PDE),K-Singular Value Decomposition(K-SVD),Convolutional Sparse Coding,and Deep Image Prior,the proposed algorithm has better subjective reconstruction and objective evaluation with small-scale image data,which realized high-fidelity inpainting,under the condition of small-scale image data.And theOn2-level time complexitymakes the proposed algorithm practical.The proposed algorithm can be effectively extended to other cross-sectional image inpainting problems,such as magnetic resonance images,and computed tomography images.
基金financially supported by the National Natural Science Foundation of China(51971071 and 52075112)Fundamental Research Projects of Science&Technology Innovation and development Plan in Yantai City(2022JCYJ023)。
文摘The in-situ growing approach was utilized in this article to construct the magnesium–aluminum layered double hydroxide(MgAl-LDH)film on the surface of a 1060 aluminum anodized film.To improve the corrosion resistance and friction qualities of aluminum alloy,the MgAl-LDH coating was treated using stearic acid(SA)and thiourea(TU).The aluminum substrate and anodized aluminum film layer corroded to varying degrees after 24 h of immersion in 3.5%(mass)NaCl solution,while the modified hydrotalcite film layer continued to exhibit the same microscopic morphology even after being immersed for 7 d.The results show that the synergistic action of thiourea and stearic acid can effectively improve the corrosion resistance of the MgAl-LDH substrate.The tribological testing reveals that the hydrotalcite film layer and the modified film layer lowered the friction coefficient of the anodized aluminum surface substantially.The results of the simulations and experiments demonstrate that SA forms the dense LDH-TU interlayer film layer by exchanging NO_(3)^(-)ions between TU layers on the one hand and the LDH-SA film layer by adsorption on the surface of LDH on the other.Together,these two processes create LDH-TUSA,which can significantly increase the substrate’s corrosion resistance.This synergistically modified superhydrophobic and retardant hydrotalcite film layer offers a novel approach to the investigation of wear reduction and corrosion protection on the surface of aluminum and its alloys.
基金Supported by the National Natural Science Foundation of China(Grant No.51909040)the Fund of Science and Technology on Underwater Vehicle Technology(Grant No.JCKYS2022SXJQR-11)+1 种基金the Heilongjiang Provincial Natural Science Foundation of China(Grant No.LH2020E073)the Key Technology Research and Development Program of Shandong(Grant No.2020CXGC010702).
文摘The Reynolds-averaged Navier–Stokes(RANS)equation was solved using computational fluid dynamics to study the effect of the circulating tank wall on the hydrodynamic coefficient of an autonomous underwater vehicle(AUV).Numerical results were compared with the experimental results in the circulating water tank of Harbin Engineering University.The numerical results of the model with different scale ratios under the same water in the flume were studied to investigate the effect of blockage on the hydrodynamic performance of AUV in the circulating flume model test.The results show that the hydrodynamic coefficient is stable with the scale reduction of the model.The influence of blocking effect on AUV is given by combining theoretical calculation with experiment.
基金This work was supported by the Kunlun Talent Action Plan of Qinghai Province(E140 WX42)National Natural Science Foundation of China(52179026)Strategy for Water Resource Security in Yellow River Sources。
文摘Global ecosystems and public health have been greatly impacted by the accumulation of heavy metal(loid)s in water.Source-specific risk apportionment is needed to prevent and manage potential groundwater contamination with heavy metal(loid)s.The heavy metal(loid)s contamination status,water quality,ecological risk,and health risk apportionment of the Shule River Basin groundwater are poorly understood.Therefore,field sampling was performed to explore the water quality and risk of heavy metal(loid)s in the groundwater of the Shule River Basin in northwestern China.A total of 96 samples were collected from the study area to acquire data for water quality and heavy metal(loid)s risk.There was noticeable accumulation of ferrum in the groundwater of the Shule River Basin.The levels of pollution were considered to be moderately low,as evaluated by the degree of contamination,heavy metal evaluation index,heavy metal pollution index,and Nemerow pollution index.The ecological risks were also low.However,an assessment of the water quality index revealed that only 58.34%of the groundwater samples had good water quality.The absolute principal component scores-multiple linear regression model was more suited for this study area than the positive matrix factorization model.There were no obvious noncarcinogenic or carcinogenic concerns for all types of receptors according to the values of the total hazard index and total carcinogenic risk.The human activities and the initial geological environment factor(65.85%)was the major source of noncarcinogenic risk(residential children:87.56%;residential adults:87.52%;recreational children:86.77%;and recreational adults:85.42%),while the industrial activity factor(16.36%)was the major source of carcinogenic risk(residential receptors:87.96%;and recreational receptors:68.73%).These findings provide fundamental and crucial information for reducing the health issues caused by heavy metal(loid)s contamination of groundwater in arid areas.
基金Financial support from the National Natural Science Foundation of China(NSFC,Nos.51972076,52272144,22205048)the Heilongjiang Provincial Natural Science Foundation of China(No.JQ2022E001)+3 种基金the Natural Science Foundation of Shandong Province(No.ZR2020ZD42)Project funded by China Postdoctoral Science Foundation(No.2022M710931)the Fundamental Research Funds for the Central Universitiesthe Special Scientific Research Starting Foundation for Young teachers of Zhengzhou University(No.32213226).
文摘Rare earth luminescence has attracted widespread attention for several decades, among which nearinfrared(NIR) light-related up-conversion luminescence and NIR-Ⅱ luminescence are widely used in the biomedical field. The NIR-related luminescence is widely studied due to the excellent performance, such as good biocompatibility, deep tissue penetration depth, low self-fluorescence and minimal light damage to organisms. In this review, we mainly introduce the mechanism for rare earth up-conversion luminescence, NIR-Ⅱ luminescence and conclude their advantages compared with traditional luminescence.These excellent priorities provide the basis for NIR-related luminescence bioimaging in vivo. Additionally,we hilglight the scheme for the sensitive detection of substances in organisms and various methods for biological therapy. In spite of the existing research, it is outlined that NIR-related luminescence has great potential to be applied in different aspects, expanding perspectives and future challenges of research in related fields. Based on the current scientific achievements, this review can provide reference for research in the areas mentioned above, expand the research direction and arouse a broad interest in different disciplines to pay attention to rare earth luminescence.
基金supported in part by the National Natural Science Foundation of China(52105589 and U1909221)in part by the China Postdoctoral Science Foundation(2021M692590)+2 种基金in part by the Beijing Advanced Innovation Center for Intelligent Robots and Systems(2019IRS08)in part by the Fundamental Research Funds for the Central Universities(China)(xzy012021009)in part by the State Key Laboratory of Robotics and Systems(HIT)(SKLRS2021KF17)。
基金financially supported by the 973 Progam of China(2011CB100602)the Special Fund forAgroscientific Research in the Public Interest,China(200903044)Key Laboratory of Biology and Genetic Improvement of Horticultural Crops(Nutrition and Physiology),Ministry of Agricultural,China
文摘We investigated the correlation between leaf/soil minerals and fruit quality in apple trees grown in orchards,with the ultimate goal of improving the latter.Leaf mineral nutrients;soil nutrients in the 0-20,20-40,and 40-60 cm layers;and fruit quality traits in 32 apple orchards in China were monitored for 2 years.Significant factors associated with fruit quality were identified via correlation analysis.An analysis of leaf data revealed that leaf nitrogen(N) and leaf magnesium(Mg) levels were extremely high in 75 and 89%of the orchards,respectively.In the Bohai Gulf region,94%of the orchards showed significantly higher values than the standard.The soil pH values of the orchards in eastern China like eastern Shandong or Liaoning were lower than 7.0,while the pH values in the Loess Plateau of northwestern China like Shaanxi were much higher than 7.Soil alkali-hydrolyzable N levels in 47%of the orchards were lower than the optimal level of 70 mg kg^(-1).Generally,the soil alkali-hydrolyzable N levels of orchards in the Bohai Gulf region were significantly higher than those in the Loess Plateau region.The available P levels in the orchards of the Bohai Gulf region were up to three times higher than those of the Loess Plateau region.However,although the available potassium(K) in most orchards was sufficient(51.39-309.94 mg kg^(-1)),leaf K content in 73%of the orchards was low,possibly due to fruit bagging or fruit overload.Approximately 63%of the orchards in Shandong and 29%of the orchards in Shannxi showed leaf Fe deficiencies.In the Loess Plateau,most orchards showed high leaf Ca levels,a strong correlation was observed between leaf and soil phosphorus/potassium(P/K)content and fruit organic acid content.The amounts of fruit soluble sugar or fructose were positively correlated with soil calcium/potassium(Ca/K) levels and leaf calcium/boron(Ca/B) levels in most orchards.The excessive leaf N levels caused by the extensive application of N fertilizers had a negative effect on fruit quality in most apple orchards in China.P,K,Ca,and B were key minerals associated with fruit quality.
基金Supported by the Shandong Key Laboratory of Marine Ecological Restoration,Shandong Marine Fisheries Research Institute(No.201211)the National Natural Science Foundation of China(No.41206120)
文摘Selected trace metals(Pb, Cd, Cu, Hg) and arsenic in seawater and surface sediments of Laizhou Bay were determined, to evaluate their spatial distribution, pollution risk and potential ecological risk. Concentrations of the elements were 0.56–2.07, 0.14–0.38, 12.70–18.40, 0.014–0.094, and 1.13–2.37 μg/L in the seawater and 8.94–32.2, 0.18–0.67, 4.51–30.5, 0.006–0.058, and 5.75–15.3 mg/kg in sediments for Pb, Cd, Cu, Hg and As, respectively. High concentrations of the trace metals and arsenic in seawater and surface sediments were generally observed near the river estuary. The pollution risk result of the elements showed that Cu was the prominent trace metal pollutant in seawater, followed by Hg, Pb, Cd and As. The metal complex pollution index in seawater was at a medium level. The most important trace metal pollutant in sediments was Cd, followed by As, Cu, Pb, and Hg. Our pollution assessment suggests that trace metal pollution in Laizhou Bay sediments was at a low level. The potential ecological risk was also low in surface sediment.
基金the National Natural Science Foundation of China(Grant Nos.U1706227 and 51979063)the Harbin Applied Technology Research and Development Project(Grant No.2015RQXXJ016)the Basic Research and Cutting-Edge Technology Projects of State Administration of Science(Grant No.JCKY2019604C003).
文摘A combined experimental and numerical investigation is carried out to study the performance of a vertical-axis eccentric-disc variable-pitch turbine(VEVT).A scheme of eccentric disc pitch control mechanism based on doubleblock mechanism is proposed.The eccentric control mechanism and the deflection angle control mechanism in the pitch control structure are designed and optimized according to the functional requirements of the turbine,and the three-dimensional model of the turbine is established.Kinematics analysis of the eccentric disc pitch control mechanism is carried out.Kinematics parameters and kinematics equations which can characterize its motion characteristics are derived.Kinematics analysis and simulation are carried out,and the motion law of the corresponding mechanical system is obtained.By analyzing the force and motion of blade of VEVT,the expressions of the important parameters such as deflection angle,attack angle and energy utilization coefficient are obtained.The lateral induced velocity coefficient is acquired by momentum theorem,the hydrodynamic parameters such as energy utilization coefficient are derived,and the hydrodynamic characteristics of VEVT are also obtained.The experimental results show that the turbine has good energy capture capability at different inflow velocities of different sizes and directions,which verifies that VEVT has good self-startup performance and high energy capture efficiency.
文摘A review is provided of various approaches that have been adopted recently to assess the fatigue of ships and offshore structures.The relevant fatigue loading is reviewed first,focusing on the successive loading and unloading of the cargo and the transient loadings.The factors influencing fatigue strength are discussed,including the geometrical parameters,material,residual stress,and ones related to the environment.Different approaches for fatigue analyses of seam-welded joints are covered,i.e.,the structural stress or strain approach,the notch stress or strain approach,notch intensity approach,and the crack propagation approach.
文摘The increase of water temperature, due to thermal discharges from two nuclear power stations, was one of the most significant environmental changes since 1982 in the Daya Bay, located in the north of the South China Sea. This study investigates the long-term (1982-2012) environmental changes in Daya Bay in response to the increase of water temperature, via comprehensively interpreting and analyzing both satellite and in situ observations along with previous data. The results show that: 1) salinity, dissolved oxygen (DO), chemical oxygen demand (COD) and nutrients had been enhanced after the thermal discharges started in 1994;2) the concentration of Chl-a increased while the net-phytoplankton abundance decreased;3) diversity of the phytoplankton community had decreased;4) fishery production had declined;and 5) frequency of Harmful Algal Bloom occurrence had increased. Satellite images show clearly that a thermal plume from the power stations extended toward the interior of Daya Bay, and that surface temperature of the seawater increased as one approached the power stations. The analysis suggests that the thermal water discharged from the two power stations was a driver of the ecosystem’s change in Daya Bay. Several factors, including nutrients, salinity, DO, and COD, varied according to the increase of water temperature. These factors affected the water quality, Chl-a, and phytoplankton in the short term and impaired aquatic organisms and the whole ecosystem in the long term.
基金financially supported by the National Natural Science Foundation of China(Grant No.51909040)the Natural Science Foundation of Heilongjiang Province(Grant No.LH2020E073)the Key Technology Research and Development Program of Shandong(Grant No.2020CXGC010702).
文摘In this paper,the mechatronic design and maneuverability analysis of a novel robotic shark are presented.To obtain good maneuverability,a barycenter regulating device is designed to assist the posture adjustment at low speeds.Based on the Newton-Euler approach,an analytical dynamic model is established with particular consideration of pectoral fins for threedimensional motions.The hydrodynamic coefficients are computed using computational fluid dynamics(CFD)methods.Oscillation amplitudes and phases are determined by fitting an optimized fish body wave.The performance of the robotic shark is estimated by varying the oscillation frequency and offset angle.The results show that with oscillation frequency increasing,the swimming speed increases linearly.The robotic shark reaches the maximum swimming speed of 1.05 m/s with an oscillation frequency of 1.2 Hz.Furthermore,the turning radius decreases nonlinearly as the offset angle increased.The robotic shark reaches the minimum turning radius of 1.4 times the body length with 0.2 Hz frequency and 12°offset angle.In the vertical plane,as the pectoral fin angle increases,the diving velocity increases nonlinearly with increase rate slowing down.
基金The NSF(11371307)of ChinaResearch Culture Funds(2014xmpy11)of Anhui Normal University
文摘Non-isomorphic two dimensional indecomposable modules over infinite dimensional hereditary path algebras are described. We infer that none of them can be determined by their dimension vectors.
基金The Weifang Sci-tech Development Project under contract No.2015ZJ1042the Research on New Model of Marine Ecological Farming and Intelligent Monitoring System under contract No.H2016-02
文摘Perinereis aibuhitensis(Grube, 1878) lives in marine sediments of estuary or shoal areas, where substrate has some crucial environmental factors affecting its burrowing and distribution. In order to provide basic data for the habitat selection and suitability evaluations of the artificial aquaculture of P. aibuhitensis, this paper conducted a quantified analysis of its burrowing ability and explored its behavioral preferences in different substrates,including mud(<75 μm), fine sand(125–250 μm), medium sand(250–500 μm), coarse sand(500–2 000 μm), gravel(2 000–4 000 μm) and ceramsite(4 000–8 000 μm). The research results revealed that substrate grain size significantly affected the burrowing time, burrowing rate, burrowing depth and distribution rate(P<0.01).Moreover, P. aibuhitensis demonstrated preferential selections relating to substrate grain sizes, had higher burrowing ability in ceramsite, mud and fine sand compared with other substrates. The strongest burrowing ability and the highest distribution rate were observed in ceramsite. The study indicated that P. aibuhitensis was sensitive to substrate grain size, which also had an impact on its burrowing process and population distribution.In the natural sea, substrates mainly composed of mud and fine sand are fit for aquaculture and stock enhancement. Based on behavioral preferences and ecological rehabilitation function of P. aibuhitensis, this paper proposes a symbiotic system of marine animals and halophytes, and constructs an ecosystem model of"Marine fish-Halophytes-Perinereis aibuhitensis" with P. aibuhitensis as the link.
文摘Seven ground cucumber varieties were cultivated in open field for the comparative experiment. The results showed that Texuan cucumber and Yantai ground cucumber had good commodity characters,good taste and high yield,and their output value exceeded 16 000 yuan/666. 7 m2,so they are more suitable for open cultivation in Yantai region. The next ones are Meiyu Diguawang and Aweishi ground cucumber.
基金Supported by the Project of Agricultural Standardization Committee of Shandong Province
文摘This procedure specifies production area environment, production technology, prevention and control of plant diseases and insect pests, and production files of pollution-free foods by taking tomato as an example. This procedure is applicable to greenhouse production of pollution-free food in Shandong Province.
基金Supported by Science and Technology Development Plan of Yantai (2010322)
文摘In order to get the formation about the content of alkali-hydrolyzable nitrogen in soil, available phosphorus and available potassium, and the input of chemical fertilizer in apple orchard, we survey 25 peasant households' input of chemical fertilizer in apple orchard, and collect soil samples for measuring and analysis. The results show that the average input of nitrogen, phosphorus and potassium nutrient is 839.6 kg/hm2, 520.4 kg/hm2, and 899.7 kg/hm2, respectively; the input proportion of nitrogen to phosphorus to potassium nutrient is 1∶0.62∶1.07; in 0-60cm soil, the average content of alkali-hydrolyzable nitrogen is 53.49 mg/kg, the average content of available phosphorus in soil is 70.73 kg/mg, and the average content of available potassium in soil is 180.1 mg/kg (the proportion of alkali-hydrolyzable nitrogen to available phosphorus to available potassium in soil is 1:1.32:3.37). It indicates that the overall level of input of chemical fertilizer in apple orchard is relatively high; the content of alkali-hydrolyzable nitrogen in soil is very low on the whole, the content of available phosphorus in soil is very high, and the content of available potassium in soil is high.
基金supported by the National Natural Sci-ence Foundation of China(No.52101383)the Fundamen-tal Research Funds for the Central Universities(No.3072021CF0802)+3 种基金the Key Laboratory of Advanced Marine Communication and Information Technology,Ministry of Industry and Information Technology(No.AMCIT2101-02)the Sino-Russian Cooperation Fund of Harbin Engi-neering University(No.2021HEUCRF006)the Ministry of Science and Higher Education of the Russian Federation(No.075-15-2020-934)the International Science&Technology Cooperation Program of China(No.2014DF R10240).
文摘The electric inversion technique reconstructs the subsurface medium distribution from acquired data.On the basis of electric inversion,objects buried under the earth or seabed,such as pipelines and unexploded ordnance,are detected and located in a contactless manner.However,the process of accurately reconstructing the shape of the target object is challenging because electric inversion is a nonlinear and ill-posed problem.In this work,we present an inverse multiquadric(IMQ)regularization method based on the level set function for reconstructing buried pipelines.In the case of locating underwater objects,the unknown inversion area is split into two parts,the background and the pipeline with known conductivity.The geometry of the pipeline is represented based on the level set function for achieving a noiseless inversion image.To obtain a binary image,the IMQ is used as the regularization term,which‘pushes’the level set function away from 0.We also provide an appropriate method to select the bandwidth and regularization parameters for the IMQ regularization term,resulting in reconstructed images with sharp edges.The simulation results and analysis show that the proposed method performs better than classical inversion methods.
基金Agricultural Major Applied Technology Innovation Project of Shandong Province。
文摘It is very important to adopt standardized production technology in the process of maize cultivation,which is conducive to giving full play to the high-yield,high-quality and multi-resistant characteristics of Jinhai 5.This paper standardized the cultivation technology of Jinhai 5 from the aspects of maize seed quality,fertilization before sowing,sowing,seedling management,mid-period management,later management,disease and pest control,and harvesting,so as to provide reference for the standardized production of maize Jinhai 5.
